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31. 发明申请

US20050288526A1 Process for production of 2-(hydroxymethyl)cyclo-propanecarboxylic acids 审中-公开
标题翻译： 2-（羟甲基）环丙烷羧酸的制备方法
公开(公告)号：US20050288526A1
公开(公告)日：2005-12-29
申请号：US10527267
申请日：2003-09-05
申请人： Ryo Minamida , Makoto Itagaki
发明人： Ryo Minamida , Makoto Itagaki
IPC分类号： C07C51/353 , C07C51/367 , C07C67/31 , C07C69/74
CPC分类号： C07C51/353 , C07C51/367 , C07C67/31 , C07C2601/02 , C07C62/08 , C07C62/02 , C07C69/757
摘要： There is provided a production method of a compound of formula (2): wherein R1, R2 and R3 are as defined below, which comprises reacting a 2-(hydroxymethyl)cyclopropanecarboxylic compound of formula (1): wherein and R1 represent a hydrogen, a linear, branched or cyclic alkyl group, a substituted or unsubstituted aryl group, R2 and R3 are the same or different and represent a hydrogen atom or a methyl group, and R4 represents C1-2 alkyl group substituted with at lest one group selected from the group consisting of a substituted aryl group and an unsubstituted aryl group, with a hydrogen-donor in the presence of a catalyst selected from the group consisting of ruthenium catalyst, cobalt catalyst, rhodium catalyst, nickel catalyst, palladium catalyst and a platinum catalyst.
摘要翻译：提供式（2）化合物的制备方法：其中R 1，R 2和R 3如下所定义，其包括使式（1）的2-（羟甲基）环丙烷羧酸化合物：其中和R 1表示氢，直链，支链或环状烷基，取代或未取代的芳基， SUP> 2和R 3相同或不同，表示氢原子或甲基，R 4表示被在选自钌催化剂，钴催化剂，铑催化剂，镍催化剂，钯催化剂的催化剂存在下，使氢选自具有取代基的芳基和未取代的芳基的组中的至少一个基团催化剂和铂催化剂。

32. 发明申请

US20050043477A1 Method of producing copolymer latex using for aqueous paint 有权
标题翻译：制备用于水性涂料的共聚物胶乳的方法
公开(公告)号：US20050043477A1
公开(公告)日：2005-02-24
申请号：US10909375
申请日：2004-08-03
申请人： Toshiyasu Nishioka , Akira Kamimura , Makoto Itagaki
发明人： Toshiyasu Nishioka , Akira Kamimura , Makoto Itagaki
IPC分类号： C08F2/22 , C08F236/04 , C08L45/00 , C09D5/02 , C09D109/08 , C09D109/10 , C09D151/00
CPC分类号： C08F2/22
摘要： A copolymer latex for chipping-resistant aqueous paint capable of remarkably improving balance of chipping-resistance, strength of adherence with metal, water-resistance and high resistance for cycles of cool and heat is provided. This is achieved by a method for producing a copolymer latex using for chipping-resistant aqueous paint, the method comprising emulsion-polymerizing 20 to 80 parts by weight of a conjugated diene as a monomer, 0.5 to 15 parts by weight of an ethylenically unsaturated carboxylic acid as a monomer, 5 to 40 parts by weight of an aromatic vinyl compound as amonomer, 5 to 40 parts by weight of an unsaturated alkyl carboxylate as a monomer and optionally not more than 69.5 parts by weight of other compound having vinyl group copolymerizable therewith as a monomer based on 100 parts by weight in the total of the monomers, wherein 100 wt % of the amount of conjugated diene, 100 wt % of the amount of ethylenically unsaturated carboxylic acid, 95 to 50 wt % of the amount of aromatic vinyl compound and 95 to 50 wt % of the amount of the unsaturated alkyl carboxylate are added in the former stage of the emulsion-polymerization, and 5 to 50 wt % of the amount of the aromatic vinyl compound and 5 to 50 wt % of the amount of the unsaturated alkyl carboxylate are added at the later stage of emulsion-polymerization.
摘要翻译：提供了一种能够显着提高耐崩裂性，与金属粘附强度，耐水性和耐热循环性高的耐破碎性水性涂料的共聚物胶乳。这是通过一种制备用于耐崩裂性水性涂料的共聚物胶乳的方法实现的，该方法包括将20至80重量份作为单体的共轭二烯进行乳液聚合，0.5至15重量份的烯键式不饱和羧酸酸作为单体，5〜40重量份作为单体的芳香族乙烯基化合物，5〜40重量份作为单体的不饱和烷基羧酸酯和任选不大于69.5重量份的可与其共聚的具有乙烯基的其它化合物作为单体的总量为100重量份的单体，其中共轭二烯的量为100重量％，烯属不饱和羧酸的量为100重量％，芳香族乙烯基的量为95〜50重量％在乳液聚合的前一阶段加入不饱和羧酸烷基酯的95〜50重量％，芳香族乙烯基化合物的5〜50重量％，5〜50重量％在乳液聚合的后期加入50重量％的不饱和羧酸烷基酯的量。

33. 发明授权

US06469198B2 Chiral copper complex catalyst composition and asymmetric production process using the same 失效
标题翻译：手性铜络合物催化剂组成和不对称生产工艺使用相同
公开(公告)号：US06469198B2
公开(公告)日：2002-10-22
申请号：US09766579
申请日：2001-01-23
申请人： Gohfu Suzukamo , Makoto Itagaki , Michio Yamamoto
发明人： Gohfu Suzukamo , Makoto Itagaki , Michio Yamamoto
IPC分类号： C07C6974
CPC分类号： C07C251/24 , C07B2200/07 , C07C67/347 , C07C2601/02 , C07C69/74 , C07C69/747
摘要： There is disclosed chiral copper complex catalyst composition, which is obtained by contacting an optically active N-salicylideneaminoalcohol compound of formula (1): with a mono-valent or di-valent copper compound in an inert solvent, wherein R1 and R2 represent an alkyl group and the like, X1 and X2 represent a hydrogen atom, a halogen atom, a nitro group, an alkyl group, an alkoxy group, a cyano group or the like, and the amount of the mono-valent or di-valent copper compound is less than 1 mole per 1 mole of the optically active N-salicylideneaminoalcohol compound of formula (1), and a process for producing an optically active cylopropane-carboxylic acid ester using the same.
摘要翻译：公开了通过使式（1）的光学活性N-亚水杨基氨基醇化合物与一价或二价铜化合物在惰性溶剂中接触而获得的手性铜络合物催化剂组合物，其中R 1和R 2表示烷基基团等，X 1和X 2表示氢原子，卤素原子，硝基，烷基，烷氧基，氰基等，一价或二价铜化合物的量为相对于1摩尔式（1）的光学活性N-亚水杨基氨基醇化合物小于1摩尔，以及使用其制备光学活性的环丙烷 - 羧酸酯的方法。

34. 发明授权

US5384341A Actinic-radiation-curing hot-melt pressure-sensitive composition 失效
标题翻译：光化辐射固化热熔压敏组合物
公开(公告)号：US5384341A
公开(公告)日：1995-01-24
申请号：US172805
申请日：1993-12-27
申请人： Makoto Itagaki , Eiichi Kawasaki , Kazuya Shinkoda , Kousuke Suewaka
发明人： Makoto Itagaki , Eiichi Kawasaki , Kazuya Shinkoda , Kousuke Suewaka
IPC分类号： C08F2/48 , C08F299/00 , C09J155/00 , C09J133/10 , C09J31/04
CPC分类号： C08F299/00 , C09J155/005
摘要： There is disclosed an actinic-radiation-curing, hot-melt pressure-sensitive adhesive composition, which comprises a mixture in a limited mixing ratio of an acrylic high-molecular-weight polymer that is made up of main chain having a molecular weight of 8,000 to 100,000 and a glass transition temperature of -75.degree. to -20.degree. C., and branched chain, in which the main chains and/or branched chains have or at least one ethylenically unsaturated group; and a low-molecular-weight polymer having a molecular weight of 500 to 8,000 and a glass transition temperature of lower than 100.degree. C., which polymer has or does not have an ethylenically unsaturated group in the molecule.
摘要翻译：公开了一种光化辐射固化的热熔压敏粘合剂组合物，其包含由具有8,000分子量的主链组成的丙烯酸类高分子量聚合物的有限混合比例的混合物至100,000，玻璃化转变温度为-75℃至-20℃，支链和/或支链具有至少一个烯键式不饱和基团; 和分子量为500〜8000，玻璃化转变温度低于100℃的低分子量聚合物，该分子内具有或不具有烯键式不饱和基团。

35. 发明申请

US20100305353A1 METHOD FOR PRODUCING PURIFIED FORMYLCYCLOPROPANE COMPOUND AND INTERMEDIATE OF SUCH FORMYLCYCLOPROPANE COMPOUND 失效
标题翻译：生产纯化的甲基环戊二烯化合物的方法和这种甲基环戊二烯化合物的中间体
公开(公告)号：US20100305353A1
公开(公告)日：2010-12-02
申请号：US12095608
申请日：2006-12-12
申请人： Kouji Yoshikawa , Ryo Minamida , Makoto Itagaki
发明人： Kouji Yoshikawa , Ryo Minamida , Makoto Itagaki
IPC分类号： C07C67/48 , C07C309/19 , C07C303/32 , C07C67/30
CPC分类号： C07C303/32 , C07C67/60 , C07C309/19 , C07C2601/02 , C07C69/757
摘要： A method for producing a purified formylcyclopropane compound represented by the formula (1) comprising (A) a step of reacting a crude formylcyclopropane compound represented by the formula (1): wherein R1 represents an alkyl group or the like, with an alkali metal hydrogen sulfite to obtain an alkali metal hydroxymethanesulfonate represented by the formula (2): wherein R1 represents the same meaning as defined above and M represents an alkali metal, and (B) a step of reacting an acid, a base or a water-soluble aldehyde with the alkali metal hydroxymethanesulfonate represented by the formula (2) obtained in the above-mentioned step (A) to obtain a purified formylcyclopropane compound represented by the formula (1).
摘要翻译：一种制备由式（1）表示的精制甲酰基环丙烷化合物的方法，包括（A）使式（1）表示的粗甲酰基环丙烷化合物：其中R 1表示烷基等与碱金属氢反应的步骤亚硫酸盐，得到由式（2）表示的碱金属羟基甲磺酸盐：其中R1表示与上述相同的含义，M表示碱金属，（B）使酸，碱或水溶性醛与上述步骤（A）中获得的式（2）表示的碱金属羟基甲磺酸酯反应，得到由式（1）表示的精制甲酰基环丙烷化合物。

36. 发明授权

US07612227B2 Processes for producing 3-methyl-2-butenyl acetate 失效
标题翻译：制备乙酸3-甲基-2-丁烯酯的方法
公开(公告)号：US07612227B2
公开(公告)日：2009-11-03
申请号：US10590991
申请日：2005-03-22
申请人： Katsuhisa Masumoto , Makoto Itagaki
发明人： Katsuhisa Masumoto , Makoto Itagaki
IPC分类号： C07C67/02
CPC分类号： C07C67/08 , C07C67/58 , C07C69/007 , C07C69/145
摘要： The present invention relates to a method for producing 3-methyl-2-butenyl acetate which comprises reacting 3-methyl-2-buten-1-ol with acetic anhydride in the presence of an inorganic base catalyst and a method for producing purified 3-methyl-2-butenyl acetate which comprises subjecting crude 3-methyl-2-butenyl acetate to a step (A) of contacting it with an aqueous solution of an alkali metal hydrogen sulfite, or a step (B) of contacting it with an aqueous solution of a base, or both steps (A) and (B).
摘要翻译：本发明涉及一种在无机碱催化剂存在下使3-甲基-2-丁烯-1-醇与乙酸酐反应的乙酸3-甲基-2-丁烯酯的制备方法，包括使乙酸3-甲基-2-丁烯酯进行与碱金属亚硫酸氢钠水溶液接触的步骤（A）的步骤（B）或使其与水碱的溶液，或步骤（A）和（B）两者。

37. 发明申请

US20080275268A1 Processes for Producing 3-Methyl-2-Butenyl Acetate 失效
标题翻译：生产3-甲基-2-丁烯酸乙酯的方法
公开(公告)号：US20080275268A1
公开(公告)日：2008-11-06
申请号：US10590991
申请日：2005-03-22
申请人： Katsuhisa Masumoto , Makoto Itagaki
发明人： Katsuhisa Masumoto , Makoto Itagaki
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , C07C67/58 , C07C69/007 , C07C69/145
摘要： The present invention relates to a method for producing 3-methyl-2-butenyl acetate which comprises reacting 3-methyl-2-buten-1-ol with acetic anhydride in the presence of an inorganic base catalyst and a method for producing purified 3-methyl-2-butenyl acetate which comprises subjecting crude 3-methyl-2-butenyl acetate to a step (A) of contacting it with an aqueous solution of an alkali metal hydrogen sulfite, or a step (B) of contacting it with an aqueous solution of a base, or both steps (A) and (B).
摘要翻译：本发明涉及一种在无机碱催化剂存在下使3-甲基-2-丁烯-1-醇与乙酸酐反应的乙酸3-甲基-2-丁烯酯的制备方法，包括使乙酸3-甲基-2-丁烯酯进行与碱金属亚硫酸氢钠水溶液接触的步骤（A）的步骤（B）或使其与水碱的溶液，或步骤（A）和（B）两者。

38. 发明授权

US07220797B2 Method of producing copolymer latex using for aqueous paint 有权
标题翻译：制备用于水性涂料的共聚物胶乳的方法
公开(公告)号：US07220797B2
公开(公告)日：2007-05-22
申请号：US10909375
申请日：2004-08-03
申请人： Toshiyasu Nishioka , Akira Kamimura , Makoto Itagaki
发明人： Toshiyasu Nishioka , Akira Kamimura , Makoto Itagaki
IPC分类号： C08L45/00
CPC分类号： C08F2/22
摘要： A copolymer latex for chipping-resistant aqueous paint capable of remarkably improving balance of chipping-resistance, strength of adherence with metal, water-resistance and high resistance for cycles of cool and heat is provided.This is achieved by a method for producing a copolymer latex using for chipping-resistant aqueous paint, the method comprising emulsion-polymerizing 20 to 80 parts by weight of a conjugated diene as a monomer, 0.5 to 15 parts by weight of an ethylenically unsaturated carboxylic acid as a monomer, 5 to 40 parts by weight of an aromatic vinyl compound as a monomer, 5 to 40 parts by weight of an unsaturated alkyl carboxylate as a monomer and optionally not more than 69.5 parts by weight of other compound having vinyl group copolymerizable therewith as a monomer based on 100 parts by weight in the total of the monomers, wherein 100 wt % of the amount of conjugated diene, 100 wt % of the amount of ethylenically unsaturated carboxylic acid, 95 to 50 wt % of the amount of aromatic vinyl compound and 95 to 50 wt % of the amount of the unsaturated alkyl carboxylate are added in the former stage of the emulsion-polymerization, and 5 to 50 wt % of the amount of the aromatic vinyl compound and 5 to 50 wt % of the amount of the unsaturated alkyl carboxylate are added at the later stage of emulsion-polymerization.
摘要翻译：提供了一种能够显着提高耐崩裂性，与金属粘附强度，耐水性和耐热循环性高的耐破碎性水性涂料的共聚物胶乳。这是通过一种制备用于耐崩裂性水性涂料的共聚物胶乳的方法实现的，该方法包括将20至80重量份作为单体的共轭二烯进行乳液聚合，0.5至15重量份的烯键式不饱和羧酸酸作为单体，5〜40重量份作为单体的芳香族乙烯基化合物，5〜40重量份作为单体的不饱和羧酸烷基酯和任选不大于69.5重量份的具有乙烯基可共聚的其它化合物作为单体，基于100个重量份的单体，其中100重量％的共轭二烯的量为100重量％，烯属不饱和羧酸的量为100重量％，芳族化合物的量为95至50重量％在乳液聚合的前一阶段加入乙烯基化合物和95〜50重量％的不饱和羧酸烷基酯，5〜50重量％的芳族乙烯基化合物和5t o在乳液聚合的后期加入50重量％的不饱和羧酸烷基酯的量。

39. 发明申请

US20070032659A1 Process for producing optically active cyclopropane compound and asymmetric copper complex for use in the same 失效
标题翻译：用于制备光学活性环丙烷化合物和不对称铜络合物的方法
公开(公告)号：US20070032659A1
公开(公告)日：2007-02-08
申请号：US10572391
申请日：2004-09-17
申请人： Makoto Itagaki , Katsuhisa Masumoto , Ryo Minamida
发明人： Makoto Itagaki , Katsuhisa Masumoto , Ryo Minamida
IPC分类号： C07F1/08 , C07C69/74
CPC分类号： C07C67/347 , C07B2200/07 , C07C68/06 , C07F1/005 , C07C69/757 , C07C69/96
摘要： A process for producing an optically active cyclopropane compound represented by the formula (4): wherein R3, R4, R5 and R6 are the same or different, and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, and so on; and R7 represents a C1-6 alkyl group; and * represents an asymmetric carbon atom, which comprises reacting a prochiral olefin represented by the formula (2): wherein R3, R4, R5, and R6 are as described above, with a diazoacetic acid ester represented by the formula (3): N2CHCO2R7 (3) wherein R7 is as defined above, in the presence of an asymmetric copper complex prepared from an optically active cycloalkylidenebisoxazoline compound represented by the formula (1): wherein R1 represents a hydrogen atom, a C1-6 alkyl group, and so on; R2 represents a C1-6 alkyl group and so on; and n represents an integer of 0 to 3; provided that, two R1s may be bonded each other together with the carbon atom to which they are bonded to form a ring; and * represents an asymmetric carbon atom, and a copper compound, is provided.
摘要翻译：一种制备由式（4）表示的光学活性环丙烷化合物的方法：其中R 3，R 4，R 5和R 5， SUP> 6相同或不同，表示氢原子，卤素原子，取代或未取代的烷基等; R 7表示C 1-6烷基; 和*表示不对称碳原子，其包括使由式（2）表示的前手性烯烃：其中R 3，R 4，R 5，和＆lt; 6＆gt;如上所述，用式（3）表示的重氮乙酸酯：<？in-line-formula description =“In-line Formulas”end =“lead （3）<？in-line-formula description =“In-line Formulas”end =“In-line formula”end =“In-line formula”end = 在由式（1）表示的光学活性亚环烷基双恶唑啉化合物制备的不对称铜络合物存在下，其中R 7定义如上所述：其中R 1， / SUP>表示氢原子，C 1-6烷基等; R 2表示C 1-6烷基等; n表示0〜3的整数，条件是两个R 1可以与它们所键合的碳原子一起形成环; 和*表示不对称碳原子，并且提供铜化合物。

40. 发明申请

US20060149077A1 Optically active bisoxazoline compounds, process for production of the same and use thereof 失效
标题翻译：光学活性双恶唑啉化合物，其制备方法及其用途
公开(公告)号：US20060149077A1
公开(公告)日：2006-07-06
申请号：US10544494
申请日：2004-02-04
申请人： Makoto Itagaki , Katsuhisa Masumoto
发明人： Makoto Itagaki , Katsuhisa Masumoto
IPC分类号： C07D413/02
CPC分类号： C07D263/12 , C07B2200/07 , C07C67/347 , C07C215/28 , C07C233/18 , C07C2601/02 , C07C69/747
摘要： Optically active bisoxazoline compounds represented by the general formula (1), a process for producing the compounds, and a process for producing cyclopropanecarboxylic esters by using the same: wherein R1 and R2 are the same and each represents C1-6 alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted phenyl or R1 and R2 are bonded each other together with the carbon atom of oxazoline ring to which they are bonded to form a ring; R3 is substituted or unsubstituted naphthyl; R4 and R5 are the same and each represent hydrogen or C1-6 alkyl, or R4 and R5 are bonded each other together with the carbon atom to which they are bonded to form a cycloalkyl ring having 3 to 6 carbon atoms; and * represents an asymmetric center.
摘要翻译：由通式（1）表示的光学活性的双恶唑啉化合物，该化合物的制备方法以及使用该化合物制备环丙烷羧酸酯的方法：其中R 1和R 2， SUP>相同，各自表示C 1-6烷基，取代或未取代的芳烷基或取代或未取代的苯基或R 1和R 2 O 2 >与它们所键合的恶唑啉环的碳原子一起形成环; R 3是取代或未取代的萘基; R 4和R 5是相同的，并且各自表示氢或C 1-6烷基，或R 4， R 5和它们所连接的碳原子一起形成具有3〜6个碳原子的环烷基环; *表示非对称中心。

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