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    • 32. 发明申请
    • Tanning agent and curing agent based on dialdehydes
    • 鞣剂和基于二醛的固化剂
    • US20050125906A1
    • 2005-06-16
    • US10511279
    • 2003-05-02
    • Stephan HüfferGunther PabstTilman TaegerStefan SchroederGerhard Wolf
    • Stephan HüfferGunther PabstTilman TaegerStefan SchroederGerhard Wolf
    • C07C45/72C14C3/16C14C3/00
    • C07C45/72C14C3/16
    • The invention relates to a tanning agent that is produced by reacting at least one aldehyde of general formula (I) with at least another identical or different aldehyde of formula (I), wherein the variables are defined as follows: Z is a single chemical bond, an optionally substituted C1-C12-alkyl, an optionally substituted C5-C12-cycloalkyl or an optionally substituted C6-C14-aryl, wherein the reaction is carried out in the presence of an acid catalyst and optionally in the presence of at least another carbonyl compound of formula (II), R1 to R4 represent, independent of one another, hydrogen, optionally substituted C1-C12-allyl, optionally substituted C3-C12-cycloalkyl, optionally substituted C7-C13-aralkyl or optionally substituted C6-C14-aryl, provided that at least another aldehyde of formula (I) in which the radical of Z contains α hydrogen atoms or at least another carbonyl compound of formula (I) is present when Z is a single chemical bond or a radical without any hydrogen atoms. The invention also relates to a method for the production of said tanning agent, to the utilization thereof as curing agent, particularly for pretannage, tannage or retannage of animal skins using the inventive tanning agents. The invention further relates to a powder active agent containing one or more of said inventive tanning agents, to a method for the production of said powder active agents and to the use thereof as curing agent and to leather produced using the inventive tanning agents or the inventive method.
    • 本发明涉及通过使至少一种通式(I)的醛与至少另一相同或不同的式(I)的醛反应制备的鞣制剂,其中变量定义如下:Z是单一化学键 ,任选取代的C 1 -C 12 - 烷基,任选取代的C 5 -C 12 - 环烷基 或任选取代的C 6 -C 14 - 芳基,其中反应在酸催化剂的存在下进行,并且任选地在至少另外一种羰基化合物存在下进行 式(II)中,R 1至R 4彼此独立地表示氢,任选取代的C 1 -C 4烷基, 12-烯丙基,任选取代的C 3 -C 12 - 环烷基,任选取代的C 7 -C 13 - 或其任选取代的C 6 -C 14 - 芳基,条件是至少另一种式(I)的醛,其中th 当Z是单个化学键或没有任何氢原子的基团时,Z的基团含有α氢原子或至少另外一个式(I)的羰基化合物。 本发明还涉及一种用于生产所述鞣剂的方法,其用作固化剂,特别是使用本发明的鞣剂对动物皮肤进行预处理,鞣制或回火处理。 本发明还涉及含有一种或多种所述本发明的鞣剂的粉末活性剂,用于制备所述粉末活性剂的方法及其作为固化剂的用途,以及使用本发明的鞣剂或本发明制备的皮革 方法。
    • 37. 发明申请
    • Formulation for use in chrome or chrome-free tannage
    • 用于铬或无铬鞣革的配方
    • US20060101584A1
    • 2006-05-18
    • US10524047
    • 2003-08-14
    • Stephan HuefferStefan SchroederEinhard WagnerThorsten RadlerKarl Vill
    • Stephan HuefferStefan SchroederEinhard WagnerThorsten RadlerKarl Vill
    • C14C3/00
    • C14C3/16C14C3/28
    • A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 μm or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.
    • 提出了用于无铬或铬鞣制剂的制剂,其包含粘土矿物,其在50℃下在水中剧烈搅拌30分钟后具有小于2μm的数均粒径或双峰尺寸分布 具有数均粒径小于0.5μm的第一细碎部分和数均粒径小于5μm的第二粗纱部分,通过组合的方法按照ISO 13320-1的方法确定 激光衍射和光散射,第一细分的份数为10至90重量%,以及一种或多种下列一种或多种物质:​​有机聚合物,醛鞣剂,砜鞣剂, 树脂鞣剂,苯酚鞣剂,加脂剂,植物鞣剂,染料和颜料。
    • 40. 发明申请
    • MULTI-PHASE CONVERTER SYSTEM AND METHOD
    • 多相转换器系统及方法
    • US20130148397A1
    • 2013-06-13
    • US13315660
    • 2011-12-09
    • Stefan SchroederPiniwan Thiwanka Bandara Wijekoon
    • Stefan SchroederPiniwan Thiwanka Bandara Wijekoon
    • H02M7/5387
    • H02M7/487H02M2001/0025H02M2007/4835
    • A multi-phase converter includes a plurality of phase paths. Each phase path includes at least one dc-link that is independent from every other phase path dc-link such that each output phase voltage is generated from a corresponding dc-link voltage source that can be different from every other phase voltage dc-link voltage source. A total dc-link voltage level is determined for each output phase voltage. A common-mode injection voltage is calculated based on all dc-link voltage levels and all phase reference voltages. Each phase path reference voltage is then adjusted based on the calculated common-mode injection voltage, such that each generated output phase voltage level is adjusted in response to its corresponding adjusted reference voltage.
    • 多相转换器包括多个相位路径。 每个相位路径包括至少一个独立于每个其它相位路径dc-link的直流链路,使得每个输出相位电压从相应的直流链路电压源产生,该相应的直流链路电压源可以与每个其它相位电压直流链路电压 资源。 确定每个输出相电压的总直流电压电平。 基于所有直流链路电压电平和所有相位参考电压计算共模注入电压。 然后基于所计算的共模注入电压来调整每个相位路径参考电压,使得每个产生的输出相电压电平响应于其对应的调整参考电压而被调整。