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31. 发明授权

US5889123A Polymer compounds and their use for the vulcanization of halogenated butyl rubbers with a low halogen content 失效
标题翻译：高分子化合物及其用于硫化卤素含量低的卤化丁基橡胶的用途
公开(公告)号：US5889123A
公开(公告)日：1999-03-30
申请号：US939423
申请日：1997-09-29
申请人： Rudiger Schubart , Rudiger Musch , Anthony Sumner , Stefan Kelbch
发明人： Rudiger Schubart , Rudiger Musch , Anthony Sumner , Stefan Kelbch
IPC分类号： C08J3/24 , B60C1/00 , C08K5/00 , C08K5/29 , C08K5/3442 , C08K5/378 , C08L21/00 , C08L23/28 , C08F14/00
CPC分类号： C08K5/3442 , B60C1/0008 , C08K5/0008 , C08K5/29 , C08L21/00 , C08L23/283
摘要： Compositions comprising new halogenated butyl rubbers with a defined, low content of halogen, a defined content of non-halogenated double bonds and a defined content of anti-agglomeration/vulcanisation control agents and containing polymer compounds comprising special amidines, mercapto or zinc mercapto compounds and polymers possess outstanding mechanical and physiological properties, so that they are suitable for the production of tyres, particularly tyre inner liners, tyre sidewalls and tyre treads.
摘要翻译：组合物包含具有限定的低含量卤素，定义的非卤化双键含量的新卤化丁基橡胶和限定含量的抗附聚/硫化控制剂并含有包含特殊脒基，巯基或锌巯基化合物的聚合物化合物和聚合物具有突出的机械和生理特性，因此它们适用于生产轮胎，特别是轮胎内衬，轮胎侧壁和轮胎胎面。

32. 发明授权

US5210152A Process for the vulcanization of polychloroprene 失效
标题翻译：聚氯乙烯聚合方法
公开(公告)号：US5210152A
公开(公告)日：1993-05-11
申请号：US624967
申请日：1990-12-10
申请人： Rudiger Musch , Rudiger Schubart
发明人： Rudiger Musch , Rudiger Schubart
IPC分类号： C08J3/24 , C08C19/30 , C08F8/00 , C08K5/29 , C08K5/3442 , C08L11/00 , C08L21/00
CPC分类号： C08K5/29 , C08K5/3442
摘要： The metal oxide vulcanization of polychloroprene in the presence of amidine compounds, but in the absence of magnesium oxide, leads to vulcanizates which are capable of withstanding high temperatures, even under dynamic stress.
摘要翻译：在脒化合物存在下，聚氯丁二烯的金属氧化物硫化，但是在不存在氧化镁的情况下，即使在动态应力下也能耐受高温的硫化胶。

33. 发明授权

US5187232A Rubber compounds of polychloroprene and hydrogenated nitrile rubber 失效
标题翻译：聚氯乙烯和氢化硅橡胶的橡胶化合物
公开(公告)号：US5187232A
公开(公告)日：1993-02-16
申请号：US594624
申请日：1990-10-09
申请人： Rudiger Musch , Joachim Thormer , Hartmuth Buding , Friedrich Leibbrandt
发明人： Rudiger Musch , Joachim Thormer , Hartmuth Buding , Friedrich Leibbrandt
IPC分类号： C08L11/00 , C08L15/00 , C08L21/00
CPC分类号： C08L11/00 , C08L15/005
摘要： Mixtures of polychloroprene and hydrogenated nitrile rubber give vulcanizates combining high modulus with a high dynamic stress absorption capacity.
摘要翻译：聚氯丁二烯和氢化丁腈橡胶的混合物得到结合高模量和高动态应力吸收能力的硫化胶。

34. 发明授权

US4740572A Process for the production of polymers containing reactive terminal groups 失效
标题翻译：制备含有反应性末端基团的聚合物的方法
公开(公告)号：US4740572A
公开(公告)日：1988-04-26
申请号：US931513
申请日：1986-11-17
申请人： Rudiger Musch , Steven Pask , Renke Mottweiler , Oskar Nuyken , Thomas Dittmer , Hans-Peter Muhlbauer
发明人： Rudiger Musch , Steven Pask , Renke Mottweiler , Oskar Nuyken , Thomas Dittmer , Hans-Peter Muhlbauer
IPC分类号： C08F2/00 , C08F2/06 , C08F2/28 , C08F2/38 , C08F2/42 , C08F4/06 , C08F4/14 , C08F110/10
CPC分类号： C08F2/38
摘要： The production of polymers containing terminal halogen groups from cationically polymerizable monomers using a metal halide boiling below 50.degree. C. at normal pressure as catalyst and an organic halide corresponding to the following general formula ##STR1## in which X is halogen,n is an integer of 1, 2, 3 or 4,R.sub.1 and R.sub.2 represent C.sub.5 -C.sub.10 cycloalkyl or linear or branched C.sub.1 -C.sub.20 alkyl andR.sub.3 represents C.sub.5 -C.sub.10 cycloalkyl, linear or branched C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.10 cycloalkylene, linear or branched C.sub.1 -C.sub.20 alkylene or aryl, and the organic halide (inifer) contains from 5 to 50 carbon atoms and is present in concentrations of from 10.sup.-1 to 10.sup.-6 moles per mole monomer while the metal halide is added in a 1.1 to 100-fold molar excess, based on halogen atoms of the organic halide, at temperatures of from +10.degree. to -130.degree. C. in an inert organic solvent or solvent mixture is possible with recovery of the catalyst and with formation of a product having a functionality differing only slightly, if at all, from the theoretical functionality providing the reaction components monomer, catalyst and inifer are continuously introduced into a polymerization apparatus in such a way that all three components are only mixed once they are inside the apparatus, the polymer solution is continuously removed from the apparatus, the polymer solution is freed from residual monomer, unreacted inifer and from the catalyst and worked up.
摘要翻译：使用在常压下沸腾低于50℃的金属卤化物作为催化剂和对应于以下通式的有机卤化物，其中X是卤素，n是整数，由阳离子可聚合单体制备含有末端卤素基团的聚合物为1,2,3或4，R1和R2表示C5-C10环烷基或直链或支链C1-C20烷基，R3表示C5-C10环烷基，直链或支链C1-C20烷基，C5-C10亚环烷基，直链或支链C1 -C 20亚烷基或芳基，有机卤化物（无机物）含有5至50个碳原子，并且以每摩尔单体10-1至10-6摩尔的浓度存在，而金属卤化物以1.1至100重量％在惰性有机溶剂或溶剂混合物中，在+10〜-130℃的温度下，以有机卤化物的卤素原子计，摩尔过量倍数是可能的，回收催化剂并形成具有官能度的产物不同之处仅在于所有这些提供反应组分的理论功能单体，催化剂和Inifer被连续地引入到聚合装置中，使得所有这三种组分一旦被置于装置内就被混合，聚合物溶液从设备中连续地除去，聚合物溶液从残留的单体，未反应的Inifer和催化剂中除去并加以处理。

35. 发明授权

US4737528A Vulcanizable polymer mixtures, their production and use and vulcanizates obtained therefrom 失效
标题翻译：可硫化的聚合物混合物，其生产和使用以及从其获得的硫化橡胶
公开(公告)号：US4737528A
公开(公告)日：1988-04-12
申请号：US921113
申请日：1986-10-21
申请人： Rudiger Musch , Wilhelm Gobel , Jean Mirza
发明人： Rudiger Musch , Wilhelm Gobel , Jean Mirza
IPC分类号： C08L23/22 , C08L1/00 , C08L7/00 , C08L11/00 , C08L21/00 , C08L23/00 , C08L23/26 , C08L27/00 , C08L101/00 , C08J3/16 , C08L27/04
CPC分类号： C08L11/00 , C08L23/283
摘要： Polychloroprene rubbers having favorable processing behavior and excellent properties are obtained if mono-, di- or trichlorosubstituted polyisobutylene is added as plasticizer before vulcanization.
摘要翻译：如果在硫化前加入一，二或三氯取代的聚异丁烯作为增塑剂，则获得具有良好加工性能和优异性能的聚氯丁二烯橡胶。

36. 发明授权

US4303765A Process for the production of storable 2-chloro-1,3-butadiene/sulfur copolymers 失效
标题翻译：用于生产可存储的2-氯-1,3-丁二烯/硫共聚物的方法
公开(公告)号：US4303765A
公开(公告)日：1981-12-01
申请号：US159770
申请日：1980-06-06
申请人： Rudiger Musch , Rudiger Schubart , Wilhelm Gobel , Gottfried Pampus
发明人： Rudiger Musch , Rudiger Schubart , Wilhelm Gobel , Gottfried Pampus
IPC分类号： C08F236/00 , C08C1/00 , C08C4/00 , C08C19/08 , C08F36/18 , C08F236/18 , C08C19/20 , C08F8/34
CPC分类号： C08F36/18 , C08C19/08
摘要： A process for the production of storable 2-chloro-1,3-butadiene/sulphur copolymers by peptization using sulphur containing petizing agents, wherein a compound corresponding to the following general formula:R.sub.1 --S.sub.n --R.sub.1whereinn represents an integer having a value of from 2 to 10, preferably from 3 to 8 and, more particularly, from 4 to 6; and R.sub.1 represents a C.sub.6 -C.sub.14 aryl radical, a C.sub.6 -C.sub.14 aryl-C.sub.1 -C.sub.3 alkyl radical or a heterocycle containing from 1 to 3 hereto atoms, such as N, which may be the same or different and which may optionally be substituted;optionally in combination with a nucleophilic substance, is added to the latex and peptized at from 5.degree. to 100.degree. C. and at pH of from 14 to 3.
摘要翻译：一种通过使用含硫化合物的胶溶而制备可存储的2-氯-1,3-丁二烯/硫共聚物的方法，其中对应于以下通式的化合物：R1-Sn-R1其中n表示具有值的整数为2至10，优选3至8，更特别为4至6; 并且R 1表示C 6 -C 14芳基，C 6 -C 14芳基-C 1 -C 3烷基或含有1至3个原子的杂环，例如N，其可以相同或不同，并且可任选被取代; 任选地与亲核物质组合，加入到胶乳中并在5℃至100℃，pH为14至3下胶溶。

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