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31. 发明授权

US06560004B2 Coupled electrochromic compounds with photostable dication oxidation states 有权
公开(公告)号：US06560004B2
公开(公告)日：2003-05-06
申请号：US09884717
申请日：2001-06-19
申请人： David A. Theiste , Kelvin L. Baumann , Punam Giri , Thomas F. Guarr
发明人： David A. Theiste , Kelvin L. Baumann , Punam Giri , Thomas F. Guarr
IPC分类号： G02F115
CPC分类号： C09K9/02 , G02F1/1521 , G02F2001/1502 , G02F2001/1512
摘要： Coupling of anodic electrochromic compounds by a covalent bond or a bridge link which provides for electronic communication between the coupled electrochromic compounds results in coupled electrochromic compounds which exhibit greater stability as well as electrochromic activity that differs from the monomeric electrochromic compounds. Extension of the absorption spectrum into the near-infrared region of the spectrum is frequently observed. The coupled electrochromic compounds are highly suitable for use in electrochromic media used to produce electrochromic devices.

32. 发明授权

US6137620A Electrochromic media with concentration-enhanced stability, process for the preparation thereof and use in electrochromic devices 有权
公开(公告)号：US6137620A
公开(公告)日：2000-10-24
申请号：US302886
申请日：1999-04-30
申请人： Thomas F. Guarr , David A. Theiste , David J. Cammenga , John S. Anderson
发明人： Thomas F. Guarr , David A. Theiste , David J. Cammenga , John S. Anderson
IPC分类号： C09K9/02 , G02B5/23 , G02F1/15 , G02F1/153 , G02F1/00
CPC分类号： G02F1/1521 , G02B5/23 , G02F2001/1512
摘要： Increased stability of electrochromic devices containing an electrochromic medium having two or more electroactive compounds is accomplished by establishing current limiting concentrations of electroactive compounds with the larger redox potential difference. A process for production of electrochromic devices uses targeted concentrations of electroactive materials during preparation of the electrochromic medium which results in substantially no devices being produced wherein the current is limited by an electroactive compound having a low redox potential difference.

33. 发明授权

US07193764B2 Reversible electrodeposition devices and associated electrochemical media 有权
标题翻译：可逆电沉积装置和相关的电化学介质
公开(公告)号：US07193764B2
公开(公告)日：2007-03-20
申请号：US10945543
申请日：2004-09-20
申请人： Rongguang Lin , David Theiste , Thomas F. Guarr , Kathy E. Roberts
发明人： Rongguang Lin , David Theiste , Thomas F. Guarr , Kathy E. Roberts
IPC分类号： G02F1/15 , G02F1/153 , G02F1/00
CPC分类号： G02F1/1506 , G02F2001/1512 , G02F2001/1536
摘要： The present invention is directed to a reversible electrodeposition device comprising: a first substrate having an electrically conductive material associated therewith; a second substrate having an electrically conductive material associated therewith; a nucleation layer at least partially covering at least one of the electrically conductive materials of the first and second substrates; an electrochemical medium contained within a chamber positioned between the first and second substrates.
摘要翻译：本发明涉及一种可逆电沉积装置，包括：具有与其相关联的导电材料的第一基板; 具有与其相关联的导电材料的第二基板; 成核层至少部分地覆盖第一和第二基底的至少一种导电材料; 包含在位于第一和第二基板之间的腔室内的电化学介质。

34. 发明授权

US07075697B2 Tristate electrochromic device 有权
标题翻译：三态电致变色装置
公开(公告)号：US07075697B2
公开(公告)日：2006-07-11
申请号：US11236071
申请日：2005-09-27
申请人： Punam Giri , Thomas F. Guarr
发明人： Punam Giri , Thomas F. Guarr
IPC分类号： G02F1/15 , G02F1/153
CPC分类号： G02F1/153 , G02F1/1521 , G02F1/163 , G02F2203/11
摘要： An electrochromic medium for use in a tristate electrochromic device, comprising: (a) at least one solvent; (b) at least one anodic material; (c) at least one cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic; (d) wherein, in a first state, the electrochromic medium exhibits a maximum light transmission; (e) wherein, in a second state, variable attenuation occurs to a significant extent in one of visible radiation or near-infrared radiation without significant attenuation in the other; and (f) wherein, in a third state, variable attenuation occurs to a significant extent in the other spectral region.
摘要翻译：一种用于三级电致变色装置的电致变色介质，包括：（a）至少一种溶剂; （b）至少一种阳极材料; （c）至少一种阴极材料，其中阳极和阴极材料都是电活性的，阳极和阴极材料中的至少一种是电致变色的; （d）其中，在第一状态下，所述电致变色介质表现出最大光透射率; （e）其中，在第二状态下，在可见辐射或近红外辐射之一中显着地发生可变衰减，而在另一个状态下没有显着的衰减; 和（f）其中，在第三状态下，可变衰减在另一光谱区域中显着地发生。

35. 发明授权

US06635194B2 Electrochromic medium having a self-healing cross-linked polymer gel and associated electrochromic device 有权
标题翻译：具有自愈合交联聚合物凝胶和相关电致变色装置的电致变色介质
公开(公告)号：US06635194B2
公开(公告)日：2003-10-21
申请号：US09940944
申请日：2001-08-28
申请人： Leroy J. Kloeppner , Thomas F. Guarr , Kevin L. Ash , Kathy E. Roberts
发明人： Leroy J. Kloeppner , Thomas F. Guarr , Kevin L. Ash , Kathy E. Roberts
IPC分类号： G02F1153
CPC分类号： C09K9/02 , G02F1/1521 , G02F1/1525 , G02F2001/1502
摘要： An electrochromic medium for use in an electrochromic device comprising: at least one solvent; a cathodic electroactive material; an anodic electroactive material; wherein at least one of the cathodic and anodic electroactive materials is electrochromic; and a self-healing cross-linked polymer gel.
摘要翻译：一种用于电致变色装置的电致变色介质，包括：至少一种溶剂; 阴极电活性材料; 阳极电活性材料; 其中阴极和阳极电活性材料中的至少一种是电致变色的; 和自愈合交联聚合物凝胶。

36. 发明授权

US06594066B2 Substituted metallocenes and electrochromic media and devices comprising the same 有权
标题翻译：取代的金属茂和电致变色介质以及包含其的装置
公开(公告)号：US06594066B2
公开(公告)日：2003-07-15
申请号：US10121760
申请日：2002-04-22
申请人： Jeffrey R. Lomprey , Thomas F. Guarr
发明人： Jeffrey R. Lomprey , Thomas F. Guarr
IPC分类号： G02F101
CPC分类号： G02F1/1521 , C07F17/02 , C09K9/02
摘要： An electrochromic device comprising at least one substantially transparent substrate having an electrically conductive material associated therewith, and an electrochromic medium which comprises a solvent, a cathodic material, and an anodic electrochromic material represented by the formula: wherein R1-R10 are the same or different and at least three of R1-R10 are the same or different and comprise a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 40 carbon atom(s), and/or a silyl or siloxyl group containing approximately 1 to approximately 40 silicon atom(s), wherein the carbon or silicon atom(s) may be a linking group to, or part of, one or more functional groups comprising nitrites; nitro constituents; sulfoxides; sulfonates; phosphonium constituents; phosphonates; phosphonites; ammonium constituents; viologens, including bipyridinyl constituents; carbonyls, including carbonates, carbamates; ketones; esters; and amides; ethers, including polyethers; amines, including tertiary amines; alkenes; alkynes; and mixtures thereof; wherein any remainder of R1-R10 comprise H; and wherein M comprises a transition metal.
摘要翻译：一种电致变色装置，包括至少一个具有与之相关的导电材料的基本上透明的基底，以及电致变色介质，其包含溶剂，阴极材料和由下式表示的阳极电致变色材料：其中R1-R10相同或不同并且R1-R10中的至少三个相同或不同，并且包含含有约1至约40个碳原子的直链或支链烷基，芳基，烷芳基或芳烷基，和/或含有约1至约40个碳原子的甲硅烷基或硅氧烷基 1至约40个硅原子，其中碳或硅原子可以是与一个或多个包含亚硝酸根的官能团的一部分或部分的连接基团; 硝基成分; 亚砜磺酸盐; 鏻成分; 膦酸盐亚膦酸盐铵成分; 紫罗兰，包括联吡啶成分; 羰基，包括碳酸酯，氨基甲酸酯; 酮类酯类和酰胺; 醚，包括聚醚; 胺，包括叔胺; 烯烃炔烃及其混合物; 其中R 1 -R 10的任何其余部分包括H; 并且其中M包含过渡金属。

37. 发明授权

US06486998B2 Color-stabilized electrochromic devices 有权
标题翻译：颜色稳定的电致变色装置
公开(公告)号：US06486998B2
公开(公告)日：2002-11-26
申请号：US10035721
申请日：2001-10-25
申请人： Jeffrey R. Lomprey , Thomas F. Guarr
发明人： Jeffrey R. Lomprey , Thomas F. Guarr
IPC分类号： G02F115
CPC分类号： C09K9/02 , G02F1/1521 , G02F1/1525 , G02F2001/1502 , G02F2001/1512
摘要： An electrochromic medium for use in a normally operating electrochromic device comprising an anodic material and a cathodic material wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic, an additive, and means associated with the additive for maintaining a colorless or nearly colorless electrochromic medium while the electrochromic medium is in a high transmission state relative to an electrochromic medium without the additive.
摘要翻译：一种用于正常操作的电致变色装置的电致变色介质，其包括阳极材料和阴极材料，其中阳极和阴极材料都是电活性的，阳极和阴极材料中的至少一种是电致变色的，添加剂和与用于维持无色或几乎无色的电致变色介质的添加剂，而电致变色介质相对于没有添加剂的电致变色介质处于高透射状态。

38. 发明授权

US07864398B2 Electro-optical element including metallic films and methods for applying the same 有权
标题翻译：包括金属膜的电光元件及其应用方法
公开(公告)号：US07864398B2
公开(公告)日：2011-01-04
申请号：US11682098
申请日：2007-03-05
申请人： Gary J. Dozeman , Henry A. Luten , George A. Neuman , William L. Tonar , Thomas F. Guarr , Leroy J. Kloeppner , David L. Eaton
发明人： Gary J. Dozeman , Henry A. Luten , George A. Neuman , William L. Tonar , Thomas F. Guarr , Leroy J. Kloeppner , David L. Eaton
IPC分类号： G02F1/15 , G02F1/153
CPC分类号： G02F1/155 , B60R1/088 , B82Y20/00 , G02F2202/36 , Y10S359/90
摘要： A method for manufacturing an electrochromic element comprises providing a first substrate having first and second surfaces opposite one another and a first edge surface, providing a second substrate having third and fourth surfaces opposite one another and a second edge surface, wherein the third surfaces faces the second surface, and providing an electrochromic medium located between the first and second substrates, wherein the electrochromic medium has a light transmittance that is variable upon the application of electric field thereto. The method further complies applying a conductive layer on at least a portion of at least a select one of a first, second, third, and fourth surfaces and the first and second edge surfaces, wherein applying the conductive layer is accomplished at substantially atmospheric pressure and including applying at least a select one of metallic particles, an organometallic, a metallo-organic, and combinations thereof, and wherein the conductive layer has a bulk resistivity of less than or equal to 150 μΩ·cm. Other aspects of this invention comprise applying the conductive layer via ink jetting, ultrasonic spraying, auger pumping and jet pumping.
摘要翻译：一种制造电致变色元件的方法包括提供具有彼此相对的第一和第二表面的第一基底和第一边缘表面，提供具有彼此相对的第三和第四表面的第二基底和第二边缘表面，其中第三表面面向并且提供位于第一和第二基板之间的电致变色介质，其中电致变色介质具有在施加电场时可变的透光率。该方法进一步遵循在至少一部分第一，第二，第三和第四表面以及第一和第二边缘表面中的至少一部分上施加导电层，其中施加导电层是在大气压下完成的，包括施加至少一种选择的金属颗粒，有机金属，金属有机物及其组合，并且其中导电层具有小于或等于150μΩ·cm的体电阻率。本发明的其它方面包括通过喷墨，超声波喷涂，螺旋推送和喷射泵送来施加导电层。

39. 发明申请

US20070201122A1 Electro-Optical Element Including Metallic Films and Methods For Applying The Same 有权
标题翻译：包括金属膜的电光元件及其应用方法
公开(公告)号：US20070201122A1
公开(公告)日：2007-08-30
申请号：US11682098
申请日：2007-03-05
申请人： Gary J. Dozeman , Henry A. Luten , George A. Neuman , William L. Tonar , Thomas F. Guarr , Leroy J. Kloeppner , David L. Eaton
发明人： Gary J. Dozeman , Henry A. Luten , George A. Neuman , William L. Tonar , Thomas F. Guarr , Leroy J. Kloeppner , David L. Eaton
IPC分类号： G02F1/15
CPC分类号： G02F1/155 , B60R1/088 , B82Y20/00 , G02F2202/36 , Y10S359/90
摘要： A method for manufacturing an electrochromic element comprises providing a first substrate having first and second surfaces and a first edge surface, providing a second substrate having third and fourth surfaces and a second edge surface, the third surfaces facing the second surface, providing an electrochromic medium located between the first and second substrates, the medium having a light transmittance that is variable upon application of electric field thereto, applying a conductive layer on a portion of at least one of the surfaces, wherein applying the layer is accomplished at substantially atmospheric pressure, and applying at least one of metallic particles, an organometallic, a metallo-organic, and combinations thereof, wherein the conductive layer has a bulk resistivity of greater than or equal to 150 μΩ·cm. The conductive layer may be applied via ink jetting, ultrasonic spraying, auger or jet pumping.
摘要翻译：一种制造电致变色元件的方法包括提供具有第一和第二表面的第一基底和第一边缘表面，提供具有第三和第四表面的第二基底和第二边缘表面，所述第三表面面向第二表面，提供电致变色介质位于第一和第二基板之间，介质具有在施加电场时变化的透光率，在至少一个表面的一部分上施加导电层，其中施加该层是在基本上大气压下完成的，以及施加金属颗粒，有机金属，金属有机物及其组合中的至少一种，其中所述导电层具有大于或等于150μmO·cm的体电阻率。可以通过喷墨，超声波喷涂，螺旋钻或喷射泵送来施加导电层。

40. 发明授权

US07031044B2 Electrochromic device having a current-reducing additive 有权
公开(公告)号：US07031044B2
公开(公告)日：2006-04-18
申请号：US10884480
申请日：2004-07-02
申请人： Kathy E. Roberts , Thomas F. Guarr
发明人： Kathy E. Roberts , Thomas F. Guarr
IPC分类号： G02F1/153 , G02B5/23
CPC分类号： G02F1/1521
摘要： An electrochromic medium for use in an electrochromic device comprising: at least one solvent; an anodic electroactive material; a cathodic electroactive material, wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and a current-reducing additive, wherein the current-reducing additive comprises a polymer present in an effective concentration to materially reduce the current of the electrochromic medium upon application of an electrical potential, relative to an electrochromic medium without the current-reducing additive, while maintaining an electrochromic medium viscosity which facilitates acceptable production rates without a problematic degree of seal or other device component failure.

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