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31. 发明授权

US08148481B2 Method for seed bed treatment for a polymerization reaction 有权
标题翻译：聚合反应的种子床处理方法
公开(公告)号：US08148481B2
公开(公告)日：2012-04-03
申请号：US13128087
申请日：2009-12-17
申请人： F. David Hussein , Mark G. Goode , Michael E Muhle , David A. Yahn , Robert O. Hagerty
发明人： F. David Hussein , Mark G. Goode , Michael E Muhle , David A. Yahn , Robert O. Hagerty
IPC分类号： C08F2/00 , C08F2/34 , C08F10/02
CPC分类号： C08F10/02 , C08F210/16 , Y10S526/901 , Y10S526/905 , C08F2/34 , C08F2/005 , C08F210/14
摘要： A method for preparing a reactor for performance of a polymerization reaction, the method including providing at least one seed bed into the reactor; wherein the at least one seed bed includes at least one organometallic compound and polymer particles.
摘要翻译：一种制备用于进行聚合反应的反应器的方法，所述方法包括在反应器中提供至少一个种子床; 其中所述至少一种种子床包括至少一种有机金属化合物和聚合物颗粒。

32. 发明申请

US20110294973A1 Method for Seed Bed Treatment for a Polymerization Reaction 有权
标题翻译：聚合反应种子床处理方法
公开(公告)号：US20110294973A1
公开(公告)日：2011-12-01
申请号：US13128087
申请日：2009-12-17
申请人： F. David Hussein , Mark G. Goode , Michael E. Muhle , David A. Yahn , Robert O. Hagerty
发明人： F. David Hussein , Mark G. Goode , Michael E. Muhle , David A. Yahn , Robert O. Hagerty
IPC分类号： C08F4/44 , C08F4/52
CPC分类号： C08F10/02 , C08F210/16 , Y10S526/901 , Y10S526/905 , C08F2/34 , C08F2/005 , C08F210/14
摘要： A method for preparing a reactor for performance of a polymerization reaction, the method including providing at least one seed bed into the reactor; wherein the at least one seed bed includes at least one organometallic compound and polymer particles.
摘要翻译：一种制备用于进行聚合反应的反应器的方法，所述方法包括在反应器中提供至少一个种子床; 其中所述至少一种种子床包括至少一种有机金属化合物和聚合物颗粒。

33. 发明申请

US20110184124A1 CONTINUITY ADDITIVES AND THEIR USE IN POLYMERIZATION PROCESSES 有权
标题翻译：连续添加剂及其在聚合工艺中的应用
公开(公告)号：US20110184124A1
公开(公告)日：2011-07-28
申请号：US12673561
申请日：2008-08-06
申请人： F. Gregory Stakem , Agapios K. Agapiou , F. David Hussein
发明人： F. Gregory Stakem , Agapios K. Agapiou , F. David Hussein
IPC分类号： C08K5/56 , C07F5/06
CPC分类号： C08F6/003 , C08F210/16 , C08F2410/02 , C08F2/005 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： A continuity additive according to one general approach includes a substance having an ability to reduce, prevent, or mitigate at least one of fouling, sheeting, and static level of a material present in a polymerization reactor system when added to the reactor system in an effective amount, with the proviso that the substance is not a polysulfone polymer, a polymeric polyamine, or an oil-soluble sulfonic acid; and a scavenger contacted with the substance, optionally, the scavenger neutralizing water coming in contact therewith. Additional continuity additives, methods of making continuity additives, and use of continuity additives are also presented.
摘要翻译：根据一般方法的连续性添加剂包括具有降低，防止或减轻聚合反应器系统中存在的材料的污垢，片材和静态水平中的至少一种的能力的物质，当加入到反应器系统中时，量，条件是该物质不是聚砜聚合物，聚合多胺或油溶性磺酸; 和与该物质接触的清除剂，任选地，与其接触的清除剂中和水。还提出了附加的连续性添加剂，制备连续性添加剂的方法和连续性添加剂的使用。

34. 发明授权

US07629422B2 Process for transitioning between Ziegler-Natta-based and chromium-based catalysts 有权
标题翻译：齐格勒 - 纳塔和铬基催化剂之间的过渡过程
公开(公告)号：US07629422B2
公开(公告)日：2009-12-08
申请号：US11312272
申请日：2005-12-20
申请人： Mark G. Goode , Kevin J. Cann , F. David Hussein , Robert L. Santana , David C. Schutz , Agapios K. Agapiou
发明人： Mark G. Goode , Kevin J. Cann , F. David Hussein , Robert L. Santana , David C. Schutz , Agapios K. Agapiou
IPC分类号： C08F2/38 , C08F2/34 , C08F210/08
CPC分类号： C08F10/02 , C08F210/16 , C08F2410/05 , Y10S526/901 , C08F2/34 , C08F2/42 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F210/08
摘要： Embodiments of our invention relate to processes for transitioning among polymerization catalyst systems including processes for transitioning among olefin polymerization reactions using Ziegler-Natta catalysts systems and chromium-based catalyst systems. Among embodiments contemplated are a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor, comprising: adding to the reactor a deactivating agent (DA) selected from one of carbon monoxide, carbon dioxide, or combinations thereof; adding to the reactor a cocatalyst adsorbing agent (CAA), comprising an inorganic oxide selected from one of silica, alumina or combinations thereof; wherein the first catalyst comprises at least one conventional Ziegler-Natta catalyst, and a cocatalyst, wherein the second catalyst comprises at least one chromium-based catalyst, wherein the reactor is a gas-phase, fluidized bed reactor, and wherein the CAA is substantially free of transition metals. In another embodiment a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor is contemplated, comprising: adding a transition aid agent (TAA) wherein the TAA is selected from one of alkoxylated amines, alkoxylated amides, or combinations thereof, wherein the first catalyst comprises at least one Ziegler-Natta catalyst comprising the catalyst, a cocatalyst and optionally a support, and the second catalyst comprises at least one chromium-based catalyst.
摘要翻译：本发明的实施方案涉及在聚合催化剂体系中过渡的方法，包括使用齐格勒 - 纳塔催化剂体系和铬基催化剂体系在烯烃聚合反应中过渡的方法。考虑的实施方案是在烯烃聚合反应器中从第一催化剂转变为第二催化剂的方法，包括：向反应器中加入选自一氧化碳，二氧化碳或其组合中的一种失活剂（DA）; 向所述反应器中加入选自二氧化硅，氧化铝或其组合的无机氧化物的助催化剂吸附剂（CAA）; 其中所述第一催化剂包含至少一种常规齐格勒 - 纳塔催化剂和助催化剂，其中所述第二催化剂包含至少一种铬基催化剂，其中所述反应器是气相流化床反应器，并且其中所述CAA基本上没有过渡金属。在另一个实施方案中考虑了在烯烃聚合反应器中从第一催化剂转变为第二催化剂的方法，包括：加入转移助剂（TAA），其中TAA选自烷氧基化胺，烷氧基化酰胺或其组合之一其中所述第一催化剂包含至少一种齐格勒 - 纳塔催化剂，其包含所述催化剂，助催化剂和任选的载体，所述第二催化剂包含至少一种铬基催化剂。

35. 发明授权

US06949612B2 Processes for transitioning between metallocene and Ziegler-Natta polymerization catalysts 有权
标题翻译：茂金属与齐格勒 - 纳塔聚合催化剂之间的过渡过程
公开(公告)号：US06949612B2
公开(公告)日：2005-09-27
申请号：US10715813
申请日：2003-11-18
申请人： Agapios Kyriacos Agapiou , Robert Olds Hagerty , F. David Hussein , Michael Elroy Muhle , Richard B. Pannell , Kathryn Ann Russell , Robert Lynn Santana , X. Simon Zhang
发明人： Agapios Kyriacos Agapiou , Robert Olds Hagerty , F. David Hussein , Michael Elroy Muhle , Richard B. Pannell , Kathryn Ann Russell , Robert Lynn Santana , X. Simon Zhang
IPC分类号： C08F2/34 , C08F2/38 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F2410/05 , Y10S526/901 , C08F2/42 , C08F210/08 , C08F2500/24
摘要： Processes for transitioning among polymerization catalyst systems, preferably catalyst systems that are incompatible with each other. In particular, the processes relate to transitioning from olefin polymerizations utilizing metallocene catalyst systems to olefin polymerizations utilizing traditional Ziegler-Natta catalyst systems.
摘要翻译：在聚合催化剂体系之间转化的方法，优选彼此不相容的催化剂体系。特别地，该方法涉及使用茂金属催化剂体系从使用传统的齐格勒 - 纳塔催化剂体系的烯烃聚合转变为烯烃聚合。

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