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    • 37. 发明授权
    • Polymeric microspheres as degradable fluid loss additives in oilfield applications
    • 聚合微球作为油田应用中的可降解流体损失添加剂
    • US07703521B2
    • 2010-04-27
    • US12353810
    • 2009-01-14
    • Philip F. SullivanGary John TustinDon WilliamsonHemant K. Ladva
    • Philip F. SullivanGary John TustinDon WilliamsonHemant K. Ladva
    • E21B33/13E21B43/267
    • C09K8/512C09K8/516C09K8/685C09K8/887
    • Methods and apparatus for forming a fluid for use within in a subterranean formation including crosslinking a polymer along the surface of microspheres in a water-in-water emulsion and introducing the microspheres into the subterranean formation. Methods and apparatus for forming a fluid for use within in a subterranean formation including crosslinking a polymer along the surface of microspheres in a water in water emulsion, isolating the microspheres from the emulsion, and introducing the microspheres into the subterranean formation. Methods and apparatus for forming a fluid to treat a subterranean formation including introducing a crosslinkable polymer, partitioning agent, and crosslinker into a solvent, crosslinking the crosslinkable polymer, isolating beads of the crosslinkable polymer from the partitioning agent, introducing the beads into a fluid for treating a subterranean formation.
    • 用于形成在地下地层内使用的流体的方法和装置,包括在水包油乳液中沿着微球表面交联聚合物,并将微球引入地下地层。 用于形成在地层内使用的流体的方法和装置,包括在水包油乳液中沿着微球表面交联聚合物,从微乳液中分离出微球体,并将微球引入到地层中。 用于形成用于处理地下地层的流体的方法和装置,包括将可交联聚合物,分配剂和交联剂引入溶剂中,交联可交联聚合物,将可交联聚合物的珠子与分配剂隔离,将珠粒引入用于 处理地层。
    • 39. 发明授权
    • Degradable additive for viscoelastic surfactant based fluid systems
    • 用于粘弹性表面活性剂的流体系统的可降解添加剂
    • US07219731B2
    • 2007-05-22
    • US11159023
    • 2005-06-22
    • Philip F. SullivanJ Ernest BrownJesse C. LeeGolchehreh Salamat
    • Philip F. SullivanJ Ernest BrownJesse C. LeeGolchehreh Salamat
    • E21B43/04E21B43/22E21B43/267
    • C09K8/68C09K8/506C09K8/62C09K8/70C09K8/72C09K8/74C09K2208/26C09K2208/30Y10S507/902
    • A method is given for treating a subterranean formation penetrated by a wellbore with a viscosified fluid. The fluid contains a solid hydrolysable polyacid that upon dissolution and hydrolysis releases an acid that is a breaker for the viscosifying system. Suitable solid hydrolysable polyacids include polylactic acid and polyglycolic acid. The fluid also contains a pH control agent, present in an amount sufficient to neutralize any acid present in the solid hydrolysable polyacid before the injection and to neutralize any acid generated by the solid hydrolysable polyacid during the injection, so that the acid breaker is not available to break the fluid during the injection. In one embodiment the viscosifier is a viscoelastic surfactant fluid system and the solid hydrolysable polyacid is of a size selected to be a fluid loss additive, for example in fracturing or gravel packing. In another embodiment, the solid hydrolysable polyacid is used in particles sufficiently small that they enter the pores of the formation. In either case, the viscosifier is broken after the solid releases more acid than can be neutralized by the pH control agent.
    • 给出了用增稠液体处理井眼渗透的地层的方法。 流体包含固体可水解的多酸,其在溶解和水解时释放酸,该酸是用于增粘体系的断裂剂。 合适的固体可水解的多元酸包括聚乳酸和聚乙醇酸。 流体还含有pH控制剂,其量足以中和注射前固体可水解的多元酸中存在的任何酸,并且在注射期间中和由固体可水解的多元酸产生的任何酸,使得酸破乳剂不可用 在注射期间打破流体。 在一个实施方案中,增粘剂是粘弹性表面活性剂流体系统,并且固体可水解的多元酸的尺寸被选择为流体损失添加剂,例如在压裂或砾石包装中。 在另一个实施方案中,固体可水解的多元酸以足够小的颗粒使用,使得它们进入地层的孔。 在任一种情况下,在固体释放比可以被pH控制剂中和的酸更多之后,粘稠剂被破坏。
    • 40. 发明授权
    • Controlling the stability of water in water emulsions
    • 控制水中乳液的稳定性
    • US09475974B2
    • 2016-10-25
    • US12869480
    • 2010-08-26
    • Philip F. Sullivan
    • Philip F. Sullivan
    • C09K8/68C09K8/588C09K8/08C09K8/12C09K8/508C09K8/514C09K8/575C09K8/88C09K8/90F17D1/17
    • C09K8/5758C09K8/08C09K8/12C09K8/508C09K8/514C09K8/68C09K8/88C09K8/90F17D1/17
    • This invention relates to compositions and methods of treating a surface in contact with a wellbore and/or a subterranean formation penetrated by a well bore, comprising forming a treatment composition comprising a rheological polymer, a partitioning agent, and a liquid medium; and injecting the treatment fluid into the well bore, wherein the treatment composition forms a heterogeneous mixture comprising a dispersed rheological polymer-rich phase and a partitioning agent-rich phase, and wherein the stability of the heterogeneous mixture is controlled by introducing a stability control agent. This invention relates to compositions and methods for forming a water in water emulsion, comprising a rheological polymer, a partitioning agent, a liquid medium; and a stability control agent, wherein the emulsion is a heterogeneous mixture comprising a dispersed rheological polymer-rich phase and a partitioning agent-rich phase.
    • 本发明涉及处理与由井眼渗透的井筒和/或地下地层接触的表面的组合物和方法,包括形成包含流变聚合物,分配剂和液体介质的处理组合物; 以及将所述处理流体注入所述井眼中,其中所述处理组合物形成包含分散的流变聚合物富集相和分配剂富相的不均匀混合物,并且其中所述非均相混合物的稳定性通过引入稳定性控制剂 。 本发明涉及用于形成水包油乳液的组合物和方法,其包含流变聚合物,分配剂,液体介质; 和稳定性控制剂,其中所述乳液是包含分散的流变聚合物富集相和富分配剂相的非均相混合物。