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31. 发明授权

US5496848A Process for the preparation of substituted difluorobenzo-1,3-dioxoles 失效
标题翻译：制备取代的二氟苯-1,3-二氧杂环戊烯的方法
公开(公告)号：US5496848A
公开(公告)日：1996-03-05
申请号：US440171
申请日：1995-05-12
申请人： Peter Ackermann , Hans-Ruedi Ka/ nel , Bruno Schaub
发明人： Peter Ackermann , Hans-Ruedi Ka/ nel , Bruno Schaub
IPC分类号： A61K31/33 , C07D317/06 , C07D317/46 , C07D405/04 , C07F1/00 , C07F1/02 , C07F3/00 , C07F5/02 , C07F7/08 , C07F7/10 , C07F19/00
CPC分类号： C07D405/04 , C07D317/46 , C07F1/00 , C07F1/02 , C07F19/00 , C07F3/00 , C07F5/025 , C07F7/0814 , C07F7/10 , Y02P20/55
摘要： The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being Cl or Br, or is --COOR.sup.2, --SIR.sup.2.sub.3 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkyl-phenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 fluoroalkyl, nitro or by cyano, or is C.sub.1 -C.sub.12 acyl, or wherein R.sup. 1 is a radical of formula II ##STR2## wherein R.sup.5 is --CN, --CF.sub.3, --COOR.sup.2, --CONH.sup.2, --CO--NHR.sup.2 or --CONR.sup.2.sub.2, R.sup.3 and R.sup.4 are a direct bond or each is H, or R.sup.3 is H and R.sup.4 independently has the meanings of R.sup.5, or R.sup.3 and R.sup.4 together are --CH.sub.2 --NR.sup.6 --CH.sub.2 --, --CH.sub.2 --NR.sup.6 --CO-- or --CO--NR.sup.6 --CO-- wherein R.sup.6 is the radical of a removable protecting group, or wherein further R.sup.1 is a radical of formula III ##STR3## Insecticides or fungicides can be prepared from the compounds of formula I.3-(2,2-difluorobenzodioxol-4-yl)-4-cyanopyrrole can be prepared by reacting 4-metallo-2,2-difluorobenzodioxole (III) with an unsaturated nitrile and then with a sulfonylmethyl isocyanide in a one-pot process. The compounds III are novel intermediates.
摘要翻译： 2,2-二氟苯-1,3-二氧杂环戊烯与（a）碱金属或碱金属化合物反应，然后（b）其中Z 1为离去基团的化合物R1-Z1或与醛反应生成化合物其中R 1是-OH，-SH，-CHO，-CN，-COOH，-B（OH）2，-COX，X是Cl或Br，或者是-COOR 2， - SIR 23或-B（OR 2）2，其中R 2是没有羟基的C 1 -C 12醇部分，其中R 1还是-C n H 2n NOR 2，n是1至4的整数，或未被取代的直链或支链C 1 -C 12羟基烷基被-F，-CN，C 1 -C 6烷氧基，苯基，氟苯基，C 1 -C 4烷氧基 - 苯基，C 1 -C 4烷硫基 - 苯基，C 1 -C 4烷基 - 苯基，C 1 -C 4氟烷基 - 苯基，硝基苯基或氰基苯基取代，或其中R 1 未被取代或被F，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基，C 1 -C 4氟烷基，硝基或氰基取代的苄醇或C 1 -C 12酰基，或其中R 1是式II的基团，（II）其中R5是-CN，-CF3，-COOR2，-CONH2，-CO-N HR 2或-CONR 22，R 3和R 4是直接键，或者各自是H，或者R 3是H，R 4独立地具有R 5的定义，或者R 3和R 4一起是-CH 2 -NR 6 -CH 2 - ， - CH 2 -NR 6 -CO - 或-CO-NR6-CO-，其中R6是可除去的保护基团的基团，或其中R 1是式III的基团。（III）杀虫剂或杀真菌剂可以由式I化合物制备。 - （2,2-二氟苯并二氧杂环戊烯-4-基）-4-氰基吡咯可以通过4-金属-2,2-二氟苯并间二氧杂环戊烯（III）与不饱和腈然后与一种磺酰基甲基异氰化物反应来制备。化合物III是新的中间体。

32. 发明授权

US5374639A Benzotriazolesulfonic acid derivatives as microbicides 失效
标题翻译：苯并三唑磺酸衍生物作为杀微生物剂
公开(公告)号：US5374639A
公开(公告)日：1994-12-20
申请号：US991677
申请日：1992-12-16
申请人： Marius Sutter , Urs Muller , Bernhard Hostettler , Peter Ackermann , Yasuchika Yamaguchi
发明人： Marius Sutter , Urs Muller , Bernhard Hostettler , Peter Ackermann , Yasuchika Yamaguchi
IPC分类号： A01N43/647 , C07D401/12 , C07D403/12 , C07D249/18
CPC分类号： C07D401/12 , A01N43/647 , C07D403/12
摘要： Benzotriazolesulfonic acid derivatives of formula I ##STR1## wherein R.sub.3 =R.sub.4 X and R.sub.4 is an unsaturated 6-membered heterocycle having a maximum of 2 nitrogen atoms, it being possible for the heterocycle to be substituted, and X is oxygen or sulfur, while R.sub.1 and R.sub.2 are as defined herein, are valuable microbicides. They can be used in plant protection in the form of suitable compositions, for example for controlling fungal diseases.
摘要翻译：式I的苯并三唑磺酸衍生物其中R 3 = R 4 X和R 4是具有最多2个氮原子的不饱和6元杂环，杂环可以被取代，X是氧或硫，而R1和R2如本文所定义，是有价值的杀微生物剂。它们可以以合适的组合物的形式用于植物保护，例如用于防治真菌疾病。

33. 发明授权

US5036084A Certain 1-(3-pyridyl)-2-phenoxy-alkanones having anti-microbial activity 失效
标题翻译：某些具有抗微生物活性的1-（3-吡啶基）-2-苯氧基 - 烷酮
公开(公告)号：US5036084A
公开(公告)日：1991-07-30
申请号：US456057
申请日：1989-12-21
申请人： Hans Tobler , Peter Ackermann , Robert Nyfeler
发明人： Hans Tobler , Peter Ackermann , Robert Nyfeler
IPC分类号： C07D213/28 , A01N43/40 , A01P3/00 , C07D213/30 , C07D213/50
CPC分类号： C07D213/30 , A01N43/40 , C07D213/50
摘要： Pyridinyl derivatives of formula I ##STR1## wherein R.sub.1 to R.sub.5 are each independently hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 haloalkoxy, cyano, C.sub.1 -C.sub.6 alkoxycarbonyl or phenyl,R.sub.6 and R.sub.7 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl, or phenyl or benzyl, each of which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 haloalkoxy,R.sub.8 is ##STR2## and R.sub.9 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, or benzyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 haloalkoxy, or R.sub.9 is an acyl radical.The preparation of these compounds and the use thereof in pest control, in particular against bacteria and fungi, are described.
摘要翻译：式I的吡啶基衍生物其中R 1至R 5各自独立地为氢，卤素，C 1 -C 6烷基，C 1 -C 6卤代烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷氧基，氰基，C 1 -C 6烷氧基羰基或苯基，R 6和R 7为 C 1 -C 6烷基，C 1 -C 6卤代烷氧基，C 1 -C 6烷氧基或C 1 -C 6卤代烷氧基取代的苯基或苄基， R 8是氢，C 1 -C 6烷基，C 3 -C 6链烯基，C 3 -C 6炔基或苄基，其未被取代或被卤素，C 1 -C 6烷基，C 1 -C 6卤代烷基，C 1 -C 6烷氧基或C 1 -C 6卤代烷氧基或R 9 是酰基。描述了这些化合物的制备及其在害虫防治中的用途，特别是针对细菌和真菌的用途。

34. 发明授权

US4798912A Substituted phenoxybenzyl-(Dihalodimethylcyclopropyl-methyl)ethers 失效
标题翻译：取代的苯氧基苄基 - （二卤代二甲基环丙基 - 甲基）醚
公开(公告)号：US4798912A
公开(公告)日：1989-01-17
申请号：US118816
申请日：1987-11-09
申请人： Laurenz Gsell , Peter Ackermann
发明人： Laurenz Gsell , Peter Ackermann
IPC分类号： A01N31/14 , A01N31/16 , C07C43/29 , C07C43/225
CPC分类号： C07C43/29 , A01N31/14 , A01N31/16
摘要： Novel substituted phenoxybenzyldihalodimethyl-cyclopropylmethyl ethers of the formula ##STR1## in which X.sub.1 and X.sub.2 each independently of the other represents fluorine, chlorine or bromine;R.sub.1 represents hydrogen or flourine; andR.sub.2 represents hydrogen, fluorine, chlorine, bromine, methyl, trifluoromethyl or methoxy, and, if X.sub.1 and X.sub.2 have different meanings, the optical isomers of the compound of the formula I; processes for the manufacture of those compounds, and compositions containing them for use in pest control, especially for the control of insects, especially the larval stages thereof, that attack plants and animals, and of phytopathogenic fungi. The novel compounds exhibit good activity especially against insects that damage plants in rice crops.
摘要翻译：新颖的取代苯基苄基二卤代二甲基 - 环丙基甲基醚，其中X1和X2各自独立地表示氟，氯或溴; R1代表氢或氟; 并且R 2表示氢，氟，氯，溴，甲基，三氟甲基或甲氧基，并且如果X1和X2具有不同含义，则式I化合物的光学异构体; 用于制造这些化合物的方法，以及含有它们的用于病虫害防治的组合物，特别是用于防治攻击植物和动物的昆虫，特别是幼虫阶段以及植物病原性真菌的组合物。新型化合物表现出良好的活性，特别是对于损害水稻作物中的植物的昆虫。

35. 发明授权

US4611004A 3-phenoxybenzyl-(2-phenyl-2,2-alkylene-ethyl) ethers and -thioethers, and their use for controlling pests 失效
标题翻译： 3-苯氧基苄基 - （2-苯基-2,2-亚烷基 - 乙基）醚和硫醚及其用于防治害虫的用途
公开(公告)号：US4611004A
公开(公告)日：1986-09-09
申请号：US716423
申请日：1985-03-27
申请人： Peter Ackermann , Laurenz Gsell
发明人： Peter Ackermann , Laurenz Gsell
IPC分类号： C07C43/263 , A01N31/14 , A01N37/34 , A01N37/38 , A01N43/30 , C07C41/00 , C07C43/267 , C07C43/29 , C07C67/00 , C07C253/00 , C07C255/37 , C07C255/53 , C07C313/00 , C07C323/16 , C07C323/52
CPC分类号： C07C255/00 , A01N31/14 , A01N37/38 , C07C43/267 , C07C43/29
摘要： 3-Phenoxybenzyl-(2-phenyl-2,2-alkylene-ethyl) ethers and -thioethers of the formula ##STR1## wherein A is oxygen or sulfur,R.sub.1 is hydrogen, methyl, cyano or ethinyl,R.sub.2 and R.sub.3 are hydrogen, halogen or C.sub.1 -C.sub.5 -alkyl,n is 2 to 4,X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.5 -alkoxy or C.sub.1 -C.sub.5 -haloalkoxy,X.sub.2 is hydrogen, halogen or C.sub.1 -C.sub.5 -alkyl, or together with X.sub.1 in the adjacent position is methylenedioxy, andX.sub.3 and X.sub.4 are each hydrogen or halogen.A process for producing these compounds and their use for controlling pests are described.
摘要翻译：式（I）的3-苯氧基苄基 - （2-苯基-2,2-亚烷基 - 乙基）醚和 - 硫醚其中A是氧或硫，R1是氢，甲基，氰基或乙炔基，R2和R3 卤素，C 1 -C 5 - 烷氧基或C 1 -C 5 - 卤代烷氧基，X 2是氢，卤素，C 1 -C 5 - 烷氧基，，卤素或C 1 -C 5 - 烷基，或与相邻位置的X1一起为亚甲二氧基，并且X 3和X 4各自为氢或卤素。描述了这些化合物的制备方法及其用于防治害虫的用途。

36. 发明授权

US4335057A 4-(2',2,2'-Trihalogenoethyl)-cyclobutane-1-sulfonic acid salts with optically active bases 失效
标题翻译： 4-（2'，2,2'-三卤代乙基） - 环丁烷-1-磺酸盐与光学活性碱
公开(公告)号：US4335057A
公开(公告)日：1982-06-15
申请号：US219803
申请日：1980-12-24
申请人： John G. Dingwall , Hans Greuter , Pierre Martin , Peter Ackermann , Laurenz Gsell
发明人： John G. Dingwall , Hans Greuter , Pierre Martin , Peter Ackermann , Laurenz Gsell
IPC分类号： C07C69/74 , C07B31/00 , C07B57/00 , C07C45/45 , C07C45/54 , C07C45/67 , C07C51/00 , C07C51/48 , C07C61/15 , C07C61/40 , C07C67/00 , C07C69/635 , C07C69/743 , C07C253/00 , C07C255/38 , C07C255/39 , C07C255/53 , C07C301/00 , C07C303/10 , C07C303/32 , C07C309/25 , C07C313/00 , C07C321/24 , C07D307/42 , C07D307/45 , C07D333/04 , C07D333/16 , C07D333/32 , C07C143/20
CPC分类号： C07C45/67 , C07C309/00 , C07C45/45 , C07C45/54 , C07C51/00
摘要： There is described a new process for the preparation of optically active 2-(2',2'-dihalogenovinyl)-cyclopropane-1-carboxylic acids substituted in the 3 position, and derivatives thereof. A racemate of certain cyclobutanones is reacted with a sulfurous acid salt of an optically active base to obtain a mixture of diastereomeric 4-(2',2',2'-trihalogenoethyl)-cyclobutane-2-sulfonic acid salts; this mixture is then separated into the pure diastereomeric sulfonic acid salts. Either the pure diastereomeric sulfonic acid salts are converted directly to the desired optically active products, or the optically active cyclobutanones obtained from the pure diastereomeric sulfonic acids salts by decomposition are converted, in the presence of a base, to the desired product. Optionally, the product, optically active 2-(2',2'-dihalogenovinyl)-cyclopropane-2-carboxylic acids can be converted to their 1',2'-dibromo derivatives.
摘要翻译：描述了制备在3位上被取代的光学活性的2-（2'，2'-二卤代乙烯基） - 环丙烷-1-羧酸及其衍生物的新方法。某些环丁酮的外消旋物与光学活性碱的亚硫酸盐反应，得到非对映异构体4-（2'，2'，2'-三卤代乙基） - 环丁烷-2-磺酸盐的混合物; 然后将该混合物分离成纯的非对映体磺酸盐。将纯的非对映异构体磺酸盐直接转化为所需的光学活性产物，或通过分解从纯非对映异构体磺酸盐获得的光学活性环丁酮在碱的存在下转化为所需产物。任选地，产物光学活性的2-（2'，2'-二卤代乙烯基） - 环丙烷-2-羧酸可以转化为它们的1'，2'-二溴衍生物。

37. 发明授权

US4265897A N-N-Dimethyl-1-(1'-methyl-2'-methoxyethyl)-1,2,4-triazolylcarbamates 失效
标题翻译： N-N-二甲基-1-（1'-甲基-2'-甲氧基乙基）-1,2,4-三唑基氨基甲酸酯
公开(公告)号：US4265897A
公开(公告)日：1981-05-05
申请号：US91631
申请日：1979-11-05
申请人： Laurenz Gsell , Peter Ackermann , Rudolf Wehrli
发明人： Laurenz Gsell , Peter Ackermann , Rudolf Wehrli
IPC分类号： A01N47/18 , A01N57/00 , C07D249/12 , A01N43/64
CPC分类号： C07D249/12 , A01N47/18
摘要： Triazolylcarbamates of the formula ##STR1## wherein R.sub.1 is hydrogen, chlorine, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio, processes for producing them, and their use for combating insect pests.
摘要翻译：其中R 1为氢，氯，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或C 1 -C 4烷硫基的三唑基氨基甲酸酯，其制备方法及其用于防治害虫。

38. 发明授权

US4219564A Vinylcyclopropanecarboxylic acid-3-phenoxy-.alpha.-vinylbenzyl esters, processes for producing them, and their use in combating pests 失效
标题翻译：乙烯基环丙烷羧酸-3-苯氧基-α-乙烯基苄基酯，其制备方法及其在防治害虫中的应用
公开(公告)号：US4219564A
公开(公告)日：1980-08-26
申请号：US51080
申请日：1979-06-22
申请人： Jozef Drabek , Peter Ackermann , Saleem Farooq , Laurenz Gsell , Odd Kristiansen
发明人： Jozef Drabek , Peter Ackermann , Saleem Farooq , Laurenz Gsell , Odd Kristiansen
IPC分类号： C07C69/747 , A01N53/00 , A01N53/08 , C07C41/30 , C07C43/23 , C07C43/29 , C07C43/295 , C07C69/74 , A01N9/30
CPC分类号： A01N53/00 , C07C41/22 , C07C41/24 , C07C41/30 , C07C69/743 , C07C2101/02
摘要： Vinylcyclopropanecarboxylic acid-3-phenoxy-.alpha.-vinylbenzyl esters of the formula ##STR1## in which X.sub.1 is fluorine, chlorine or bromine,X.sub.2 is hydrogen or bromine, andY is hydrogen or methyl,processes for producing them, and their use in combating pests.
摘要翻译：其中X1是氟，氯或溴，X2是氢或溴，Y是氢或甲基的式“IMAGE”的乙烯基环丙烷羧酸-3-苯氧基-α-乙烯基苄基酯，它们用于制备它们的用途害虫

39. 发明授权

US07205301B2 Microbiocidal N-phenyl-n-[4-(4-pyridyl)-2-pyrimidin-2-yl]-amine derivatives 失效
标题翻译：杀微生物N-苯基 - 正 - [4-（4-吡啶基）-2-嘧啶-2-基] - 胺衍生物
公开(公告)号：US07205301B2
公开(公告)日：2007-04-17
申请号：US10497974
申请日：2002-12-05
申请人： Peter Ackermann , Daniel Stierli , Pierre Marcel Joseph Jung , Peter Maienfisch , Fredrik Emil Malcolm Cederbaum , Jean-Frederic Wenger
发明人： Peter Ackermann , Daniel Stierli , Pierre Marcel Joseph Jung , Peter Maienfisch , Fredrik Emil Malcolm Cederbaum , Jean-Frederic Wenger
IPC分类号： C07D401/14 , A01N43/56 , A01N43/58
CPC分类号： C07D401/14 , A01N43/56 , A01N43/58 , C07D401/04 , C07D405/14 , C07D409/14 , C07D417/14
摘要： Fungicidal compounds of Formula (I) wherein m is 0, 1, 2 or 3; n and p are independently of each other 0 or 1; R1 is halogen, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted alkenyloxy, optionally substituted alkynyloxy, optionally substituted thioalkyl optionally substituted aryl, COOR11, CONR12R13, S(O)qR14, SO2NR15R16 or NR15aR16a; q is 1 or 2; and R2, R2a, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, R16, R15a, R16a, are specified organic groups or a salt thereof; their preparation and compositions containing them
摘要翻译：式（I）的杀真菌化合物，其中m为0,1,2或3; n和p彼此独立地为0或1; R 1是卤素，任选取代的烷基，任选取代的烷氧基，任选取代的烯氧基，任选取代的炔氧基，任选取代的硫代烷基任选取代的芳基，COOR 11，CONR 12 R 13，S（O）q R 14，SO 2 NR 15 R 16或/或NR 15 R 16 16a; q为1或2; 和R 2，R 2a，R 3，R 4，R 5， R 6，R 7，R 8，R 9，R 10， R 11，R 12，R 13，R 14，R 15， R 16，R 15a，R 16a是指定的有机基团或其盐; 它们的制备和含有它们的组合物

40. 发明授权

US07074787B2 Microbiocidal N-phenyl-N-[4-(4-pyridyl-2-pyrimidin-2-yl]-amine derivatives 失效
公开(公告)号：US07074787B2
公开(公告)日：2006-07-11
申请号：US10451930
申请日：2001-12-20
申请人： Martin Eberle , Hugo Ziegler , Fredrik Cederbaum , Peter Ackermann , Anita Schnyder
发明人： Martin Eberle , Hugo Ziegler , Fredrik Cederbaum , Peter Ackermann , Anita Schnyder
IPC分类号： C07D401/04 , C07D413/04 , A01N43/54
CPC分类号： C07D401/04 , C07D401/14 , C07D413/14 , C07D417/14 , C07D419/14
摘要： The invention relates to novel N-phenyl-4-(4-pyridyl)-2-pyrimidineamine derivatives of the general formula (I) wherein the sum of (m+p) together is 0, 1, 2 or 3; n and q are independently of each other 0 or 1, and the sum of (m+p+q) together is 1, 2, 3 or 4; R1 is hydrogen, halogen, alkoxy, haloalkyl, haloalkoxy or alkyl; R2 is hydrogen, C1–C6-alkyl, C1–C6-haloalkyl or C1–C6-alkoxy; R2A is hydrogen, C1–C6-alkyl, C3–C4-alkenyl or C3–C4-alkynyl; each of R3, R4, R5 and R6 is, independently of the others, hydrogen, C1–C6-alkyl, C1–C6-haloalkyl, hydroxy-C1–C6-alkyl or C1–C6-alkoxy-C1–C6-alkyl, or the ring members CR3R4 or CR5R6 or CR2R2A are independently of each other a carbonyl group (C═O) or a group C═S; X is C═O, C═S, S═O or O═S═O; Y is O, S, C═O, CH2, —N(R8)—, —O—N(R8)—, —N(R8)—O— or NH—; R7 is hydrogen, C1–C4-alkyl, C3–C4-alkenyl, C3–C4-alkynyl, —CH2OR8, CH2SR8, —C(O)R8, —C(O)OR8, SO2R8, SOR8 or SR8; and R8 is C1–C8-alkyl, C1–C8-alkoxyalkyl, C1–C8 haloalkyl or phenylC1–C2-alkyl wherein the phenyl may be substituted by up to three groups selected from halo or C1–C4-alkyl; or a salt thereof. The invention also relates to the preparation of the compounds and to agrochemical compositions comprising at least one of those compounds as active ingredient as well as the preparation of the said compositions and to the use of the compounds or of the compositions in controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

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