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31. 发明授权

US08501872B2 Curable fluoroelastomer compositions 有权
标题翻译：可固化的含氟弹性体组合物
公开(公告)号：US08501872B2
公开(公告)日：2013-08-06
申请号：US13611083
申请日：2012-09-12
申请人： Ming-Hong Hung , Bruno Ameduri , Guillaume Tillet
发明人： Ming-Hong Hung , Bruno Ameduri , Guillaume Tillet
IPC分类号： C08F8/00 , C08F214/00
CPC分类号： C08L27/16 , C08L2205/025 , C08L71/02
摘要： This invention relates to curable fluoroelastomer compositions comprising a) fluoroelastomers having either nitrile, alkyne or azide cure sites and b) fluorinated curatives containing diazide, dinitrile or dialkyne groups for reacting with cure sites on the fluoroelastomer. Fluoroelastomers having azide cure sites form crosslinks with curatives having dinitrile or dialkyne groups. Fluoroelastomers having nitrile or alkyne cure sites form crosslinks with curatives having diazide groups.
摘要翻译：本发明涉及可固化的含氟弹性体组合物，其包含a）具有腈，炔或叠氮化物固化位点的含氟弹性体和b）含有重氮化物，二腈或二炔基的氟化固化剂，用于与含氟弹性体上的固化位点反应。具有叠氮化物固化位点的氟弹性体与具有二腈或二炔基的固化剂形成交联。具有腈或炔炔固化位点的氟弹性体与具有二叠氮基的固化剂形成交联。

32. 发明申请

US20110257423A1 PROCESS FOR PRODUCING FLUOROELASTOMERS 审中-公开
标题翻译：生产荧光体的方法
公开(公告)号：US20110257423A1
公开(公告)日：2011-10-20
申请号：US13169329
申请日：2011-06-27
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C07F9/09
CPC分类号： C08F14/18 , C07F9/091 , C08F2/26 , C08F2/20
摘要： An emulsion polymerization process for the production of fluoroelastomers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X—Rf—(CH2)n—O—P(O)(OM)2, wherein n=1 or 2, X=H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
摘要翻译：公开了用于生产含氟弹性体的乳液聚合方法，其中使用至少一种含氟表面活性剂作为分散剂，所述含氟表面活性剂是式X-Rf-（CH2）n-O-P（O）（OM）2的氟代烷基磷酸酯其中n = 1或2，X = H或F，M =一价阳离子，Rf为C4-C6氟代烷基或氟代烷氧基。任选地，在聚合中可以使用第二分散剂，所述第二试剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚，磷酸及其盐。

33. 发明申请

US20110136999A1 PROCESS FOR PREPARATION OF FLUOROSILICON POLYMER 有权
标题翻译：制备氟聚硅氧烷聚合物的方法
公开(公告)号：US20110136999A1
公开(公告)日：2011-06-09
申请号：US12632982
申请日：2009-12-08
申请人： Ming-Hong Hung , Bruno Ameduri
发明人： Ming-Hong Hung , Bruno Ameduri
IPC分类号： C08F16/24 , C08F4/00
CPC分类号： C08F214/18 , C08F8/00 , C08F8/04 , C08F8/26 , C08F8/42 , C08F214/184 , C08F214/22 , C08F214/222 , C08F216/1408
摘要： Fluorosilicon polymers are disclosed that are prepared by a process comprising reacting a) iodinated oligomers having copolymerized units of perfluoro(methyl vinyl ether) and vinylidene fluoride or tetrafluoroethylene that contain 40-90 mole percent copolymerized units of vinylidene fluoride or tetrafluoroethylene and 10-60 mole percent copolymerized units of perfluoro(methyl vinyl ether), said oligomers having two functional endgroups and having a number average molecular weight between 1000 and 25,000 with b) a methoxyvinyl silane or an ethoxyvinyl silane to form a silicon-containing polymeric adduct that is further reacted with an acid to form a crosslinked fluorinated polymer.
摘要翻译：公开了通过以下方法制备的氟硅聚合物，该方法包括使a）具有全氟（甲基乙烯基醚）共聚单元和含偏氟乙烯或四氟乙烯的共聚单元40-90摩尔的偏二氟乙烯或四氟乙烯的碘化低聚物和10-60摩尔百分比的全氟（甲基乙烯基醚）共聚单元，所述低聚物具有两个官能端基，数均分子量在1000和25,000之间，b）甲氧基乙烯基硅烷或乙氧基乙烯基硅烷，以形成进一步反应的含硅聚合物加合物与酸形成交联的氟化聚合物。

34. 发明申请

US20110015359A1 Crosslinked Fluoropolymer Networks 失效
标题翻译：交联氟聚合物网络
公开(公告)号：US20110015359A1
公开(公告)日：2011-01-20
申请号：US12504320
申请日：2009-07-16
申请人： Ming-Hong Hung , Bruno Ameduri , Georgi Kostov
发明人： Ming-Hong Hung , Bruno Ameduri , Georgi Kostov
IPC分类号： C08F16/24 , C08F14/18 , C08F14/28 , C08F14/22
CPC分类号： C08F214/184 , C08F8/00 , C08F8/02 , C08F8/04 , C08F8/12 , C08F8/14 , C08F8/20 , C08F214/18 , C08F299/00 , C08F214/222
摘要： Disclosed herein is a crosslinked fluoropolymer network formed by the free radical initiated crosslinking of a diacrylate fluoropolymer The diacrylate copolymer is of formula CH2═CR′COO—(CH2)n—R—(CH2)n—OOCR′═CH2, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R′ is H or —CH3, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons. The source of the free radicals may be a photoinitiator or an organic peroxide.
摘要翻译：本文公开了通过二丙烯酸酯含氟聚合物的自由基引发交联形成的交联的氟聚合物网络。二丙烯酸酯共聚物具有式CH 2 = CR'COO-（CH 2）n -R-（CH 2）n -OOCR' = CH 2，其中R为选自i）包含偏二氟乙烯和全氟（甲基乙烯基醚）的共聚单元的低聚物，ii）包含偏二氟乙烯和六氟丙烯的共聚单元的低聚物，iii）包含四氟乙烯和全氟（甲基）丙烯的共聚单元的低聚物乙烯基醚），和iv）包含四氟乙烯和烃烯烃的共聚单元的低聚物，R'是H或-CH 3，n是1-4，并且其中所述低聚物的数均分子量为1000-25,000道尔顿。自由基的来源可以是光引发剂或有机过氧化物。

35. 发明申请

US20100113691A1 FLUORO OLEFIN POLYMERIZATION 审中-公开
标题翻译：氟聚烯烃聚合
公开(公告)号：US20100113691A1
公开(公告)日：2010-05-06
申请号：US12265942
申请日：2008-11-06
申请人： Sheng Peng , Ming-Hong Hung , Christopher P. Junk
发明人： Sheng Peng , Ming-Hong Hung , Christopher P. Junk
IPC分类号： C08L67/00
CPC分类号： C08F14/18 , C08F2/20
摘要： A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, wherein said polymerization agent is a compound of the formula (I): Rf—O—(CF2)n—COOX (I) wherein Rf is CF3CF2CF2—, n is an integer equal to 3, 5 or 7, and X is H, NH4, Li, Na or K.
摘要翻译：一种方法，其包括在含有引发剂和聚合剂的水性介质中聚合至少一种氟化单体以形成含氟聚合物颗粒的水分散体，其中所述聚合剂是式（I）的化合物：Rf-O-（CF 2）n -COOX（I）其中Rf是CF 3 CF 2 CF 2 - ，n是等于3,5或7的整数，X是H，NH 4，Li，Na或K.

36. 发明申请

US20090124774A1 FLUOROOLEFIN MONOMERS AND COPOLYMERS THEREOF 失效
标题翻译：氟橡胶单体及其共聚物
公开(公告)号：US20090124774A1
公开(公告)日：2009-05-14
申请号：US12250758
申请日：2008-10-14
申请人： Ming-Hong Hung , Sheng Peng
发明人： Ming-Hong Hung , Sheng Peng
IPC分类号： C08F16/24 , C07C43/15 , C07C51/29
CPC分类号： C08F214/186 , C07C41/22 , C07C41/24 , C07C41/30 , C07C43/17 , C07C51/285 , C07C59/135 , C07C43/123
摘要： Disclosed herein are novel fluoroolefins of formula Rf-O—(CF2CF2)n(CH2CF2)m—CH═CH2, wherein n is 1 or 2, m is 0 or 1 and Rf is a C1-C8 fluoroalkyl or fluoroalkoxy group. The fluoroolefins may be oxidized to manufacture fluorinated carboxylic acids. Also disclosed are fluoropolymers comprising copolymerized units of the fluoroolefins of the invention and at least one other fluoromonomer.
摘要翻译：本文公开了新的式Rf-O-（CF 2 CF 2）n（CH 2 CF 2）m -CH-CH 2的氟烯烃，其中n为1或2，m为0或1，R f为C 1 -C 8氟烷基或氟代烷氧基。氟烯烃可以被氧化以制造氟化羧酸。还公开了包含本发明的氟代烯烃的共聚单元和至少一种其它含氟单体的含氟聚合物。

37. 发明申请

US20090124755A1 PROCESS FOR PRODUCING FLUOROPOLYMERS 审中-公开
标题翻译：生产氟聚合物的方法
公开(公告)号：US20090124755A1
公开(公告)日：2009-05-14
申请号：US12255142
申请日：2008-10-21
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C08K5/42
CPC分类号： C08F14/26 , C08F214/262 , C08F2/22 , C08F2/26
摘要： An emulsion polymerization process for the production of fluoropolymers that contain polymerized units of tetrafluoroethylene is disclosed wherein a perfluoroaliphatic sulfinate is employed as dispersant.
摘要翻译：公开了一种用于制备含有四氟乙烯聚合单元的含氟聚合物的乳液聚合方法，其中使用全氟脂族亚磺酸酯作为分散剂。

38. 发明申请

US20090105435A1 DIFUNCTIONAL OLIGOMERS OF PERFLUORO(METHYL VINYL ETHER) 有权
标题翻译：全氟代（甲基乙烯基醚）的二官能
公开(公告)号：US20090105435A1
公开(公告)日：2009-04-23
申请号：US12209302
申请日：2008-09-12
申请人： Ming-Hong Hung , Bruno Ameduri , Cyrille Andre Boyer
发明人： Ming-Hong Hung , Bruno Ameduri , Cyrille Andre Boyer
IPC分类号： C08F16/24 , C08F214/18
CPC分类号： C08F214/18 , C08F214/184 , C08F214/222 , C08F214/262
摘要： Oligomers of perfluoro(methyl vinyl ether) with vinylidene fluoride or tetrafluoroethylene are disclosed that contain 40-90 mole percent copolymerized units of vinylidene fluoride or tetrafluoroethylene and 10-60 mole percent copolymerized units of perfluoro(methyl vinyl ether), said oligomers having two functional endgroups and having a number average molecular weight between 1000 and 25,000.
摘要翻译：公开了具有偏氟乙烯或四氟乙烯的全氟（甲基乙烯基醚）的低聚物，其含有40-90摩尔％的偏二氟乙烯或四氟乙烯的共聚单元和10-60摩尔％的全氟（甲基乙烯基醚）共聚单元，所述低聚物具有两个官能并且数均分子量在1000至25,000之间。

39. 发明申请

US20070088143A1 Alpha, alpha-dihydrofluorovinyl ethers, homopolymers and copolymers thereof 审中-公开
标题翻译： α，α-二氢氟乙烯基醚，其均聚物和共聚物
公开(公告)号：US20070088143A1
公开(公告)日：2007-04-19
申请号：US11498907
申请日：2006-08-03
申请人： Ming-Hong Hung , Phan Tang
发明人： Ming-Hong Hung , Phan Tang
IPC分类号： C08F16/24
CPC分类号： C07C43/17 , C08F14/18 , C08F2/24
摘要： Disclosed herein are novel α,α-dihydrofluorovinyl ethers, homopolymers thereof and copolymers containing more than 22 mole percent copolymerized units of said ether. The ethers have the general formula Rf—[CH2]n-OCF═CF2, wherein n is 1 or 2, and Rf is selected from the group consisting of a perfluoroalkyl group, a perfluoroalkoxy group, a fluoroalkyl group and a fluoroalkoxy group.
摘要翻译：本文公开了新的α，α-二氢氟乙烯基醚，其均聚物和含有超过22摩尔％的所述醚的共聚单元的共聚物。醚具有以下通式：其中n为0或1，其中n为1或2，为1或2，且R f选自全氟烷基，全氟烷氧基，氟代烷基和氟代烷氧基。

40. 发明申请

US20060135716A1 Fluoroelastomers having low glass transition temperature 审中-公开
标题翻译：具有低玻璃化转变温度的氟弹性体
公开(公告)号：US20060135716A1
公开(公告)日：2006-06-22
申请号：US11280024
申请日：2005-11-16
申请人： Ming-Hong Hung , Phan Tang
发明人： Ming-Hong Hung , Phan Tang
IPC分类号： C08F216/12
CPC分类号： C08F214/184 , C08F214/222 , C08F214/262
摘要： Fluoroelastomers are disclosed which have a glass transition temperature less than −10° C. The elastomers contain copolymerized units of a perfluorovinylpolyether that is derived from a trimer or tetramer of hexafluoropropylene oxide.
摘要翻译：公开了玻璃化转变温度低于-10℃的氟弹性体。弹性体含有衍生自六氟环氧丙烷的三聚体或四聚体的全氟乙烯基聚醚的共聚单元。

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