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31. 发明授权

US07737202B2 Free-flowing filler composition and rubber composition containing same 有权
标题翻译：自由流动的填料组合物和含有它的橡胶组合物
公开(公告)号：US07737202B2
公开(公告)日：2010-06-15
申请号：US11647903
申请日：2006-12-28
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Prashant Joshi
IPC分类号： B60C1/00 , C08K5/24
CPC分类号： C08K5/548 , C08K3/013 , C08K3/04 , C08K3/36 , C08K9/06 , C08L21/00
摘要： This invention relates to novel free-flowing filler compositions containing silated cyclic core polysulfide coupling agents, and to a rubber containing the filler composition.
摘要翻译：本发明涉及含有硅烷化环状核多硫化物偶联剂的新型自由流动填料组合物和含有填料组合物的橡胶。

32. 发明申请

US20080161459A1 Silated cyclic core polysulfides, their preparation and use in filled elastomer compositions 有权
标题翻译：硅酸化的环状核心多硫化物，它们的制备和在填充的弹性体组合物中的用途
公开(公告)号：US20080161459A1
公开(公告)日：2008-07-03
申请号：US11647901
申请日：2006-12-28
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
IPC分类号： C08G77/06 , C08J3/05
CPC分类号： C08K5/548 , C07F7/1804
摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要翻译：本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。这些新型硅烷可以带有机和无机填料。本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

33. 发明授权

US06608125B2 Blocked mercaptosilane coupling agents for filled rubbers 有权
标题翻译：用于填充橡胶的封闭的巯基硅烷偶联剂
公开(公告)号：US06608125B2
公开(公告)日：2003-08-19
申请号：US09986514
申请日：2001-11-09
申请人： Richard W. Cruse , Robert J. Pickwell , Keith J. Weller , Eric R. Pohl
发明人： Richard W. Cruse , Robert J. Pickwell , Keith J. Weller , Eric R. Pohl
IPC分类号： C07F718
CPC分类号： C07F9/4075 , C07F7/1804 , C07F9/1651 , C08J3/203 , C08J2321/00 , C08K3/013 , C08K3/36 , C08K5/0025 , C08K5/5406 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A blocked mercaptosilane of the structure: G—C(═O)—S—CH2CH2CH2SiX3 is disclosed wherein each X is an independently selected RO— group wherein each R is independently selected from the group consisting of hydrogen, alkyl that may or may not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, such moieties other than hydrogen having from 1 to 18 carbon atoms, and G is a monovalent alkyl of from 2 to 12 carbon atoms.
摘要翻译：公开了其中每个X是独立选择的RO-基团的封端的巯基硅烷，其中每个R独立地选自氢，可以含有或可以不含有不饱和键的烷基，烯基，芳基和芳烷基，除了具有1至18个碳原子的氢以外的这些部分，G是2至12个碳原子的一价烷基。

34. 发明授权

US06359046B1 Hydrocarbon core polysulfide silane coupling agents for filled elastomer compositions 有权
标题翻译：用于填充弹性体组合物的烃芯聚硫硅烷偶联剂
公开(公告)号：US06359046B1
公开(公告)日：2002-03-19
申请号：US09657934
申请日：2000-09-08
申请人： Richard W. Cruse
发明人： Richard W. Cruse
IPC分类号： C08K334
CPC分类号： C08K5/548 , C07F7/1804 , C08L21/00
摘要： The present invention discloses novel hydrocarbon core polysulfide silanes and methods of preparing the hydrocarbon core polysulfide silanes. Preferably, the silanes of the present invention contain assemblies of a single unit of a hydrolyzable silane group, tethered to one end of a chain of sulfur atoms, and several of these assemblies are bound to a common central hydrophobic core via the other end of the sulfur atoms chain. The hydrocarbon core polysulfide silanes may be incorporated into filled elastomeric compositions providing improved dispersiblity of the filler materials. Mineral fillers may be pre-treated with the hydrocarbon core polysulfide silanes prior to use in elastomeric compositions.
摘要翻译：本发明公开了新型烃核聚硫硅烷及其制备方法。优选地，本发明的硅烷含有与水解性硅烷基团的单一单元的组合，其结合到硫原子链的一端，并且这些组合中的几个通过另一端结合到共同的中心疏水性核心硫原子链。烃核心多硫化硅烷可以加入到填充的弹性体组合物中，从而提供填料材料的改进的分散性。矿物填料可以在用于弹性体组合物之前用烃核心多硫化硅烷预处理。

35. 发明授权

US08895770B2 Selective non-precious metal-catalyzed mono-hydrosilylation polyunsaturated compounds 有权
标题翻译：选择性非贵金属催化单氢化硅烷化多不饱和化合物
公开(公告)号：US08895770B2
公开(公告)日：2014-11-25
申请号：US13302506
申请日：2011-11-22
申请人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G. P. Delis , Susan A. Nye , Paul J. Chirik
发明人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G. P. Delis , Susan A. Nye , Paul J. Chirik
IPC分类号： C07F7/08 , C07F7/18 , C07F15/02 , B01J31/18
CPC分类号： C07F15/025 , B01J31/1805
摘要： Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.
摘要翻译：本文公开了多不饱和化合物的单氢化硅烷化衍生物的选择性合成，例如使用非贵金属的吡啶二亚胺和三联吡啶络合物作为选择性氢化硅烷化催化剂的三乙烯基环己烷。

36. 发明授权

US08383850B2 Blocked mercaptosilane coupling agents, process for making and uses in rubber 有权
标题翻译：封闭的巯基硅烷偶联剂，橡胶制造和使用过程
公开(公告)号：US08383850B2
公开(公告)日：2013-02-26
申请号：US12820198
申请日：2010-06-22
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Tiberiu L. Simandan , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Tiberiu L. Simandan , Prashant Joshi
IPC分类号： C07F7/02 , C07F7/04 , C07F7/08
CPC分类号： C08K5/548 , C07F7/1804 , Y02T10/862 , C08L21/00
摘要： The invention relates to sulfur silane coupling agents containing multiple blocked mercapto groups which are in a state of reduced activity until activated. The coupling agents are advantageously used in rubber formulations, for example, for fabricating tires with low rolling resistance.
摘要翻译：本发明涉及含有多个封闭的巯基的硫硅烷偶联剂，它们在活化之前处于活性降低的状态。偶联剂有利地用于橡胶制剂中，例如用于制造具有低滚动阻力的轮胎。

37. 发明申请

US20130018212A1 TRIVINYLCYCLOHEXANE STEREOISOMERIC COMPOSITIONS AND METHODS FOR PREPARING SAME 有权
标题翻译： TRIVINYLCYCLOHEXANE STEREOISOMERIC COMPOSITIONS AND METHODS FOR PREPARTING SAME
公开(公告)号：US20130018212A1
公开(公告)日：2013-01-17
申请号：US13547703
申请日：2012-07-12
申请人： Richard W. Cruse , Vivek Khare , Jozef Kowalski , Wlodzimierz Stanczyk
发明人： Richard W. Cruse , Vivek Khare , Jozef Kowalski , Wlodzimierz Stanczyk
IPC分类号： C07C5/29 , C07C13/19
CPC分类号： C07C5/22 , C07B2200/07 , C07C5/29 , C07C2601/14 , C07C13/19
摘要： Disclosed herein is a process for making 1,2,4-trivinylcyclohexane that is enriched in a particular geometric isomer. The process involves the thermal isomerization of 1,5,9-cyclododecatriene at temperature between 400° C. and 600° C. followed by an equilibration of the resultant intermediate in either the gas phase or liquid phase at temperature between 180° C. and 375° C. and at pressures ranging from 0.101 kPa to 1.013 kPa. Also disclosed are 1,2,4-trivinylcyclohexane compositions that are enriched in a particular geometric isomer.
摘要翻译：本文公开了一种制备富含特定几何异构体的1,2,4-三乙烯基环己烷的方法。该方法涉及在400℃和600℃之间的温度下1,5,9-环十二碳三烯的热异构化，然后在180℃和180℃之间的温度下在气相或液相中平衡所得中间体 375℃，压力范围为0.101kPa至1.013kPa。还公开了富含特定几何异构体的1,2,4-三乙烯基环己烷组合物。

38. 发明授权

US08067491B2 Silated cyclic core polysulfides, their preparation and use in filled elastomer compositions 有权
标题翻译：硅酸化的环状核心多硫化物，它们的制备和在填充的弹性体组合物中的用途
公开(公告)号：US08067491B2
公开(公告)日：2011-11-29
申请号：US12706193
申请日：2010-02-16
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
IPC分类号： B60C1/00 , C08K5/24 , C08K3/34 , C08K3/04
CPC分类号： C08K5/548 , C07F7/1804
摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要翻译：本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。这些新型硅烷可以带有机和无机填料。本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

39. 发明授权

US07960460B2 Free-flowing filler composition and rubber composition containing same 有权
标题翻译：自由流动的填料组合物和含有它的橡胶组合物
公开(公告)号：US07960460B2
公开(公告)日：2011-06-14
申请号：US11648460
申请日：2006-12-28
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Prashant Joshi
IPC分类号： B60C1/00 , C08K5/24 , C08K3/34 , C08K3/04
CPC分类号： C08K5/548 , C08G75/14 , C08K3/04 , C08K3/36 , C08K5/372 , C08K5/5419 , C08L21/00 , C08L81/04 , Y02T10/862
摘要： This invention relates to novel free-flowing filler compositions containing sulfur-containing silane coupling agents, and to a rubber containing the filler composition.
摘要翻译：本发明涉及含有含硫硅烷偶联剂的新型自由流动填料组合物和含有填料组合物的橡胶。

40. 发明申请

US20100256273A1 Blocked Mercaptosilane Coupling Agents, Process for Making and Uses in Rubber 有权
标题翻译：封闭的巯基硅烷偶联剂，橡胶制造和使用过程
公开(公告)号：US20100256273A1
公开(公告)日：2010-10-07
申请号：US12820198
申请日：2010-06-22
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Tiberiu L. Simandan , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Tiberiu L. Simandan , Prashant Joshi
IPC分类号： C08K5/548 , C07F7/08 , C09K3/00
CPC分类号： C08K5/548 , C07F7/1804 , Y02T10/862 , C08L21/00
摘要： The invention relates to sulfur silane coupling agents containing multiple blocked mercapto groups which are in a state of reduced activity until activated. The coupling agents are advantageously used in rubber formulations, for example, for fabricating tires with low rolling resistance.
摘要翻译：本发明涉及含有多个封闭的巯基的硫硅烷偶联剂，它们在活化之前处于活性降低的状态。偶联剂有利地用于橡胶制剂中，例如用于制造具有低滚动阻力的轮胎。

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