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31. 发明授权

US3947555A Process for the reclamation of uncemented tungsten carbide powders 失效
标题翻译：无碳化钨粉的回收方法
公开(公告)号：US3947555A
公开(公告)日：1976-03-30
申请号：US408493
申请日：1973-10-23
申请人： Martin B. MacInnis , Clarence D. Vanderpool
发明人： Martin B. MacInnis , Clarence D. Vanderpool
IPC分类号： C01B32/949 , C01B31/34
CPC分类号： C01B31/34
摘要： A process suitable for recovering refractory metal carbide values from contaminated uncemented refractory metal carbides containing an iron group metal comprises heating an admixture of the powders of the contaminated refractory metal carbides and glacial acetic acid to the boiling point of the admixture for at least about 30 minutes, the weight of the powders divided by the weight of the acid is less than 5, thereafter removing the resulting carbide solids from the acid and washing the solids with sufficient water to remove the residual acid and drying the solids.
摘要翻译：适用于从含有铁族金属的被污染的未熔化的难熔金属碳化物中回收难熔金属碳化物值的方法包括将被污染的难熔金属碳化物和冰醋酸的粉末的混合物加热到混合物的沸点至少约30分钟，粉末的重量除以酸的重量小于5，此后从酸中除去所得的碳化物固体，并用足够的水洗涤固体以除去残留的酸并干燥固体。

32. 发明授权

US3947332A Preparation of heteropoly acids of tungsten and molybdenum 失效
标题翻译：钨和钼杂多酸的制备
公开(公告)号：US3947332A
公开(公告)日：1976-03-30
申请号：US477257
申请日：1974-06-07
申请人： Clarence D. Vanderpool , James C. Patton, Jr. , Tai K. Kim , Martin B. MacInnis
发明人： Clarence D. Vanderpool , James C. Patton, Jr. , Tai K. Kim , Martin B. MacInnis
IPC分类号： C01G39/00 , C01G41/00 , C25B1/22 , C25B1/24
CPC分类号： C25B1/22 , C01G39/003 , C01G39/006 , C01G41/00 , C01P2006/40 , C01P2006/80
摘要： Heteropoly acids of tungsten and molybdenum, such as tungstosilicic acid and molybdosilicic acid, are produced by first preparing an aqueous solution of an alkali metal tungstate or molybdate and an alkali metal salt of the hetero atom, and then removing the alkali metal cations from the solution by means of a cation exchange membrane under the influence of an applied electrical potential, whereby the reactive tungstate or molybdate and hetero species anions react to form the desired heteropoly acid.
摘要翻译：通过首先制备碱金属钨酸盐或钼酸盐的水溶液和杂原子的碱金属盐，然后从溶液中除去碱金属阳离子来制备钨和钼如钨硅酸和钼硅酸的杂多酸在施加的电势的影响下通过阳离子交换膜，由此反应性钨酸盐或钼酸盐和杂种阴离子反应形成所需的杂多酸。

33. 发明授权

US4718995A Recovery of tungsten, scandium, iron, and manganese from tungsten bearing material 失效
标题翻译：从钨轴承材料回收钨，钪，铁和锰
公开(公告)号：US4718995A
公开(公告)日：1988-01-12
申请号：US903940
申请日：1986-09-05
申请人： Clarence D. Vanderpool , Martin B. MacInnis , Judith A. Ladd
发明人： Clarence D. Vanderpool , Martin B. MacInnis , Judith A. Ladd
IPC分类号： C01F17/00 , C01G45/12 , C22B3/08 , C22B3/28 , C22B34/36 , C22B47/00 , C22B59/00
CPC分类号： C22B59/00 , C01F17/0006 , C01G45/1214 , C22B3/0012 , C22B3/08 , C22B34/36 , C22B47/00 , Y02P10/234
摘要： A process is disclosed for recovering scandium from a tungsten bearing material containing tungsten, iron manganese and scandium. The process involves digesting the material in an aqueous solution selected from the group consisting of a saturated solution of sulfur dioxide and a sulfuric acid solution containing an additional reducing agent at a sufficient temperature for a sufficient time to form a digestion solution containing the major portion of the scandium, iron, and manganese, and a digestion solid containing the major portion of the tungsten which is separated from the digestion solution. The major portion of the scandium is extracted from the digestion solution with an organic consisting essentially of an extracting agent which is essentially a mixture of alkyl primary amines which are present in an amount sufficient to extract the major portion of the scandium without extracting appreciable amounts of iron and manganese, and the balance an essentially aromatic solvent. After separation of the scandium containing organic from the raffinate, the organic is stripped of the scandium with hydrochloric acid which is then separated from the stripped organic. In an optional additional steps, iron is recovered by adjusting the pH of the raffinate to precipitate the major portion of the iron and manganese which is separated from the resulting liquor. A sufficient amount of chlorine gas is contacted with an aqueous slurry of the precipitate at a sufficient temperature for a sufficient time to form a manganese containing solution containing the major portion of the manganese which was in the precipitate and a solid containing the major portion of the iron which was in the precipitate.
摘要翻译：公开了从含有钨，铁锰和钪的含钨材料回收钪的方法。该方法包括在足够温度下将选自二氧化硫饱和溶液和含有另外还原剂的硫酸溶液的水溶液中的材料消化足够的时间以形成含有主要部分的消化液钪，铁和锰，以及含有与消解溶液分离的钨的主要部分的消解固体。钪的主要部分从消解溶液中提取，其中有机物基本上由提取剂提取，所述萃取剂基本上是烷基伯胺的混合物，其以足以提取主要部分钪的量存在，而不提取可观量的铁和锰，余量为基本芳香族溶剂。从萃余液中分离含钪的有机物后，用盐酸汽提有机物，然后与汽提的有机物分离。在可选的附加步骤中，通过调节萃余液的pH以回收从所得液体中分离的铁和锰的主要部分来回收铁。在足够的温度下，将足够量的氯气与沉淀物的含水浆料接触足够的时间以形成含有主要部分在沉淀中的锰的含锰溶液和含有主要部分的固体处于沉淀中的铁。

34. 发明授权

US4626280A Recovery of tungsten, scandium, iron, and manganese from tungsten bearing material 失效
标题翻译：从钨轴承材料回收钨，钪，铁和锰
公开(公告)号：US4626280A
公开(公告)日：1986-12-02
申请号：US838482
申请日：1986-01-24
申请人： Clarence D. Vanderpool , Martin B. MacInnis , Judith A. Ladd
发明人： Clarence D. Vanderpool , Martin B. MacInnis , Judith A. Ladd
IPC分类号： C01F17/00 , C01G45/12 , C22B3/08 , C22B3/28 , C22B34/36 , C22B47/00 , C22B59/00 , C22B3/00
CPC分类号： C22B59/00 , C01F17/0006 , C01G45/1214 , C01G49/02 , C22B3/0012 , C22B3/08 , C22B34/36 , C22B47/00 , Y02P10/234
摘要： A process is disclosed for recovering tungsten, iron, and manganese from tungsten bearing material. The process involves digesting the material in a sulfur dioxide solution at a sufficient temperature for a sufficient time to form a digestion solution containing the major portion of the scandium, iron, and manganese, and a digestion solid containing the major portion of the tungsten which is separated from the digestion solution. The major portion of the scandium is extracted from the digestion solution with an organic consisting essentially of an extracting agent which is essentially a mixture of alkyl primary amines which are present in an amount sufficient to extract the major portion of the scandium without extracting appreciable amounts of iron and manganese, and the balance an essentially aromatic solvent. After separation of the scandium containing organic from the raffinate, the organic is stripped of the scandium with hydrochloric acid which is then separated from the stripped organic. The raffinate is adjusted to a pH of at least about 3.5 with a base to precipitate the major portion of the iron and manganese which is separated from the resulting liquor. A sufficient amount of chlorine gas is contacted with an aqueous slurry of the precipitate at a sufficient temperature for a sufficient time to form a manganese containing solution containing the major portion of the manganese which was in the precipitate and a solid containing the major portion of the iron which was in the precipitate.
摘要翻译：公开了从含钨材料中回收钨，铁和锰的方法。该方法包括在足够的温度下将二氧化硫溶液中的材料消化足够的时间以形成含有主要部分钪，铁和锰的消解溶液，以及含有主要部分钨的消解固体，与消化液分离。钪的主要部分从消解溶液中提取，其中有机物基本上由提取剂提取，所述萃取剂基本上是烷基伯胺的混合物，其以足以提取主要部分钪的量存在，而不提取可观量的铁和锰，余量为基本上为芳族溶剂。从萃余液中分离含钪的有机物后，用盐酸汽提有机物，然后与汽提的有机物分离。将萃余液用碱调节至至少约3.5的pH，以沉淀与所得液体分离的铁和锰的主要部分。在足够的温度下，将足够量的氯气与沉淀物的含水浆料接触足够的时间以形成含有主要部分在沉淀中的锰的含锰溶液和含有主要部分的固体处于沉淀中的铁。

35. 发明授权

US4612183A Method of producing crystalline ammonium metatungstate 失效
标题翻译：生产结晶态偏钨酸铵的方法
公开(公告)号：US4612183A
公开(公告)日：1986-09-16
申请号：US704992
申请日：1985-02-25
申请人： Tai K. Kim , Carl W. Boyer , Martin B. MacInnis , Donald H. Ennis
发明人： Tai K. Kim , Carl W. Boyer , Martin B. MacInnis , Donald H. Ennis
IPC分类号： C01G41/00
CPC分类号： C01G41/00
摘要： A method is disclosed for producing crystalline ammonium metatungstate from ammonium paratungstate. The method involves heating ammonium paratungstate in a multiple hearth furnace at from about 200.degree. C. to about 400.degree. C. to form a relatively uniformly heated ammonium paratungstate. A slurry of the heated ammonium paratungstate in water is then digested at from about 70.degree. C. to about 100.degree. C. for less than about 6 hours at relatively constant volume while maintaining the pH of the slurry at from about 4.2 to about 3.0 by the addition of ammonia as necessary to form a solution of ammonium metatungstate. The resulting ammonium metatungstate solution is then evaporated to a fraction of its original volume to concentrate it and any insolubles are removed. The ammonium metatungstate is then crystallized from the concentrated solution.
摘要翻译：公开了一种从仲钨酸铵生产结晶态偏钨酸铵的方法。该方法包括在约200℃至约400℃的多床炉中加热仲钨酸铵，形成相对均匀加热的仲钨酸铵。然后将加热的仲钨酸铵的浆液在约70℃至约100℃下以相对恒定的体积消化少于约6小时，同时通过以下方式将浆料的pH维持在约4.2至约3.0，通过根据需要添加氨以形成偏钨酸铵溶液。然后将所得的偏钨酸铵溶液蒸发至其原始体积的一部分以使其浓缩并除去任何不溶物。然后从浓缩溶液中结晶偏钨酸铵。

36. 发明授权

US4447404A Recovery of molybdenum from molybdenum disulfide 失效
标题翻译：从二硫化钼回收钼
公开(公告)号：US4447404A
公开(公告)日：1984-05-08
申请号：US451120
申请日：1982-12-20
申请人： Clarence D. Vanderpool , Martin B. MacInnis
发明人： Clarence D. Vanderpool , Martin B. MacInnis
IPC分类号： C01G39/00
CPC分类号： C01G39/00
摘要： Ammonium molybdate is produced from molybdenum disulfide concentrate by contacting the concentrate with an aqueous solution of ammonium chloride and chlorine at suitable concentrations and for a sufficient period of time to solubilize molybdenum disulfide present in said concentrate as molybdate ions and form a solution of ammonium molybdate.
摘要翻译：通过使浓缩物与氯化铵和氯的水溶液以合适的浓度接触并持续足够的时间以溶解存在于所述浓缩物中的二硫化钼作为钼酸根离子并形成钼酸铵溶液，由钼酸二铵制备钼酸铵。

37. 发明授权

US4381937A Method for producing cobalt metal powder 失效
标题翻译：钴金属粉末的制造方法
公开(公告)号：US4381937A
公开(公告)日：1983-05-03
申请号：US304400
申请日：1981-09-21
申请人： Richard G. Gingerich , Clarence D. Vanderpool , Richard A. Scheithauer , Martin B. MacInnis
发明人： Richard G. Gingerich , Clarence D. Vanderpool , Richard A. Scheithauer , Martin B. MacInnis
IPC分类号： B22F9/24 , C01G51/12 , B22F9/00
CPC分类号： C22B23/0423 , C01G51/12 , C22B23/0461 , Y02P10/212
摘要： In a process for producing fine cobalt metal powder from scrap material containing brazing compositions, the scrap is digested with hydrochloric acid to form a cobalt chloride solution which the silver is removed by precipitation with a suitable alkali metal halide at a pH of about 7 to result in a cobalt amine chloride solution which is further processed to fine cobalt powder.
摘要翻译：在由含有钎焊组合物的废料制造精细钴金属粉末的方法中，废料用盐酸消化以形成氯化钴溶液，通过在约7的pH下用合适的碱金属卤化物沉淀除去银，得到在钴胺氯化物溶液中，其进一步加工成细小的钴粉末。

38. 发明授权

US4360502A Recovery of tungsten values from alkali tungstate solutions by solvent extraction 失效
标题翻译：通过溶剂萃取从碱式钨酸盐溶液中回收钨值
公开(公告)号：US4360502A
公开(公告)日：1982-11-23
申请号：US292378
申请日：1981-08-13
申请人： Martin B. MacInnis , Robert P. McClintic , Tai K. Kim
发明人： Martin B. MacInnis , Robert P. McClintic , Tai K. Kim
IPC分类号： C01G41/00 , C22B3/28
CPC分类号： C22B3/0012 , C01G41/00 , C01G41/003 , Y02P10/234 , Y10S423/14
摘要： After stripping tungsten values from a loaded organic extractant in a two component extraction system for producing ammonium tungstate from aqueous alkali metal tungstate solutions, the organic extractant and aqueous solution of ammonium tungstate are fed into a settling container which includes a pair of electrodes and means for applying a direct current voltage potential for promoting coalescence of the aqueous and organic phase.
摘要翻译：在从碱金属钨酸盐水溶液中生产钨酸铵的双组分提取系统中的负载有机萃取剂中除去钨值后，将有机萃取剂和钨酸铵水溶液进料到沉淀容器中，该沉淀容器包括一对电极和用于施加直流电压以促进水相和有机相的聚结。

39. 发明授权

US4278463A Process for recovering cobalt 失效
标题翻译：回收钴的方法
公开(公告)号：US4278463A
公开(公告)日：1981-07-14
申请号：US135050
申请日：1980-03-28
申请人： Clarence D. Vanderpool , Martin B. MacInnis , Robert P. McClintic , Richard G. W. Gingerich
发明人： Clarence D. Vanderpool , Martin B. MacInnis , Robert P. McClintic , Richard G. W. Gingerich
IPC分类号： C22B23/00 , C22B23/04
CPC分类号： C22B23/0469
摘要： Cobalt is recovered from byproduct streams from a basic process by contacting the byproduct streams with aluminum metal for a sufficient period of time to produce cobalt metal as a precipitate. The basic process is the type wherein cobalt ions in solution are complexed with ammonia in the presence of halide ions to form an ammine halide solution from which a cobalt containing precipitate is separated. The precipitate is subsequently reduced to form a cobalt metal powder.
摘要翻译：通过使副产物流与铝金属接触足够的时间以产生作为沉淀物的钴金属，从碱性方法从副产物流中回收钴。基本方法是其中在卤化物离子存在下，溶液中的钴离子与氨络合的形式，以形成分离有钴的沉淀物的卤化铵溶液。随后将沉淀物还原形成钴金属粉末。

40. 发明授权

US4185078A Extraction process for recovery of rhenium 失效
标题翻译：铼的回收提取工艺
公开(公告)号：US4185078A
公开(公告)日：1980-01-22
申请号：US926167
申请日：1978-07-19
申请人： L. Rita Quatrini , Martin B. MacInnis
发明人： L. Rita Quatrini , Martin B. MacInnis
IPC分类号： C01G47/00 , C22B3/28 , C22B34/34 , C22B61/00
CPC分类号： C22B61/00 , C01G47/00 , C22B3/0016 , C22B34/34 , Y02P10/234
摘要： A process is disclosed wherein essentially all of the rhenium can be removed from an aqueous solution of molybdenum without the extraction of molybdenum using a particular solvent extraction solution. The extraction solution consists essentially of quaternary ammonium compound and at least about 50 percent by volume of a highly aromatic solvent which dissolves a quaternary ammonium-rhenium complex to the extent of at least 0.1 percent by volume selected from the group consisting of benzene and an aromatic solvent containing primarily lower alkyl benzenes having molecular weights of either 106, 120, 134 or 148 with minor amounts of relatively long chain aliphatic hydrocarbons containing greater than 8 carbon atoms and minor amounts of napthalene.
摘要翻译：公开了一种方法，其中基本上所有的铼可以从钼水溶液中除去，而不用特定的溶剂萃取溶液提取钼。提取溶液基本上由季铵化合物和至少约50体积％的高度芳族溶剂组成，其将季铵 - 铼络合物溶解至至少0.1体积％，其选自苯和芳族主要含有分子量为106,120,134或148的低级烷基苯的溶剂，其中少量含有大于8个碳原子的相对长链脂族烃和少量的萘。

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