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31. 发明授权

US07385015B2 Trialkylaluminum treated supports 有权
标题翻译：三烷基铝处理的载体
公开(公告)号：US07385015B2
公开(公告)日：2008-06-10
申请号：US11220164
申请日：2005-09-06
申请人： Matthew W. Holtcamp
发明人： Matthew W. Holtcamp
IPC分类号： C08F4/02 , C08F4/6392 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/02 , C08F4/65916 , C08F210/14 , C08F2500/03
摘要： This invention relates to a process to prepare a trialkylaluminum treated support comprising: 1) combining a support with first trialkylaluminum compound(s), where the alkyl groups have at least 2 carbon atoms; then 2) calcining the combination of the support and the trialkylaluminum compound(s); then 3) combining the calcined support with second trialkylaluminum compound(s), where the alkyl groups have at least 2 carbon atoms; where the first and second trialkylaluminum compound(s) may be the same or different. This invention further relates to catalyst systems comprising catalyst compounds and such supports, as well as processes to polymerize unsaturated monomers using the supports in combination with catalyst compounds.
摘要翻译：本发明涉及一种制备三烷基铝处理的载体的方法，包括：1）将载体与第一三烷基铝化合物组合，其中烷基具有至少2个碳原子; 然后2）煅烧载体和三烷基铝化合物的组合; 然后3）将煅烧的载体与第二个三烷基铝化合物组合，其中烷基具有至少2个碳原子; 其中第一和第二三烷基铝化合物可以相同或不同。本发明还涉及包含催化剂化合物和这种载体的催化剂体系，以及使用该载体与催化剂化合物组合使不饱和单体聚合的方法。

32. 发明授权

US07285679B2 Oxidation of alkanes 失效
标题翻译：烷烃氧化
公开(公告)号：US07285679B2
公开(公告)日：2007-10-23
申请号：US11431944
申请日：2006-05-10
申请人： Matthew W. Holtcamp , James C. Vartuli
发明人： Matthew W. Holtcamp , James C. Vartuli
IPC分类号： C07C27/10 , C07C53/00
CPC分类号： C07C5/48 , B01J23/002 , B01J27/0576 , B01J31/1805 , B01J31/181 , B01J35/0006 , B01J2231/70 , B01J2523/00 , B01J2531/828 , C07C45/33 , C07C51/215 , C07C2531/36 , Y02P20/52 , Y02P20/582 , C07C11/06 , C07C57/03 , C07C57/04 , C07C47/22 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/828
摘要： Alkanes are oxidised to oxygenates such as carboxylic acids with molecular oxygen employing a two component catalyst system which uses a liganded heavy metal compound and a mixed metal oxide.
摘要翻译：使用双组分催化剂体系，使用配体重金属化合物和混合金属氧化物，将烷烃氧化成含氧化合物，例如具有分子氧的羧酸。

33. 发明授权

US07060766B2 Methods of forming a supported activated catalyst composition 失效
标题翻译：形成负载型活化催化剂组合物的方法
公开(公告)号：US07060766B2
公开(公告)日：2006-06-13
申请号：US11039533
申请日：2005-01-20
申请人： Laughlin G. McCullough , Matthew W. Holtcamp
发明人： Laughlin G. McCullough , Matthew W. Holtcamp
IPC分类号： C08F4/102 , C08F4/642
CPC分类号： B01J31/165 , B01J27/12 , B01J31/143 , B01J31/1616 , B01J31/2226 , B01J31/2295 , B01J35/002 , B01J2531/48 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/65916
摘要： Processes of forming a supported activated catalyst composition and method of polymerization are disclosed, the process of forming the composition including combining a halogenated aromatic aluminum activator compound with a fluorinated support and a catalyst to form a supported activated catalyst composition. Also disclosed is a supported activated catalyst composition, comprising the reaction product of a fluorinated support, a perfluorophenyl aluminum activator and in one embodiment a metallocene catalyst. In one embodiment, the halogenated aromatic aluminum activator is represented by the formula RnAl(ArHal)3-n, wherein ArHal is a halogenated aryl group, R is a monoanionic ligand, and n is 1 or 2.
摘要翻译：公开了形成负载型活化催化剂组合物和聚合方法的方法，该方法包括将卤化芳族铝活化剂化合物与氟化载体和催化剂组合以形成负载型活化催化剂组合物。还公开了一种负载的活化催化剂组合物，其包含氟化载体，全氟苯基铝活化剂和在一个实施方案中为茂金属催化剂的反应产物。在一个实施方案中，卤化芳族铝活化剂由式R n Al（ArHal）3-n N表示，其中ArHal是卤代芳基，R是单阴离子配体，n为1或2。

34. 发明授权

US06806328B2 Polymerization catalyst activator complexes and their use in a polymerization process 有权
标题翻译：聚合催化剂活化剂配合物及其在聚合过程中的应用
公开(公告)号：US06806328B2
公开(公告)日：2004-10-19
申请号：US10310306
申请日：2002-12-05
申请人： Matthew W. Holtcamp
发明人： Matthew W. Holtcamp
IPC分类号： C08F452
CPC分类号： C08F210/16 , C08F4/659 , C08F4/6592 , C08F4/65922 , C08F4/65912 , C08F210/14 , C08F2500/03
摘要： The present invention includes polymerization catalyst activator complexes which include at least Group 13 metals. The activator complexes of the invention are prepared, in general, by reacting a halogenated aryl Group 13 metal compound with a diol. The activator compound is represented in one aspect by: wherein each M1 is a Group 13 atom; each R3, R3′, R3″, and R3′″ group is independently selected from, for example, C1 to C30 alkyls, halogenated C1 to C30 alkyls, C6 to C60 halogenated aryls; with the proviso that at least one of R3, R3′, R3″, and R3′″ is a fluorinated C6 to C60 aryl group; R1 and R2 are independently selected from substituted or unsubstituted C1 to C100 hydrocarbylenes; R, when present, is a substituted or unsubstituted C30 hydrocarbylene; wherein when R is absent, R1 and R2 are bound together; and x is 0 or an integer from 1 to 100.
摘要翻译：本发明包括至少包含第13族金属的聚合催化剂活化剂配合物。通常通过使卤代芳基13族金属化合物与二醇反应来制备本发明的活化剂配合物。活化剂化合物在一个方面由下式表示：其中每个M 1是13族原子; 每个R 3，R 3'，R 3“和R 3”基团独立地选自例如C 1至C 30烷基，卤代C 1至C 30烷基，C 6至C 60 卤代芳基; 条件是R 3，R 3'，R 3“和R 3”中的至少一个是氟化的C 6至C 60芳基; R 1和R 2独立地选自取代或未取代的C1至C100烃基; 当存在时，R是取代或未取代的C30亚烃基; 其中当R不存在时，R 1和R 2结合在一起; x为0或1〜100的整数。

35. 发明授权

US06703338B2 Polymerization catalyst activators, method of preparing, and their use in polymerization processes 失效
公开(公告)号：US06703338B2
公开(公告)日：2004-03-09
申请号：US10186361
申请日：2002-06-28
申请人： Matthew W. Holtcamp , David Arthur Cano
发明人： Matthew W. Holtcamp , David Arthur Cano
IPC分类号： B01J314
CPC分类号： C07F5/066 , C08F4/65916 , C08F4/65922 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , Y10S526/943 , C08F4/65912 , C08F2500/03 , C08F2500/01 , C08F210/14
摘要： New polymerization catalyst activators are disclosed which include a heterocyclic compound, which may or may not be substituted, and an aluminum alkyl or an aluminoxane. Supported activators of the invention include the heterocyclic compound, combined with an alkylaluminum or aluminoxane, and a support material, preferably a silica support material. Also disclosed are methods for preparing these catalyst activators and polymerization processes utilizing same.

36. 发明授权

US06642400B2 Linked metallocene complexes, catalyst systems, and olefin polymerization processes using same 有权
公开(公告)号：US06642400B2
公开(公告)日：2003-11-04
申请号：US09963840
申请日：2001-09-26
申请人： Matthew W. Holtcamp , Laughlin G. McCullough
发明人： Matthew W. Holtcamp , Laughlin G. McCullough
IPC分类号： C07F1700
CPC分类号： C07F17/00 , C07F17/02 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F2410/03 , Y10S526/943 , C08F210/16 , C08F4/65904 , C08F210/14 , C08F2500/11 , C08F2500/12
摘要： Disclosed are metallocene complexes containing two or more metallocene components where the components may be independently bridged or unbridged. In particular, the invention provides metallocene complexes including a bridged metallocene component linked to an unbridged metallocene component where a ligand structure of the unbridged metallocene component is linked to the bridging group of the bridged metallocene component. The invention provides metallocene complexes including a first unbridged metallocene component linked to second unbridged metallocene component via their ligand structures. The invention also provides metallocene complexes including a bridged metallocene component linked to a second bridged metallocene component via their ligand structures. The invention further provides methods of preparing the linked metallocene complexes described above, catalyst systems including these linked metallocene complexes, polymerization processes utilizing these complexes, and polymers made thereby.

37. 发明授权

US06420580B1 Catalyst compositions and method of polymerization therewith 失效
标题翻译：催化剂组合物及其聚合方法
公开(公告)号：US06420580B1
公开(公告)日：2002-07-16
申请号：US09434696
申请日：1999-11-05
申请人： Matthew W. Holtcamp , Ching-Tai Lue
发明人： Matthew W. Holtcamp , Ching-Tai Lue
IPC分类号： C07F708
CPC分类号： C08F230/08 , C08F2/34 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/18 , C08F2500/03
摘要： Catalyst compositions, systems and methods, useful in polymerization processes, are disclosed, which utilize bridged metallocene catalysts, preferably including indenyl groups, bound to the transition metal and a vinyl group bound to the bridge.
摘要翻译：公开了可用于聚合方法的催化剂组合物，体系和方法，其利用结合到过渡金属的桥连茂金属催化剂，优选包括茚基和与桥结合的乙烯基。

38. 发明授权

US06420297B2 Haloaryl containing group 13 substituents on bridged metallocene polyolefin catalysts 有权
标题翻译：含桥基金属茂聚烯烃催化剂上含有13个取代基的卤代芳基
公开(公告)号：US06420297B2
公开(公告)日：2002-07-16
申请号：US09905331
申请日：2001-07-13
申请人： Matthew W. Holtcamp
发明人： Matthew W. Holtcamp
IPC分类号： C08F3138
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F210/16 , Y02P20/544 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/02 , C08F2500/03
摘要： A process for the preparation of polyolefins from one or more olefinic monomers is described in which the olefins are combined with a catalyst complex derived from a catalyst compound having a bis-haloaryl-Group 13 element substituted Group 13-15 atom-containing bridging element, and a co-catalyst activator a tri-n-alkyl aluminum compound or aluminoxy derivative thereof. The process is particularly useful with bisarylboron substituted silicon-bridged metallocenes under gas phase, slurry, solution or supercritical high pressure coordination polymerization conditions for polyolefins derived from olefinic monomers selected from the group consisting of ethylene, &agr;-olefins, cyclic olefins, non-conjugated diolefins, vinyl aromatic olefins, and geminally disubstituted olefins.
摘要翻译：描述了从一种或多种烯烃单体制备聚烯烃的方法，其中烯烃与衍生自具有双卤代芳基 - 第13族元素取代的含13-15原子的桥连元素的催化剂化合物的催化剂络合物组合，和三 - 正烷基铝化合物或其铝氧基衍生物的助催化剂活化剂。该方法对于在气相，浆液，溶液或超临界高压配位聚合条件下的双芳基硼取代的硅桥连金属茂特别有用，所述聚烯烃衍生自烯烃单体，所述烯烃选自乙烯，α-烯烃，环烯烃，非共轭二烯烃，乙烯基芳族烯烃和双取代烯烃。

39. 发明授权

US06211105B1 Nitrogen-containing group 13 anionic complexes for olefin polymerization 失效
标题翻译：含氮基团13用于烯烃聚合的阴离子配合物
公开(公告)号：US06211105B1
公开(公告)日：2001-04-03
申请号：US09619953
申请日：2000-07-20
申请人： Matthew W. Holtcamp
发明人： Matthew W. Holtcamp
IPC分类号： B01J3100
CPC分类号： C08F10/02 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F210/16 , Y10S526/943 , C08F4/65912 , C08F4/65908 , C08F210/14 , C08F2500/03
摘要： This description addresses a process for the preparation of polyolefins from one or more olefinic monomers comprising combining said olefins under olefin polymerization conditions with an organometallic catalyst compound that is activated for olefin polymerization by reaction with a Group 13 element cocatalyst complex comprising at least one halogenated, nitrogen-containing aromatic group ligand. High number-average molecular weight polymers and copolymers at high rates of productivity were observed from the use of metallocene catalysts complexes when activated with [(C6H5)3C][(C6F5)3B(C5F4N)].
摘要翻译：该描述涉及从一种或多种烯烃单体制备聚烯烃的方法，其包括在烯烃聚合条件下将所述烯烃与通过与包含至少一种卤代，烷氧基的组合的13族元素助催化剂络合物反应而进行烯烃聚合的有机金属催化剂化合物，含氮芳族基团配体。当用[（C 6 H 5）3 C] [（C 6 F 5）3 C（C 5 F 4 N）]活化时，使用茂金属催化剂络合物观察到高生产率的高数均分子量聚合物和共聚物。

40. 发明授权

US09334460B2 Ring opening cross metathesis of vinyl terminated polymers and their functionalized derivatives for fouling mitigation in hydrocarbon refining processes 有权
标题翻译：乙烯基封端聚合物的开环交叉复分解及其在烃精炼过程中污染缓解的官能化衍生物
公开(公告)号：US09334460B2
公开(公告)日：2016-05-10
申请号：US13804907
申请日：2013-03-14
申请人： ManKit NG , Glen Barry Brons , Matthew W. Holtcamp , Donna J. Crowther , Patrick Brant , Hong Cheng , Clarence Chase
发明人： ManKit NG , Glen Barry Brons , Matthew W. Holtcamp , Donna J. Crowther , Patrick Brant , Hong Cheng , Clarence Chase
IPC分类号： C10G75/04 , C10L10/04 , C07D209/52 , C08F8/32 , C10L1/238
CPC分类号： C10G75/04 , C07D209/52 , C08F8/32 , C08F210/06 , C08F210/08 , C10L1/238 , C10L10/04
摘要： A compound useful for reducing fouling in a hydrocarbon refining process is provided. A method for preparing the compound includes functionalizing a polymer having a vinyl chain end to obtain a terminal group having one or more anhydride units, and reacting the anhydride units with a polyamine. Methods of using the compound and compositions thereof are also provided.
摘要翻译：提供了一种可用于减少烃精炼过程中结垢的化合物。制备该化合物的方法包括将具有乙烯基链端的聚合物官能化以获得具有一个或多个酸酐单元的端基，并使该酸酐单元与多胺反应。还提供了使用该化合物及其组合物的方法。

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