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31. 发明授权

US06733959B2 Chemically sensitized aqueous-based photothermographic emulsions and materials and methods of using same 失效
标题翻译：化学敏化水性光热敏成像乳剂及其使用方法
公开(公告)号：US06733959B2
公开(公告)日：2004-05-11
申请号：US09923039
申请日：2001-08-06
申请人： Henry J. Gysling , David A. Dickinson , Mark Lelental , John W. Boettcher
发明人： Henry J. Gysling , David A. Dickinson , Mark Lelental , John W. Boettcher
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C1/08 , G03C1/09 , G03C1/498 , G03C2001/098 , Y10S430/145 , Y10S430/165
摘要： Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n (II) Pd(X2)2[Te(R′)2]2 (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.
摘要翻译：使用水性制剂制备的光热照相材料包括使用某些含碲化合物化学增感的卤化银。这种含碲的化学增感化合物通常提供在水溶液或水性固体颗粒分散体中，并且可以由以下结构I，II或III表示：其中X表示相同或不同的COR，CSR，CNRRa，CR， PRRa或P（OR）2基团，R和Ra独立地是烷基，烯基或芳基，L是衍生自中性路易斯碱的配体，X 1和X 2独立地表示卤素，OCN， SCN，S2CNRRa，S2COR，S2CSR S2P（OR）2，S2PRRa，SeCN，TeCN，CN，SR，OR，烷基，芳基，N 3或O 2 CR基团，R'为烷基或芳基，p为2或4， m为0,1,2或4，n为2或4，条件是当m为0或2时，n为2或4，当m为1或4时，n为2。

32. 发明授权

US06509296B1 Thermographic imaging elements and processes for their use 失效
公开(公告)号：US06509296B1
公开(公告)日：2003-01-21
申请号：US09536181
申请日：2000-03-27
申请人： Mark Lelental , Henry J. Gysling , David F. Jennings
发明人： Mark Lelental , Henry J. Gysling , David F. Jennings
IPC分类号： B41M530
CPC分类号： B41M5/32 , B41M5/30
摘要： A thermally imageable element can be imaged using heat alone without the need for photosensitivity or post-imaging processing. The element contains image-forming chemistry that comprises i) image precursor chemistry and ii) a catalyst or a catalyst precursor that upon imagewise heating is capable of promoting thermally induced image formation with the image precursor chemistry. The image-forming chemistry i) and ii) components are in reactive association and uniformly dispersed or dissolved within a binder in one or more layers of the element. Thus, the element is capable of being thermally addressed to provide a visible image as a result of thermally induced catalytic transformation of the image-forming chemistry.

33. 发明授权

US5955250A Electrically-conductive overcoat layer for photographic elements 失效
标题翻译：用于摄影元件的导电外涂层
公开(公告)号：US5955250A
公开(公告)日：1999-09-21
申请号：US991288
申请日：1997-12-16
申请人： Paul A. Christian , Mark Lelental , Dennis J. Eichorst
发明人： Paul A. Christian , Mark Lelental , Dennis J. Eichorst
IPC分类号： G03C1/76 , B41M5/42 , G03C1/04 , G03C1/38 , G03C1/795 , G03C1/85 , G03G5/10 , G03G5/147 , G03C1/89
CPC分类号： B41M5/426 , G03C1/85 , G03G5/104 , G03G5/14704 , G03G5/14708 , G03C1/04 , G03C1/38 , G03C1/385 , G03C1/7954 , G03C1/853
摘要： The present invention is a multilayer imaging element which includes a support, one or more image-forming layers superposed on the support, and an outermost transparent electrically-conductive, non-charging, overcoat layer superposed on the support. The over coat layer is colloidal, acicular electrically-conductive metal-containing particles, dispersed in a film-forming binder at a volume percentage of acicular conductive metal-containing particles of from 2 to 60. The overcoat layer further includes a first charge control agent which imparts positive charging properties and a second charge control agent which imparts negative charging properties.
摘要翻译：本发明是一种多层成像元件，其包括支撑体，叠置在支撑体上的一个或多个图像形成层和叠置在支撑体上的最外侧的透明导电的不带电覆盖层。外涂层是以2至60的针状含导电金属颗粒的体积百分数分散在成膜粘合剂中的胶体，针状导电金属颗粒。外涂层还包括第一电荷控制剂这赋予了正的带电性质和赋予负带电特性的第二电荷控制剂。

34. 发明授权

US5927206A Ferroelectric imaging member and methods of use 失效
标题翻译：铁电成像构件及使用方法
公开(公告)号：US5927206A
公开(公告)日：1999-07-27
申请号：US995311
申请日：1997-12-22
申请人： Robert E. Bacon , Arun K. Mehrotra , Mark Lelental , Daniel J. Gisser
发明人： Robert E. Bacon , Arun K. Mehrotra , Mark Lelental , Daniel J. Gisser
IPC分类号： G03G5/02 , B41N1/00 , B41N1/14
CPC分类号： B41N1/006
摘要： An imagewise polarizable imaging member can be used to print the same or different images with an electrically responsive marking media. The imaging member includes a matrix-addressable microelectronic layer in proximate relationship with an imagewise polarizable ferroelectric layer. Imaging is accomplished by forming an imagewise electrical pattern in the ferroelectric layer using signals from the matrix-addressable microelectronic layer, and applying the electrically responsive marking media to the electrically polarized ferroelectric layer, creating thereon an identifiable image pattern. The marking media can then be transferred to a suitable receiver material to form the desired printed image.
摘要翻译：可以使用成像极化成像构件用电响应标记介质打印相同或不同的图像。成像构件包括与成像可极化铁电层成近邻关系的矩阵寻址微电子层。通过使用来自矩阵寻址微电子层的信号在铁电层中形成图像电图案，并将电响应标记介质施加到电极化铁电层，从而在其上产生可识别的图像图案来实现成像。然后可以将标记介质转移到合适的接收器材料以形成所需的打印图像。

35. 发明授权

US5681687A Imaging element comprising an electrically-conductive layer formed by a glow discharge process 失效
标题翻译：成像元件包括通过辉光放电过程形成的导电层
公开(公告)号：US5681687A
公开(公告)日：1997-10-28
申请号：US597554
申请日：1996-02-02
申请人： Mark Lelental , Bradley Keith Coltrain , David Appler Glocker , Dennis R. Freeman , Jeremy Matthew Grace
发明人： Mark Lelental , Bradley Keith Coltrain , David Appler Glocker , Dennis R. Freeman , Jeremy Matthew Grace
IPC分类号： B41M5/40 , B41M5/42 , B41M5/44 , G03C1/85 , G03C1/91 , G03G5/10 , G03G7/00
CPC分类号： B41M5/426 , G03C1/85 , G03C1/915 , G03G5/10 , G03G5/104 , G03G7/0013 , G03G7/002 , G03G7/0053 , B41M5/44
摘要： Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer produced by coating a layer comprised of a metallo-organic compound and a film-forming binder and subjecting such layer to glow discharge treatment to render it electrically conductive. Use of a metallo-organic compound in combination with a glow discharge treatment provides a controlled degree of electrical conductivity and beneficial chemical, physical and optical properties which adapt the electrically-conductive layer for such purposes as providing protection against static or serving as an electrode which takes part in an image-forming process.
摘要翻译：诸如照相，静电和热成像元件的成像元件由支撑体，图像形成层和通过涂覆由金属有机化合物和成膜粘合剂组成的层制成的导电层组成，这种层进行辉光放电处理以使其导电。使用金属有机化合物与辉光放电处理相结合提供可控程度的电导率和有利的化学，物理和光学性质，其适应导电层用于提供防静电或用作电极的目的参与图像形成过程。

36. 发明授权

US4752547A Dye-forming electrothermographic material and process 失效
标题翻译：染料电热成像材料及工艺
公开(公告)号：US4752547A
公开(公告)日：1988-06-21
申请号：US870572
申请日：1986-06-04
申请人： Stanley W. Cowen , James C. Fleming , Mark Lelental
发明人： Stanley W. Cowen , James C. Fleming , Mark Lelental
IPC分类号： B41M5/323 , B41M5/20 , G03C1/67 , G03C7/46 , G03G5/00 , G03G15/24 , G03G13/22
CPC分类号： G03G5/00 , G03C1/67 , G03C7/46
摘要： A dye-forming electrothermographic element comprises an electrically activatable recording layer comprising (a) a reducing agent or reducing agent precursor capable of being activated by a Lewis base; (b) a cobalt(III) Lewis base complex; and (c) at least one of (i) a reducible dye-forming compound that has an oxidation state above that of the conjugate dye, (ii) a dye capable of changing its wavelength of absorption by reaction with a Lewis base, and (iii) a dye-forming coupler capable of reacting with the oxidized form of the reducing agent in (a) to form a dye. A negative or positive dye image is formed in such a dye-forming electrothermographic element by applying an electrical potential imagewise to the element of a magnitude and for a time sufficient to produce in the image areas a charge density sufficient to produce a latent image; and, then, heating the element to a temperature and for a time sufficient to form a dye image in the element. The dye-forming electrothermographic element can be a multicolor, multilayer electrothermographic element.
摘要翻译：染料形成电热成像元件包括电可活化记录层，其包含（a）能够被路易斯碱活化的还原剂或还原剂前体; （b）一种钴（III）路易斯碱络合物; 和（c）至少一种（i）具有高于该共轭染料的氧化态的可还原的形成染料的化合物，（ii）能够通过与路易斯碱反应来改变其吸收波长的染料和（ iii）能够在（a）中与氧化形式的还原剂反应形成染料的染料形成成色剂。在这种染料形成的电热成像元件中，通过将图像上的电位成像到该元件的大小和时间足以在图像区域中产生足以产生潜像的电荷密度来形成负或正的染料图像; 然后，将元件加热到足以在元件中形成染料图像的温度和时间。染料形成电热元件可以是多色多层电热元件。

37. 发明授权

US4410614A Polymeric electrically active conductive layer (EAC) for electrically activatable recording element and process 失效
标题翻译：用于电可激活记录元件和工艺的聚合物电活性导电层（EAC）
公开(公告)号：US4410614A
公开(公告)日：1983-10-18
申请号：US388376
申请日：1982-06-14
申请人： Mark Lelental , James M. Pearson
发明人： Mark Lelental , James M. Pearson
IPC分类号： G03G5/026 , G03G5/153 , G03G13/22 , G03G17/00
CPC分类号： G03G5/026 , G03G5/153
摘要： In an electrically activatable recording element and process comprising a polymeric electrically active conductive layer improvements are provided wherein the polymeric electrically active conductive layer comprises a polymer that has recurring units represented by the structure: ##STR1## wherein R is hydrogen or alkyl containing 1 to 20 carbon atoms;R.sup.1 and R.sup.3 are individually hydrogen or methyl;R.sup.2 is alkyl containing 2 to 20 carbon atoms;x is 0 or 1;y is 0 to 4;R.sup.4 is C.sub.6 H.sub.5-z X.sub.z ; wherein z is 1 to 5;X is chlorine, bromine or iodine;n is 40 to 100 weight percent;and the polymer has a glass transition temperature within the range of 20.degree. C. to 40.degree. C.Such a polymeric electrically active conductive layer is useful in, for example, an electrically activatable recording element comprising an electrically conductive support having thereon, in sequence:(a) a polymeric electrically active conductive layer, as described,(b) an electrically activatable recording layer comprising:(A) a dye-forming coupler, and(B) an oxidation-reduction combination comprising:(i) an organic silver salt oxidizing agent consisting essentially of a silver salt of a 1,2,4-mercaptotriazole derivative with(ii) a reducing agent which, in its oxidized form, forms a dye with said dye-forming coupler,(c) a photoconductive layer separated from (b) by an air gap of up to 20 microns or separated from (b) by an electrically conductive interlayer, and(d) an electrically conductive layer.The recording element is light handleable and provides a dye image and silver image by dry development processing.
摘要翻译：在可激活的记录元件和包含聚合物电活性导电层的方法中，提供了改进的改进，其中聚合物电活性导电层包含具有由以下结构表示的重复单元的聚合物：其中R是氢或含有1至20个碳原子 R1和R3分别是氢或甲基; R2是含有2-20个碳原子的烷基; x为0或1; y为0〜4; R4为C6H5-zXz; 其中z为1至5; X是氯，溴或碘; n为40〜100重量％并且聚合物的玻璃化转变温度在20℃至40℃的范围内。这种聚合物电活性导电层可用于例如依次具有其上的导电载体的可电激活的记录元件（a）聚合物电活性导电层，如上所述，（b）可电致活化的记录层，包括：（A）染料形成成色剂，和（B）氧化还原组合，其包含：（i）有机银基本上由1,2,4-巯基三唑衍生物的银盐组成的盐氧化剂，和（ii）以氧化形式与所述成色剂形成染料的还原剂，（c）分离的光电导层从（b）到达20微米的气隙或者由（b）由导电中间层分离，和（d）导电层。记录元件可轻易处理，并通过干式显影处理提供染料图像和银色图像。

38. 发明授权

US4332875A Polymeric electrically active conductive layer for electrically activatable recording element and process 失效
标题翻译：用于电可激活记录元件和工艺的聚合物电活性导电层
公开(公告)号：US4332875A
公开(公告)日：1982-06-01
申请号：US229701
申请日：1981-01-29
申请人： Mark Lelental , Richard C. Sutton
发明人： Mark Lelental , Richard C. Sutton
IPC分类号： G03C1/498 , G03G17/00 , G03G5/026 , G03G5/04
CPC分类号： G03G17/00 , G03C1/49872 , G03C1/4989
摘要： In an electrically activatable recording element, such as one comprising an electrically conductive support having thereon, in sequence: (a) a polymeric electrically active conductive (EAC) layer, (b) an electrically activatable recording layer comprising (A) a dye-forming coupler, and (B) an oxidation-reduction combination comprising (i) an organic silver salt oxidizing agent consisting essentially of a silver salt of a 1,2,4-mercaptotriazole derivative, with (ii) a reducing agent which, in its oxidized form, forms a dye with the dye-forming coupler, (c) a photoconductive layer separated from (b) by an air gap of up to 20 microns, and (d) an electrically conductive layer; improvements are provided by means of a polymeric EAC layer (a) consisting essentially of a vinyl addition polymer, such as poly(methyl acrylate-co-vinylidene chloride). The recording element is room light handleable and provides a dye image and silver image by dry development processing.
摘要翻译：在可激活的记录元件中，例如包括其上的导电载体的顺序：（a）聚合物电活性导电（EAC）层，（b）可电激活的记录层，其包含（A）成染染色剂成色剂和（B）氧化还原组合，其包含（i）基本上由1,2,4-巯基三唑衍生物的银盐组成的有机银盐氧化剂与（ii）还原剂，其在其氧化形成染料，与染料形成成色剂形成染料，（c）通过高达20微米的气隙与（b）分离的光电导层，和（d）导电层; 通过基本上由乙烯基加成聚合物如聚（丙烯酸甲酯 - 共 - 偏二氯乙烯）组成的聚合物EAC层（a）提供改进。记录元件是室内光线处理，通过干式显影处理提供染色图像和银色图像。

39. 发明授权

US4155761A Electrically activated charge sensitive recording material and process 失效
公开(公告)号：US4155761A
公开(公告)日：1979-05-22
申请号：US918877
申请日：1978-06-26
申请人： Mark Lelental , Henry J. Gysling
发明人： Mark Lelental , Henry J. Gysling
IPC分类号： G03C1/73 , G03G5/14 , G03G5/153 , G03G5/026 , G03G5/04
CPC分类号： G03G5/153 , G03C1/734 , G03G5/14 , Y10S430/10 , Y10S430/167
摘要： A non-silver, charge-sensitive recording composite element having an ohmic resistivity of at least about 1.times.10.sup.10 ohm-cm comprising (a) a first electrically conducting layer in association with (b) a photoconductor layer, (c) a non-silver, electrically activated recording layer comprising an image-forming combination of (i) a certain tellurium (II) coordination complex with (ii) a reducing agent, and a binder and (d) a second electrical conducting layer can provide a non-silver image having a density equal to silver images. Silica, especially colloidal silica, is also very useful in the recording layer. The recording element can be room light handleable and can provide a developed image by dry development processes.

40. 发明授权

US4152155A Organotellurium (II) and (IV) compounds in heat-developable imaging materials and process with physically developable nuclei 失效
标题翻译：有机碲化合物（II）和（IV）化合物在可热显影成像材料和具有物理发育核的过程中
公开(公告)号：US4152155A
公开(公告)日：1979-05-01
申请号：US848063
申请日：1977-11-03
申请人： Mark Lelental , Henry J. Gysling
发明人： Mark Lelental , Henry J. Gysling
IPC分类号： G03C1/735 , B41M5/32 , G03C1/73 , G03C5/56 , G03C5/24 , G03C1/00 , G03C1/02 , G03C1/76
CPC分类号： G03C5/56 , B41M5/32 , G03C1/734 , Y10S428/913 , Y10T428/31678
摘要： An imaging combination comprising (i) a tellurium (II) or (IV) compound as an oxidizing agent and (ii) a reducing agent provides an improved amplified image. This imaging combination is useful in heat-developable materials containing sources of physically developable nuclei. A developed image can be provided in the material containing the developable nuclei and can be provided by heating the element to moderately elevated temperatures.
摘要翻译：包含（i）碲（II）或（IV）化合物作为氧化剂和（ii）还原剂的成像组合提供改进的放大图像。该成像组合可用于含有物理可显影核的来源的可热显影物质。可以在包含可显影核的材料中提供显影的图像，并且可以通过将元件加热到适度升高的温度来提供。

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