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31. 发明授权

US5169576A Method of making metal oxide ceramic membranes with small pore sizes 失效
标题翻译：制造孔径小的金属氧化物陶瓷膜的方法
公开(公告)号：US5169576A
公开(公告)日：1992-12-08
申请号：US654150
申请日：1991-02-11
申请人： Marc A. Anderson , Qunyin Xu
发明人： Marc A. Anderson , Qunyin Xu
IPC分类号： B01D71/02 , B01J8/00 , B01J19/24 , B01J35/06 , C04B35/46 , C04B35/486 , C04B35/49 , C04B35/624 , C04B38/00
CPC分类号： B01D67/0048 , B01D71/024 , B01J19/2475 , B01J35/065 , B01J8/009 , C04B35/46 , C04B35/486 , C04B35/49 , C04B35/624 , C04B38/0051 , B01D2323/08 , B01J2208/00017 , B01J2208/00548 , B01J2208/00592 , B01J2219/00051 , B01J2219/00164 , B01J2219/00177
摘要： A method for the production of metal oxide ceramic membranes is composed of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.
摘要翻译：金属氧化物陶瓷膜的制造方法由非常小的孔径组成。该方法在钛和其它过渡金属氧化物膜的制备中特别有用。该方法利用溶胶 - 凝胶方法，其中通过用金属醇盐中较大的醇代替并限制可利用的水来控制颗粒形成速率。产生稳定的，透明的金属氧化物陶瓷膜，其具有窄的孔径分布，孔径可操作在5至40埃的范围内。

32. 发明授权

US5104539A Metal oxide porous ceramic membranes with small pore sizes 失效
标题翻译：金属氧化物多孔陶瓷膜，孔径小
公开(公告)号：US5104539A
公开(公告)日：1992-04-14
申请号：US681088
申请日：1991-04-05
申请人： Marc A. Anderson , Qunyin Xu
发明人： Marc A. Anderson , Qunyin Xu
IPC分类号： B01D71/02 , B01J8/00 , B01J35/06 , C04B35/46 , C04B35/486 , C04B35/49 , C04B35/624 , C04B38/00
CPC分类号： B01D67/0048 , B01D71/024 , B01J35/065 , B01J8/009 , C04B35/46 , C04B35/486 , C04B35/49 , C04B35/624 , C04B38/0051 , B01D2323/08 , B01D2325/02 , B01J2208/00592 , C04B2111/00801
摘要： A method is disclosed for the production of metal oxide ceramic membranes of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.
摘要翻译：公开了用于生产非常小孔径的金属氧化物陶瓷膜的方法。该方法在钛和其它过渡金属氧化物膜的制备中特别有用。该方法利用溶胶 - 凝胶方法，其中通过用金属醇盐中较大的醇代替并限制可利用的水来控制颗粒形成速率。产生稳定的，透明的金属氧化物陶瓷膜，其具有窄的孔径分布，孔径可操作在5至40埃的范围内。

33. 发明授权

US5096745A Preparation of titanium oxide ceramic membranes 失效
标题翻译：氧化钛陶瓷膜的制备
公开(公告)号：US5096745A
公开(公告)日：1992-03-17
申请号：US561491
申请日：1990-08-01
申请人： Marc A. Anderson , Qunyin Xu
发明人： Marc A. Anderson , Qunyin Xu
IPC分类号： B01D71/02 , C01G23/053 , C04B35/46
CPC分类号： B01D67/0046 , B01D67/0004 , B01D67/0048 , B01D71/024 , C01G23/053 , C04B35/46 , B01D2323/08 , B01D2323/12
摘要： A procedure is disclosed for the reliable production of either particulate or polymeric titanium ceramic membranes by a highly constrained sol-gel procedure. The critical constraints in the procedure include the choice of alkyl alcohol solvent, the amount of water and its rate of addition, the pH of the solution during hydrolysis, and the limit of sintering temperature applied to the resulting gels.
摘要翻译：公开了通过高度约束的溶胶 - 凝胶方法可靠地生产颗粒或聚合物钛陶瓷膜的方法。该方法中的关键限制包括烷基醇溶剂的选择，水的量及其加入速率，水解期间溶液的pH以及施加于所得凝胶的烧结温度的极限。

34. 发明授权

US08216445B2 Nanoporous insulating oxide deionization device having asymmetric electrodes and method of use thereof 有权
标题翻译：具有不对称电极的纳米绝缘氧化物去离子器件及其使用方法
公开(公告)号：US08216445B2
公开(公告)日：2012-07-10
申请号：US11932741
申请日：2007-10-31
申请人： Marc A. Anderson , Kevin C. Leonard
发明人： Marc A. Anderson , Kevin C. Leonard
IPC分类号： H01G9/042 , H01G9/045 , H01G9/048 , C02F1/469 , C02F1/58
CPC分类号： C02F1/4691 , C02F1/4602 , C02F1/4604 , C02F1/46114 , C02F1/4672 , C02F2001/46133 , C02F2001/46161 , C02F2201/46115 , C02F2201/4613
摘要： A nanoporous insulating oxide deionization device, method of manufacture and method of use thereof for deionizing a water supply (such as a hard water supply), for desalinating a salt water supply, and for treating a bacteria-containing water supply. The device contains two composite electrodes each constructed from a conductive backing electrode and a composite oxide layer being an insulating oxide or a non-insulating oxide and an intermediate porous layer. The composite layer being substantially free of mixed oxidation states and nanoporous and having a median pore diameter of 0.5-500 nanometers and average surface area of 300-600 m2/g. The composite layer made from a stable sol-gel suspension containing particles of the insulating oxide, the median primary particle diameter being 1-50 nanometers. The difference in zeta potential, at a pH in the range of 6-9, being sufficient to suitably remove alkaline and alkaline earth cations (such as Ca2+ and Na1+), various organic and other inorganic cations and organic and inorganic anions from water, preferably household hard water. One composite layer being constructed from a mixture of Al2O3, MgAl2O4 and/or Mg-doped Al2O3 particles, and the other composite layer being constructed from SiO2 or TiO2.
摘要翻译：一种纳米多孔绝缘氧化物去离子装置，其制造方法及其使用方法，用于使供水（例如硬水供应）去离子，用于盐水供应盐的脱盐和用于处理含细菌的水源。该装置包含两个复合电极，每个复合电极由导电背衬电极和作为绝缘氧化物或非绝缘氧化物的复合氧化物层和中间多孔层构成。复合层基本上没有混合氧化态和纳米多孔，中值孔径为0.5-500纳米，平均表面积为300-600平方米/克。复合层由含有绝缘氧化物颗粒的稳定溶胶 - 凝胶悬浮液制成，中值一次粒径为1-50纳米。 ζ电位差在6-9范围内的pH值足以适当地去除碱金属和碱土金属阳离子（如Ca2 +和Na1 +），各种有机和其他无机阳离子以及水中的有机和无机阴离子家用硬水。一个复合层由Al2O3，MgAl2O4和/或掺杂Mg的Al2O3颗粒的混合物构成，另一个复合层由SiO2或TiO2构成。

35. 发明申请

US20100015429A1 METAL SUBSTRATES INCLUDING METAL OXIDE NANOPOROUS THIN FILMS AND METHODS OF MAKING THE SAME 有权
标题翻译：包含金属氧化物纳米薄膜的金属基材及其制备方法
公开(公告)号：US20100015429A1
公开(公告)日：2010-01-21
申请号：US12503150
申请日：2009-07-15
申请人： Marc A. Anderson , M. Isabel Tejedor , Ole Christensen
发明人： Marc A. Anderson , M. Isabel Tejedor , Ole Christensen
IPC分类号： B32B3/26 , B05D3/02 , B05D3/12 , C23C28/00
CPC分类号： F28F19/02 , B32B2305/026 , C09J2400/166 , C23C18/04 , C23C18/1241 , C23C18/1254 , C23C24/00 , C23F11/185 , F28F21/089 , Y10T428/24926 , Y10T428/24975 , Y10T428/24997 , Y10T428/249979
摘要： The present disclosure is directed to a metal-containing apparatus including a substrate member constructed of a metal that is highly resistant to pitting corrosion and wear in aggressive media. An exemplary metal-containing apparatus is a plate heat exchanger. The metal includes an oxidation layer on the surface thereof and a thin metal oxide nanoporous film on top of the oxidation layer. The nanoporous film is highly compliant and is comprised of oxygen and aluminum, titanium, silicon, zirconium and combinations thereof.
摘要翻译：本公开涉及一种含金属的设备，其包括由金属制成的基底构件，该金属具有高抗侵蚀性介质中的点蚀和磨损。示例性的含金属的设备是板式热交换器。该金属在其表面上包括氧化层，在氧化层顶部包括薄金属氧化物纳米多孔膜。纳米多孔膜是高度柔顺的，并且由氧和铝，钛，硅，锆及其组合构成。

36. 发明授权

US07540955B2 Photocatalytic water treatment apparatus 有权
标题翻译：光催化水处理设备
公开(公告)号：US07540955B2
公开(公告)日：2009-06-02
申请号：US11400568
申请日：2006-04-07
申请人： Gary L. Hatch , Michael D. Steinhardt , Michael J. Kurth , Marc A. Anderson
发明人： Gary L. Hatch , Michael D. Steinhardt , Michael J. Kurth , Marc A. Anderson
IPC分类号： C02F1/32
CPC分类号： C02F1/725 , C02F1/001 , C02F1/325 , C02F2201/3223 , C02F2305/10
摘要： A cartridge for a water treatment system, effective to assist in the removal of contaminants by photocatalytic oxidation and by adsorption, includes a plurality of stacked disks, preferably made of a UV light transmissive material, which disks define circuitous flow paths for water being treated. In a preferred embodiment, the disk surfaces contacted by the water are provided with a coating of a catalyst, such as TiO2, activated by a UV light source positioned in the center of the cartridge.
摘要翻译：用于水处理系统的墨盒有效地帮助通过光催化氧化和吸附除去污染物，包括多个堆叠的盘，优选地由UV透光材料制成，该盘限定了被处理水的迂回流动路径。在优选实施例中，与水接触的盘表面设置有由位于盒的中心的UV光源激活的催化剂（例如TiO 2）的涂层。

37. 发明授权

US5342709A Battery utilizing ceramic membranes 失效
标题翻译：电池利用陶瓷膜
公开(公告)号：US5342709A
公开(公告)日：1994-08-30
申请号：US56452
申请日：1993-05-03
申请人： Mark S. Yahnke , Golan Shlomo , Marc A. Anderson
发明人： Mark S. Yahnke , Golan Shlomo , Marc A. Anderson
IPC分类号： H01M2/16 , H01M6/12 , H01M6/46 , H01M10/28
CPC分类号： H01M6/12 , H01M10/287 , H01M2/1646 , H01M2300/0014
摘要： A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range.
摘要翻译：基于使用陶瓷膜技术公开了薄膜电池。电池包括一对导电收集器，其上可以旋涂用于阳极和阴极的材料。分离器由浸渍有电解质的多孔金属氧化物陶瓷膜形成，使得在保持离子迁移率的同时保持电分离。整个电池可以制成小于10微米厚，同时在1伏范围内产生电位。

38. 发明授权

US5308454A Reactor process using metal oxide ceramic membranes 失效
标题翻译：使用金属氧化物陶瓷膜的反应器工艺
公开(公告)号：US5308454A
公开(公告)日：1994-05-03
申请号：US925443
申请日：1992-08-11
申请人： Marc A. Anderson
发明人： Marc A. Anderson
IPC分类号： C02F1/32 , C02F1/461 , C02F1/72 , C25B1/00 , C25B3/00
CPC分类号： C02F1/46104 , C25B1/003 , C02F1/32 , C02F1/725 , Y02P20/135 , Y10S204/03
摘要： A reaction vessel for use in photoelectrochemical reactions includes as its reactive surface a metal oxide porous ceramic membrane of a catalytic metal such as titanium. The reaction vessel includes a light source and a counter electrode. A provision for applying an electrical bias between the membrane and the counter electrode permits the Fermi levels of potential reaction to be favored so that certain reactions may be favored in the vessel. The electrical biasing is also useful for the cleaning of the catalytic membrane. Also disclosed is a method regenerating a porous metal oxide ceramic membrane used in a photoelectrochemical catalytic process by periodically removing the reactants and regenerating the membrane using a variety of chemical, thermal, and electrical techniques.
摘要翻译：用于光电化学反应的反应容器包括催化金属如钛的金属氧化物多孔陶瓷膜作为其反应性表面。反应容器包括光源和对电极。在膜和对电极之间施加电偏压的规定允许有利于费米能级的潜在反应，使得某些反应可能在容器中有利。电偏置也可用于清洁催化膜。还公开了一种再生用于光电化学催化方法的多孔金属氧化物陶瓷膜的方法，其通过使用各种化学，热和电技术周期性地除去反应物并再生膜。

39. 发明授权

US5208190A Microporous alumina ceramic membranes 失效
标题翻译：微孔氧化铝陶瓷膜
公开(公告)号：US5208190A
公开(公告)日：1993-05-04
申请号：US773168
申请日：1991-10-08
申请人： Marc A. Anderson , Guangyao Sheng
发明人： Marc A. Anderson , Guangyao Sheng
IPC分类号： B01D39/20 , B01D71/02 , C01F7/36 , C04B38/00
CPC分类号： B01D67/0048 , B01D71/027 , C04B38/0051 , B01D2323/08 , C04B2111/00801
摘要： Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

40. 发明授权

US5128064A Cadmium sulfide membranes 失效
标题翻译：硫化镉膜
公开(公告)号：US5128064A
公开(公告)日：1992-07-07
申请号：US694594
申请日：1991-05-02
申请人： Lubomir Spanhel , Marc A. Anderson
发明人： Lubomir Spanhel , Marc A. Anderson
IPC分类号： C01G11/02 , C09K11/56 , H01B1/10 , H01S3/16
CPC分类号： C09K11/565 , C01G11/02 , H01B1/10 , H01S3/16
摘要： A method is described for the creation of novel q-effect cadmium sulfide membranes. The membranes are made by first creating a dilute cadmium sulfide colloid in aqueous suspension and then removing the water and excess salts therefrom. The cadmium sulfide membrane thus produced is luminescent at room temperature and may have application in laser fabrication.
摘要翻译：描述了创建新型q-效应硫化镉膜的方法。膜通过首先在水悬浮液中产生稀释的硫化镉胶体，然后从其中除去水和过量的盐来制备。这样生成的硫化镉膜在室温下是发光的，可以应用于激光制造。

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