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    • 32. 发明授权
    • Pyridyl esters of N-alkylidene-substituted phosphor- and phosphonamidic
acids
    • N-亚烷基取代的磷 - 和膦酰胺酸的吡啶基酯
    • US4226859A
    • 1980-10-07
    • US46299
    • 1979-06-07
    • Leonard J. Stach
    • Leonard J. Stach
    • A01N57/32C07F9/58A01N57/24C07D213/02
    • C07F9/585A01N57/32
    • This invention discloses chemical compounds of the formula ##STR1## wherein X.sup.1 is selected from the group consisting of oxygen and sulfur; R.sup.1 is selected from the group consisting of hydrogen, alkyl, phenyl, alkoxy and alkylthio; R.sup.2 is selected from the group consisting of alkoxy, alkylthio, amino, alkylamino and dialkylamino; with the proviso that a maximum of one of R.sup.1 and R.sup.2 is alkoxy or alkylthio; Z is selected from the group consisting of alkyl, alkoxy, nitro and halogen; and n is an integer from 0 to 4; and wherein R.sup.3 is selected from the group consisting of alkyl, alkoxy, alkylthio and ##STR2## wherein X.sup.2 is selected from the group consisting of oxygen and sulfur; X.sup.3 is halogen; k is the integer 0 or 1; and 1 and m are each integers from 0 to 3.Further disclosed are insecticidal compositions utilizing the compound of the present invention.
    • 本发明公开了下式化合物,其中X1选自氧和硫; R 1选自氢,烷基,苯基,烷氧基和烷硫基; R2选自烷氧基,烷硫基,氨基,烷基氨基和二烷基氨基; 条件是R 1和R 2中的最多一个是烷氧基或烷硫基; Z选自烷基,烷氧基,硝基和卤素; n为0〜4的整数。 并且其中R 3选自烷基,烷氧基,烷硫基和其中X 2选自氧和硫; X3是卤素; k是整数0或1; 1和m各自为0至3的整数。还公开了利用本发明化合物的杀虫组合物。
    • 39. 发明授权
    • Compositions and methods of killing insects and acarids using
alkoxyimino carbamoyloxy phosphorus compounds
    • 杀虫剂和杀虫剂的组合物和方法使用烷基酰胺氧羰基磷酸酯化合物
    • US3937824A
    • 1976-02-10
    • US498496
    • 1974-08-19
    • Leonard J. Stach
    • Leonard J. Stach
    • C07F9/09C07F9/165C07F9/24C07F9/32C07F9/40C07F9/44A01N9/36
    • C07F9/44C07F9/091C07F9/1651C07F9/2408C07F9/3264C07F9/4075
    • This invention discloses compounds of the formula ##EQU1## wherein R.sup.1 is alkyl; R.sup.2 is selected from the group consisting of hydrogen, alkyl, alkenyl, haloalkyl and cycloalkyl; R.sup.3 is selected from the group consisting of hydrogen, alkyl, alkenyl, haloalkyl, cycloalkyl and ##EQU2## WHEREIN D is selected from the group consisting of alkyl, alkenyl, alkoxy, alkylthio, halogen, haloalkyl, nitro and dialkylamino; and u is an integer from 0 to 3; X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are independently selected from the group consisting of oxygen and sulfur; m and n are each integers from 0 to 1; Z.sup.1 is selected from the group consisting of alkyl, alkenyl and ##EQU3## WHEREIN A is selected from the group consisting of alkyl, alkenyl, alkoxy, alkylthio, haloalkyl, halogen, nitro, alkylsulfoxide, alkylsulfone and dialkylamino; and q and p are each integers from 0 to 3; Z.sup.2 is selected from the group consisting of hydrogen and Z.sup.1, provided that when Z.sup.2 is hydrogen then n is zero; and Y is selected from the group consisting of alkyl, alkenyl, alkoxy, alkenyloxy, alkylthio, amino, alkylamino, dialkylamino and ##EQU4## WHEREIN E is selected from the group consisting of alkyl, alkenyl, alkoxy, alkylthio, halogen, nitro, alkylsulfoxide, alkylsulfone and dialkylamino; f is an integer from 0 to 3; Q is selected from the group consisting of oxygen, sulfur, alkylene, alkyleneoxy and alkylenethio; and t is an integer from 0 to 1. The above compounds are useful as insecticides and acaricides.