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31. 发明申请

US20050101698A1 Nanocomposite material for the production of index of refraction gradient films 有权
$Nanocomposite material for the production of index of refraction gradient films$
标题翻译：用于生产折射率梯度膜的纳米复合材料
公开(公告)号：US20050101698A1
公开(公告)日：2005-05-12
申请号：US10500194
申请日：2003-01-03
申请人： Takamasa Harada , Fumio Kita , Andreas Zimmermann , Ulrike Dellwo , Martin Mennig , Peter Oliveira , Helmut Schmidt , Heike Schneider
发明人： Takamasa Harada , Fumio Kita , Andreas Zimmermann , Ulrike Dellwo , Martin Mennig , Peter Oliveira , Helmut Schmidt , Heike Schneider
IPC分类号： G03H1/02 , B32B27/18 , C08J7/04 , C08K3/00 , C08K9/04 , C08L83/04 , C08L101/00 , C09D4/02 , C09D7/12 , C09D163/00 , C09D183/06 , C09D183/07 , C09D201/00 , G02B1/04 , G02B3/00 , C08K9/10
CPC分类号： C08L83/06 , C08K3/013 , C09D183/06 , G02B1/04 , G03H2260/12 , C08L2666/04
摘要： The invention relates to solid or gel-type nanocomposite material which can be polymerised, containing a) 4.9 95.9 wt. % of a soluble polymer; b) 4-95 wt. % of a partially or totally condensed silane selected from the group of epoxyalkoxysilanes, alkoxysilanes and alkylalkoxysilanes, the silane having an inorganic condensation degree of between 33-100% and an organic conversion degree of between 0-95%; c) 0-60 wt. % of an acrylate; d) 0.1-50 wt. % of surface modified nanometric particles selected from the group of oxides, sulphides, selenides, tellurides, halogenides, carbides, arsenides, antimonides, nitrides, phosphides, carbonates, carboxylates, phosphates, sulphates, silicates, titanates, zirconates, aluminates, stannates, plumbates and a mixed oxides; e) 0-50 wt.-% of a plasticiser, f) 0-5 wt. % of a thermal or photochemical cross-linking initiator, sensitizer, auxiliary wetting agent, adhesive agent, antioxidant, stabiliser, colouring agent, photochrome material and thermochrome material in relation to the total weight (dry weight) of the nanocomposite material.
摘要翻译：本发明涉及可以聚合的固体或凝胶型纳米复合材料，其包含a）4.9 95.9wt。％的可溶性聚合物; b）4-95wt。选自环氧烷氧基硅烷，烷氧基硅烷和烷基烷氧基硅烷的部分或全部冷凝的硅烷的％，硅烷的无机缩合度在33-100％之间，有机转化度在0-95％之间; c）0-60wt。％的丙烯酸酯; d）0.1-50wt。选自氧化物，硫化物，硒化物，碲化物，卤化物，碳化物，砷化物，锑化物，氮化物，磷化物，碳酸盐，羧酸盐，磷酸盐，硫酸盐，硅酸盐，钛酸盐，锆酸盐，铝酸盐，锡酸盐，铅酸铅的表面改性纳米颗粒的％和混合氧化物; e）0-50重量％的增塑剂，f）0-5重量％相对于纳米复合材料的总重量（干重），热或光化学交联引发剂，敏化剂，辅助润湿剂，粘合剂，抗氧化剂，稳定剂，着色剂，感光材料和热变色材料的％。

32. 发明授权

US06863923B1 Method and compositions for printing substrates 失效
标题翻译：用于印刷基材的方法和组合物
公开(公告)号：US06863923B1
公开(公告)日：2005-03-08
申请号：US10088794
申请日：2000-09-28
申请人： Axel Kalleder , Rainer Kreutzer , Martin Mennig , Helmut Schmidt
发明人： Axel Kalleder , Rainer Kreutzer , Martin Mennig , Helmut Schmidt
IPC分类号： H01B1/20 , B41M1/12 , B41M1/26 , B41M1/28 , B41M1/30 , B41M1/34 , B41M7/00 , C03C17/00 , C08L83/04 , H01B13/00 , H01L21/48 , H05K1/09 , B05D3/02
CPC分类号： H01L21/4867 , B41M1/12 , B41M1/26 , B41M1/28 , B41M1/30 , B41M1/34 , B41M7/009 , C03C17/007 , C03C17/008 , C03C2217/445 , C03C2217/475 , C03C2217/479 , C03C2217/485 , C03C2218/113 , C08G77/04 , C08G77/045 , C08G77/16 , C08L83/04 , H05K1/092 , H05K1/095 , Y10T428/31663 , C08L2666/54
摘要： Processes and compositions for printing substrates. A printing paste containing a matrix-forming precondensate containing polyorganosiloxanes obtained by a sol-gel process and at least one coloring, luminescent, conductive and/or catalytically active filler is applied imagewise to the substrate and is densified by heat treatment at a temperature below the glass transition temperature of the matrix being formed. The processes and printing pastes are suitable, for example, for the production of conductor tracks and decorative patterns.
摘要翻译：用于印刷基材的方法和组合物。将含有通过溶胶 - 凝胶法和至少一种着色，发光，导电和/或催化活性填料获得的含有聚有机硅氧烷的基质形成预缩合物的印刷浆料成像施加到基材上，并通过在低于形成基体的玻璃化转变温度。工艺和印刷浆料适用于例如生产导体轨迹和装饰图案。

33. 发明授权

US06790532B1 Coating composition, based on organically modified inorganic condensates 失效
标题翻译：涂料组合物，基于有机改性无机缩合物
公开(公告)号：US06790532B1
公开(公告)日：2004-09-14
申请号：US10111175
申请日：2002-04-18
申请人： Andreas Gier , Martin Mennig , Helmut Schmidt
发明人： Andreas Gier , Martin Mennig , Helmut Schmidt
IPC分类号： B32B904
CPC分类号： C09D183/08 , C03C17/30 , C09D183/14 , Y10T428/31663
摘要： A coating composition comprises a polycondensate obtained by reacting a prehydrolysate based on at least on epoxide-containing hydrolysable silane; at least one amine component selected from a prehydrolysate based on at least one amino-containing hydrolysable silane and an amine compound containing at least two amino groups; and an amino group protective reagent. The coating composition is particulary suitable for coating glass, glass ceramic, ceramic, and plastic, and permits an increase in strength and protection against damage.
摘要翻译：涂料组合物包含通过基于至少含有环氧化物的可水解硅烷使预水解产物反应获得的缩聚物; 至少一种胺组分，其选自基于至少一种含氨基的可水解硅烷的预水解产物和含有至少两个氨基的胺化合物; 和氨基保护试剂。涂料组合物特别适用于涂覆玻璃，玻璃陶瓷，陶瓷和塑料，并且允许增加强度和防止损坏。

34. 发明授权

US06378599B1 Foundry binder 有权
标题翻译：铸造粘合剂
公开(公告)号：US06378599B1
公开(公告)日：2002-04-30
申请号：US09297572
申请日：1999-05-03
申请人： Helmut Schmidt , Martin Mennig , Gerhard Jonschker
发明人： Helmut Schmidt , Martin Mennig , Gerhard Jonschker
IPC分类号： B22C116
CPC分类号： C09C3/12 , C01P2004/64 , C03C17/007 , C03C2217/445 , C03C2217/475 , C09D183/04 , C08L2666/54
摘要： A foundry binder is obtainable by surface modification of a) colloidal inorganic particles with b) one or more silanes of the general formula (I) Rx—Si—A4−x (I) where the radicals A are identical or different and are hydroxyl groups or groups which can be removed hydrolytically, except methoxy, the radicals R are identical or different and are groups which cannot be removed hydrolytically and x is 0, 1, 2 or 3, where x≧1 in at least 50 mol % of the silanes; under the conditions of the sol-gel process with a below-stoichiometric amount of water, based on the hydrolysable groups which are present, with formation of a nanocomposite sol, and further hydrolysis and condensation of the nanocomposite sol, if desired, before it is brought into contact with the foundry sand.
摘要翻译：一种铸造粘结剂可以通过a）胶体无机颗粒的表面改性获得，b）一种或多种通式（I）的硅烷，其中基团A相同或不同，并且是羟基或水解除外的基团，除了甲氧基，基团R相同或不同，并且是不能被水解除去的基团，x是0,1,2或3，其中在至少50mol％的硅烷中x> = 1;在溶胶 - 凝胶法与基于存在的可水解基团，形成纳米复合溶胶的低于化学计算量的水，并且如果需要，在与铸造砂接触之前，进一步水解和缩合纳米复合溶胶。

35. 发明授权

US6162498A Method for providing a metal surface with a vitreous layer 有权
标题翻译：提供具有玻璃质层的金属表面的方法
公开(公告)号：US6162498A
公开(公告)日：2000-12-19
申请号：US402742
申请日：1999-10-08
申请人： Martin Mennig , Gerhard Jonschker , Helmut Schmidt
发明人： Martin Mennig , Gerhard Jonschker , Helmut Schmidt
IPC分类号： C03C1/00 , C23C18/12 , B05D3/02
CPC分类号： C03C1/008 , C03C2207/00 , C03C2207/04 , C03C2207/08 , C23C18/1212 , C23C18/1225 , C23C18/1241 , C23C18/127 , C23C18/1295 , Y02T50/67
摘要： Disclosed is a process for providing a metallic surface with a vitreous layer which is both decorative and scratch resistant and corrosion inhibiting. Said process is characterized in that a coating composition which is obtainable by a process comprising the hydrolysis and polycondensation of one or more silanes of the general formula (I)R.sub.n SiX.sub.4-n (I)wherein the groups X, the same or different from each other, are hydrolyzable groups or hydroxyl groups, the radicals R, the same or different from each other, represent hydrogen, alkyl, alkenyl or alkynyl groups having up to 12 carbon atoms and aryl, aralkyl and alkaryl groups having 6 to 10 carbon atoms, and n is 0, 1 or 2, provided that at least one silane with n=1 or 2 is employed, or oligomers derived therefrom, in the presence ofa) nanoscaled SiO.sub.2 particles and/orb) at least one compound selected from the group consisting of the oxides and hydroxides of the alkali and alkaline earth metals;is applied onto said metallic surface and the resulting coating is thermally densified to form a vitreous layer.
摘要翻译： PCT No.PCT / EP98 / 02076 Sec。 371 1999年10月8日第 102（e）1999年10月8日PCT PCT 1998年4月9日PCT公布。公开号WO98 / 45502 日期1998年10月15日公开是为金属表面提供玻璃质层的方法，其具有装饰性和耐刮擦性和腐蚀抑制性。所述方法的特征在于，通过包括通式（I）的R 1 SiX 4-n（I）的一种或多种硅烷的水解和缩聚的方法获得的涂料组合物，其中基团X彼此相同或不同是可水解基团或羟基，基团R彼此相同或不同，表示具有至多12个碳原子的氢，烷基，烯基或炔基和具有6至10个碳原子的芳基，芳烷基和烷芳基，以及 n是0,1或2，条件是在a）纳米尺度的SiO 2颗粒和/或b）存在下，使用至少一种n = 1或2的硅烷或由其衍生的低聚物，或b）至少一种选自以下的化合物由碱金属和碱土金属的氧化物和氢氧化物组成; 施加到所述金属表面上，并将所得涂层热致密化以形成玻璃质层。

36. 发明授权

US6156388A Method for manufacturing substrates with transparent and color coatings stable at high temperatures and in the presence of ultraviolet rays 失效
标题翻译：用于制造在高温和紫外线存在下稳定的透明和彩色涂层的基材的方法
公开(公告)号：US6156388A
公开(公告)日：2000-12-05
申请号：US297163
申请日：1999-04-26
申请人： Klaus Endres , Marion Lindenstruth , Martin Mennig , Matthias Pietsch , Helmut Schmidt
发明人： Klaus Endres , Marion Lindenstruth , Martin Mennig , Matthias Pietsch , Helmut Schmidt
IPC分类号： B32B17/06 , C03C17/00 , C03C17/25 , C04B41/50 , C04B41/87 , C09D1/00 , C23C18/12 , H01J9/20 , H01J61/35 , H01J61/38 , H01K1/32 , B05D3/02 , B05D5/06 , C03C8/18
CPC分类号： H01K1/32 , C03C17/007 , C03C17/008 , C04B41/009 , C04B41/5027 , C04B41/87 , C23C18/1216 , C23C18/1245 , C23C18/1254 , H01J61/38 , H01J9/20 , C03C2217/45 , C03C2217/479 , C04B2111/80 , Y10S501/905
摘要： A method of manufacturing a substrate coated with a transparent, colored coating stable to high temperature and UV includes coating the substrate with a coating composition including at least one element which is able to form a vitreous, crystalline, or partially crystalline oxide, in the form of a compound which on heat treatment yields the oxide and is present as a sol or solution in an at least predominantly aqueous medium, as the matrix-forming component, and at least one member selected from the group consisting of metal colloids, metal compound colloids, metal alloy colloids, and metal compounds which form metal colloids under reducing conditions, as the coloring component; and heat-curing the resulting coating. Particularly suitable substrates are glass substrates, such as (halogen) lamp bulbs and gas discharge tubes.
摘要翻译： PCT No.PCT / EP97 / 06006 Sec。 371日期1999年4月26日 102（e）日期1999年4月26日PCT 1997年10月30日PCT公布。公开号WO98 / 18736 日期1998年5月7日制造涂覆有稳定于高温和UV的透明着色涂层的基材的方法包括用包含至少一种能够形成玻璃态，结晶状或部分结晶氧化物的元素的涂料组合物涂覆基材以化合物的形式，其在热处理下产生氧化物并且以至少主要是水性介质中的溶胶或溶液形式存在，作为基质形成组分，以及选自金属胶体中的至少一种金属化合物胶体，金属合金胶体和在还原条件下形成金属胶体的金属化合物作为着色成分; 并对所得涂层进行热固化。特别合适的基板是玻璃基板，例如（卤素）灯泡和气体放电管。

37. 发明授权

US06136083A Coated inorganic pigments, process for their production and their use 失效
标题翻译：涂层无机颜料，其生产和使用的过程
公开(公告)号：US06136083A
公开(公告)日：2000-10-24
申请号：US952975
申请日：1997-12-08
申请人： Helmut Schmidt , Martin Mennig , Axel Kalleder
发明人： Helmut Schmidt , Martin Mennig , Axel Kalleder
IPC分类号： C04B33/14 , C04B41/80 , C09C1/00 , C09C1/30 , C09C1/36 , C09C1/56 , C09C1/62 , C09C3/06 , C09D1/00
CPC分类号： C09C1/3054 , C09C1/3661 , C09C1/56 , C09C1/62 , C09C3/063 , C01P2002/88 , C01P2004/62 , C01P2004/64 , Y10T428/2911 , Y10T428/2991 , Y10T428/2993
摘要： A description is given of coated inorganic pigments comprising an organic pigment which has a coating, prepared by the sol-gel process from glass-forming components and densified to form a xerogel or glass, having a layer thickness of at least 0.8 .mu.m. These pigments are prepared by spray drying a sol-pigment dispersion, followed if desired by thermal densification of the xerogel layer to form a glass layer. The coated pigments are suitable for producing enamels and moldings.
摘要翻译： PCT No.PCT / EP96 / 02017 Sec。 371 1997年12月8日第 102（e）日期1997年12月8日PCT提交1996年5月10日PCT公布。公开号WO96 / 41840 日期1996年12月27日描述了包含有机颜料的涂层无机颜料，其具有通过溶胶 - 凝胶法由玻璃形成组分制备并致密化以形成干凝胶或玻璃的有机颜料，其具有至少 0.8亩。这些颜料通过喷雾干燥溶胶 - 颜料分散体制备，随后如果需要，干燥剂层的热致密化以形成玻璃层。涂覆的颜料适用于生产搪瓷和模制品。

38. 发明授权

US5716424A Method of producing glass substrates with improved long-term rigidity at elevated temperatures 失效
标题翻译：在高温下生产具有改善的长期刚性的玻璃基材的方法
公开(公告)号：US5716424A
公开(公告)日：1998-02-10
申请号：US338516
申请日：1994-12-09
申请人： Martin Mennig , Gerhard Jonschker , Helmut Schmidt
发明人： Martin Mennig , Gerhard Jonschker , Helmut Schmidt
IPC分类号： C03C17/22 , C03C17/02 , C03C17/25 , C03C25/10 , C09D185/00 , D06M13/02 , D06M13/50 , D06M13/503 , D06M13/507 , D06M13/51 , D06M13/513 , D06M101/00 , C03C17/00
CPC分类号： C03C17/02 , C03C17/25 , C03C2217/229 , C03C2217/23 , C03C2218/113
摘要： Described is a process for the manufacture of glass substrates with improved long-term stability at raised temperatures, in which process a glass substrate is provided with a coating, this coating being prepared from a composition, which was obtained through hydrolysis and condensation of a compound that was dissolved in a solvent and belonged to at least one element from the group Si, Al, Ti and Zr and/or a suitable precondensate, optionally in combination with compounds, which are soluble in the reaction medium, of at least one element from the group of alkali metals, alkali earth metals, and boron. After the coating composition is deposited, the coating obtained thus is heat treated. The process is characterized in that the coating is not completely compacted.
摘要翻译： PCT No.PCT / EP93 / 00484 Sec。 371 1994年12月9日第 102（e）日期1994年12月9日PCT 1993年3月3日PCT公布。出版物WO93 / 24424 PCT 日期1993年12月2日描述了一种在升高的温度下具有改善的长期稳定性的玻璃基材的制造方法，其中玻璃基板具有涂层，该涂层由通过水解获得的组合物制备和溶解在溶剂中并属于Si，Al，Ti和Zr族中的至少一种元素的化合物和/或合适的预缩合物，任选地与可溶于反应介质的化合物组合，来自碱金属，碱土金属和硼的至少一种元素。在沉积涂料组合物后，由此得到的涂层进行热处理。该方法的特征在于涂层未完全压实。

39. 发明授权

US08133573B2 Scratch-resistant optical multi-layer system applied to a crystalline substrate 失效
标题翻译：耐刮擦光学多层系统应用于晶体衬底
公开(公告)号：US08133573B2
公开(公告)日：2012-03-13
申请号：US10591598
申请日：2005-03-16
申请人： Mohammad Jilavi , Martin Mennig , Peter William Oliveira , Helmut Schmidt
发明人： Mohammad Jilavi , Martin Mennig , Peter William Oliveira , Helmut Schmidt
IPC分类号： B32B5/16 , G02B1/10
CPC分类号： G02B1/02 , G02B1/115 , G04B39/006 , Y10T428/24628 , Y10T428/25 , Y10T428/256 , Y10T428/257 , Y10T428/31855
摘要： A process for producing a crystalline substrate with an optical multi-layer system thereon and the crystalline substrate obtainable thereby. The process comprises the successive application of at least two free-flowing compositions which comprise nanoscale inorganic solid particles comprising at least one of a polymerizable and a polycondensable organic group to a surface of the crystalline substrate and the polymerization and/or polycondensation of the organic groups of the solid particles to form organically crosslinked layers on the substrate and a single-stage thermal consolidation of these layers with a burnout of organic constituents thereof. The at least two compositions give rise to layers with different refractive indices.
摘要翻译：一种其上具有光学多层系统的晶体衬底的制造方法以及由此获得的结晶衬底。该方法包括连续施加至少两种自由流动的组合物，其包含纳米级无机固体颗粒，其包含可聚合和可缩聚有机基团中的至少一种，并且至少在有机基团的表面上进行聚合和/或缩聚的固体颗粒以在衬底上形成有机交联层，并且这些层的单层热固化与其有机组分的烧尽。至少两种组合物产生具有不同折射率的层。

40. 发明授权

US08119221B2 Composition having a non-Newtonian behavior 有权
标题翻译：具有非牛顿行为的组合
公开(公告)号：US08119221B2
公开(公告)日：2012-02-21
申请号：US11269593
申请日：2005-11-09
申请人： Martin Mennig , Peter W. Oliveira , Helmut Schmidt
发明人： Martin Mennig , Peter W. Oliveira , Helmut Schmidt
IPC分类号： B32B5/00 , B32B9/04
CPC分类号： C08J5/005 , B82Y30/00 , C08K9/02 , C08K9/04 , Y10T428/24355 , Y10T428/24372 , Y10T428/24388 , Y10T428/24479 , Y10T428/24802 , Y10T428/24893 , Y10T428/31663
摘要： A composition with non-Newtonian behaviour which comprises a matrix former and nanoscale solid particles whose surface charge has been increased by reaction with an acid or base, and a process for the preparation thereof. The process is suitable for adjusting the rheology of materials.
摘要翻译：具有非牛顿行为的组合物及其制备方法，其包含基质前体和表面电荷通过与酸或碱反应而增加的纳米级固体颗粒。该方法适用于调节材料的流变性。

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