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    • 32. 发明授权
    • Process and apparatus for producing ketoisophorone
    • 用于生产酮异佛尔酮的方法和设备
    • US06346651B1
    • 2002-02-12
    • US09482923
    • 2000-01-14
    • Tomohide InaNoboru KameiHiroyuki Miura
    • Tomohide InaNoboru KameiHiroyuki Miura
    • C07C4528
    • C07C45/67B01J8/20B01J19/002B01J19/18B01J31/0235B01J31/1805B01J2208/00283B01J2208/00707B01J2208/00867C07C45/34C07C45/82C07C49/603
    • &bgr;-isophorone is formed by isomerizing &agr;-isophorone in the presence of an isomerizing catalyst (an aliphatic C5-20 polycarboxylic acid) in an isomerizing-reaction unit 1. The &bgr;-isophorone thus formed is oxidized with oxygen in an inert solvent in the presence of an oxidizing catalyst (a complex salt of a transition metal and an N,N′-disalicylidenediamine) in an oxidizing-reaction unit 2, thereby forming ketoisophorone. After removing a low-boiling point component, which is an impurity (non-conjugated cyclic ketone), from the reaction mixture using a distilling unit 3, a high-boiling component (oxidizing catalyst) is separated in a distilling unit 4, and then ketoisophorone is separated from the solvent in the separation unit 5. Thereafter, the solvent containing 0 to 5,000 ppm (weight basis) of the impurities and substantially free from ketoisophorone is recycled to the oxidizing reaction through a recycling line 6. According to the present invention, the combination of the isomerizing reaction and the oxidizing reaction makes it possible to produce ketoisophorone from &agr;-isophorone while maintaining the activity of the oxydizing catalyst.
    • 在异构化反应单元1中异构化催化剂(脂族C 5-20多元羧酸)存在下,通过异构化α-异佛尔酮形成β-异佛尔酮。由此形成的β-异佛尔酮在惰性溶剂中用氧气 在氧化反应单元2中存在氧化催化剂(过渡金属和N,N'-二水杨酸二胺的配盐),从而形成酮异佛尔酮。 使用蒸馏单元3从反应混合物中除去作为杂质(非共轭环酮)的低沸点成分后,在蒸馏单元4中分离高沸点成分(氧化催化剂),然后 在分离单元5中将酮异二酮与溶剂分离。此后,含有0〜5,000ppm(重量)的杂质且基本上不含酮异二酮的溶剂通过再循环管线6再循环至氧化反应。根据本发明 异构化反应和氧化反应的组合使得可以在保持氧化催化剂的活性的同时,从α-异佛尔酮生产酮异二酮。
    • 33. 发明授权
    • Process for producing acetic acid
    • 生产乙酸的方法
    • US09115071B2
    • 2015-08-25
    • US13994373
    • 2011-12-01
    • Masahiko ShimizuRyuji SaitoHiroyuki Miura
    • Masahiko ShimizuRyuji SaitoHiroyuki Miura
    • C07C51/12
    • C07C51/12C07C53/08
    • Acetic acid is produced while inhibiting an increased concentration or production of hydrogen iodide in a carbonylation reactor or corrosion of the carbonylation reactor.A production process of acetic acid comprises a reaction step for continuously allowing methanol to react with carbon monoxide in the presence of a catalyst system comprising a metal catalyst (e.g., a rhodium catalyst), an ionic iodide (e.g., lithium iodide), and methyl iodide in a carbonylation reactor; and in the process, (i) the concentration of the metal catalyst is maintained at not less than 860 ppm on the basis of weight, the concentration of water is maintained at 0.8 to 15% by weight, the concentration of methyl iodide is maintained at not more than 13.9% by weight, and the concentration of methyl acetate is maintained at not less than 0.1% by weight, in a whole liquid phase in the reactor, and/or (ii) the concentration of the metal catalyst is maintained at not less than 660 ppm on the basis of weight, the concentration of water is maintained at 0.8 to 3.9% by weight, the concentration of the ionic iodide is maintained at not more than 13% by weight, the concentration of methyl iodide is maintained at not more than 13.9% by weight, and the concentration of methyl acetate is maintained at not less than 0.1% by weight, in a whole liquid phase in the reactor.
    • 产生乙酸,同时抑制羰基化反应器中碘化氢的浓度增加或羰基化反应器的腐蚀。 乙酸的生产方法包括在包含金属催化剂(例如,铑催化剂),离子碘化物(例如碘化锂)和甲基的催化剂体系存在下,连续使甲醇与一氧化碳反应的反应步骤 碘化物在羰基化反应器中; 在该过程中,(i)金属催化剂的浓度基于重量维持在不低于860ppm,水的浓度保持在0.8至15重量%,甲基碘的浓度保持在 不超过13.9重量%,乙酸甲酯的浓度在反应器的整个液相中保持在不小于0.1重量%,和/或(ii)金属催化剂的浓度保持不变 基于重量小于660ppm,水的浓度保持在0.8〜3.9重量%,离子碘的浓度保持在不超过13重量%,甲基碘的浓度保持不变 大于13.9重量%,并且在反应器中的整个液相中,乙酸甲酯的浓度保持在不小于0.1重量%。
    • 35. 发明授权
    • Piezoelectric device
    • 压电元件
    • US08749123B2
    • 2014-06-10
    • US13074672
    • 2011-03-29
    • Yoichi MurakiTomohiro OhyaAtsushi MuraokaHiroyuki Miura
    • Yoichi MurakiTomohiro OhyaAtsushi MuraokaHiroyuki Miura
    • H03H9/10
    • H03H9/1021G01K7/16G01K7/32H03H9/0552
    • A piezoelectric device has a plate-shaped substrate, a first frame defining a first concave portion at one surface of the substrate, a second frame defining a second concave portion at the other surface of the substrate, a first electrode member provided at one surface of the substrate, a second electrode member provided at the other surface of the substrate, a piezoelectric unit in which a first electrode section of the piezoelectric vibration plate is fixed to the first electrode member by a conductive binder, a cover sealing the first concave portion, and a temperature detection unit in which a second electrode section of the thermistor element is fixed to the second electrode member by a conductive joining material.
    • 压电装置具有板状基板,在基板的一个表面限定第一凹部的第一框架,在基板的另一表面限定第二凹部的第二框架,设置在基板的一个表面的第一电极构件 基板,设置在基板的另一个表面的第二电极部件,压电单元,压电振动板的第一电极部分通过导电粘合剂固定到第一电极部件,密封第一凹部的盖子, 以及温度检测单元,其中热敏电阻元件的第二电极部分通过导电接合材料固定到第二电极部件。
    • 37. 发明授权
    • Distillation process
    • 蒸馏过程
    • US07884241B2
    • 2011-02-08
    • US11791326
    • 2005-12-05
    • Hiroyuki MiuraKenichiro Kawazumi
    • Hiroyuki MiuraKenichiro Kawazumi
    • C07C51/42
    • C07C51/44C07C53/08
    • A mixture containing hydrogen iodide and water and having a water content of not more than 5% by weight (particularly not more than 3% by weight) in a distillation system is distilled to prevent condensation of hydrogen iodide in the distillation system. The mixture may comprise hydrogen iodide, water, methanol, methyl iodide, acetic acid, and methyl acetate. Even when the mixture contains hydrogen iodide at a concentration of 1 to 3000 ppm on the basis of weight, an acetic acid product having a concentration of hydrogen iodide of not more than 50 ppm can be obtained by withdrawing a fraction containing hydrogen iodide from the top of the column, and withdrawing acetic acid as a side-cut stream or a stream from the bottom of the column. Such a process (distillation process) effectively inhibits condensation of hydrogen iodide in the distillation system and corrosion in the distillation system.
    • 在蒸馏系统中蒸馏含有碘化氢和水并且含水量不超过5重量%(特别是不超过3重量%)的混合物,以防止蒸馏系统中碘化氢的冷凝。 该混合物可以包含碘化氢,水,甲醇,甲基碘,乙酸和乙酸甲酯。 即使当混合物含有基于重量的浓度为1至3000ppm的碘化氢时,可以通过从顶部抽出含有碘化氢的馏分来获得碘化氢浓度不大于50ppm的乙酸产物 并且从塔的底部排出乙酸作为侧馏分物流或物流。 这种方法(蒸馏方法)有效地抑制了蒸馏系统中碘化氢的冷凝和蒸馏系统中的腐蚀。