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31. 发明授权

US07553883B2 Aqueous pigment ink composition and method of manufacturing the same 有权
标题翻译：水性颜料墨水组合物及其制造方法
公开(公告)号：US07553883B2
公开(公告)日：2009-06-30
申请号：US11130431
申请日：2005-05-16
申请人： Masahiro Yatake
发明人： Masahiro Yatake
IPC分类号： C09D11/00
CPC分类号： C09D11/322
摘要： The invention provides an aqueous pigment ink composition that ensures excellent recording characteristics on any type of recording mediums. An aqueous pigment ink composition of the invention includes a pigment, a water-dispersible polymer, water, and a water-soluble organic solvent, where the pigment is dispersed as primary particles having an average primary particle diameter of not greater than 50 nm and as secondary particles having a ratio of an average secondary particle diameter to the average primary particle diameter in a range of 1 to 10, and the water-dispersible polymer has a minimum glass transition temperature of lower than 100° C. Using this polymer ensures good dispersion stability and favorable glossiness on a glossy medium.
摘要翻译：本发明提供一种在任何类型的记录介质上确保优异的记录特性的水性颜料油墨组合物。本发明的水性颜料墨水组合物包含颜料，水分散性聚合物，水和水溶性有机溶剂，其中颜料分散为平均一次粒径不大于50nm的一次粒子，并且以二次粒子的平均二次粒径与平均一次粒径的比例在1〜10的范围内，水分散性聚合物的玻璃化转变温度低于100℃。使用该聚合物可确保良好的分散性在光泽介质上的稳定性和良好的光泽度。

32. 发明申请

US20080146727A1 Ink-jet recording ink 有权
标题翻译：喷墨记录油墨
公开(公告)号：US20080146727A1
公开(公告)日：2008-06-19
申请号：US12001522
申请日：2007-12-12
申请人： Masahiro Yatake
发明人： Masahiro Yatake
IPC分类号： C09D11/10
CPC分类号： C09D11/326
摘要： An inkjet recording ink comprising water, a pigment dispersed using a polymer having an acid value of at least 50 mg KOH/g but not more than 200 mg KOH/g and a weight-average molecular weight of at least 20,000 but not more than 120,000, along with an alkyl alcohol polyoxypropylene and polyoxyethylene addition product with 8 to 16 carbon atoms.
摘要翻译：包含水的喷墨记录油墨，使用酸值至少为50mg KOH / g但不大于200mg KOH / g，重均分子量为至少20,000但不超过120,000的聚合物分散的颜料以及具有8至16个碳原子的烷基醇聚氧丙烯和聚氧乙烯加成产物。

33. 发明授权

US07307110B2 Water-based pigment ink composition 有权
标题翻译：水性颜料墨水组合物
公开(公告)号：US07307110B2
公开(公告)日：2007-12-11
申请号：US10468238
申请日：2002-02-22
申请人： Masahiro Yatake
发明人： Masahiro Yatake
IPC分类号： C09D11/10 , C08K9/10 , C08K9/04
CPC分类号： B82Y30/00 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/22 , C01P2006/60 , C09C3/08 , C09C3/10 , C09D11/322 , C09D11/324
摘要： Disclosed is a water-based pigment ink composition comprising, as colorants, (1) a surface treated pigment having a water-dispersibility imparting group introduced to the surface thereof and (2) a water-dispersible polymer-encapsulated pigment which is a pigment wholly coated with a polymer. The water-based ink composition exhibits good color developability and satisfactory abrasion resistance, causes little blurring, and has excellent storage stability.
摘要翻译：公开了一种水性颜料墨水组合物，其包含作为着色剂的（1）向其表面引入的赋予水的分散性基团的表面处理颜料，（2）作为颜料的水分散性聚合物包封颜料涂覆聚合物。水性油墨组合物显色性良好，耐磨性良好，模糊不清，贮存稳定性优异。

34. 发明申请

US20070054980A1 Ink for inkjet recording 有权
标题翻译：墨水用于喷墨记录
公开(公告)号：US20070054980A1
公开(公告)日：2007-03-08
申请号：US11407380
申请日：2006-04-19
申请人： Masahiro Yatake , Yasuhiro Oki , Motoki Masuda , Hiroko Hayashi
发明人： Masahiro Yatake , Yasuhiro Oki , Motoki Masuda , Hiroko Hayashi
IPC分类号： C03C17/00 , C09D11/00
CPC分类号： C09D11/326
摘要： An ink for inkjet recording of the invention includes water and a pigment, where the pigment is dispersed using a polymer having a refractive index of at least 1.58 or more, an acid value of 50 mgKOH/g to 120 mgKOH/g, and a weight average molecular weight of 20000 to 120000. It is preferable that the polymer is prepared by using a (meta)acrylate and/or a sulfur-containing (meth)acrylate which have at least a plurality of aromatic rings.
摘要翻译：本发明的喷墨记录用油墨包括水和颜料，其中使用折射率为至少1.58以上，酸值为50mgKOH / g至120mgKOH / g的聚合物和颜料的重量分散颜料平均分子量为20000至120000.优选使用具有至少多个芳环的（甲基）丙烯酸酯和/或含硫（甲基）丙烯酸酯制备聚合物。

35. 发明授权

US07052536B2 Water-based ink 失效
标题翻译：水性油墨
公开(公告)号：US07052536B2
公开(公告)日：2006-05-30
申请号：US10677627
申请日：2003-10-02
申请人： Masahiro Yatake
发明人： Masahiro Yatake
IPC分类号： C09D11/00
CPC分类号： C09D11/322 , C09D11/38
摘要： There is provided a water-based ink that gives good coloration and little blurring on regular paper, gives adequate coloration on specialist paper, and has good fixability, and further gives excellent discharge stability with ink jet recording, and moreover exhibits the effect of a chelating agent even in a small amount, and is not harmful due to evaporating, subliming or the like. The water-based ink of the present invention comprises a colorant, water, a water-soluble organic solvent, a surfactant, and a chelating agent, wherein the chelating agent is nitrilotriacetic acid (NTA) or a salt thereof, methylglycine diacetic acid (MGDA) or a salt thereof, L-glutamine diacetic acid (GLDA) or a salt thereof, L-aspartic acid diacetic acid (ASDA) or a salt thereof, diethylenetriamine pentaacetic acid (DTPA) or a salt thereof, gluconic acid (GA) or a salt thereof, citric acid (CA) or a salt thereof, nitrilotripropionic acid (NTP) or a salt thereof, nitrilotrisphosphonic acid (NTPO) or a salt thereof, dihydroxyethylglycine (DHEG) or a salt thereof, hydroxyethyliminodiacetic acid (HIDA) or a salt thereof, 1,3-diamino-2-hydroxypropane tetraacetic acid (DPTA-OH) or a salt thereof, hydroxyethylidene diphosphonic acid (HEDP) or a salt thereof, nitrilotrimethylene phosphonic acid (NTMP) or a salt thereof, or phosphonobutane tricarboxylic acid (PBTC) or a salt thereof.
摘要翻译：提供了一种水性油墨，其在常规纸上具有良好的着色和模糊，在专用纸上赋予足够的着色性，并且具有良好的定影性，并且通过喷墨记录进一步提供优异的喷射稳定性，此外还显示出螯合作用即使少量，并且由于蒸发，升华等而不是有害的。本发明的水性油墨包括着色剂，水，水溶性有机溶剂，表面活性剂和螯合剂，其中螯合剂是次氮基三乙酸（NTA）或其盐，甲基甘氨酸二乙酸（MGDA ）或其盐，L-谷氨酰胺二乙酸（GLDA）或其盐，L-天冬氨酸二乙酸（ASDA）或其盐，二亚乙基三胺五乙酸（DTPA）或其盐，葡萄糖酸（GA）或其盐，柠檬酸（CA）或其盐，次氮基丙酸（NTP）或其盐，次氮基三膦酸（NTPO）或其盐，二羟基乙基甘氨酸（DHEG）或其盐，羟乙基亚氨基二乙酸（HIDA）或其盐，1,3-二氨基-2-羟基丙烷四乙酸（DPTA-OH）或其盐，羟乙叉基二膦酸（HEDP）或其盐，次氮基三亚甲基膦酸（NTMP）或其盐或膦酸丁烷三羧酸（PBTC）或其盐。

36. 发明申请

US20050004261A1 Aqueous ink composition and method of manufacturing the same 失效
标题翻译：水性油墨组合物及其制造方法
公开(公告)号：US20050004261A1
公开(公告)日：2005-01-06
申请号：US10819096
申请日：2004-04-06
申请人： Masahiro Yatake
发明人： Masahiro Yatake
IPC分类号： B41J2/01 , B41M5/00 , C09D11/00 , C09D11/322 , C09D11/38 , C03C17/00 , C09D5/00
CPC分类号： C09D11/322 , C09D11/16
摘要： An aqueous ink composition comprising: a pigment, having a particle diameter as determined by the light scattering method of no less than 20 nm and no more than 200 nm; and a water dispersible polymer, having a styrene-equivalent number average molecular weight of as determined by gel permeation chromatography no less than 5000 and no more than 200000, having a surface tension of no less than 20 mN/m and no more than 40 mN/m, and wherein the abovementioned pigment is a polymer-coated pigment that is coated with the abovementioned water dispersible polymer, is provided. The water-dispersible polymer may be a copolymer of monomers, mainly comprising acrylic acid and/or methacrylic acid and an acrylate and/or methacrylate. With this ink composition, the printing quality can be improved.
摘要翻译：一种水性墨水组合物，其特征在于，含有：通过光散射法测定的粒径不小于20nm且不大于200nm的颜料; 和水分散性聚合物，其具有通过凝胶渗透色谱法测定的苯乙烯当量数均分子量不小于5000且不大于200000，表面张力不小于20mN / m且不大于40mN / m，并且其中上述颜料是涂覆有上述水分散性聚合物的聚合物涂覆的颜料。水分散性聚合物可以是主要包含丙烯酸和/或甲基丙烯酸和丙烯酸酯和/或甲基丙烯酸酯的单体的共聚物。利用这种油墨组合物，可以提高打印质量。

37. 发明授权

US06234601B1 Ink jet recording method and apparatus for forming an image on either plain paper or a specialty recording medium 失效
标题翻译：用于在普通纸或特种记录介质上形成图像的喷墨记录方法和装置
公开(公告)号：US06234601B1
公开(公告)日：2001-05-22
申请号：US09061386
申请日：1998-04-16
申请人： Hiroko Hayashi , Masahiro Yatake , Yoshiyuki Ozawa , Masayuki Momose
发明人： Hiroko Hayashi , Masahiro Yatake , Yoshiyuki Ozawa , Masayuki Momose
IPC分类号： B41J2938
CPC分类号： C09D11/30 , B41J2/01 , B41J2/2107 , B41J3/407 , B41M5/0017 , B41M5/0023 , B41M7/0018 , C09D11/40
摘要： An ink jet recording method which can produce a good image on both plain papers and specialty recording media for ink jet recording, and an ink jet recording apparatus for the ink jet recording method are disclosed. The ink jet recording method comprises: providing a black ink composition comprising a pigment as a colorant and a black ink composition comprising a dye as a colorant; and, when the recording medium comprises a gloss layer and/or an ink-receptive layer, printing only the black ink composition comprising a dye as the colorant on the recording medium, and, when the recording medium is plain paper, both the black ink composition comprising a pigment as the colorant and the black ink composition comprising a dye as the colorant are printed. According to this recording method, in the case of printing on plain paper, the density of black can be enhanced, while in the case of printing on a specialty paper for ink jet recording, an image having high chroma and good reproduction range can be produced.
摘要翻译：公开了能够在普通纸和用于喷墨记录的专用记录介质上产生良好图像的喷墨记录方法，以及用于喷墨记录方法的喷墨记录装置。喷墨记录方法包括：提供包含着色剂颜料和包含染料作为着色剂的黑色油墨组合物的黑色油墨组合物; 并且当记录介质包含光泽层和/或油墨接收层时，仅将包含染料的黑色油墨组合物作为着色剂印刷在记录介质上，并且当记录介质为普通纸时，黑色油墨印刷包含颜料作为着色剂的组合物和包含染料作为着色剂的黑色油墨组合物。根据这种记录方法，在普通纸上打印的情况下，可以提高黑色的浓度，而在用于喷墨记录的专用纸上打印的情况下，可以产生具有高色度和良好再现范围的图像。

38. 发明授权

US6051057A Ink jet recording ink 失效
标题翻译：喷墨记录油墨
公开(公告)号：US6051057A
公开(公告)日：2000-04-18
申请号：US80733
申请日：1998-05-18
申请人： Masahiro Yatake , William Marritt
发明人： Masahiro Yatake , William Marritt
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/30
摘要： An ink for ink jet recording and an ink jet recording method are provided which can realize a print having high color density and, even on recycled paper, a print having no significant feathering. The ink for ink jet recording comprises a water-soluble colorant, a water-soluble organic solvent, water, and a compound represented by the following formula (I), (II), or (III): ##STR1##
摘要翻译：提供了用于喷墨记录的墨水和喷墨记录方法，其可以实现具有高色密度的打印，并且甚至在再生纸上也可以实现不具有显着羽化的印刷。用于喷墨记录的油墨包括水溶性着色剂，水溶性有机溶剂，水和由下式（I），（II）或（III）表示的化合物：

39. 发明授权

US5616174A Ink composition and ink jet recording method using the same 失效
标题翻译：油墨组合物和使用其的喷墨记录方法
公开(公告)号：US5616174A
公开(公告)日：1997-04-01
申请号：US566834
申请日：1995-12-04
申请人： Miharu Kanaya , Akio Owatari , Junko Takatsuna , Masahiro Yatake , Hiroko Hayashi , Takashi Ono , Yoshihiro Sawatari , Tatsuya Yagyu
发明人： Miharu Kanaya , Akio Owatari , Junko Takatsuna , Masahiro Yatake , Hiroko Hayashi , Takashi Ono , Yoshihiro Sawatari , Tatsuya Yagyu
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： An ink composition is provided which enables high-quality recording on plain paper and can record an image having excellent water resistance. The ink composition comprises a dye represented by the following formula (I): ##STR1## wherein M represents an unsubstituted or substituted ammonium, R.sup.1 represents COOM, R.sup.2 represents --P(=O)n--(OM).sub.2, where n is 0 or 1, R.sup.3 represents SO.sub.3 M, R.sup.4 and R.sup.5 independently represent H, an alkyl group, or an alkoxyl group, R.sup.6 represents H, a phenyl group which may be substituted, an alkylcarbonyl group, or an alkyl group which may be substituted with a hydroxyl or alkoxyl group, and m is 0 or 1.
摘要翻译：提供了一种能够在普通纸上进行高质量记录并且能够记录具有优异耐水性的图像的油墨组合物。油墨组合物包含由下式（I）表示的染料：其中M表示未取代或取代的铵，R 1表示COOM，R 2表示-P（= O）n - （OM） 2其中n为0或1，R 3表示SO 3 M，R 4和R 5独立地表示H，烷基或烷氧基，R 6表示H，可被取代的苯基，烷基羰基或烷基可以被羟基或烷氧基取代，m是0或1。

40. 发明授权

US08556400B2 Inkjet recording ink 有权
标题翻译：喷墨记录油墨
公开(公告)号：US08556400B2
公开(公告)日：2013-10-15
申请号：US11660812
申请日：2005-10-24
申请人： Masahiro Yatake , Motoki Masuda , Jyun Ito , Yasuhiro Oki , Hiroko Hayashi
发明人： Masahiro Yatake , Motoki Masuda , Jyun Ito , Yasuhiro Oki , Hiroko Hayashi
IPC分类号： C09D11/00
CPC分类号： C09D11/40 , C09D11/326
摘要： The present invention aims to provide an ink for ink jet recording that is excellent in storage stability and discharge stability and attains high coloration on regular paper or gloss paper and high glossiness on gloss paper. The ink for ink jet recording of the invention includes: water; and a pigment dispersed by using a polymer which is obtained by polymerizing at least 50% by weight or more of benzylacrylate and 15% by weight or less of (meth)acrylic acid as components of the polymer and has an acid value of no less than 50 mgKOH/g and no more than 120 mgKOH/g and a weight average molecular weight of no less than 10000 and no more than 120000.
摘要翻译：本发明的目的在于提供一种喷墨记录用油墨，其在储存稳定性和排出稳定性方面优异，在普通纸或光泽纸上得到高着色，在光泽纸上具有高光泽度。本发明的喷墨记录用墨水包括：水; 以及通过使用通过聚合至少50重量％以上的丙烯酸苄酯和15重量％以下的（甲基）丙烯酸作为聚合物的成分而得到的聚合物分散的颜料，其酸值为不小于 50mgKOH / g和不大于120mgKOH / g，重均分子量不小于10000且不大于120000。

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