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31. 发明授权

US4740572A Process for the production of polymers containing reactive terminal groups 失效
标题翻译：制备含有反应性末端基团的聚合物的方法
公开(公告)号：US4740572A
公开(公告)日：1988-04-26
申请号：US931513
申请日：1986-11-17
申请人： Rudiger Musch , Steven Pask , Renke Mottweiler , Oskar Nuyken , Thomas Dittmer , Hans-Peter Muhlbauer
发明人： Rudiger Musch , Steven Pask , Renke Mottweiler , Oskar Nuyken , Thomas Dittmer , Hans-Peter Muhlbauer
IPC分类号： C08F2/00 , C08F2/06 , C08F2/28 , C08F2/38 , C08F2/42 , C08F4/06 , C08F4/14 , C08F110/10
CPC分类号： C08F2/38
摘要： The production of polymers containing terminal halogen groups from cationically polymerizable monomers using a metal halide boiling below 50.degree. C. at normal pressure as catalyst and an organic halide corresponding to the following general formula ##STR1## in which X is halogen,n is an integer of 1, 2, 3 or 4,R.sub.1 and R.sub.2 represent C.sub.5 -C.sub.10 cycloalkyl or linear or branched C.sub.1 -C.sub.20 alkyl andR.sub.3 represents C.sub.5 -C.sub.10 cycloalkyl, linear or branched C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.10 cycloalkylene, linear or branched C.sub.1 -C.sub.20 alkylene or aryl, and the organic halide (inifer) contains from 5 to 50 carbon atoms and is present in concentrations of from 10.sup.-1 to 10.sup.-6 moles per mole monomer while the metal halide is added in a 1.1 to 100-fold molar excess, based on halogen atoms of the organic halide, at temperatures of from +10.degree. to -130.degree. C. in an inert organic solvent or solvent mixture is possible with recovery of the catalyst and with formation of a product having a functionality differing only slightly, if at all, from the theoretical functionality providing the reaction components monomer, catalyst and inifer are continuously introduced into a polymerization apparatus in such a way that all three components are only mixed once they are inside the apparatus, the polymer solution is continuously removed from the apparatus, the polymer solution is freed from residual monomer, unreacted inifer and from the catalyst and worked up.
摘要翻译：使用在常压下沸腾低于50℃的金属卤化物作为催化剂和对应于以下通式的有机卤化物，其中X是卤素，n是整数，由阳离子可聚合单体制备含有末端卤素基团的聚合物为1,2,3或4，R1和R2表示C5-C10环烷基或直链或支链C1-C20烷基，R3表示C5-C10环烷基，直链或支链C1-C20烷基，C5-C10亚环烷基，直链或支链C1 -C 20亚烷基或芳基，有机卤化物（无机物）含有5至50个碳原子，并且以每摩尔单体10-1至10-6摩尔的浓度存在，而金属卤化物以1.1至100重量％在惰性有机溶剂或溶剂混合物中，在+10〜-130℃的温度下，以有机卤化物的卤素原子计，摩尔过量倍数是可能的，回收催化剂并形成具有官能度的产物不同之处仅在于所有这些提供反应组分的理论功能单体，催化剂和Inifer被连续地引入到聚合装置中，使得所有这三种组分一旦被置于装置内就被混合，聚合物溶液从设备中连续地除去，聚合物溶液从残留的单体，未反应的Inifer和催化剂中除去并加以处理。

32. 发明授权

US4737528A Vulcanizable polymer mixtures, their production and use and vulcanizates obtained therefrom 失效
标题翻译：可硫化的聚合物混合物，其生产和使用以及从其获得的硫化橡胶
公开(公告)号：US4737528A
公开(公告)日：1988-04-12
申请号：US921113
申请日：1986-10-21
申请人： Rudiger Musch , Wilhelm Gobel , Jean Mirza
发明人： Rudiger Musch , Wilhelm Gobel , Jean Mirza
IPC分类号： C08L23/22 , C08L1/00 , C08L7/00 , C08L11/00 , C08L21/00 , C08L23/00 , C08L23/26 , C08L27/00 , C08L101/00 , C08J3/16 , C08L27/04
CPC分类号： C08L11/00 , C08L23/283
摘要： Polychloroprene rubbers having favorable processing behavior and excellent properties are obtained if mono-, di- or trichlorosubstituted polyisobutylene is added as plasticizer before vulcanization.
摘要翻译：如果在硫化前加入一，二或三氯取代的聚异丁烯作为增塑剂，则获得具有良好加工性能和优异性能的聚氯丁二烯橡胶。

33. 发明授权

US4521576A Continuous polymerization of chloroprene 失效
标题翻译：氯丁二烯的连续聚合
公开(公告)号：US4521576A
公开(公告)日：1985-06-04
申请号：US556580
申请日：1983-11-30
申请人： Rudiger Musch , Wilhelm Gobel , Wolfgang Konter , Wilfried Nolte
发明人： Rudiger Musch , Wilhelm Gobel , Wolfgang Konter , Wilfried Nolte
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F36/00 , C08F36/18 , C08F20/20
CPC分类号： C08F36/18
摘要： A process for the production of storable polychloroprene having reduced tackiness on mixing rolls by the continuous polymerization of chloroprene and, optionally, up to 50%, by weight, of a monomer copolymerizable with chloroprene in aqueous alkaline emulsion in the presence of emulsifiers and radical initiators at temperatures of from 0.degree. to 70.degree. C., followed by isolation, characterized in that from 90 to 150 parts, by weight, of water, from 2.5 to 4.0 parts, by weight of a potassium salt of disproportionated abietic acid (based on acid), from 0.3 to 1.0 parts, by weight, of a condensation product of naphthalene sulphonic acid and formaldehyde and from 0.2 to 1.5 parts, by weight, of potassium hydroxide, all the quantities being based on 100 parts, by weight, of monomer, are used for the polymerization reaction.
摘要翻译：在乳化剂和自由基引发剂的存在下，通过连续聚合氯丁二烯和任选地至多50重量％的可与氯丁二烯共聚的单体在水性碱性乳液中连续聚合制备具有降低的混合辊粘性的方法在0℃至70℃的温度下，然后分离，其特征在于，90至150重量份的水，2.5至4.0重量份歧化松香酸钾盐（基于酸），0.3至1.0重量份的萘磺酸和甲醛的缩合产物和0.2至1.5重量份的氢氧化钾，所有量基于100重量份的单体，用于聚合反应。

34. 发明授权

US4433106A Production of sulphur-modified polychloroprene rubbers 失效
标题翻译：生产硫改性聚氯丁二烯橡胶
公开(公告)号：US4433106A
公开(公告)日：1984-02-21
申请号：US436198
申请日：1982-10-25
申请人： Rudiger Musch , Wolfgang Konter , Wilhelm Gobel
发明人： Rudiger Musch , Wolfgang Konter , Wilhelm Gobel
IPC分类号： C08L7/00 , C08C1/00 , C08C1/14 , C08L11/00 , C08L21/00 , C08L27/22
CPC分类号： C08L11/02 , C08L9/08
摘要： Vulcanizable, elastomeric, sulphur-modified polychloroprene rubbers having improved properties are obtained by adding up to 40%, by weight, of SBR latex (solids, based on total solids) before working-up and before or after peptization.
摘要翻译：具有改进性能的可硫化橡胶，弹性体，硫改性聚氯丁二烯橡胶通过在加工前和胶溶之前或之后加入高达40重量％的SBR胶乳（固体，基于总固体）。

35. 发明授权

US4405742A Process for the production of high molecular weight polychloroprene and its use as a starting material for adhesives 失效
标题翻译：用于生产高分子量聚氯丁二烯的方法及其用作粘合剂的起始材料
公开(公告)号：US4405742A
公开(公告)日：1983-09-20
申请号：US280018
申请日：1981-06-30
申请人： Rudiger Musch , Rudiger Schubart , Wilhelm Gobel , Heinrich Alberts , Gerhard Hohmann
发明人： Rudiger Musch , Rudiger Schubart , Wilhelm Gobel , Heinrich Alberts , Gerhard Hohmann
IPC分类号： C08F36/18 , C09J3/12 , C08F2/24 , C08F2/38
CPC分类号： C08F36/18
摘要： By adding substances corresponding to the following general formula I ##STR1## in which X=O, S or N--R.sub.5 ; R.sub.1 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.12 -cycloalkenyl; R.sub.2 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.12 -alkenyl, phenyl or C.sub.1 -C.sub.4 -alkylene phenyl; R.sub.3 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, acryl formyl or acetyl; R.sub.4 and R.sub.5 =same or different, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, acryl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.12 -cycloalkenyl; R.sub.4 and R.sub.5 may also form a C.sub.4 -C.sub.7 -ring which may optionally contain an oxygen atom in ether form and the radicals R.sub.1 and R.sub.2 may form a C.sub.5 -C.sub.12 -alkylene bridge or a C.sub.5 -C.sub.12 -alkenylene bridge, the radicals R.sub.1 and R.sub.4 may form a C.sub.2 -C.sub.9 -alkylene bridge and the radicals R.sub.1 and R.sub.3 may form a C.sub.3 -C.sub.10 -alkylene bridge; where R.sub.1 and R.sub.2 are attached, the ring formed may be bridged by a C.sub.1 -C.sub.4 -alkylene bridge and the ring systems formed may be substituted by the radical R.sub.6 which represents hydrogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl, in quantities of from 0.05 to 3% by weight, based on 100 parts by weight of monomer, to the aqueous emulsion polymerization of chloroprene at the beginning of the reaction, during or after polymerization, but at the latest before the residual monomers are removed, high-viscosity polychloroprenes characterized by excellent processing behaviour and product properties are obtained.
摘要翻译：通过添加对应于下列通式I（I）的物质，其中X = O，S或N-R 5; R1 =氢，C1-C19 - 烷基，C2-C19 - 烯基，苯基，C1-C4-亚烷基苯基，C5-C12-环烷基或C5-C12-环烯基; R2 =氢，C1-C19 - 烷基，C2-C12-烯基，苯基或C1-C4-亚烷基苯基; R3 =氢，C1-C19 - 烷基，C2-C19 - 烯基，苯基，C1-C4-亚烷基苯基，丙烯酰甲酰基或乙酰基; R 4和R 5相同或不同，C 1 -C 19 - 烷基，C 2 -C 19 - 烯基，苯基，C 1 -C 4亚烷基苯基，丙烯酰基，C 5 -C 12 - 环烷基或C 5 -C 12 - 环烯基; R4和R5还可以形成可以任选地含有醚形式的氧原子的C 4 -C 7环，并且基团R 1和R 2可以形成C 5 -C 12亚烷基桥或C 5 -C 12 - 亚烯基桥，基团R 1和 R4可以形成C 2 -C 9 - 亚烷基桥，基团R 1和R 3可以形成C 3 -C 10亚烷基桥; 其中R 1和R 2连接，所形成的环可以被C 1 -C 4 - 亚烷基桥桥连，所形成的环体系可以被代表氢，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基的基团R 6代替，在反应开始时，在聚合过程中或之后的氯丁二烯的水乳液聚合中，基于100重量份的单体，以0.05重量％的量计，残留单体除去之前的量高获得以优异的加工性能和产品性能为特征的粘性聚氯乙烯。

36. 发明授权

US4303765A Process for the production of storable 2-chloro-1,3-butadiene/sulfur copolymers 失效
标题翻译：用于生产可存储的2-氯-1,3-丁二烯/硫共聚物的方法
公开(公告)号：US4303765A
公开(公告)日：1981-12-01
申请号：US159770
申请日：1980-06-06
申请人： Rudiger Musch , Rudiger Schubart , Wilhelm Gobel , Gottfried Pampus
发明人： Rudiger Musch , Rudiger Schubart , Wilhelm Gobel , Gottfried Pampus
IPC分类号： C08F236/00 , C08C1/00 , C08C4/00 , C08C19/08 , C08F36/18 , C08F236/18 , C08C19/20 , C08F8/34
CPC分类号： C08F36/18 , C08C19/08
摘要： A process for the production of storable 2-chloro-1,3-butadiene/sulphur copolymers by peptization using sulphur containing petizing agents, wherein a compound corresponding to the following general formula:R.sub.1 --S.sub.n --R.sub.1whereinn represents an integer having a value of from 2 to 10, preferably from 3 to 8 and, more particularly, from 4 to 6; and R.sub.1 represents a C.sub.6 -C.sub.14 aryl radical, a C.sub.6 -C.sub.14 aryl-C.sub.1 -C.sub.3 alkyl radical or a heterocycle containing from 1 to 3 hereto atoms, such as N, which may be the same or different and which may optionally be substituted;optionally in combination with a nucleophilic substance, is added to the latex and peptized at from 5.degree. to 100.degree. C. and at pH of from 14 to 3.
摘要翻译：一种通过使用含硫化合物的胶溶而制备可存储的2-氯-1,3-丁二烯/硫共聚物的方法，其中对应于以下通式的化合物：R1-Sn-R1其中n表示具有值的整数为2至10，优选3至8，更特别为4至6; 并且R 1表示C 6 -C 14芳基，C 6 -C 14芳基-C 1 -C 3烷基或含有1至3个原子的杂环，例如N，其可以相同或不同，并且可任选被取代; 任选地与亲核物质组合，加入到胶乳中并在5℃至100℃，pH为14至3下胶溶。

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