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31. 发明授权

US08722563B2 Hydroprocessing catalysts and their production 有权
标题翻译：加氢催化剂及其生产
公开(公告)号：US08722563B2
公开(公告)日：2014-05-13
申请号：US13150662
申请日：2011-06-01
申请人： Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Iulian Nistor , Pallassana S. Venkataraman , Chris E. Kliewer , Robert J. Chimenti , Javier Guzman , Gordon Kennedy , Doron Levin
发明人： Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Iulian Nistor , Pallassana S. Venkataraman , Chris E. Kliewer , Robert J. Chimenti , Javier Guzman , Gordon Kennedy , Doron Levin
IPC分类号： B01J31/00
CPC分类号： B01J31/04 , B01J23/882 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J31/0237 , B01J31/0247 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0203 , B01J37/08 , B01J37/20 , B01J2231/60 , B01J2523/00 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/06 , C10G45/08 , C10G2300/1074 , C10G2300/202 , C10G2300/703 , C11B3/02 , B01J2523/56 , B01J2523/69 , B01J2523/847 , B01J2523/55 , B01J2523/845 , B01J2523/68
摘要： Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group, and (ii) a second organic compound separate from said first organic compound and containing at least one carboxylic acid group. A process for preparing the catalyst precursor composition is also described, as is sulfiding the bulk mixed metal oxide catalyst precursor composition to form a hydroprocessing catalyst.
摘要翻译：本文描述的催化剂前体组合物包含元素周期表第6族中的至少一种金属，元素周期表第8-10族的至少一种金属和由（i）含有至少一个胺基的第一有机化合物，和（ii）与所述第一有机化合物分离并含有至少一个羧酸基团的第二有机化合物。还描述了制备催化剂前体组合物的方法，就是将本体混合金属氧化物催化剂前体组合物硫化以形成加氢处理催化剂。

32. 发明授权

US08183424B2 Transalkylation of heavy aromatic hydrocarbon feedstocks 有权
标题翻译：重芳香烃原料的烷基转移
公开(公告)号：US08183424B2
公开(公告)日：2012-05-22
申请号：US12973358
申请日：2010-12-20
申请人： Doron Levin , April D. Ross , James H. Beech, Jr.
发明人： Doron Levin , April D. Ross , James H. Beech, Jr.
IPC分类号： C07C6/12
CPC分类号： B01J8/04 , B01J29/064 , B01J29/072 , B01J29/076 , B01J29/44 , B01J29/46 , B01J29/7034 , B01J29/7669 , B01J35/0006 , B01J35/023 , B01J37/0009 , B01J37/20 , B01J2229/42 , C07C6/12 , C07C2529/42 , Y02P20/52 , C07C15/08
摘要： In a process for producing xylene by transalkylation of a C9+ aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+ aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst comprising (i) a first molecular sieve having a Constraint Index in the range of about 3 to about 12 and (ii) at least first and second different metals or compounds thereof of Groups 6 to 12 of the Periodic Table of the Elements. Contacting with the first catalyst is conducted under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+ alkyl groups and to saturate C2+ olefins formed so as to produce a first effluent. At least a portion of the first effluent is then contacted with a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 under conditions effective to transalkylate C9+ aromatic hydrocarbons with said at least one C6-C7 aromatic hydrocarbon to form a second effluent comprising xylene.
摘要翻译：在通过C 9 +芳族烃原料与C 6和/或C 7芳烃的烷基转移生产二甲苯的方法中，C 9 +芳烃原料，至少一种C 6和/或C 7芳烃和氢与第一催化剂接触，所述第一催化剂包含（ i）具有在约3至约12范围内的约束指数的第一分子筛和（ii）至少元素周期表第6至12族的第一和第二不同金属或其化合物。与第一催化剂接触在有效地使含有C 2 +烷基的原料中芳族烃脱烷基化并使形成的C 2 +烯烃饱和以产生第一流出物的条件下进行。然后至少一部分第一流出物与包含第二分子筛的第二催化剂接触，该第二催化剂在有效使C 9+芳族烃与所述至少一种C 6 -C 7芳族烃烷基转移的条件下具有小于3的约束指数，以形成第二流出物包括二甲苯。

33. 发明申请

US20110190556A1 Transalkylation of Heavy Aromatic Hydrocarbon Feedstocks 有权
标题翻译：重芳香烃原料的烷基转移
公开(公告)号：US20110190556A1
公开(公告)日：2011-08-04
申请号：US12973358
申请日：2010-12-20
申请人： Doron Levin , April D. Ross , James H. Beech, JR.
发明人： Doron Levin , April D. Ross , James H. Beech, JR.
IPC分类号： C07C2/00 , B01J35/02
CPC分类号： B01J8/04 , B01J29/064 , B01J29/072 , B01J29/076 , B01J29/44 , B01J29/46 , B01J29/7034 , B01J29/7669 , B01J35/0006 , B01J35/023 , B01J37/0009 , B01J37/20 , B01J2229/42 , C07C6/12 , C07C2529/42 , Y02P20/52 , C07C15/08
摘要： In a process for producing xylene by transalkylation of a C9+ aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+ aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst comprising (i) a first molecular sieve having a Constraint Index in the range of about 3 to about 12 and (ii) at least first and second different metals or compounds thereof of Groups 6 to 12 of the Periodic Table of the Elements. Contacting with the first catalyst is conducted under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+ alkyl groups and to saturate C2+ olefins formed so as to produce a first effluent. At least a portion of the first effluent is then contacted with a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 under conditions effective to transalkylate C9+ aromatic hydrocarbons with said at least one C6-C7 aromatic hydrocarbon to form a second effluent comprising xylene.
摘要翻译：在通过C 9 +芳族烃原料与C 6和/或C 7芳烃的烷基转移生产二甲苯的方法中，C 9 +芳烃原料，至少一种C 6和/或C 7芳烃和氢与第一催化剂接触，所述第一催化剂包含（ i）具有在约3至约12范围内的约束指数的第一分子筛和（ii）至少元素周期表第6至12族的第一和第二不同金属或其化合物。与第一催化剂接触在有效地使含有C 2 +烷基的原料中芳族烃脱烷基化并使形成的C 2 +烯烃饱和以产生第一流出物的条件下进行。然后至少一部分第一流出物与包含第二分子筛的第二催化剂接触，该第二催化剂在有效使C 9+芳族烃与所述至少一种C 6 -C 7芳族烃烷基转移的条件下具有小于3的约束指数，以形成第二流出物包括二甲苯。

34. 发明申请

US20090131726A1 Method of Making Mixed Metal Oxide Containing Sulfur 审中-公开
标题翻译：制备含硫混合金属氧化物的方法
公开(公告)号：US20090131726A1
公开(公告)日：2009-05-21
申请号：US12272510
申请日：2008-11-17
申请人： James Clarke Vartuli , Doron Levin , Stephen John McCarthy
发明人： James Clarke Vartuli , Doron Levin , Stephen John McCarthy
IPC分类号： C07C29/10
CPC分类号： C07C29/00 , B01J23/002 , B01J23/10 , B01J27/053 , B01J2523/00 , C07C1/20 , C07C29/10 , C07C2523/10 , C07C11/02 , B01J2523/3712 , B01J2523/48 , B01J2523/62 , C07C31/10
摘要： The invention relates to a method of making Group 3 and Group 4 mixed metal oxide catalyst suitable for the decomposition of ethers to alkenes and alkanols. In an embodiment, it relates to a method of making a cerium-zirconium mixed metal oxide catalyst. In an embodiment, the catalyst made by the process of the invention is used for the production of isopropanol (IPA) from isopropyl ether (IPE).
摘要翻译：本发明涉及一种制备适合于将醚分解成烯烃和链烷醇的第3族和第4族混合金属氧化物催化剂的方法。在一个实施方案中，它涉及一种制备铈 - 锆混合金属氧化物催化剂的方法。在一个实施方案中，由本发明方法制备的催化剂用于从异丙醚（IPE）生产异丙醇（IPA）。

35. 发明申请

US20090112034A1 Heavy Aromatics Processing Catalyst and Process of Using the Same 有权
标题翻译：重芳烃加工催化剂及其使用方法
公开(公告)号：US20090112034A1
公开(公告)日：2009-04-30
申请号：US12249279
申请日：2008-10-10
申请人： Doron Levin
发明人： Doron Levin
IPC分类号： C07C5/52
CPC分类号： C07C6/126 , B01J29/44 , B01J29/48 , B01J29/7469 , B01J29/80 , B01J35/0006 , B01J35/026 , B01J37/18 , B01J2229/186 , B01J2229/42 , C07C2529/44 , C07C2529/74 , Y02P20/52 , C07C15/08
摘要： This disclosure relates to a catalyst system adapted for transalkylation a C9+ aromatic feedstock with a C6-C7 aromatic feedstock, comprising: (a) a first catalyst comprising a first molecular sieve having a Constraint Index in the range of 3-12 and 0.01 to 5 wt. % of at least one source of a first metal element of Groups 6-10; and (b) a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 and 0 to 5 wt. % of at least one source of a second metal element of Groups 6-10, wherein the weight ratio of the first catalyst over the second catalyst is in the range of 5:95 to 75:25 and wherein the first catalyst is located in front of the second catalyst when they are brought into contacting with the C9+ aromatic feedstock and the C6-C7 aromatic feedstock in the present of hydrogen.
摘要翻译：本公开涉及一种适于使C 9+芳族原料与C 6 -C 7芳族原料进行烷基转移的催化剂体系，其包含：（a）第一催化剂，其包含第一分子筛，其约束指数为3-12和0.01至5 重量至少一个第6-10族第一金属元素源的％; 和（b）包含第二分子筛的第二催化剂，所述第二分子筛具有小于3和0-5重量％的约束指数。至少一种第6-10族第二金属元素源的％，其中第一催化剂与第二催化剂的重量比在5:95至75:25的范围内，其中第一催化剂位于前面的第二催化剂当它们与C9 +芳族原料和当前氢气中的C6-C7芳族原料接触时。

36. 发明授权

US07446232B2 Process for oxidizing alkylaromatic compounds 有权
标题翻译：氧化烷基芳族化合物的方法
公开(公告)号：US07446232B2
公开(公告)日：2008-11-04
申请号：US11827952
申请日：2007-07-13
申请人： Jihad Mohammed Dakka , Doron Levin , John Scott Buchanan , Jon Edmond Randolph Stanat
发明人： Jihad Mohammed Dakka , Doron Levin , John Scott Buchanan , Jon Edmond Randolph Stanat
IPC分类号： C07C409/02 , C07C37/68
CPC分类号： C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/10 , C07C49/04 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing alkylaromatic compounds to the corresponding hydroperoxide, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, with oxygen in the presence of an added catalyst comprising tert-butyl hydroperoxide and in the absence of any other catalyst, to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I). The hydroperoxide may then be converted into a phenol and a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I).
摘要翻译：在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有如果R 1和R 2可以连接形成具有4至10个碳原子的环状基团，则所述环状基团任选被取代 R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基，在含有叔丁基过氧化氢的加成催化剂存在下，在不存在任何其它催化剂，以制备通式（II）的氢过氧化物：其中R 1，R 2和R 3 3具有相同的含义如式（I）所示。然后将氢过氧化物转化成通式为R 1，R 2，R 2，（III）的苯酚和酮，其中R ＆lt; SUP＆gt;和＆lt; 2＆gt;具有与式（I）中相同的含义。

37. 发明授权

US07307196B2 Molecular sieve compositions, catalyst thereof, their making and use in conversion processes 有权
标题翻译：分子筛组合物，其催化剂，其制备和在转化过程中的应用
公开(公告)号：US07307196B2
公开(公告)日：2007-12-11
申请号：US10910739
申请日：2004-08-03
申请人： Doron Levin , James Clark Vartuli
发明人： Doron Levin , James Clark Vartuli
IPC分类号： C07C1/20 , C07C1/00 , C07C5/333
CPC分类号： C07C1/20 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , C07C2521/06 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one oxide of a metal from Group 4, optionally in combination with at least one metal from Groups 2 and 3, of the Periodic Table of Elements.
摘要翻译：本发明涉及一种催化剂组合物，其制备方法及其在将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子筛和至少一种来自组4的金属的氧化物，任选地与元素周期表中的至少一种第2和3族的金属组合。

38. 发明授权

US07282192B2 Mixed metal oxide containing sulfur 有权
标题翻译：含硫的混合金属氧化物
公开(公告)号：US07282192B2
公开(公告)日：2007-10-16
申请号：US11644619
申请日：2006-12-22
申请人： James Clarke Vartuli , Jeffrey T. Elks , El-Mekki El-Malki , William G. Borghard , Doron Levin , Stephen John McCarthy
发明人： James Clarke Vartuli , Jeffrey T. Elks , El-Mekki El-Malki , William G. Borghard , Doron Levin , Stephen John McCarthy
IPC分类号： C01F17/00 , C01G23/00 , C01G25/00 , C01G27/00
CPC分类号： B01J23/002 , B01J23/10 , B01J27/053 , B01J35/002 , B01J2523/00 , C07C1/20 , C07C29/10 , C07C11/02 , B01J2523/3712 , B01J2523/48 , B01J2523/62 , C07C31/10
摘要： The invention relates to a composition of matter comprising at least one metal from Group 3, at least one metal from Group 4, sulfur and oxygen, particularly useful as a catalyst for ether decomposition to alkanols and alkenes.
摘要翻译：本发明涉及包含至少一种第3族金属，至少一种第4族金属，硫和氧的物质组合物，特别可用作乙醚分解成链烷醇和烯烃的催化剂。

39. 发明申请

US20070161840A1 Molecular sieve compositions, catalyst thereof, their making and use in conversion processes 有权
标题翻译：分子筛组合物，其催化剂，其制备和在转化过程中的应用
公开(公告)号：US20070161840A1
公开(公告)日：2007-07-12
申请号：US11713873
申请日：2007-03-05
申请人： Teng Xu , Stephen Vaughn , Richard Hall , Doron Levin , James Vartuli
发明人： Teng Xu , Stephen Vaughn , Richard Hall , Doron Levin , James Vartuli
IPC分类号： C07C1/00
CPC分类号： B01J37/0009 , B01J21/06 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , B01J35/023 , B01J35/10 , B01J2229/42 , C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/16 , C07C2523/10 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one metal oxide, such as a magnesium oxide that, when saturated with acetone and contacted with said acetone for 1 hour at 25° C., converts more than 80% of the acetone.
摘要翻译：本发明涉及一种催化剂组合物，其制备方法及其在将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子筛和至少一种金属氧化物，例如氧化镁，当用丙酮饱和并与所述丙酮在25℃下接触1小时时，其转化超过80％的丙酮。

40. 发明授权

US07199277B2 Pretreating a catalyst containing molecular sieve and active metal oxide 有权
标题翻译：预处理含有分子筛和活性金属氧化物的催化剂
公开(公告)号：US07199277B2
公开(公告)日：2007-04-03
申请号：US10883438
申请日：2004-07-01
申请人： Teng Xu , Nicolas P. Coute , Kenneth R. Clem , Doron Levin , James C. Vartuli
发明人： Teng Xu , Nicolas P. Coute , Kenneth R. Clem , Doron Levin , James C. Vartuli
IPC分类号： C07C1/00 , B01J27/182 , B01J21/00
CPC分类号： C07C1/20 , C07C2529/85 , C10G3/48 , C10G3/49 , C10G3/62 , C10G2300/1088 , C10G2300/703 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： This invention relates to processes for converting oxygenates to olefins that include a step of pretreating catalyst, which comprises molecular sieve and one or more active metal oxides of one or more metals, with a hydrocarbon composition to provide an integrated hydrocarbon co-catalyst within the molecular sieve. The combination of molecular sieve and hydrocarbon co-catalyst converts oxygenate to an olefin product with high selectivity to light olefins (i.e., ethylene or propylene, or mixture thereof).
摘要翻译：本发明涉及将含氧化合物转化为烯烃的方法，包括将包含分子筛和一种或多种金属的一种或多种活性金属氧化物的催化剂预处理成烃类组合物以在分子内提供整合的烃助催化剂的步骤筛。分子筛和烃助催化剂的组合将含氧化合物转化为对轻质烯烃（即乙烯或丙烯或其混合物）具有高选择性的烯烃产物。

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