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31. 发明授权

US4302603A Producing alkylamines from olefins with alkali metal amide catalyst 失效
标题翻译：用碱金属酰胺催化剂由烯烃生产烷基胺
公开(公告)号：US4302603A
公开(公告)日：1981-11-24
申请号：US217937
申请日：1980-12-18
申请人： Guido P. Pez
发明人： Guido P. Pez
IPC分类号： C07B61/00 , B01J27/00 , C07C67/00 , C07C209/00 , C07C209/60 , C07C211/03 , C07C85/18
CPC分类号： C07C209/60
摘要： Monolefins such as ethylene are reacted with ammonia using alkali metal amide catalysts such as cesium or rubidium amides, or low melting mixtures of amides such as cesium/potassium, cesium/sodium or sodium/potassium amides. Conversions are improved compared to reactions using sodium or potassium amide alone. Conversions of ethylene are improved also when liquid ammonia is present.
摘要翻译：使用碱金属酰胺催化剂如铯或铷酰胺或诸如铯/钾，铯/钠或钠/钾的酰胺的低熔点混合物，使乙烯等单烯与氨反应。与使用单独使用钠或钾的反应相比，转化率有所改善。当液氨存在时，乙烯的转化也得到改善。

32. 发明授权

US4268454A Anionic group VIII metal hydride catalysts 失效
标题翻译：阴离子VIII族金属氢化物催化剂
公开(公告)号：US4268454A
公开(公告)日：1981-05-19
申请号：US70583
申请日：1979-08-29
申请人： Guido P. Pez , Roger A. Grey
发明人： Guido P. Pez , Roger A. Grey
IPC分类号： B01J31/24 , C07C5/03 , C07C5/08 , C07C5/09 , C07C29/141 , C07C29/145 , C07C29/17 , C07C45/62 , C07F15/00 , C07F15/02
CPC分类号： B01J31/2404 , C07C29/141 , C07C29/145 , C07C45/62 , C07C5/03 , C07C5/08 , C07C5/09 , C07C67/303 , C07F15/0013 , C07F15/02 , B01J2231/643 , B01J2231/645 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/842 , C07C2101/14 , C07C2531/24
摘要： A novel class of compounds, anionic Group VIII metal hydrides containing phosphorus, arsenic and antimony organoligands is described, such as potassium tris and bis(triphenylphosphine) ruthenium hydride. The compounds are useful as homogeneous catalysts in the hydrogenation of aldehydes, ketones, olefins or alkynes. Processes for producing the compounds are also described.
摘要翻译：描述了一类新颖的化合物，含有磷，砷和锑有机液体的阴离子Ⅷ族金属氢化物，如三（三苯基膦）三钌钾和氢化钌。该化合物可用作醛，酮，烯烃或炔烃氢化中的均相催化剂。还描述了用于生产化合物的方法。

33. 发明授权

US4046790A Catalytically active complex of titanium, cyclopentadienyl ligands, and ammonia 失效
标题翻译：钛，环戊二烯基配体和氨的催化活性配合物
公开(公告)号：US4046790A
公开(公告)日：1977-09-06
申请号：US712107
申请日：1976-08-05
申请人： John N. Armor , Guido P. Pez
发明人： John N. Armor , Guido P. Pez
IPC分类号： C07F7/28
CPC分类号： C07F7/28
摘要： A catalytically active compound or complex from the complex "bis-titanocene" (U.S. Pat. No. 3,776,932 of Dec. 4, 1973 to G. P. Pez) by reaction thereof with ammonia at low temperature and in absence of contaminants, giving a characteristic powder x-ray diffraction pattern and characteristic radiation and e.s.r. spectra.
摘要翻译：来自复合物“双 - 二茂钛”的催化活性化合物或络合物（1973年12月4日授予美国专利号3,776,932，GP GPZ）通过在低温和不存在污染物下与氨反应，得到特征粉末x 射线衍射图和特征辐射光谱。

34. 再颁专利

USRE29368E Metal-organo compounds with sterically exposed metal-metal bonds, and a method for their production 失效
标题翻译：具有空间暴露的金属 - 金属键的金属有机化合物及其制备方法
公开(公告)号：USRE29368E
公开(公告)日：1977-08-23
申请号：US631777
申请日：1975-11-13
申请人： Guido P. Pez
发明人： Guido P. Pez
IPC分类号： C07F17/00
CPC分类号： C07F17/00
摘要： Metal-organo complex characterized as having at least one sterically exposed metal-metal bond, and having the structure:R.sub.n M M'R.sub.nwherein R represents a ligand which may contain one or more atoms of carbon, hydrogen, oxygen, nitrogen, sulfur or phosphorus; n is an integer of from 1 to 3; M and M' each represent the same or a different transition metal; and the symbol represents at least one sterically exposed metal-metal bond.The preparative method involves the low temperature reaction between an alkali metal naphthalene in an ethereal solvent, with the dihalogenide of at least one metal-organic species. The reaction mixture is allowed to slowly warm to ambient temperatures, the solvent is evaporated, and the naphthalene sublimed at temperatures below 40.degree. C. The remaining crude product is extracted with an organic solvent, the extract is separated from the insoluble portion, and the product recovered by evaporating the solvent.The metal-organo complex has utility as an absorbent of nitrogen when present as a contaminant in argon. .Iadd.When M and M' in the above formula are both titanium, and R is cyclopentadienyl, and n is 2 the above preparative method results in a metal-organo complex, as above defined, wherein pairs of the ligands are pi-bonded to each titanium atom, and one of these four ligands bridges the two titanium atoms by a pi-bond to one titanium and a sigma-bond to the other. .Iaddend.

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