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31. 发明授权

US4491513A Process for beneficiating oil-shale 失效
标题翻译：油页岩选矿工艺
公开(公告)号：US4491513A
公开(公告)日：1985-01-01
申请号：US600431
申请日：1984-04-16
申请人： Michael Siskin , Glen B. Brons
发明人： Michael Siskin , Glen B. Brons
IPC分类号： C10G1/00 , C10G1/04 , C10L9/02
CPC分类号： C10L9/02 , C10G1/00 , C10G1/04
摘要： Disclosed is a process for removing mineral matter from oil-shale by contacting the oil-shale with (a) an ammonium salt solution and (b) an organic solvent, at a temperature from about 0.degree. C. to about 300.degree. C. for a time which is sufficient to substantially separate at least about 80 wt. % of the carbonate mineral matter from the oil-shale.
摘要翻译：公开了一种通过使油页岩与（a）铵盐溶液和（b）有机溶剂在约0℃至约300℃的温度下接触来从油页岩中除去矿物质的方法，用于足以基本分离至少约80wt。来自油页岩的碳酸盐矿物质的百分比。

32. 发明授权

US4069268A Regeneration of metal halide catalysts via halogenation 失效
标题翻译：通过卤化再生金属卤化物催化剂
公开(公告)号：US4069268A
公开(公告)日：1978-01-17
申请号：US628587
申请日：1975-11-04
申请人： Michael Siskin , Ronald J. Gillespie
发明人： Michael Siskin , Ronald J. Gillespie
IPC分类号： B01J27/32 , C07C2/54 , C07C2/60 , C07C2/68 , C07C5/22 , C07C5/28 , C07C3/54 , C10G35/06
CPC分类号： C07C2/68 , B01J27/32 , C07C2/54 , C07C2/60 , C07C5/2253 , C07C2527/1206 , C07C2527/133 , Y02P20/584
摘要： Deactivated or partially deactivated hydrocarbon conversion catalysts comprising (a) one or more Lewis acids of the formula MX.sub.n where M is a component selected from Group IIIA, IVB, V, VIB or VIII Elements of the Periodic Table or their mixtures, X is a halogen, and n is the atomic ratio of halogen to M and varies from 1 to 8, and (b) a strong Bronsted acid, may be regenerated by contacting said catalysts with a halogen selected from the group consisting of fluorine or chlorine. If a portion of the catalyst has been hydrolyzed, the catalyst may be regenerated via halogenation as above or by contact with a hydrogen halide selected from the group consisting of hydrogen fluoride or hydrogen chloride and then fluorine. The preferred Lewis acid is a metal halide, preferably tantalum pentafluoride, niobium pentafluoride or mixtures thereof. The preferred Bronsted acid is a hydrogen halide, preferably hydrogen fluoride.
摘要翻译：包括（a）一种或多种式MXn的路易斯酸，其中M是选自元素周期表的IIIA，IVB，V，VIB或VIII族元素的组分或其混合物，X是卤素，n为卤素与M的原子比，为1〜8，（b）强布朗斯台德酸可通过使所述催化剂与选自氟或氯的卤素接触而再生。如果催化剂的一部分已经被水解，则催化剂可以通过如上所述的卤化或通过与选自氟化氢或氯化氢然后氟化物的卤化氢接触来再生。优选的路易斯酸是金属卤化物，优选五氟化钽，五氟化铌或其混合物。优选的布朗斯台德酸是卤化氢，优选氟化氢。

33. 发明授权

US3948761A Isomerization of aliphatic hydrocarbons 失效
标题翻译：脂肪族烃的异构化
公开(公告)号：US3948761A
公开(公告)日：1976-04-06
申请号：US445163
申请日：1974-02-25
申请人： Michael Siskin , Joseph J. Porcelli
发明人： Michael Siskin , Joseph J. Porcelli
IPC分类号： B01J27/08 , C07C5/27 , C07C5/28 , C10G35/06
CPC分类号： C07C5/2721 , B01J27/08 , C07C2527/08 , C07C2527/10 , C07C2527/11 , C07C2527/12 , C07C2527/1206 , C07C2527/125 , C07C2527/126 , C07C2527/132 , C07C2527/133 , C07C2527/135
摘要： Acyclic and alicyclic aliphatic hydrocarbons are isomerized by contacting the same with hydrogen in the presence of a difficultly reduceable metal halide in combination with at least a molar equivalent of hydrogen halide. The preferred catalyst system is tantalum pentafluoride, niobium pentafluoride or their mixtures in combination with at least a five-fold molar excess of hydrogen fluoride.
摘要翻译：通过在难以还原的金属卤化物与至少一摩尔当量的卤化氢的组合的存在下使其与氢接触来使非环和脂环族脂族烃异构化。优选的催化剂体系是五氟化钽，五氟化铌或其混合物与至少五倍摩尔过量的氟化氢的组合。

34. 发明授权

US09376756B2 Inhibition of corrosion in boiler systems with etheramines 有权
标题翻译：用醚胺抑制锅炉系统的腐蚀
公开(公告)号：US09376756B2
公开(公告)日：2016-06-28
申请号：US14285686
申请日：2014-05-23
申请人： Michael Siskin , Robert Basil Fedich , Michel A. Daage
发明人： Michael Siskin , Robert Basil Fedich , Michel A. Daage
IPC分类号： C23F11/14 , F22B1/00 , F22B37/02
CPC分类号： C23F11/146 , C23F11/141 , F22B1/00 , F22B37/025
摘要： Aminoethers are used as corrosion inhibitors in boiler systems in which a working fluid comprising water with an aminoether corrosion inhibitor is circulated from a heater to a utilization site at which the working fluid gives up energy and decreases in temperature. A preferred class of aminoethers are the alkoxytriethyleneglycol-tert-alkylamines such as methoxy triethyleneglycol-tert-butylamine.
摘要翻译：氨基醚用作锅炉系统中的腐蚀抑制剂，其中包含水与氨基醚腐蚀抑制剂的工作流体从加热器循环到工作流体释放能量并降低温度的使用场所。优选的氨基醚类是烷氧基三乙二醇 - 叔烷基胺，例如甲氧基三乙二醇 - 叔丁胺。

35. 发明申请

US20160038872A1 NON-AQUEOUS AMINE SCRUBBING FOR REMOVAL OF CARBON DIOXIDE 有权
标题翻译：用于去除二氧化碳的非水性氨洗涤剂
公开(公告)号：US20160038872A1
公开(公告)日：2016-02-11
申请号：US14885214
申请日：2015-10-16
申请人： David Charles CALABRO , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
发明人： David Charles CALABRO , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.
摘要翻译：描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子溶剂在足以吸附至少一些CO 2的条件下进行。然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富CO 2的吸附溶液，然后循环至用于解吸CO 2的再生区（有利地<100℃）。在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

36. 发明授权

US09186617B2 Non-aqueous amine scrubbing for removal of carbon dioxide 有权
标题翻译：用于去除二氧化碳的非水胺洗涤
公开(公告)号：US09186617B2
公开(公告)日：2015-11-17
申请号：US13228652
申请日：2011-09-09
申请人： David C. Calabro , Lisa S. Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis G. Peiffer , Quanchang Li
发明人： David C. Calabro , Lisa S. Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis G. Peiffer , Quanchang Li
IPC分类号： B01D53/62 , B01D53/14 , B01D53/77 , B01D53/78 , B01D53/96
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.
摘要翻译：描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子溶剂在足以吸附至少一些CO 2的条件下进行。然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富含CO 2的吸附剂溶液，然后循环至用于解吸CO 2的再生区（有利地<100℃）。在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

37. 发明授权

US08715397B2 Mixed amine and non-nucleophilic base CO2 scrubbing process for improved adsorption at increased temperatures 有权
标题翻译：混合胺和非亲核碱性CO 2洗涤方法，以改善在升高的温度下的吸附
公开(公告)号：US08715397B2
公开(公告)日：2014-05-06
申请号：US13228869
申请日：2011-09-09
申请人： Pavel Kortunov , Lisa S. Baugh , David C. Calabro , Michael Siskin , Preeti Kamakoti , Quanchang Li
发明人： Pavel Kortunov , Lisa S. Baugh , David C. Calabro , Michael Siskin , Preeti Kamakoti , Quanchang Li
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A CO2 amine scrubbing process uses an absorbent mixture combination of an amine CO2 sorbent in combination with a non-nucleophilic, relatively stronger, typically nitrogenous, base. The weaker base(s) are nucleophilic and have the ability to react directly with the CO2 in the gas stream while the relatively stronger bases act as non-nucleophilic promoters for the reaction between the CO2 and the weaker base. The sorption and desorption temperatures can be varied by selection of the amine/base combination, permitting effective sorption temperatures of 70 to 90° C., favorable to scrubbing flue gas.
摘要翻译： CO 2胺洗涤方法使用胺二氧化碳吸附剂与非亲核相对较强的通常含氮碱的组合的吸收混合物组合。较弱的碱是亲核的，并且具有与气流中的CO 2直接反应的能力，而相对较强的碱作为CO 2和较弱碱之间的反应的非亲核促进剂。吸附和解吸温度可以通过选择胺/碱组合来改变，允许有效吸附温度为70-90℃，有利于洗涤烟道气。

38. 发明授权

US08603325B2 Biomass oil conversion process 有权
标题翻译：生物质油转化过程
公开(公告)号：US08603325B2
公开(公告)日：2013-12-10
申请号：US13038107
申请日：2011-03-01
申请人： Michael Siskin , Glen E. Phillips , Simon R. Kelemen , Walter Weissman
发明人： Michael Siskin , Glen E. Phillips , Simon R. Kelemen , Walter Weissman
IPC分类号： C10L1/02
CPC分类号： C10G1/02 , C10B57/045 , C10B57/06 , C10G1/002 , C10G9/005 , C10G2300/1014 , Y02P20/145 , Y02P30/20
摘要： A biomass pyrolysis oil is used as a co-feed for a heavy petroleum oil coking process to improve the operation of the coking process and to utilize biomaterial for the production of transportation fuels. The coking process may be a delayed coking process or a fluidized bed coking process and in each case, the presence of the biomass pyrolysis oil will decrease the coke drying time while reducing coke handling problems in the unit besides forming a superior coke product. In the case of a fluidized bed coking process using a gasifier for the coke, the addition of an alkali metal salt improves the operation of the gasifier.
摘要翻译：生物质热解油用作重石油焦化工艺的共同进料，以改善焦化工艺的运行并利用生物材料生产运输燃料。焦化过程可以是延迟焦化方法或流化床焦化方法，并且在每种情况下，除了形成优异的焦炭产物之外，生物质热解油的存在将降低焦炭干燥时间，同时减少该单元中的焦炭处理问题。在使用气化炉用于焦炭的流化床焦化方法的情况下，加入碱金属盐改善了气化器的操作。

39. 发明授权

US08480765B2 Biomass oil conversion process 有权
标题翻译：生物质油转化过程
公开(公告)号：US08480765B2
公开(公告)日：2013-07-09
申请号：US13038010
申请日：2011-03-01
申请人： Michael Siskin , Glen E. Phillips , Simon R. Kelemen
发明人： Michael Siskin , Glen E. Phillips , Simon R. Kelemen
IPC分类号： C10L1/00
CPC分类号： C10G3/40 , C10G2300/1014 , C10G2300/4006 , C10L1/04 , C10L9/086 , Y02P30/20
摘要： Biomass pyrolysis oil is converted into precursors for hydrocarbon transportation fuels by contacting the oil with liquid superheated water or supercritical water to depolymerize and deoxygenate the components of the oil and form the transportation fuel precursors. Temperatures above 200° C. and preferably above 300° C. are preferred with supercritical water at temperatures above 374° C. and pressures above 22 MPA providing the capability for fast conversion rates.
摘要翻译：通过使油与液体过热水或超临界水接触来将生物质热解油转化为烃运输燃料的前体，以解聚和脱氧油组分并形成运输燃料前体。超过200℃，优选高于300℃的温度优选超过374℃的超临界水，高于22MPA的压力提供快速转化率的能力。

40. 发明授权

US08147676B2 Delayed coking process 失效
标题翻译：延迟焦化工艺
公开(公告)号：US08147676B2
公开(公告)日：2012-04-03
申请号：US11256728
申请日：2005-10-21
申请人： Michael Siskin , David T. Ferrughelli , Martin L. Gorbaty , Simon R. Kelemen , Leo D. Brown
发明人： Michael Siskin , David T. Ferrughelli , Martin L. Gorbaty , Simon R. Kelemen , Leo D. Brown
IPC分类号： C10B55/00
CPC分类号： C10B57/06 , C10B55/00 , C10B57/08 , C10G9/005 , C10G55/04 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/206
摘要： The present invention relates to an improved delayed coking process. A coker feed, such as a vacuum resid, is treated with (i) a metal-containing agent and (ii) an oxidizing agent. The feed is treated with the oxidizing agent at an oxidizing temperature. The oxidized feed is then pre-heated to coking temperatures and conducted to a coking vessel for a coking time to allow volatiles to evolve and to produce a substantially free-flowing coke. A metals-containing composition is added to the feed at at least one of the following points in the process: prior to the heating of the feed to coking temperatures, during such heating, and/or after such heating.
摘要翻译：本发明涉及一种改进的延迟焦化方法。用（i）含金属试剂和（ii）氧化剂处理焦化饲料如真空渣油。在氧化温度下用氧化剂处理进料。然后将氧化的进料预加热至焦化温度，并导入焦化容器中以获得焦化时间，以允许挥发物放出并产生基本上自由流动的焦炭。在此过程中，将进料加热至焦化温度，在此加热期间和/或在此类加热之后，将含金属的组合物加入到进料中的至少一个方面。

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