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31. 发明授权

US06231751B1 Oxide materials and catalyst compositions containing them 有权
标题翻译：含有它们的氧化物材料和催化剂组合物
公开(公告)号：US06231751B1
公开(公告)日：2001-05-15
申请号：US09068289
申请日：1998-10-28
申请人： Avelino Corma Canos , Vicente Fornes Segui , Sibelle Berenice Castella Pergher
发明人： Avelino Corma Canos , Vicente Fornes Segui , Sibelle Berenice Castella Pergher
IPC分类号： C10G1104
CPC分类号： C10G11/05 , B01J29/04 , C01B33/38 , C01B39/48
摘要： A process for making a calcined, oxide material by at least partially delaminating a swollen, layered oxide material prior to calcination, and the product thereof having an increased active surface area that corresponds to an adsorption capacity for 1,3,5-trimethylbenzene of at least 0.50 mmol/g at a temperature of 42° C. and a pressure of 173.3 Pa. The calcined, oxide material retains a porous shape although non-pillared.
摘要翻译：一种煅烧氧化物材料的制造方法，该方法是在煅烧之前至少部分地分解溶胀的层状氧化物材料，并且其产物具有增加的活性表面积，其对应于1,3,5-三甲基苯的吸附能力在42℃的温度和173.3Pa的压力下，至少0.50mmol / g。煅烧的氧化物材料尽管没有柱状，但保持多孔形状。

32. 发明授权

US06191323B1 Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta 有权
标题翻译：使用锡取代沸石β将酮和醛还原成醇的方法
公开(公告)号：US06191323B1
公开(公告)日：2001-02-20
申请号：US09557300
申请日：2000-04-25
申请人： Laszlo T. Nemeth , Avelino Corma Canos , Susana Valencia Valencia , Jaime G. Moscoso , Marcelo Eduardo Domine
发明人： Laszlo T. Nemeth , Avelino Corma Canos , Susana Valencia Valencia , Jaime G. Moscoso , Marcelo Eduardo Domine
IPC分类号： C07C2914
CPC分类号： C07C29/14 , B01J29/04 , B01J29/89 , C07C29/143 , C07C2601/14 , Y10S423/27 , C07C35/12 , C07C35/08
摘要： A process for the reduction of ketones or aldehydes to alcohols has been developed. The process involves contacting the ketone or aldehyde with a primary or secondary alcohol and a catalyst at reduction conditions. The catalyst is a molecular sieve having the empirical formula: (MwSnxTiySi1-x-y-zGez)O2 where M is a trivalent metal such as aluminum or boron. These molecular sieves have a microporous three dimensional framework structure of at least SiO2 and SnO2 tetrahedral units, a crystallographically regular pore system and the characteristic x-ray diffraction pattern of zeolite beta.
摘要翻译：已经开发了将酮或醛还原成醇的方法。该方法包括在还原条件下使酮或醛与伯醇或仲醇和催化剂接触。催化剂是具有以下经验式的分子筛：其中M是三价金属如铝或硼。这些分子筛具有至少SiO 2和SnO 2四面体单元的微孔三维骨架结构，晶体学规则孔系统和β沸石的特征X射线衍射图。

33. 发明申请

US20140058181A1 PROCESS FOR MANUFACTURE OF A ZEOLITE BASED CATALYST FOR THE CONVERSION OF METHANOL TO OLEFINS 有权
标题翻译：用于将甲醇转化为烯烃的基于沸石的催化剂的制备方法
公开(公告)号：US20140058181A1
公开(公告)日：2014-02-27
申请号：US14005325
申请日：2012-03-15
申请人： Manfred Frauenrath , Stefan Klingelhofer , Gotz Burgfels , Avelino Corma Canos , Joaquin Martinez Triguero , Elena Corresa Mateu
发明人： Manfred Frauenrath , Stefan Klingelhofer , Gotz Burgfels , Avelino Corma Canos , Joaquin Martinez Triguero , Elena Corresa Mateu
IPC分类号： B01J29/40 , C07C1/22
CPC分类号： B01J29/40 , B01J37/0018 , B01J37/0036 , B01J2229/18 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2529/70 , Y02P20/52 , C07C11/02 , C07C11/06
摘要： The present invention relates to a process for preparing phosphorus containing zeolite type catalysts based on crystalline aluminosilicates, the catalysts of this process and the use of these catalysts for the conversion of methanol to olefins.
摘要翻译：本发明涉及一种制备基于结晶硅铝酸盐的含磷沸石型催化剂的方法，该方法的催化剂以及这些催化剂用于将甲醇转化为烯烃的方法。

34. 发明申请

US20140001028A1 METHOD FOR CONVERTING METHANE INTO OXYGENATED DERIVATIVES OF ONE CARBON ATOM 审中-公开
标题翻译：将甲烷转化为一种碳原子的氧化衍生物的方法
公开(公告)号：US20140001028A1
公开(公告)日：2014-01-02
申请号：US13981691
申请日：2012-01-10
申请人： Francesc Sastre Calabuig , Avelino Corma Canos , Hermenegildo García Gómez
发明人： Francesc Sastre Calabuig , Avelino Corma Canos , Hermenegildo García Gómez
IPC分类号： C07C29/36
CPC分类号： C07C29/36 , B01J19/123 , B01J29/035 , B01J29/041 , B01J29/7007 , B01J35/004 , B01J2219/0875 , C07C2/76 , C07C27/12 , C07C29/50 , C07C45/33 , C07C2521/08 , C07C2529/035 , C07C2529/70 , Y02P20/52 , C07C31/04 , C07C47/04 , C07C9/06 , C07C9/08
摘要： Method for converting methane into oxygenated derivates, characterized in that it comprises irradiating a solid surface using UV light with a wavelength of less than 200 nm and in that it takes place on the surface of a solid, preferably a microporous solid, wherein the selectivities achieved are greater than 90% for conversions of about 10%.
摘要翻译：将甲烷转化为氧化衍生物的方法，其特征在于，其包括使用波长小于200nm的UV光照射固体表面，并且其发生在固体，优选微孔固体的表面上，其中所述选择性达到大约90％转换为10％左右。

35. 发明授权

US08426633B2 Carbonylation process for the production of acetic acid and/or methyl acetate 有权
标题翻译：用于生产乙酸和/或乙酸甲酯的羰基化方法
公开(公告)号：US08426633B2
公开(公告)日：2013-04-23
申请号：US12735180
申请日：2008-12-16
申请人： Avelino Corma Canos , Gordon John Haining , David John Law
发明人： Avelino Corma Canos , Gordon John Haining , David John Law
IPC分类号： C07C67/36 , C07C51/12
CPC分类号： C07C67/36 , B01J29/20 , B01J35/023 , C07C51/12 , C07C67/37 , C07C53/08 , C07C69/14
摘要： Process for the manufacture of at least one of acetic acid and methyl acetate by carbonylating at least one carbonylatable reactant selected from methanol, dimethyl ether and dimethyl carbonate with carbon monoxide in the presence of a zeolite of structure type MOR. The zeolite has greater than 50% of its crystals in the size range to 3 microns.
摘要翻译：通过在结构型MOR的沸石存在下，用一氧化碳羰基化至少一种选自甲醇，二甲醚和碳酸二甲酯的羰基化反应物来制备乙酸和乙酸甲酯中的至少一种的方法。沸石具有大于50微米的晶体，其尺寸范围为3微米。

36. 发明申请

US20130066057A1 METHOD FOR OBTAINING BIODEGRADABLE SURFACTANTS FROM CELLULOSE IN A SINGLE REACTOR 审中-公开
标题翻译：在单反应器中从纤维素获得生物可降解的表面活性剂的方法
公开(公告)号：US20130066057A1
公开(公告)日：2013-03-14
申请号：US13634231
申请日：2011-03-10
申请人： Avelino Corma Canos , Nicolás David Villandier
发明人： Avelino Corma Canos , Nicolás David Villandier
IPC分类号： C07H15/04
CPC分类号： C07H15/04
摘要： The invention relates to a method for obtaining surfactants from cellulose and hemicellulose, which comprises one reaction in a single reactor (one pot) and which includes at least the following steps: a) a first hydrolysis step, in which the cellulose is mixed with at least one ionic liquid, water and a catalyst; and b) a second glycosylation step, in which at least one alcohol is added when the hydrolysis level of the cellulose is between 10 and 80%. The resulting products are preferably alkyl-α,β-glycosides.
摘要翻译：本发明涉及从纤维素和半纤维素获得表面活性剂的方法，其包括在单个反应器（一锅）中的一个反应，其包括至少以下步骤：a）第一水解步骤，其中纤维素与至少一种离子液体，水和催化剂; 和b）第二糖基化步骤，其中当纤维素的水解水平为10至80％时，加入至少一种醇。所得产物优选为烷基-α，β-葡糖苷。

37. 发明申请

US20110313142A1 PREPARATION OF AZO COMPOUNDS WITH SOLID CATALYSTS 审中-公开
标题翻译：用固体催化剂制备AZO化合物
公开(公告)号：US20110313142A1
公开(公告)日：2011-12-22
申请号：US13063551
申请日：2009-09-10
申请人： Avelino Corma Canos , Hermenegildo Garcia Gomez , Adbessamad Grirrane
发明人： Avelino Corma Canos , Hermenegildo Garcia Gomez , Adbessamad Grirrane
IPC分类号： C07C245/02
CPC分类号： B01J23/52 , B01J21/06 , B01J21/063 , B01J31/064 , B01J35/0013 , B01J35/006 , B01J37/035 , B01J37/16 , B01J2231/70 , B01J2531/18 , C07C245/08 , C07C253/30 , C07D213/74 , C07C255/67
摘要： The present invention relates to a preparation process of azo compounds which comprises the reaction between at least: one amine or polyamine, molecular oxygen, a catalyst formed by at least one support selected from among at least one metal oxide of one of the elements of groups 3, 4, 5, 6, 8, 9, 11 and 13, silica, anionic laminar compound of hydrotalcite type or its derivatives, active carbon or an organic polymer. In addition, said catalyst may contain gold nanoparticles.
摘要翻译：本发明涉及一种偶氮化合物的制备方法，其包括在至少一种胺或多胺，分子氧，由至少一种载体形成的催化剂之间的反应，所述载体选自基团元素之一的至少一种金属氧化物 3，4，5，6，8，9，11和13，二氧化硅，水滑石型阴离子层状化合物或其衍生物，活性炭或有机聚合物。此外，所述催化剂可以含有金纳米颗粒。

38. 发明申请

US20100312018A1 Processes for Producing Levosandal and Levosandol 审中-公开
标题翻译：产生左旋糖和左旋糖酐的方法
公开(公告)号：US20100312018A1
公开(公告)日：2010-12-09
申请号：US12753279
申请日：2010-04-02
申请人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty
发明人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty
IPC分类号： C07C45/74 , C07C29/159
CPC分类号： C07C29/14 , C07C45/74 , C07C2601/10 , C07C33/12 , C07C47/225
摘要： The present invention relates to processes for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal and 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol using heterogeneous bifunctional catalysts with a good yield. There is provided a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal by the cross-aldol condensation between campholenic aldehyde and butanal using bifunctional heterogeneous catalysts in the presence of controlled amounts of an aliphatic alcohol; and a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol useful as perfume, starting from 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal through a MPV reduction using an acid-base bifunctional heterogeneous catalyst. Both process can be coupled in a cascade process which involves the cross-aldol condensation between campholenic aldehyde and butanal followed by the Meerwein-Ponndorf-Verley (MPV) reduction in the presence of a secondary alcohol using the same heterogeneous bifunctional catalyst for obtaining (2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol).
摘要翻译：本发明涉及2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛和2-乙基-4-（2,2,3-三甲基 -3-环戊烯-1-基）-2-丁烯-1-醇，使用异构双官能催化剂，产率很高。提供了一种通过使用双功能非均相催化剂在camp醛和丁醛之间的交换醛醇缩合产生2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛的方法存在受控量的脂族醇; 和用作香料的2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇的制备方法，由2-乙基-4-（2 ，2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛，通过使用酸碱双功能多相催化剂的MPV还原。这两种方法可以在级联方法中偶合，其涉及在醛醇和丁醛之间的交叉醛醇缩合，随后在仲醇存在下使用相同的异构双功能催化剂还原Meerwein-Ponndorf-Verley（MPV）以获得（2 - 乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇）。

39. 发明申请

US20090234145A1 METHOD AND CATALYSTS FOR THE EPOXIDATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF OXYGEN 审中-公开
标题翻译：氧气存在下氧化烯烃的方法和催化剂
公开(公告)号：US20090234145A1
公开(公告)日：2009-09-17
申请号：US11911836
申请日：2006-04-06
申请人： Avelino Corma Canos , Marcelo Eduardo Domine
发明人： Avelino Corma Canos , Marcelo Eduardo Domine
IPC分类号： C07D301/04
CPC分类号： B01J29/0325 , B01J21/063 , B01J23/66 , B01J29/89 , B01J31/0274 , B01J35/006 , B01J2229/18 , B01J2229/32 , C07D301/10 , C07D303/04
摘要： The invention relates to a method for the epoxidation of an olefinic compound, which is characterised in that it comprises an oxidation reaction of at least one olefinic compound containing one or more double bonds C═C with oxygen in the presence of one or more reaction initiating agents, at least one catalyst containing at least one metal that is selected from a noble metal, a transition metal and mixtures of same, and at least one hydrocarbon that is selected from one or more branched alkanes, one or more alkyl cyclic or cyclic hydrocarbons, one or more alkyl aromatic or aromatic compounds and mixtures of same.
摘要翻译：本发明涉及一种烯烃化合物的环氧化方法，其特征在于它包含在一种或多种反应引发剂存在下至少一种含有一个或多个双键CC与氧的烯属化合物的氧化反应，至少一种含有至少一种选自贵金属，过渡金属及其混合物的金属的催化剂和至少一种选自一种或多种支链烷烃，一种或多种烷基环状或环状烃的烃，一种或更多烷基芳族或芳族化合物及其混合物。

40. 发明申请

US20090220661A1 MICROPOROUS CRYSTALLINE MATERIAL, ZEOLITE ITQ-37, PREPARATION METHOD AND USE 有权
标题翻译：微波晶体材料，沸石ITQ-37，制备方法和用途
公开(公告)号：US20090220661A1
公开(公告)日：2009-09-03
申请号：US12280590
申请日：2007-02-22
申请人： Manuel Moliner Marin , Maria Jose Diaz Cabanas , Angel Cantin Sanz , Avelino Corma Canos
发明人： Manuel Moliner Marin , Maria Jose Diaz Cabanas , Angel Cantin Sanz , Avelino Corma Canos
IPC分类号： A23L1/48 , B01J29/04
CPC分类号： B01J29/70 , B01J29/04 , B01J2229/20 , C01B37/005 , C01B39/06 , C01B39/12 , C10G11/05 , C10G47/16 , C10G47/18 , C10G47/20 , C10G50/00
摘要： The present invention relates to a microporous crystalline material characterized in that it has the following chemical composition in the calcined from: xX2O3:nYO2:mGeO2 in which (n+m) is at least 5, X is one or more trivalent elements, Y corresponds to one or more tetravalent elements other than Ge, “x” may have any value, including zero, and the ratio Y/Ge is greater than 0.1, and it has a characteristic X-ray diffraction pattern. Its also relates to a method for preparing it and to its use in the conversion of organic-compounds supplies.
摘要翻译：微孔结晶材料本发明涉及一种微孔结晶材料，其特征在于它具有以下煅烧成的化学组成：<？在线配方说明=“在线配方”末端=“铅”→xX 2 O 3 :nYO 2 :mGeO 2 其中（n + m）至少为5，X为一个或多个三价元素，Y对应于一个或多个四价元素除了Ge之外，“x”可以具有包括0的任何值，并且比率Y / Ge大于0.1，并且具有特征X射线衍射图案。它还涉及其制备方法及其在有机化合物用品转化中的应用。

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