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31. 发明申请

US20100093960A1 Potassium Based Catalyst Systems For Synthesizing Rubbery Polymers 有权
标题翻译：用于合成橡胶聚合物的基于钾的催化剂体系
公开(公告)号：US20100093960A1
公开(公告)日：2010-04-15
申请号：US12248601
申请日：2008-10-09
申请人： John Robert Zuppo, III , Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu
发明人： John Robert Zuppo, III , Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu
IPC分类号： C08F4/52 , B01J31/02
CPC分类号： B60C1/0016 , C08F36/06 , C08F4/52
摘要： The present invention is directed to a catalyst system for synthesizing rubbery polymers, such as styrene-butadiene rubber, that can be utilized in tire tread rubbers. The catalyst system, in one embodiment, includes an organolithium compound and a potassium alkyl borohydride or potassium alkyl aluminum hydride defined by: (R)3A−(H)K+, wherein A is boron or aluminum, H is hydrogen, K is potassium, and R, which is the same or different, is either H, a C1-C10 alkyl, a C3-C10 cycloalkyl, phenyl, or phenyl substituted C1-C10 alkyl, or a C3-C10 cycloalkyl, with the proviso that at least one R is a C1-C10 alkyl, and further wherein any two R's may optionally be part of a carbocyclic ring. The rubbery polymers can have low to medium vinyl microstructure content, i.e., from about 10% to about 40%, and are useful in tire tread rubber compounds which can exhibit improved wear and tear characteristics.
摘要翻译：本发明涉及可用于轮胎胎面橡胶中的用于合成橡胶状聚合物如丁苯橡胶的催化剂体系。催化剂体系在一个实施方案中包括有机锂化合物和烷基硼氢化钾或烷基氢化铝钾，其定义为：（R）3A-（H）K +，其中A是硼或铝，H是氢，K是钾，和R相同或不同，为H，C 1 -C 10烷基，C 3 -C 10环烷基，苯基或苯基取代的C 1 -C 10烷基或C 3 -C 10环烷基，条件是至少一个 R是C 1 -C 10烷基，并且其中任何两个R可以任选地是碳环的一部分。橡胶状聚合物可以具有低至中等乙烯基微结构含量，即约10％至约40％，并且可用于可显示改善的磨损和撕裂特性的轮胎胎面橡胶化合物。

32. 发明申请

US20080161518A1 Catalyst System for Synthesizing Amine Functionalized Rubbery Polymers Having a High Trans Microstructure 有权
标题翻译：用于合成具有高转移微结构的胺官能化橡胶聚合物的催化剂体系
公开(公告)号：US20080161518A1
公开(公告)日：2008-07-03
申请号：US11617361
申请日：2006-12-28
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Laurie Elizabeth Austin , Chad Aaron Jasiunas , Steven Kristofer Henning
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Laurie Elizabeth Austin , Chad Aaron Jasiunas , Steven Kristofer Henning
IPC分类号： C08F4/48 , B60C1/00 , C08K3/04 , C08K3/36
CPC分类号： C08F36/04 , C08F4/48 , C08F4/54
摘要： The present invention is directed to a catalyst system for synthesizing rubbery polymers, such as polybutadiene rubber, styrene-butadiene rubber, isoprene-butadiene rubber, or styrene-isoprene-butadiene rubber, that are amine functionalized and have a high trans microstructure. The catalyst system, in one embodiment, includes (a) an organolithium amine compound, (b) a group IIa metal salt of an amino glycol or a glycol ether, (c) an organoaluminum compound, and optionally (d) an amine compound. The amine functionalized rubbery polymers can be utilized in tire tread rubbers where the rubbery polymers may provide desirable wear properties without substantially sacrificing other performance characteristic(s), e.g., traction properties.
摘要翻译：本发明涉及一种用于合成胺官能化并具有高反相微观结构的橡胶状聚合物如聚丁二烯橡胶，苯乙烯 - 丁二烯橡胶，异戊二烯 - 丁二烯橡胶或苯乙烯 - 异戊二烯 - 丁二烯橡胶的催化剂体系。在一个实施方案中，催化剂体系包括（a）有机锂胺化合物，（b）氨基二醇或二醇醚的IIa族金属盐，（c）有机铝化合物和任选的（d）胺化合物。胺官能化橡胶状聚合物可用于轮胎胎面橡胶中，其中橡胶状聚合物可提供期望的耐磨性，而基本上不会牺牲其它性能特征，例如牵引性能。

33. 发明授权

US07199201B2 Synthetic polyisoprene rubber 有权
标题翻译：合成聚异戊二烯橡胶
公开(公告)号：US07199201B2
公开(公告)日：2007-04-03
申请号：US11287562
申请日：2005-11-23
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Aaron Michael Ryba , Jin-Ping Zhou , Chad Aaron Jasiunas , Paul Harry Sandstrom
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Aaron Michael Ryba , Jin-Ping Zhou , Chad Aaron Jasiunas , Paul Harry Sandstrom
IPC分类号： C08F36/08 , C08F136/08
CPC分类号： B01J31/143 , B01J31/04 , B60C1/0016 , C08F36/04 , C08L9/00 , C08L21/00 , C08F4/545 , C08F4/44 , C08L2666/08
摘要： The neodymium catalyst system prepared by the technique of this invention can be used in the polymerization of isoprene monomer into synthetic polyisoprene rubber having an extremely high cis-microstructure content and high stereo regularity. This polyisoprene rubber will crystallize under strain and can be compounded into rubber formulations in a manner similar to natural rubber. This invention more specifically discloses a process for the synthesis of polyisoprene rubber which comprises polymerizing isoprene monomer in the presence of a neodymium catalyst system, wherein the neodymium catalyst system is prepared by a process that comprises (1) reacting a neodymium carboxylate with an organoaluminum compound in an organic solvent to produce neodymium-aluminum catalyst component, and (2) subsequently reacting the neodymium-aluminum catalyst component with an elemental halogen to produce the neodymium catalyst system, wherein the neodymium catalyst system is void of nickel-containing compounds.
摘要翻译：通过本发明技术制备的钕催化剂体系可用于将异戊二烯单体聚合成具有非常高的顺式微结构含量和高立体规律性的合成聚异戊二烯橡胶。该聚异戊二烯橡胶将在应变下结晶，并且可以以与天然橡胶相似的方式配合成橡胶制剂。本发明更具体地公开了一种用于合成聚异戊二烯橡胶的方法，其包括在钕催化剂体系存在下聚合异戊二烯单体，其中所述钕催化剂体系通过以下方法制备，所述方法包括：（1）使羧酸钕与有机铝化合物在有机溶剂中制备钕 - 铝催化剂组分，和（2）随后使钕 - 铝催化剂组分与元素卤素反应以产生钕催化剂体系，其中钕催化剂体系不含含镍化合物。

34. 发明授权

US07166747B2 Synthesis of soluble functionalized lithium initiators 失效
标题翻译：可溶性官能化锂引发剂的合成
公开(公告)号：US07166747B2
公开(公告)日：2007-01-23
申请号：US10713122
申请日：2003-11-14
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C07C221/00
CPC分类号： B60C1/0016 , C07F1/005 , C07F1/02 , C08C19/44 , C08F36/04 , C08F4/488
摘要： This invention discloses a process for making dilithium initiators in high purity. This process can be conducted in the absence of amines which is desirable since amines can act as modifiers for anionic polymerizations. The dilithium compounds made are highly desirable because they are soluble in aromatic solvents. The present invention more specifically discloses a process for synthesizing a dilithium initiator which comprises reacting diisopropenylbenzene with a tertiary alkyl lithium compound in an aromatic solvent at a temperature which is within the range of about 0° C. to about 100° C. The present invention further discloses a process for synthesizing m-di-(1-lithio-1-methyl-3,3-dimethylbutyl) benzene which comprises reacting diisopropenylbenzene with tertiary-butyllithium in an aromatic solvent at a temperature which is within the range of about 0° C. to about 100° C. The present invention also discloses a process for synthesizing a functionalized lithium initiator which comprises reacting a dilithium initiator with an alkylaminoaryl compound of the structural formula: wherein R, R′, and R″ can be the same or different, wherein R is selected from the group consisting of hydrogen atoms, alkyl groups, aryl groups, alkaryl groups, and amino aryl groups, and wherein R′ and R″ represent alkyl groups.
摘要翻译：本发明公开了一种制备高纯度二锂引发剂的方法。该方法可以在不存在胺的情况下进行，因为胺可以用作阴离子聚合的改性剂。所制备的二锂化合物是非常需要的，因为它们可溶于芳族溶剂。本发明更具体地公开了一种合成二锂引发剂的方法，其包括在芳族溶剂中在约0℃至约100℃的温度范围内使二异丙烯基苯与叔烷基锂化合物反应。本发明进一步公开了一种合成间二 - （1-锂 - 1-甲基-3,3-二甲基丁基）苯的方法，该方法包括使二异丙烯基苯与叔丁基锂在芳族溶剂中在约0℃的范围内本发明还公开了一种合成官能化的锂引发剂的方法，其包括使二锂引发剂与以下结构式的烷基氨基芳基化合物反应：其中R，R'和R“可以相同或不同的，其中R选自氢原子，烷基，芳基，烷芳基和氨基芳基，并且其中R'和R“表示烷基。

35. 发明授权

US07091150B2 Synthetic polyisoprene rubber 失效
标题翻译：合成聚异戊二烯橡胶
公开(公告)号：US07091150B2
公开(公告)日：2006-08-15
申请号：US10942517
申请日：2004-09-16
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Aaron Michael Ryba , Jin-Ping Zhou , Chad Aaron Jasiunas , Paul Harry Sandstrom
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Aaron Michael Ryba , Jin-Ping Zhou , Chad Aaron Jasiunas , Paul Harry Sandstrom
IPC分类号： B01J31/04 , B01J37/04
CPC分类号： B01J31/143 , B01J31/04 , B60C1/0016 , C08F36/04 , C08L9/00 , C08L21/00 , C08F4/545 , C08F4/44 , C08L2666/08
摘要： The neodymium catalyst system prepared by the technique of this invention can be used in the polymerization of isoprene monomer into synthetic polyisoprene rubber having an extremely high cis-microstructure content and high stereo regularity. This polyisoprene rubber will crystallize under strain and can be compounded into rubber formulations in a manner similar to natural rubber. This invention more specifically discloses a process for preparing a neodymium catalyst system which comprises (1) reacting a neodymium carboxylate with an organoaluminum compound in an organic solvent to produce neodymium-aluminum catalyst component, and (2) subsequently reacting the neodymium-aluminum catalyst component with an elemental halogen to produce the neodymium catalyst system. The present invention further discloses a synthetic polyisoprene rubber which is comprised of repeat units that are derived from isoprene, wherein the synthetic polyisoprene rubber has a cis-microstructure content which is within the range of 98.0% to 99.5%, a 3,4-microstructure content which is within the range of 0.5% to 2.0%, and a trans-microstructure content which is within the range of 0.0% to 0.5%.
摘要翻译：通过本发明技术制备的钕催化剂体系可用于将异戊二烯单体聚合成具有非常高的顺式微结构含量和高立体规律性的合成聚异戊二烯橡胶。该聚异戊二烯橡胶将在应变下结晶，并且可以以与天然橡胶相似的方式配合成橡胶制剂。本发明更具体地公开了一种制备钕催化剂体系的方法，其包括：（1）使羧酸钕与有机铝化合物在有机溶剂中反应以制备钕 - 铝催化剂组分，和（2）随后使钕 - 铝催化剂组分用元素卤素制备钕催化剂体系。本发明还公开了一种合成聚异戊二烯橡胶，其由衍生自异戊二烯的重复单元组成，其中合成聚异戊二烯橡胶的顺式微结构含量在98.0％至99.5％的范围内，3,4-微结构含量在0.5％至2.0％的范围内，反式微结构含量在0.0％至0.5％的范围内。

36. 发明授权

US07055566B2 Light weight rubber composition containing clay 失效
标题翻译：轻质橡胶组合物含有粘土
公开(公告)号：US07055566B2
公开(公告)日：2006-06-06
申请号：US10923071
申请日：2004-08-20
申请人： Manoj Ajbani , Wen-Liang Hsu , Adel Farhan Halasa , Ginger Lee , Eric Sean Castner
发明人： Manoj Ajbani , Wen-Liang Hsu , Adel Farhan Halasa , Ginger Lee , Eric Sean Castner
IPC分类号： B60C11/00 , B60C27/00 , B60C1/00
CPC分类号： C08K3/346 , C08K9/04 , Y10S152/905 , C08L19/006
摘要： This invention relates to a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of: (1) an amino group containing rubbery polymer, wherein said amino group containing rubbery polymer contains from about 0.1 weight percent to about 20 weight percent monomer units containing an amino group, (2) from 0.1 to about 25 phr of an organophilic 2:1 layered silicate clay selected from the group consisting of montmorillonite clays, bentonite clays, hectorite clays, saponite clays, nontronite clays, beidellite clays, fluorohectorite clays, stevensite clays, volkonskoite clays, sauconite clays, and laponite clays, and (3) a silica coupling agent.
摘要翻译：本发明涉及一种轮胎，该轮胎由具有外周胎面的大致环形胎体，两个间隔开的胎圈，从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中所述胎面由以下组成：（1）含氨基的橡胶状聚合物，其中所述含氨基的橡胶状聚合物含有约0.1重量％至约20重量％的含有氨基的单体单元，（2）0.1至约25 选自蒙脱石粘土，膨润土，锂蒙脱石粘土，皂石粘土，白云石粘土，贝得石粘土，氟代锂蒙脱石粘土，硬石榴石粘土，膨润土，粘土，松节油粘土等亲水性2:1层状硅酸盐粘土，和（3）二氧化硅偶联剂。

37. 发明授权

US06936669B2 Functionalized monomers for synthesis of rubbery polymers 有权
标题翻译：用于合成橡胶状聚合物的官能化单体
公开(公告)号：US06936669B2
公开(公告)日：2005-08-30
申请号：US10731782
申请日：2003-12-09
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Jin-Ping Zhou , Chad Aaron Jasiunas , Corey Stanton Yon
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Jin-Ping Zhou , Chad Aaron Jasiunas , Corey Stanton Yon
IPC分类号： C07D211/08 , C07D265/30 , C08C19/44 , C08F4/46 , C08F26/06 , C08F126/06 , C08F236/10 , C08F236/14
CPC分类号： C08F236/14 , C08C19/44 , C08F236/10
摘要： This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of wherein R and R′ can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula wherein R and R′ can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.
摘要翻译：本发明公开了一种合成胺官能化单体的方法，其包括（1）使仲胺与2,3-二卤代丙烯反应以制备含有仲胺的乙烯基卤化物，所述仲胺具有选自下组的结构式：其中R和R' 可以相同或不同，表示含有1至约10个碳原子的烯丙基，烷氧基或烷基，其中X表示卤素原子，其中m表示4至约10的整数，并且其中X表示卤素原子 ; 和（2）使含有乙烯基卤的仲胺与乙烯基卤化镁反应以制备具有结构式的单体，其中R和R'可以相同或不同，并且代表含有1至约10个碳原子的烷基，烯丙基或烷氧基原子，其中m表示约4至约10的整数。

38. 发明授权

US06901982B2 Functionalized monomers for synthesis of rubbery polymers 失效
标题翻译：用于合成橡胶状聚合物的官能化单体
公开(公告)号：US06901982B2
公开(公告)日：2005-06-07
申请号：US10916385
申请日：2004-08-10
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08C19/44 , C08F236/10 , C08F236/14 , B60C5/00
CPC分类号： C08C19/44 , C08F236/10 , C08F236/14 , Y10T152/10495
摘要： The present invention relates to a process for synthesizing a rubbery polymer that comprises copolymerizing at least one conjugated diolefin monomer and at least one functionalized monomer in an organic solvent at a temperature which is within the range of 0° C. to about 150° C., wherein the polymerization is initiated with an anionic initiator, wherein the polymerization is conducted in the absence of conventional polar modifiers, and wherein the functionalized monomer is of the structural formula: wherein the R′ groups in repeat units and in different repeat units can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to about 4 carbon atoms, wherein x represents an integer from 1 to about 10, and wherein the R groups in repeat units and in different repeat units can be the same or different and represent alkyl groups containing from 1 to about 10 carbon atoms or alkoxy groups containing from 1 to about 10 carbon atoms.
摘要翻译：本发明涉及一种合成橡胶状聚合物的方法，该方法包括在0℃至约150℃的温度范围内使至少一种共轭二烯烃单体与至少一种官能化单体在有机溶剂中共聚。其中所述聚合由阴离子引发剂引发，其中所述聚合在不存在常规极性改性剂的情况下进行，并且其中所述官能化单体具有以下结构式：其中重复单元和不同重复单元中的R'基团可以是相同或不同，表示含有1至约4个碳原子的氢原子或烷基，其中x表示1至约10的整数，并且其中重复单元和不同重复单元的R基团可以相同或不同并且表示含有1至约10个碳原子的烷基或含有1至约10个碳原子的烷氧基。

39. 发明授权

US06812307B2 Functionalized monomers for synthesis of rubbery polymers 失效
标题翻译：用于合成橡胶状聚合物的官能化单体
公开(公告)号：US06812307B2
公开(公告)日：2004-11-02
申请号：US10624188
申请日：2003-07-22
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08F23614
CPC分类号： C08F236/14 , C08C19/44 , C08F236/10
摘要： This invention is based upon the unexpected finding that random copolymers of 1,3-butadiene monomer and 3-(2-pyrrolidinoethyl) styrene and/or 4-(2-pyrrolidinoethyl) styrene having a low vinyl content can be synthesized by anionic polymerization at normal polymerization temperatures without the need for a conventional polar modifier. The subject invention more specifically discloses a process for synthesizing a rubbery polymer that comprises copolymerizing at least one conjugated diolefin monomer and at least one functionalized monomer in an organic solvent at a temperature which is within the range of 20° C. to about 100° C., wherein the polymerization is initiated with an anionic initiator, wherein the functionalized monomer is of the structural formula: wherein n represents an integer from 4 to about 10, and wherein the polymerization is conducted in the absence of conventional polar modifiers.
摘要翻译：本发明基于意想不到的发现，即可以通过阴离子聚合法合成具有低乙烯基含量的1,3-丁二烯单体和3-（2-吡咯烷基乙基）苯乙烯和/或4-（2-吡咯烷基乙基）苯乙烯的无规共聚物正常聚合温度，而不需要常规的极性改性剂。本发明更具体地公开了一种合成橡胶状聚合物的方法，该方法包括在20℃至约100℃的温度范围内使有机溶剂中的至少一种共轭二烯烃单体和至少一种官能化单体共聚合其中所述聚合由阴离子引发剂引发，其中所述官能化单体具有以下结构式：其中n表示4至约10的整数，并且其中聚合在不存在常规极性改性剂的情况下进行。

40. 发明授权

US06646054B1 Adhesion between rubber components 失效
标题翻译：橡胶部件之间的粘合力
公开(公告)号：US06646054B1
公开(公告)日：2003-11-11
申请号：US08865784
申请日：1997-05-30
申请人： Bruce Raymond Hahn , Adel Farhan Halasa , Wen-Liang Hsu
发明人： Bruce Raymond Hahn , Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08L4700
CPC分类号： C08J5/124 , C08J2321/00 , C08L2666/08 , C09J121/00 , Y10T428/31826
摘要： The process of this invention can be utilized to improve the adhesion between rubber components. It is generally most useful for improving the adhesion between two different pre-cured rubber components or for improving the adhesion between a pre-cured rubber component and an uncured (green) rubber component. However, the technique of this invention can also be employed to improve the adhesion between two uncured rubber components. The technique of this invention is based upon the unexpected discovery that low molecular weight trans-1,4-polybutadiene containing rubber compounds can be used to improve the adhesion between rubber components. This invention more specifically reveals a technique for improving the adhesion between a first rubber component and a second rubber component in a process for manufacturing a cured rubber article, said technique comprising the steps of: (1) positioning a layer of an adhesion-promoting rubber composition which is comprised of a low molecular weight trans-1,4-polybutadiene rubber between the first rubber component and the second rubber component, (2) bringing the first rubber component into contact with one side of the layer of adhesion-promoting rubber composition and bringing the second rubber composition into contact with the other side of the layer of adhesion-promoting rubber composition and (3) curing the first rubber composition, the second rubber composition and the adhesion-promoting rubber composition together under conditions of heat and pressure to produce the cured rubber article.
摘要翻译：本发明的方法可用于改善橡胶组分之间的粘合性。通常最有用的是改善两种不同的预固化橡胶组分之间的粘附性或改善预固化橡胶组分和未固化的（绿色）橡胶组分之间的粘合性。然而，本发明的技术也可用于改善两种未固化橡胶组分之间的粘合性。本发明的技术基于意想不到的发现，即低分子量的反式-1,4-聚丁二烯的橡胶化合物可用于改善橡胶组分之间的粘合性。本发明更具体地揭示了在固化橡胶制品的制造方法中提高第一橡胶组分和第二橡胶组分之间的粘合力的技术，所述技术包括以下步骤：（1）将粘合促进橡胶层在第一橡胶组分和第二橡胶组分之间由低分子量反式1,4-聚丁二烯橡胶组成的组合物，（2）使第一橡胶组分与粘合促进橡胶组合物层的一侧接触并使第二橡胶组合物与粘合促进橡胶组合物的另一侧接触，以及（3）在热和压力条件下将第一橡胶组合物，第二橡胶组合物和粘合促进橡胶组合物固化在一起，生产固化橡胶制品。

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