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    • 33. 发明授权
    • Cationic Toner processes
    • 阳离子调色剂工艺
    • US5645968A
    • 1997-07-08
    • US726600
    • 1996-10-07
    • Guerino G. SacripanteMaureen M. KedianRaj D. PatelWalter MychajlowskijBeng S. Ong
    • Guerino G. SacripanteMaureen M. KedianRaj D. PatelWalter MychajlowskijBeng S. Ong
    • G03G9/087G03G9/08
    • G03G9/0804
    • A process for the preparation of toner comprising(i) preparing, or providing a cationic emulsion resin latex comprised of a resin derived from at least one olefinic nonpolar monomer, a cationic olefinic monomer, a cationic free radical initiator, and optionally a chain transfer agent in an aqueous mixture comprised of a nonionic surfactant and a cationic surfactant, and which mixture is heated at a temperature of from about 60.degree. C. to about 95.degree. C.;(ii) adjusting the pH of said cationic latex to from about 10 to about 14 by the addition of a base;(iii) preparing, or providing a pigment dispersion, which dispersion is comprised of a pigment and an anionic surfactant, and optionally a charge control agent;(iv) shearing said pigment dispersion with the pH adjusted latex of (ii) and heating below about the resin Tg to form electrostatically bound toner size aggregates, and optionally adding a cationic surfactant to stabilize the size of the toner aggregates; and(v) heating said electrostatically bound toner size aggregates above about the Tg of the resin to form coalesced toner particles; followed by optionally filtering, washing and drying the toner obtained.
    • 一种制备调色剂的方法,包括(i)制备或提供由至少一种烯属非极性单体衍生的树脂,阳离子烯烃单体,阳离子自由基引发剂和任选的链转移剂组成的阳离子乳液树脂胶乳 在由非离子表面活性剂和阳离子表面活性剂组成的含水混合物中,将混合物在约60℃至约95℃的温度下加热; (ii)通过加入碱将所述阳离子胶乳的pH调节至约10至约14; (iii)制备或提供颜料分散体,该分散体由颜料和阴离子表面活性剂以及任选的电荷控制剂组成; (iv)用(ii)的pH调节的胶乳剪切所述颜料分散体,并加热到树脂Tg附近,以形成静电结合的调色剂尺寸聚集体,以及任选地加入阳离子表面活性剂以稳定调色剂聚集体的尺寸; 和(v)在所述树脂的Tg附近加热所述静电结合的调色剂尺寸聚集体以形成聚结的调色剂颗粒; 然后任选地过滤,洗涤和干燥获得的调色剂。
    • 34. 发明授权
    • Carrier processes
    • 运营商流程
    • US5582951A
    • 1996-12-10
    • US498284
    • 1995-07-03
    • Raj D. PatelGrazyna E. Kmiecik-LawrynowiczMichael A. HopperWalter MychajlowskijBeng S. Ong
    • Raj D. PatelGrazyna E. Kmiecik-LawrynowiczMichael A. HopperWalter MychajlowskijBeng S. Ong
    • G03G9/107G03G9/113
    • G03G9/1133G03G9/107G03G9/1132
    • A process for the preparation of carrier particles which comprises mixing a dispersion of water, submicron magnetic particles, and ionic surfactant with a latex comprised of resin particles suspended in an aqueous solution containing a surfactant that is counterionic in charge to said ionic surfactant, and a nonionic surfactant; thereafter heating the resulting mixture below about the latex resin glass transition temperature (Tg) while stirring to form aggregates, followed by increasing the temperature of said mixture to about above the latex resin Tg, and subsequently adding additional counterionic or nonionic surfactant solution to minimize, or avoid any further growth in particle size during heating of the mixture about above the latex resin Tg, and wherein said resin Tg is in the range of from between about 45.degree. C. to about 100.degree. C.
    • 一种制备载体颗粒的方法,其包括将水,亚微米磁性颗粒和离子表面活性剂的分散体与悬浮在含有负离子表面活性剂的水溶液中的树脂颗粒混合到所述离子表面活性剂上的胶乳混合,以及 非离子表面活性剂 然后在搅拌下将所得混合物在胶乳树脂玻璃化转变温度(Tg)以下加热以形成聚集体,随后将所述混合物的温度升高至胶乳树脂Tg的大约,然后加入另外的抗衡离子或非离子表面活性剂溶液, 或者避免混合物加热到胶乳树脂Tg以上时粒径的任何进一步增长,并且其中所述树脂Tg在约45℃至约100℃的范围内。