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    • 24. 发明授权
    • Per(halo-oxygen) acid oxidation,purification and recovery process and apparatus therefor
    • PER(HALO-OXYGEN)酸氧化,净化和回收过程及其设备
    • US3703508A
    • 1972-11-21
    • US3703508D
    • 1970-10-07
    • SYBRON CORP
    • HEIT ALLYN HAROLDWILLIAMSON JAMES NORRIS
    • C01B11/18C08B15/02C08B31/18C08B15/00
    • B01D61/44C01B11/18C08B15/02C08B31/18
    • AN ELECTRODIALYTIC APPARATUS UTILIZING ANION AND CATION PERMSELECTIVE MEMBRANES AND HAVING AT LEAST ONE TWOCHAMBER CELL FOR PURIFICATION AND AT LEAST ONE THREE-CHAMBER CELL PROXIMAL THE TWO-CHAMBER UNIT FOR CONCENTRATION OF AQUEOUS PER(HALO-OXYGEN) ACIDS AND THEIR SALTS, ALL ANOLYTE CHAMBERS SHARING A COMMON ANOLYTE STREAM, ALL CATHOLYTE CHAMBERS SHARING A COMMON CATHOLYTE STREAM, AND AT LEAST ONE OF THE ANOLYTE CHAMBERS OF THE PURIFICATION AND THE CONCENTRATION CELLS SHARING A COMMON ANODE. A MULTI-STEP PROCESS FOR RECOVERING AND REGENERATING THE PERIODATE OXIDANT USED IN PREPARING OXIDIZED POLYSACCHARIDES IN WHICH THE PRIMARY LIQUOR AND SUBSEQUENT WASH LIQUORS FROM THE OXIDIZED POLYSACCHARIDE FILTER CAKE ARE CIRCULATED IN THE ANOLYTE AND MIDDLE CHAMBERS OF THE ELECTRODIALYTIC APPARATUS HAVING TWO-CHAMBER AND THREECHAMBER CELLS FOR RE-OXIDATION AND CONCENTRATION RESPECTIVELY, THE LIQUORS HAVING A CONCENTRATION OF 4 TO 15 WEIGHT PERCENT BEING CIRCULATED IN THE ANOLYTE CHAMBERS; THOSE LIQUORS HAVING A CONCENTRATION OF 0.5 TO 5 WEIGHT PERCENT BEING CIRCULATED IN THE MIDDLE CHAMBER, ALL LIQUORS AND EFFLUENTS HAVING A CONCENTRATION OF LESS THAN 0.5 WEIGHT PERCENT BEING PASSED THROUGH A STRONG BASE ANION EXCHANGE RESIN WHICH REMOVES THE REMAINING PERIODATE, OR CHEMICALLY REDUCED PERIODATES, WHICH ARE SUBSEQUENTLY ELUTED BY THE SODIUM HYDROXIDE CATHOLYTE, WHICH IN TURN IS CIRCULATED IN THE ANOLYTE CHAMBERS OF THE APPARAUS FOR REGENERATION.