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    • 25. 发明授权
    • Pigmented paper coating and adhesive compositions containing a polyvinyl alcohol binder and a modifier therefor
    • 含有聚乙烯醇类粘合剂及其改性剂的印刷纸涂料和粘合剂组合物
    • US3477970A
    • 1969-11-11
    • US3477970D
    • 1962-09-04
    • DU PONT
    • BEEMAN ROBERT H
    • C09J129/04D21H19/38D21H19/40D21H19/52D21H19/58D21H19/60C09J3/14
    • D21H19/60C08L2666/02C08L2666/54C09J129/04D21H19/385D21H19/40D21H19/52D21H19/58
    • Paper coating or adhesive compositions comprise 100 parts by weight of pigment, 1 to 15 parts by weight of water-soluble polyvinyl alcohol and 0.1 to 4 parts by weight of sodium carboxymethyl cellulose, hydroxyethylcellulose, methylcellulose, sodium polyacrylate or sodium alginate or a water-soluble modifier. The pigment may be kaolin, calcium carbonate or titanium dioxide. The polyvinyl alcohol may be a partially or completely hydrolysed polyvinyl acetate. The compositions may be dissolved and dispersed in water and used for coating and laminating paper. They may also comprise wax emulsions; tinting pigments and dyes; plasticizers, e.g. calcium and ammonium stearates; dispersing agents, e.g. tetrasodium pyrophosphate and sodium hexametaphosphate; insolubilizers for the polyvinyl alcohol, e.g. triazone resins; and catalysts for the insolubilization, e.g. ammonium chloride.ALSO:Paper may be coated with compositions comprising 100 parts by weight of pigment, 1-15 parts by weight of water-soluble polyvinyl alcohol and 0,1-4 parts by weight of sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, sodium polyacrylate or sodium alginate. The pigment may be kaolin, calcium carbonate or titanium dioxide. The compositions may be applied from aqueous media and may also comprise wax emulsions; tinting pigments and dyes; plasticizers, e.g. calcium and ammonium stearates; dispersing agents, e.g. tetrasodium pyrophosphate and sodium hexametaphosphate; insolubilizers for the polyvinyl alcohol, e.g. triazone resins; and catalysts for the insolubilization, e.g. ammonium chloride. In examples, paper is coated with aqueous compositions comprising clay, polyvinyl alcohol, and (1-4) sodium carboxymethyl cellulose, (6) hydroxyethyl cellulose, (7) methyl cellulose, (8) sodium polyacrylate, and (9) sodium alginate; and comprising polyvinyl alcohol, sodium carboxymethyl cellulose, and (11) titanium dioxide, and (13) calcium carbonate.