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    • 21. 发明授权
    • A method of bonding non woven fabrics
    • 粘合非织造布的方法
    • US3720562A
    • 1973-03-13
    • US3720562D
    • 1970-08-21
    • JOHNSON & JOHNSON
    • DRELICH A
    • C08J3/03D04H1/66D06M11/17D06M11/20D06M11/28D06M11/56D06M11/65D06M15/233D06M15/244D06M15/263D06M15/267D06M15/333D06M23/16D06Q1/00B32B7/14
    • D06M11/20C08J3/03D04H1/66D06M11/17D06M11/28D06M11/56D06M11/65D06M15/233D06M15/244D06M15/263D06M15/267D06M15/333D06M23/16D06Q1/00Y10T428/24826
    • Bonded fibrous nonwoven textile fabrics having excellent strength and textile-like softness, drape and hand which are intermittently bonded with synthetic resins in predetermined print patterns of binder areas having a relatively high, uniform concentration of from about 50 percent to about 120 percent by weight of resin binder in the binder areas, based on the weight of the fibers therein, said binder areas having very sharply defined borders or edges with a minimum of binder feathering thereat whereby the optical density of the bonded fibrous nonwoven textile fabric very sharply increases from substantially zero to a maximum of at least from about 0.6 to about 1.0 or greater in a distance of less than about 1 mm. (0.04 inch), and methods of depositing such synthetic resins from colloidal aqueous dispersions thereof into wet fibrous webs to form the bonded fibrous nonwoven textile fabrics, comprising the use of (1) metal complex coordination compounds and (2) synthetic resins and/or surfactants, at least one of which contains a specific coordinating ligand capable of being affected by ions or said metals to control the total migration of the resin binder during such deposition.
    • 具有优异强度的粘合纤维非织造织物织物和织物状柔软度,悬垂性和手感,其间以合成树脂间隔地粘合有预定的印刷图案的粘合剂区域,所述粘合剂区域具有相对高的均匀浓度,其浓度为约50%至约120% 粘合剂区域中的树脂粘合剂基于其中的纤维的重量,所述粘合剂区域具有非常清晰的边界或边缘,其中最少的粘合剂在其上羽化,由此粘合的纤维非织造织物织物的光密度从基本上零开始增加 在小于约1mm的距离中至多为至少约0.6至约1.0或更大。 (0.04英寸),以及将这种合成树脂从其胶体水分散体沉积到湿纤维网中以形成粘合的纤维无纺织物的方法,其包括使用(1)金属络合物配位化合物和(2)合成树脂和/或 表面活性剂,其中至少一种含有能够被离子或所述金属影响的特异性配位配体,以控制在这种沉积过程中树脂粘合剂的总迁移。
    • 22. 发明授权
    • Single bath process for orange to brown mineral dyeings,with and without fungicide,using iron,manganese,and zirconium (zirc-ox process)
    • 使用铁,锰和锆(ZIRC-OX工艺)对褐色矿物染色剂单独使用,不含真菌,
    • US3671178A
    • 1972-06-20
    • US3671178D
    • 1970-05-19
    • US AGRICULTURE
    • CONNER CHARLES J
    • D06M11/28D06M11/46D06M11/71D06M13/192D06P1/00D06P3/60A61L13/00
    • D06M13/192D06M11/28D06M11/46D06M11/71D06P1/0076
    • ORANGE TO BROWN MINERAL DYEING ARE CONVENTIONALLY PREPARED FROM TWO BATH SYSTEMS, WHERE THE FABRIC IS WETTED WITH ONE BATH CONTAINING AN IRON SALT, AND THEN WETTED WITH ANOTHER BATH CONTAINING ALKALI, TO CAUSE THE COLORED IRON OXIDE TO DEPOSIT IN THE FABRIC AS A MINERAL DYE. THIS HAS BEEN NECESSARY UP TO NOW, SINCE IT HAS BEEN CHEMICALLY INCOMPATIBLE TO HAVE THE IRON IN THE SAME ALKALINE BATH WITH THE ALKALI. THIS INVENTION DEMONSTRATES THAT A HEAT DECOMPOSABLE COMPLEX OF THE IRON, WITH OR WITHOUT MANGANESE, CAN BE COMPATIBLE WITH ALKALINE ZIRCONYL AMMONIUM CARBONATE SOLUTIONS IN THE SAME BATH, WHEN CELLULOSICS CAN BE WETTED IN THIS BATH, AND SUBSEQUENTLY MINERAL DYED BY HEAT CURING, WHEN THE COPMPLEX OF IRON DECOMPOSES TO DEPOSIT IRON OXIDE WITH ZIRCONIA, THE ZIRCONYL AMMONIUM CARBANATE DECOMPOSING AT THE SAME TIME TO DEPOSIT ZIRCONIA. WHEN HEPTAVALENT MANGANESE (KMNO4) IS INCORPORATED INTO THE BATH WITH THE COMPLEXED IRON IT IS SOLUBLE AND COMPATIBLE, PRODUCING MANGANESE DIOXIDE (MNO2) BY REDUCTION PRODUCTS FROM THE IRON COMPLEX, RESULTING IN VARIOUS SHADES OF ORANGE TO BROWN WITH THE IRON OXIDE AND ZIRCONIA ALSO DEPOSITED. THIS PROCESS MAKES IT POSSIBLE TO DEPOSIT ORANGE TO BROWN WASH-FAST MINERAL DYEING FROM A SINGLE BATH. THE DEPOSITED ZIRCONIA ATTRIBUTES A DEGREE OF WATER REPELLENCY AND ALGAECIDAL RESISTANCE TO THE FABRIC, AND A COPPER OR PHENYL-MERCURY SALT CAN BE INCORPORATED INTO THE ZIRCONYL AMMONIUM CARBONATE COMPONENT OF THE SYSTEM TO DEPOSIT A FUNGICIDAL MINERAL DYE OF ORANGE TO BROWN SHADE ON HEAT CURING, MAKING IT POSSIBLE TO APPLY AN IRON AND/OR MANGANESE MINERAL DYE WITH OR WITHOUT FUNGICIDE FROM A SINGLE BATH, REDUCING CONVENTIONAL DYEING PROCEDURES FROM TWO OR MORE BATHS, TO A SINGLE BATH REQUIRING ONLY A SIMPLE PAD, DRY, AND CURE PROCEDURE TO EFFECT THE DYEING. THE FABRICS ARE NOT SERIOUSLY TENDERED AND THE RESIDUAL BY-PRODUCT SALTS MAY OR MAY NOT BE REMOVED BY WASHING, SINCE THE FABRIC IS NOT STIFFENED BY THEIR PRESENCE AND THE DYED COLORS ARE UNAFFECTED ON STANDING.
    • 29. 发明授权
    • Method of modifying keratin fiber
    • 改变角蛋白纤维的方法
    • US5824113A
    • 1998-10-20
    • US784962
    • 1997-01-16
    • Hiroshi Hojo
    • Hiroshi Hojo
    • D06M11/84D06M11/00D06M11/28D06M11/49D06M11/50D06M11/55D06M11/62D06M101/00D06M101/02D06M101/10D06M101/12D06M13/262
    • D06M11/55D06M11/28D06M11/50D06M11/62D06M2101/12D06M2200/45
    • An improved method of modifying keratin fiber represented by wool is disclosed. Mechanical force is applied to keratin fiber in the presence of an aqueous solution of a transition metal salt to weaken and destroy the structure of the parts under the keratin layers in scales (surface cells) so that the transition metal may be introduced in the under-keratin layers locally at high a concentration. Then, the keratin fiber is immersed in a bath containing oxidizing agents such as hydrogen peroxide and monopersulfuric acid. The oxidizing agents are decomposed by catalytic effect of the transition metal. Mainly due to pressure of oxygen gas evolved by the decomposition keratin layers, which are scales on the keratin fiber, are peeled off. Thus, it is possible to remove only the keratin parts, which are not agreeable to the touch, without damaging the non-keratin protein, and to provide modified fiber which substantially contains no remaining metal. High shrink proof effect may be achieved without using the conventional chlorine compounds as the oxidizing agents.
    • 公开了改进由羊毛代表的角蛋白纤维的改进方法。 在过渡金属盐水溶液的存在下,对角蛋白纤维施加机械力,以削弱和破坏鳞片(表面细胞)角质层下部分的结构,使得过渡金属可以引入到底层 局部高浓度的角蛋白层。 然后,将角蛋白纤维浸渍在含有氧化剂如过氧化氢和单过硫酸的浴中。 氧化剂通过过渡金属的催化作用而分解。 主要是由角蛋白纤维上鳞片上的分解角蛋白层释放的氧气的压力被剥离。 因此,可以仅去除不符合触摸的角蛋白部分,而不损害非角蛋白蛋白质,并且提供基本上不含剩余金属的改性纤维。 不使用常规氯化合物作为氧化剂可以实现高收缩效果。