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    • 21. 发明申请
    • PEO COATING ON MG SCREWS
    • PEO涂层在MG螺丝上
    • US20160144080A1
    • 2016-05-26
    • US15010583
    • 2016-01-29
    • AAP IMPLANTATE AG
    • Elvira DINGELDEINCyrille GASQUERESAmir ELIEZERMarco WOLFSTADTERLydia HEIMANN
    • A61L31/08C25D11/02A61L31/02C25D11/30
    • A61L31/086A61L31/022A61L31/148A61L2400/18A61L2420/02C25D11/024C25D11/026C25D11/30
    • The present invention relates generally to a bio-degradable implant based on magnesium having a reduced corrosion rate and to a method for the production of such an implant. It is a a method for treating a surface of a bio-degradable metallic implant comprising the following steps: providing a dispersed system comprising a colloid-dispersed apatite and adding an apatite powder to the dispersed system, subjecting an implant to the dispersed system such that a surface of the implant which is to be treated is immersed in the dispersed system wherein the implant comprises a magnesium based alloy, applying an AC voltage difference between the implant as a first electrode and a second electrode positioned in the dispersed system for generating a plasma electrolytic oxidation on the immersed surface of the implant so that the immersed surface is converted to an oxide film which is at least partially covered by apatites formed by the colloid-dispersed apatite and the apatite powder. The evolution of corrosion induced hydrogen gas evolution is decreased and osseointegration is improved.
    • 本发明一般涉及具有降低的腐蚀速率的基于镁的生物可降解植入物和用于生产这种植入物的方法。 它是用于处理生物可降解金属植入物的表面的方法,包括以下步骤:提供包含胶体分散的磷灰石并将磷灰石粉末加入到分散体系中的分散体系,使植入物经受分散体系,使得 将待处理的植入物的表面浸入分散体系中,其中植入物包括镁基合金,在作为第一电极的植入物和位于分散系统中的第二电极之间施加AC电压差以产生等离子体电解质 在植入物的浸渍表面上氧化,使得浸入的表面转化为至少部分被由胶体分散的磷灰石和磷灰石粉末形成的磷灰石覆盖的氧化膜。 腐蚀诱导氢气演化的演化减少,骨整体提高。
    • 25. 发明授权
    • Process for producing a coating on the surface of a substrate based on lightweight metals by plasma-electrolytic oxidation
    • 通过等离子体电解氧化在基于轻质金属的基板表面上生产涂层的方法
    • US08828215B2
    • 2014-09-09
    • US13438418
    • 2012-04-03
    • Carsten BlawertDaniel HocheYuanding HuangJun Liang
    • Carsten BlawertDaniel HocheYuanding HuangJun Liang
    • C25D11/00C25D9/00C25D15/00C25D11/02C25D11/34C25D11/30C25D11/06
    • C25D11/026C25D11/06C25D11/30C25D11/34C25D15/00
    • The present invention relates to a process for producing a coating on the surface of a substrate by plasma-electrolytic oxidation. Improved corrosion protection for lightweight metals, in particular for magnesium or magnesium alloys, is achieved by the process. Furthermore, biocompatible protective layers can also be produced on these materials, with the option of controlling degradation of the substrate. The layers are amorphous. They are produced by plasma-electrolytic oxidation in which the substrate is dipped as electrode together with a counterelectrode into an electrolyte liquid and a sufficient electric potential for generating spark discharges at the surface of the substrate is applied, wherein the electrolyte comprises clay particles dispersed therein. Substrates can therefore be any machine components, automobile components, railroad components, aircraft components, ships' components, etc., or bioimplants such as bone replacement materials or medical bone screws made of a lightweight metal such as magnesium or a magnesium alloy.
    • 本发明涉及通过等离子体电解氧化在基板的表面上制造涂层的方法。 通过该过程可以实现轻金属,特别是镁或镁合金的改进的防腐蚀保护。 此外,还可以在这些材料上产生生物相容的保护层,并且可以选择控制底物的降解。 这些层是无定形的。 它们是通过等离子体 - 电解氧化制备的,其中将基底作为电极与反电极一起浸入电解质液体中,并且施加足够的电位以在基底表面产生火花放电,其中电解质包括分散在其中的粘土颗粒 。 因此,底物可以是任何机械部件,汽车部件,铁路部件,飞机部件,船舶部件等,或诸如骨替代材料或由诸如镁或镁合金的轻质金属制成的医用骨螺钉的生物体。
    • 30. 发明授权
    • Two-step chemical/electrochemical process for coating magnesium alloys
    • 镁合金涂层的两步化学/电化学工艺
    • US5240589A
    • 1993-08-31
    • US918946
    • 1992-07-22
    • Duane E. BartakBrian E. LemieuxEarl R. Woolsey
    • Duane E. BartakBrian E. LemieuxEarl R. Woolsey
    • C25D11/30
    • C25D11/30
    • A two-step process for the coating of magnesium and its alloys is disclosed. The first step comprises immersing the magnesium workpiece in an aqueous solution comprising about 0.2 to 5 molar ammonium fluoride having a pH of about 5 to 8 and a temperature of about 40.degree. to 100.degree. C. The second step is an electrochemical treatment of the pretreated article in an aqueous electrolytic solution having a pH of at least about 12.5 and which solution comprises about 2 to 12 g/L of a aqueous soluble hydroxide, about 2 to 15 g/L of a fluoride-containing composition selected from the group consisting of fluorides and fluorosilicates, and about 5 to 30 g/L of a silicate. This process results in a superior coating which has increased abrasion and corrosion resistance.
    • 公开了一种用于涂覆镁及其合金的两步法。 第一步包括将镁工件浸入包含约0.2至5摩尔氟化铵的水溶液中,pH约为5-8,温度约为40至100℃。第二步是将预处理过的 在pH为至少约12.5的电解水溶液中制备该溶液,该溶液包含约2至12g / L水溶性氢氧化物,约2至15g / L的含氟化合物组合物,其选自 氟化物和氟硅酸盐,以及约5至30g / L的硅酸盐。 该方法产生了优异的涂层,其具有增加的耐磨性和耐腐蚀性。