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    • 22. 发明授权
    • Solvent-free, low-monomer or monomer-free polymerizable hot melt
composition
    • 无溶剂,低单体或单体无机聚合物熔体组合物
    • US5070121A
    • 1991-12-03
    • US343945
    • 1989-04-25
    • Rudolf HinterwaldnerGeorg Bolte
    • Rudolf HinterwaldnerGeorg Bolte
    • C09D4/00C08F290/02C08F299/02C08F299/04C08L67/07C09D5/08C09D157/04C09D157/10
    • C09D157/04C08F290/02C08F299/022C08F299/0478C08L67/07C09D157/10
    • The invention concerns a solvent-free, polymerizing hotmelt substance free of, or low in monomers, for corrosion- and/or abrasion proofing and/or forming a protective film with barrier properties on a real substrates and molded bodies made of metal, plastic, cellulose materials and/or inorganic materials, in particular for wrapping purposes, and consisting of(a) one or more polymerizing polymers containing hydroxyls with an average molecular weight (M.sub.w) between 1,000 and 500,000 and with a glass transition temperature (T.sub.g).gtoreq.20.degree. C., and/or(b) one or more polymerizing, linear, unbranched and/or unbranched polyesters and/or their copolymers with an average molecular weight (M.sub.w) between 900 and 50,000 and with a glass transition temperature (T.sub.g).gtoreq.-50.degree. C., and/or(c) a polymerizing oligomer bearing ethylene-unsaturated groups of acryl-, methacryl-, ether-, ester-, urethane-, amide-, imide-, epoxy-, siloxane-, phenol-, novolak- and/or mercapto-compounds with an average molecular weight (M.sub.w) between 400 and 10,000, and(d) where called further known additives, which is characterized by containing such components (a), (b) and/or (c) which were functionalized with one or more dimeric and/or oligomeric acrylic acid(s) of the general formula ##STR1## wherein R.dbd.H, --CN, halogen and/or an alkyl group with 1 to 4 C atoms, and m is a number between 1 and 5, and it further concerns a process for the preparation of said substance.
    • 本发明涉及一种无溶剂,聚合的热熔体物质,不含或不含单体,用于腐蚀和/或耐磨损和/或形成具有阻挡性能的保护膜,在真实的基材和由金属,塑料, 纤维素材料和/或无机材料,特别是用于包装目的,并由以下组成:(a)一种或多种含有平均分子量(&上和下限)的羟基的聚合聚合物,其平均分子量(& / = 20℃,和/或(b)一种或多种聚合,线性,非支链和/或无支链的聚酯和/或其共聚物,其平均分子量(&上和下限)为900至50,000,并具有玻璃化转变温度 (Tg)> / = -50℃,和/或(c)具有丙烯酰基,甲基丙烯酰基,醚 - ,酯 - ,氨基甲酸酯 - ,酰胺 - ,酰亚胺 - ,环氧 - ,硅氧烷,苯酚,酚醛清漆和/或巯基化合物 在400至10,000之间的损耗分子量(&上升&Mw),和(d)其中所谓的另外已知的添加剂,其特征在于含有这样的组分(a),(b)和/或(c),其被一个或多个二聚体 和/或通式为“IMAGE”的低聚丙烯酸,其中R = H,-CN,卤素和/或具有1至4个C原子的烷基,m为1至5之间的数,并且其 还涉及制备所述物质的方法。