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    • 22. 发明申请
    • Dispersant Comprising Copolymer Mixture
    • 分散剂包含共聚物混合物
    • US20120041104A1
    • 2012-02-16
    • US13133043
    • 2009-11-25
    • Klaus LorenzMario VierleBarbara WimmerPetra WagnerChristian Schôlz
    • Klaus LorenzMario VierleBarbara WimmerPetra WagnerChristian Schôlz
    • C04B16/04C08L35/08C08L41/00C04B28/02C08L35/00C08L33/02C08L37/00C08J3/07C08L39/04C08L43/02
    • C04B24/2647C04B24/2658C04B24/267C04B40/0039C04B2103/32C04B2103/408C08G65/2609C08L29/10C08L33/02C08L33/066C08L33/14C08L33/26C08L35/08C08L43/02C08L71/02C08L2205/02C08L2666/04C08L2666/22
    • The invention relates to a polymer composition containing 3 to 95% by weight of a copolymer H and 3 to 95% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymers H and K having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymers H and K varying in each case in such a way that the corresponding frequency distribution diagrams, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted in each case along the abscissae and the respectively associated frequencies for the copolymers H or K are plotted in each case along the ordinates, contain in each case at least 2 maxima whose abscissa values differ in each case by more than 7 ether oxygen atoms from one another, the frequency distribution diagrams of the copolymers H and K differing from one another in that the abscissa value of at least one maximum of the copolymer H differs in each case by more than 5 ether oxygen atoms from the abscissa values of all maxima of the copolymer K and/or that the arithmetic means of the ether oxygen atoms of the polyether macromonomer structural units of the copolymers H and K differ from one another by more than 5 ether oxygen atoms.
    • 本发明涉及含有3〜95重量%共聚物H和3〜95重量%共聚物K的聚合物组合物,共聚物H和K各自具有聚醚大分子单体结构单元和酸单体结构单元,其存在 在共聚物H和K中的摩尔比为1:20至1:1的共聚物中,共聚物H的全部结构单元的至少20摩尔%和共聚物K的所有结构单元的至少25摩尔% 在各种情况下以酸单体结构单元的形式存在,共聚物H和K的聚醚大分子单体结构单元具有侧链,每种情况下含有至少5个醚氧原子,每个侧链的醚氧原子数 共聚物H和K的聚醚大分子单体结构单元在每种情况下变化,使得相应的频率分布图,其中聚醚大分子单体结构单元每侧链的醚氧原子数为pl 在每个情况下沿着横坐标分别表示,并且在每种情况下沿着纵坐标绘制共聚物H或K的分别相关联的频率,每种情况下包含至少2个最大值,其横坐标值在每种情况下不同于7个以上的醚氧原子 另一方面,共聚物H和K的频率分布图彼此不同,因为共聚物H的至少一个最大值的横坐标值在每种情况下都不同于5个以上的醚氧原子,从所有最大值的横坐标值 共聚物K和/或共聚物H和K的聚醚大分子单体结构单元的醚氧原子的算术手段彼此间隔超过5个醚氧原子。
    • 29. 发明授权
    • Two-component chemical fastening systems
    • 双组分化学紧固系统
    • US07166670B2
    • 2007-01-23
    • US10451103
    • 2001-12-19
    • Jan H UddingAgnes E WoltersHeinz WilhelmArmin PfeilThomas BürgelLutz Sager
    • Jan H UddingAgnes E WoltersHeinz WilhelmArmin PfeilThomas BürgelLutz Sager
    • C08L35/08
    • C08G18/672C08F283/00C08F283/01C08F290/06C08G18/6715
    • The invention relates to two-component chemical fastening systems, the A-component containing an unsaturated polyester and a reactive diluent, and the B-component containing a peroxide and an extender, wherein the extender is either a monomeric component according to formula 1 (A—CH═CH—O)n—R   (formula 1) or a resinous compound comprising, in a covalently built-in manner, a component having vinyl ether group(s), and the content of the peroxide in the B-component is from 0.5 to 99 wt. %. In the formula A, R and n are specified as hydrogen or C1-3 alkyl; C1-20 (hetero)-aliphatic with hydroxyl or amino groups, or poly(C2 or 3)glycol with 2–120 glycol units; and 1 to 4, respectively. The resinous compounds with built-in vinyl ether group(s) (0.5 to 50 wt. %, calculated as indicated) are obtained by reaction of a mixture of appropriate amounts of: a) a first compound (HVE) containing at least one hydroxyl group and at least one vinyl ether group, and b) a second compound (D/HIC), being an isocyanate; and c) a third compound (G/P/HP) from (1) C2-6 glycols, (2) C5-20 polyols having 2–5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1–5 free hydroxyl groups and 2–50 monomeric units, or mixtures thereof. The invention also relates to methods for preparing (the B-component) of such two-component chemical fastening systems, as well as to use of the systems for chemical fastening.
    • 本发明涉及双组分化学紧固系统,含有不饱和聚酯和反应性稀释剂的A组分和含有过氧化物和增量剂的B组分,其中增量剂是根据式1的单体组分。 (A-CH-CH-O)n(式1)<?在线公式描述=“In-line formula”end =“lead”? 或者含有乙烯基醚基的成分,B成分中的过氧化物的含量以共价构成的方式构成的树脂状化合物 为0.5〜99wt。 %。 在式A中,R和n被指定为氢或C 1-3烷基; 具有羟基或氨基的C 1-20(杂) - 脂族基或具有2-120个二醇单元的聚(C 2或3)二醇; 和1至4。 通过将适当量的混合物反应获得含有内置乙烯基醚基团的树脂化合物(0.5至50重量%,如所示计算):a)含有至少一个羟基的第一化合物(HVE) 基团和至少一个乙烯基醚基团,和b)第二化合物(D / HIC),其为异氰酸酯; 和c)来自(1)C 2-6二醇的第三化合物(G / P / HP),(2)具有2-5个羟基的C 5-20-20多元醇 基团和(3)羟基封端的聚酯化合物,不是醇酸树脂,具有1-5个游离羟基和2-50个单体单元,或其混合物。 本发明还涉及这种双组分化学紧固系统的制备(B组分)的方法以及用于化学固定的系统。