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21. 发明授权

US09000081B2 Organic-inorganic composite, molded product, and optical element 有权
标题翻译：有机 - 无机复合材料，模制产品和光学元件
公开(公告)号：US09000081B2
公开(公告)日：2015-04-07
申请号：US13822251
申请日：2011-09-01
申请人： Takahiro Kojima , Katsumoto Hosokawa
发明人： Takahiro Kojima , Katsumoto Hosokawa
IPC分类号： C08K3/22 , G02B1/04 , C08G64/06 , C08G64/32
CPC分类号： G02B1/041 , C08G64/06 , C08G64/326 , C08K3/22 , G02B1/04 , C08L69/00
摘要： There are provided an organic-inorganic composite having a high refractive index and a low Abbe number in which metal oxide particles of at least one type is added to a polymer containing a repeating unit having the general formula (1) described in Claim 1, and a molded product and an optical element made of the organic-inorganic composite.In the general formula (1), R1 and R2 independently denote a hydrogen atom or an alkyl group having 1 or more and 6 or less carbon atoms, and Q denotes an oxyethylene group, a thioethylene group, or a single bond.
摘要翻译：提供了一种具有高折射率和低阿贝数的有机 - 无机复合材料，其中至少一种类型的金属氧化物颗粒被加入到含有权利要求1所述的通式（1）的重复单元的聚合物中，和模制品和由有机 - 无机复合材料制成的光学元件。在通式（1）中，R 1和R 2分别表示氢原子或碳原子数1以上且6以下的烷基，Q表示氧乙烯基，硫代亚乙基或单键。

22. 发明申请

US20140228537A1 METHOD FOR ACTIVATING DOUBLE METAL CYANIDE CATALYSTS FOR PRODUCING POLYETHER POLYOLS 有权
标题翻译：用于生产聚醚多元醇的双金属氰化物催化剂的活化方法
公开(公告)号：US20140228537A1
公开(公告)日：2014-08-14
申请号：US14232015
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G64/32
CPC分类号： C08G64/323 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts and to a process for the preparation of polyethercarbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) (α1) the DMC catalyst and one or more H-functional starter compounds are placed in a reactor, (α2) an inert gas, an inert gas/carbon dioxide mixture or carbon dioxide is passed through the reactor at a temperature of 50 to 200° C. and at the same time a reduced pressure (absolute) of 10 mbar to 800 mbar is established in the reactor by removal of the inert gas or carbon dioxide, (β) under an atmosphere of inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, alkylene oxide is added to the mixture from step (α) at temperatures of 50 to 200° C., and (γ) one or more alkylene oxides and carbon dioxide are metered into the mixture resulting from step (β).
摘要翻译：本发明涉及一种活化双金属氰化物（DMC）催化剂的方法，以及一种由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳在存在下制备聚醚碳酸酯多元醇的方法一种双金属氰化物催化剂，其特征在于将（α）（α1）DMC催化剂和一种或多种H官能起始化合物置于反应器中，（α2）惰性气体，惰性气体/二氧化碳混合物或二氧化碳在50至200℃的温度下通过反应器，同时通过除去惰性气体或二氧化碳，在反应器中建立10毫巴至800毫巴的减压（绝对）（绝对）。）在惰性气体/二氧化碳混合物的气氛下或在纯二氧化碳气氛下，在步骤（α）的混合物中，在50〜200℃的温度下加入环氧烷，（γ）一种或多种环氧烷烃并将二氧化碳计量加入由（步骤（bgr））产生的混合物。

23. 发明授权

US07977501B2 Polyether carbonate polyols made via double metal cyanide (DMC) catalysis 有权
标题翻译：通过双金属氰化物（DMC）催化制备的聚醚碳酸酯多元醇
公开(公告)号：US07977501B2
公开(公告)日：2011-07-12
申请号：US11491680
申请日：2006-07-24
申请人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
发明人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
IPC分类号： C07C69/96 , C08G64/02 , C08G64/32
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译：本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。％至约0.2wt。％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。％至约40wt。％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。

24. 发明授权

US5795952A Two-stage process for the preparation of polycarbonate copolyether diols 失效
标题翻译：用于制备聚碳酸酯共聚醚二醇的两阶段方法
公开(公告)号：US5795952A
公开(公告)日：1998-08-18
申请号：US818939
申请日：1997-03-17
申请人： Alberto Greco
发明人： Alberto Greco
IPC分类号： B01J23/02 , C07B61/00 , C07C68/06 , C07C69/96 , C08G18/44 , C08G64/18 , C08G64/30 , C08G64/32 , C08G64/00
CPC分类号： C08G64/305 , C08G18/44 , C08G64/183
摘要： A process for the preparation of polycarbonate copolyether diols comprising two successive reaction stages wherein in the first stage the precursor, bisdimethylcarbonate of polyether diols is synthesized by reacting, in a reactor equipped with a distillation column, one or more polyetherglycols with dimethyl carbonate, in the presence of a basic catalyst selected from the group consisting of an oxide, a hydroxide, a carbonate and an alcoholate of a metal belonging to the group of alkaline or earth-alkaline metals and in the second stage, the precursor, after being freed from the catalyst and excess dimethylcarbonate, is converted to polycarbonate copolyether diols by transesterification reaction with polyetherglycols in the presence of a solvent and an organometallic catalyst selected from compounds of tin, lead, titanium, zirconium and antimonium, said polycarbonate polyether diols having utility as additives in the field of polyurethane end-products, thermoelastomers, paints and adhesives.
摘要翻译：一种制备聚碳酸酯共聚醚二醇的方法，包括两个连续的反应阶段，其中在第一阶段中，聚醚二醇的前体，双二甲基碳酸酯通过在装有蒸馏塔的反应器中与一种或多种聚醚二醇与碳酸二甲酯反应合成，存在选自属于碱金属或碱土金属组的金属的氧化物，氢氧化物，碳酸盐和醇化物的碱性催化剂，并且在第二阶段中，所述前体在从催化剂和过量的二甲基碳酸酯通过在溶剂和选自锡，铅，钛，锆和锑的化合物的有机金属催化剂的存在下与聚醚二醇进行酯交换反应而转化为聚碳酸酯共聚醚二醇，所述聚碳酸酯聚醚二醇可用作添加剂聚氨酯最终产品领域，热弹性体，涂料和粘合剂活塞

25. 发明授权

US5344934A Preparation of urethane and caronate products 失效
标题翻译：氨基甲酸酯和加成产物的制备
公开(公告)号：US5344934A
公开(公告)日：1994-09-06
申请号：US976633
申请日：1992-11-16
申请人： William D. McGhee , Dennis P. Riley , John J. Talley , Barry L. Parnas
发明人： William D. McGhee , Dennis P. Riley , John J. Talley , Barry L. Parnas
IPC分类号： C07C68/04 , C07C69/96 , C07C269/04 , C07C271/06 , C07C271/12 , C07C271/16 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/38 , C07C271/42 , C07D295/20 , C08G64/32 , C08G71/04 , C07D211/08
CPC分类号： C07C269/04 , C07C68/04 , C08G64/323 , C08G71/04
摘要： The present invention provides a process for preparing urethanes and carbonates from an amine or an alcohol, carbon dioxide and a hydrocarbyl halide. The amine or alcohol is reacted with carbon dioxide in a suitable solvent system and in the presence of an amidine or guanidine base, to form the ammonium carbamate or carbonate salt which is then reacted in a polar aprotic solvent with a hydrocarbyl halide. Polymer products can also be prepared utilizing this process or utilizing the resulting urethanes and carbonates under standard polymerization conditions.
摘要翻译：本发明提供了由胺或醇，二氧化碳和烃基卤化物制备氨基甲酸酯和碳酸酯的方法。胺或醇在合适的溶剂体系中和在脒或胍碱的存在下与二氧化碳反应，形成氨基甲酸铵或碳酸盐，然后在极性非质子溶剂中与烃基卤化物反应。也可以使用该方法制备聚合物产物，或者在标准聚合条件下利用所得的聚氨酯和碳酸酯。

26. 发明授权

US11634539B2 Polycarbonate block copolymers and methods thereof 有权
公开(公告)号：US11634539B2
公开(公告)日：2023-04-25
申请号：US16580705
申请日：2019-09-24
申请人： Saudi Aramco Technologies Company
发明人： Scott D. Allen , Dibyendu Debnath
IPC分类号： C08G64/18 , C08G64/32 , C08G64/34 , B01J31/14 , B01J31/18 , C08G64/30
摘要： The present disclosure relates to block copolymers comprising, and methods of making thereof, a polycarbonate chain linked to a hydrophilic polymer. Such block copolymers may have the formula B-A-B, where A is a polycarbonate or polyethercarbonate chain and B is a polyether. Provided methods are useful in reducing the amount of waste generated from the synthesis of polycarbonates and provide improved thermal stability and high primary hydroxyl content. Provided block copolymers also have utility as additives in enhanced oil recovery methods, and foam polymer applications.

27. 发明授权

US10800880B2 Use of additives to fine-tune the composition of carbonate units in a polymer formed by copolymerization of CO2 with epoxide: application to the synthesis of polycarbonate-based block copolymers and of telechelics 有权
公开(公告)号：US10800880B2
公开(公告)日：2020-10-13
申请号：US16563269
申请日：2019-09-06
申请人： King Abdullah University of Science and Technology
发明人： Xiaoshuang Feng , Dongyue Zhang , Yves Gnanou , Nikolaos Hadjichristidis
IPC分类号： C08G64/34 , C08G64/32 , C08G81/00 , C08K5/057 , C08K5/19 , C08K5/53 , C08K5/5399
摘要： Embodiments of the present disclosure describe a method of making a polycarbonate, comprising contacting one or more cyclic monomers and carbon dioxide in the presence of one or more of a Lewis acid catalyst, an initiator, and an ionic liquid; and agitating, sufficient to copolymerize the one or more cyclic monomers and carbon dioxide to create a polycarbonate. Embodiments of the present disclosure further describe a method of controlling a polymer composition, comprising contacting one or more cyclic monomers and carbon dioxide; adjusting an amount of one or more of a Lewis acid catalyst, an ionic liquid, and an initiator in the presence of the one or more cyclic monomers and carbon dioxide, sufficient to selectively modify a resulting polycarbonate; and agitating, sufficient to copolymerize the one or more cyclic monomers and carbon dioxide to create the polycarbonate.

28. 发明授权

US10450412B2 Use of additives to fine-tune the composition of carbonate units in a polymer formed by copolymerization of CO2 with epdxide: application to the synthesis of polycarbonate-based block copolymers and of telechelics 有权
公开(公告)号：US10450412B2
公开(公告)日：2019-10-22
申请号：US15571631
申请日：2016-06-15
申请人： King Abdullah University of Science and Technology
发明人： Xiaoshuang Feng , Dongyue Zhang , Yves Gnanou , Nikolaos Hadjichristidis
IPC分类号： C08G64/34 , C08G64/32 , C08G81/00 , C08K5/057 , C08K5/19 , C08K5/53 , C08K5/5399
摘要： Embodiments of the present disclosure describe a method of making a polycarbonate, comprising contacting one or more cyclic monomers and carbon dioxide in the presence of one or more of a Lewis acid catalyst, an initiator, and an ionic liquid; and agitating, sufficient to copolymerize the one or more cyclic monomers and carbon dioxide to create a polycarbonate. Embodiments of the present disclosure further describe a method of controlling a polymer composition, comprising contacting one or more cyclic monomers and carbon dioxide; adjusting an amount of one or more of a Lewis acid catalyst, an ionic liquid, and an initiator in the presence of the one or more cyclic monomers and carbon dioxide, sufficient to selectively modify a resulting polycarbonate; and agitating, sufficient to copolymerize the one or more cyclic monomers and carbon dioxide to create the polycarbonate.

29. 发明申请

US20180186930A1 USE OF ADDITIVES TO FINE-TUNE THE COMPOSITION OF CARBONATE UNITS IN A POLYMER FORMED BY COPOLYMERIZATION OF CO2 WITH EPOXIDE: APPLICATION TO THE SYNTHESIS OF POLYCARBONATE-BASED BLOCK COPOLYMERS AND OF TELECHELICS 审中-公开
公开(公告)号：US20180186930A1
公开(公告)日：2018-07-05
申请号：US15571631
申请日：2016-06-15
申请人： King Abdullah University of Science and Technology
发明人： Xiaoshuang FENG , Dongyue ZHANG , Yves GNANOU , Nikolaos HADJICHRISTIDIS
IPC分类号： C08G64/34 , C08G64/32
摘要： Embodiments of the present disclosure describe a method of making a polycarbonate, comprising contacting one or more cyclic monomers and carbon dioxide in the presence of one or more of a Lewis acid catalyst, an initiator, and an ionic liquid; and agitating, sufficient to copolymerize the one or more cyclic monomers and carbon dioxide to create a polycarbonate. Embodiments of the present disclosure further describe a method of controlling a polymer composition, comprising contacting one or more cyclic monomers and carbon dioxide; adjusting an amount of one or more of a Lewis acid catalyst, an ionic liquid, and an initiator in the presence of the one or more cyclic monomers and carbon dioxide, sufficient to selectively modify a resulting polycarbonate; and agitating, sufficient to copolymerize the one or more cyclic monomers and carbon dioxide to create the polycarbonate.

30. 发明申请

US20180118884A1 USE OF CO2 FOR THE SYNTHESIS OF CYCLIC GLYCOCARBONATES AND LINEAR POLYGLYCOCARBONATES BY POLYCONDENSATION FROM GLYCANS 审中-公开
公开(公告)号：US20180118884A1
公开(公告)日：2018-05-03
申请号：US15566473
申请日：2016-04-13
申请人： King Abdullah University of Science and Technology
发明人： Yves GNANOU , Debasis PATI , Xiaoshuang FENG , Nikolaos HADJICHRISTIDIS
IPC分类号： C08G64/32 , C08G64/02 , C07H1/00 , C07H13/12
CPC分类号： C08G64/323 , C07H1/00 , C07H13/12 , C08G64/0208
摘要： Provided herein are methods for synthesizing cyclic carbonates, glycocarbonates, and polyglycocarbonates by reacting polyol glycans with carbon dioxide. Synthesis can include selective polycondensation of polyol glycan hydroxyl moieties.

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