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21. 发明授权

US6117277A Process for the distillation of alcohols 失效
标题翻译：蒸馏醇的方法
公开(公告)号：US6117277A
公开(公告)日：2000-09-12
申请号：US894601
申请日：1997-08-22
申请人： Wolfgang Zgorzelski , Peter Lappe , Kurt Schalapski , Wilhelm Gick
发明人： Wolfgang Zgorzelski , Peter Lappe , Kurt Schalapski , Wilhelm Gick
IPC分类号： C07C29/80 , C07C29/94 , C07C31/02 , B01D3/34 , C07C27/28
CPC分类号： C07C29/80
摘要： The invention relates to a process for the purification of C.sub.3 -C.sub.10 -alcohols by distillation, by distilling the alcohols at 150 to 200.degree. C. in the presence of 10 to 1000 ppm of alkali metal hydroxide.
摘要翻译： PCT No.PCT / EP96 / 00633 Sec。 371日期1997年8月22日 102（e）日期1997年8月22日PCT 1996年2月14日PCT PCT。公开号WO96 / 26173 日期：1996年8月29日本发明涉及通过蒸馏在10〜1000ppm碱金属氢氧化物存在下，在150〜200℃下蒸馏醇来纯化C 3 -C 10醇的方法。

22. 发明授权

US5998679A Methods for converting lower alkanes and alkanes to alcohols and diols 失效
标题翻译：将低级烷烃和烷烃转化为醇和二醇的方法
公开(公告)号：US5998679A
公开(公告)日：1999-12-07
申请号：US121768
申请日：1998-07-26
申请人： Jorge Miller
发明人： Jorge Miller
IPC分类号： C07C29/04 , C01B7/09 , C07C17/02 , C07C17/10 , C07C29/00 , C07C29/09 , C07C29/124 , C07C31/02 , C07C31/04 , C07C31/20 , C07C29/62
CPC分类号： C07C29/095 , C01B7/096 , C07C17/02 , C07C17/10 , Y02P20/582
摘要： The present invention is directed to methods for converting lower alkanes and alkenes to the corresponding lower alkanols and diols. In the methods of the present invention, a gaseous halogen, preferably bromine, is produced by decomposing a metal halide in a liquid having a melting point below and a boiling point above the decomposition temperature of the metal halide. The preferred liquid is molten, hydrated ferric chloride maintained at a temperature between about 37-280.degree. C. The lower alkane or alkene is halogenated in a gas phase reaction with the produced halogen. The alkyl halide or alkyl dihalide is contacted with a metal hydroxide, preferably an aqueous solution of ferric hydroxide, to regenerate the metal halide and produce the corresponding lower alkanol or diol. The present invention is particularly efficient for converting methane to methanol using ferric bromide to provide the halogen.
摘要翻译：本发明涉及将低级烷烃和烯烃转化成相应的低级链烷醇和二醇的方法。在本发明的方法中，通过在熔点低于和高于金属卤化物的分解温度的沸点的液体中分解金属卤化物来制备气态卤素，优选溴。优选的液体是熔融的，水合氯化铁保持在约37-280℃之间。低级烷烃或烯烃在与所生产的卤素的气相反应中被卤化。烷基卤化物或烷基二卤化物与金属氢氧化物，优选氢氧化铁水溶液接触，以再生金属卤化物并产生相应的低级链烷醇或二醇。本发明特别有效的是使用溴化铁将甲烷转化成甲醇以提供卤素。

23. 发明授权

US5856316A Mixture of higher primary aliphatic alcohols, its obtention from sugar cane wax and its pharmaceutical uses 失效
标题翻译：较高级脂族醇的混合物，其从甘蔗蜡中获得及其药物用途
公开(公告)号：US5856316A
公开(公告)日：1999-01-05
申请号：US771970
申请日：1996-12-23
申请人： Abilio Laguna Granja , Juan Magraner Hernandez , Daisy Carbajal Quintana , Lourdes Arruzazabala Valmana , Rosa Mas Ferreiro , Milagros Garcia Mesa
发明人： Abilio Laguna Granja , Juan Magraner Hernandez , Daisy Carbajal Quintana , Lourdes Arruzazabala Valmana , Rosa Mas Ferreiro , Milagros Garcia Mesa
IPC分类号： A61K9/16 , A61K9/20 , A61K9/48 , A61K31/045 , A61K31/405 , A61K31/60 , A61K36/899 , A61K47/02 , A61K47/12 , A61K47/26 , A61K47/36 , A61K47/38 , A61P1/04 , A61P3/06 , A61P7/02 , A61P9/08 , A61P9/10 , C07C29/74 , C07C29/76 , C07C29/78 , C07C29/88 , C07C31/02 , C07C31/125
CPC分类号： C07C29/88 , A61K31/045 , A61K31/60 , C07C29/76 , C07C31/02 , C07C31/125
摘要： A mixture of higher primary aliphatic alcohols of 22 to 38 carbon atoms can be obtained by saponifying and extracting steps with organic solvents from sugar cane wax. The mixture which contains tetracosanol, hexacosanol, heptacosanol, octacosanol, nonacosanol, triacontanol, dotriacontanol and tetratriacontanol can be used for the treatment of hypercholesterolemia, and atherosclerotic complications as platelet hyperaggregabiulity, ischemia and thrombosis, and prevents drug induced gastric ulcer and improves male sexual activity.
摘要翻译：通过用甘蔗蜡的有机溶剂皂化和萃取步骤可获得22至38个碳原子的高级伯脂肪醇的混合物。含有二十四烷醇，二十六烷醇，二十七烷醇，二十八烷醇，壬三醇，三十烷醇，三十烷醇和四十六烷醇的混合物可用于治疗高胆固醇血症和动脉粥样硬化并发症，如血小板超聚集，缺血和血栓形成，并防止药物诱导的胃溃疡，改善男性性活动。

24. 发明授权

US5734075A Process for recovery of the light noble products present in the distillation residues from the processes for the manufacture of acrylic acid and of its esters 失效
标题翻译：从制备丙烯酸及其酯的方法中回收存在于蒸馏残余物中的轻度贵重产物的方法
公开(公告)号：US5734075A
公开(公告)日：1998-03-31
申请号：US570773
申请日：1995-12-12
申请人： Michel Fauconet , Norbert Richard , Patrick Delafin
发明人： Michel Fauconet , Norbert Richard , Patrick Delafin
IPC分类号： C07C27/00 , C07C27/28 , C07C29/80 , C07C31/02 , C07C51/44 , C07C51/487 , C07C57/04 , C07C57/055 , C07C57/07 , C07C67/08 , C07C67/327 , C07C67/54 , C07C67/60 , C07C69/54 , C07C67/48 , C07C51/42
CPC分类号： C07C51/487 , C07C51/44 , C07C67/327 , C07C67/60
摘要： To recover these noble products consisting of acrylic acid monomer, acrylic ester monomers and alcohols, a thermal cracking is performed in the absence of catalyst on a mixture of heavy distillation residues originating, on the one hand, from the manufacture of acrylic acid and, on the other hand, from the manufacture of the esters, the light fraction originating from the dissociation reactions is continuously vaporized during the cracking operation and this light fraction is distilled in order to recover, after condensation, the required products. The process according to the invention may consist in conducting the cracking of the mixture of heavy residues, optionally preheated, in a reactor (R1); feeding a distillation column (C1) with the light cracking products; recovering the required mixture of light noble products at the head of column (C1); recycling the flow recovered at the foot of column (C1) into the reactor (R1); recovering the heavy residue from the reactor (R1) and sending it to a removal treatment, if appropriate after having diluted it with a part of the flow recovered at the foot of column (C1), the remainder of the said flow being recycled into the reactor (R1). Figure to be published: FIG. 1
摘要翻译：为了回收由丙烯酸单体，丙烯酸酯单体和醇组成的这些贵重产物，在不存在催化剂的情况下，在重馏分残余物的混合物上进行热裂解，一方面源于丙烯酸的制备，另一方面，从酯的制造出发，解离反应中的轻馏分在裂解操作期间被连续蒸发，并将该轻馏分蒸馏以在冷凝后回收所需产物。根据本发明的方法可以包括在反应器（R1）中进行任选预热的重残余物混合物的裂化; 向轻馏分产物中加入蒸馏塔（C1）; 在色谱柱（C1）的头部回收所需的淡色产物混合物; 将在柱（C1）的脚处回收的流回收到反应器（R1）中; 从反应器（R1）中回收重质残余物，并将其送入去除处理（如果适用），将其用塔（C1）底部回收的一部分流体稀释后，将其余的所述流回收到反应器（R1）。图将被公布：

25. 发明授权

US5623090A Method for production of alcohol, ketone, and epoxide by oxidation of hydrocarbon 失效
标题翻译：通过烃的氧化生产醇，酮和环氧化物的方法
公开(公告)号：US5623090A
公开(公告)日：1997-04-22
申请号：US547812
申请日：1995-10-25
申请人： Masatake Haruta , Susumu Tsubota , Toshio Hayashi
发明人： Masatake Haruta , Susumu Tsubota , Toshio Hayashi
IPC分类号： B01J23/52 , C07B61/00 , C07C27/12 , C07C27/14 , C07C29/50 , C07C31/02 , C07C45/33 , C07C49/04 , C07D301/04 , C07D301/10
CPC分类号： C07C29/50 , B01J23/52 , C07C45/33 , C07D301/04 , C07D301/10
摘要： An alcohol or a ketone or a mixture thereof is produced from a saturated hydrocarbon or an epoxide is produced from an unsaturated hydrocarbon by passing a mixture comprising of molecular hydrogen, the saturated or unsaturated hydrocarbon and oxygen through a bed of a catalyst comprising a titanium dioxide carrier and ultrafine gold particles deposited on the carrier, thereby effecting the oxidation of the hydrocarbon with oxygen.
摘要翻译：由饱和烃产生醇或酮或其混合物，或者由不饱和烃生成环氧化物，通过使包含分子氢，饱和或不饱和烃和氧的混合物通过包含二氧化钛的催化剂床载体和超细金颗粒沉积在载体上，从而用氧气氧化烃。

26. 发明授权

US5409876A Process for oxidating paraffinic compounds with oxygen 失效
标题翻译：用氧氧化链烷烃化合物的方法
公开(公告)号：US5409876A
公开(公告)日：1995-04-25
申请号：US37344
申请日：1993-03-25
申请人： Mario G. Clerici , Giuseppe Bellussi
发明人： Mario G. Clerici , Giuseppe Bellussi
IPC分类号： B01J29/04 , B01J29/89 , C07B61/00 , C07C27/12 , C07C29/50 , C07C31/02 , C07C31/125 , C07C45/28 , C07C45/33 , C07C49/04 , B01J21/06 , B01J23/38
CPC分类号： C07C45/33 , B01J29/89 , C07C29/50 , C07C45/28 , Y02P20/582
摘要： Process for oxidating paraffinic compounds into their corresponding alcoholic and/or ketonic derivatives, which process consists in causing said paraffins to react, at a temperature comprised within the range of from 0.degree. C. to 100.degree. C., preferably in an acidic medium, with a mixture of oxygen and hydrogen, in the presence of a catalyst on the basis of titanium-silicalite and of a noble metal and/or a derivative of such a metal.
摘要翻译：将链烷烃化合物氧化成其相应的醇和/或酮衍生物的方法，该方法包括在0℃至100℃范围内，优选在酸性介质中使所述链烷烃反应，在钛 - 硅沸石和贵金属和/或这种金属的衍生物的催化剂存在下，用氧和氢的混合物。

27. 发明授权

US5345011A New manganese catalyst for light alkane oxidation 失效
标题翻译：新型烷烃氧化锰催化剂
公开(公告)号：US5345011A
公开(公告)日：1994-09-06
申请号：US124087
申请日：1993-09-20
申请人： Vincent A. Durante , James E. Lyons , Darrell W. Walker , Bonita K. Marcus
发明人： Vincent A. Durante , James E. Lyons , Darrell W. Walker , Bonita K. Marcus
IPC分类号： B01J29/83 , B01J29/84 , C07B61/00 , C07C27/14 , C07C29/50 , C07C31/02 , C07C31/04 , C07C27/00 , C07C31/08
CPC分类号： C07C29/50 , B01J29/84 , C07C27/14 , Y02P20/52
摘要： Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.
摘要翻译：在结构骨架中含有锰的磷酸铝用于烷烃的氧化，例如甲烷气相氧化成甲醇。

28. 发明授权

US5334779A Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters 失效
标题翻译：催化剂组合物及其在羧酸酯氢化中的用途
公开(公告)号：US5334779A
公开(公告)日：1994-08-02
申请号：US69489
申请日：1993-06-01
申请人： Yeong-Jen Kuo
发明人： Yeong-Jen Kuo
IPC分类号： B01J23/80 , C07B61/00 , C07C29/141 , C07C29/145 , C07C29/149 , C07C31/02 , C07C31/18 , C07C31/27 , C07C29/14 , C07C27/04
CPC分类号： C07C29/149 , B01J23/80 , C07C29/141 , C07C29/145 , Y02P20/52
摘要： Disclosed are catalyst compositions comprised of the oxides of copper, zinc, and a third element selected from the group consisting of aluminum, magnesium, zirconium, and mixtures thereof, and the use of such catalyst compositions in the hydrogenation of carbonyl compounds such as carboxylate esters to obtain the alcohol corresponding to the acid residue of the ester.
摘要翻译：公开了由铜，锌的氧化物和选自铝，镁，锆及其混合物的第三元素组成的催化剂组合物，以及这些催化剂组合物在羰基化合物如羧酸酯的氢化中的用途以获得对应于酯的酸残基的醇。

29. 发明授权

US5157168A Process for the production of fatty alcohols 失效
标题翻译：生产脂肪醇的方法
公开(公告)号：US5157168A
公开(公告)日：1992-10-20
申请号：US721438
申请日：1991-08-12
申请人： Martyn Wilmott , George E. Harrison , John Scarlett , Michael A. Wood , Donald H. McKinley
发明人： Martyn Wilmott , George E. Harrison , John Scarlett , Michael A. Wood , Donald H. McKinley
IPC分类号： C07C29/149 , C07C29/80 , C07C31/02 , C07C31/125 , C07C67/03 , C07C67/08
CPC分类号： C07C29/177 , C07C29/149 , C07C67/03 , C07C67/08
摘要： An improved process for the production of fatty alcohols is provided. The fatty alcohols are produced by hydrogenation of lower alkyl esters, especially methyl esters, of fatty acids derived from natural triglycerides, under conditions which minimize formation of by-product alkanes and ethers. The hydrogenation is followed by refining of any resulting ester-containing hydrogenation product to produce a substantially ester free fatty alcohol.
摘要翻译： PCT No.PCT / GB90 / 00063 Sec。 371日期1991年8月12日 102（e）日期1991年8月12日PCT 1990年1月16日PCT PCT。出版物WO90 / 08121 日期为1990年7月26日。提供了用于生产脂肪醇的改进方法。在最小化副产物烷烃和醚的形成条件下，通过氢化衍生自天然甘油三酸酯的脂肪酸的低级烷基酯，特别是甲基酯来生产脂肪醇。氢化之后是任何所得含酯氢化产物的精制，以产生基本上无酯的脂肪醇。

30. 发明授权

US5120853A Process for producing optically active compounds 失效
标题翻译：生产光学活性化合物的方法
公开(公告)号：US5120853A
公开(公告)日：1992-06-09
申请号：US652607
申请日：1991-02-08
申请人： Yukio Yoneyoshi , Gohfu Suzukamo , Yoji Sakito
发明人： Yukio Yoneyoshi , Gohfu Suzukamo , Yoji Sakito
IPC分类号： B01J23/40 , B01J23/44 , B01J25/02 , B01J31/14 , C07B31/00 , C07B41/02 , C07B43/04 , C07B53/00 , C07B61/00 , C07C27/00 , C07C29/143 , C07C31/02 , C07C31/125 , C07C33/20 , C07C67/00 , C07C209/00 , C07C209/40 , C07C211/03 , C07C211/27 , C07C211/29 , C07C211/35 , C07C211/42 , C07C211/44 , C07C211/57 , C07C213/00 , C07C213/02 , C07C215/50 , C07C217/58 , C07C251/48 , C07D249/08 , C07D521/00 , C07F5/02
CPC分类号： C07D249/08 , C07C29/143 , C07D231/12 , C07D233/56 , C07B2200/07
摘要： The optically active benzylamine derivatives of the present invention are very useful for use as the asymmetric ligand of an asymmetric reducing agent. By using the optically active amine-boron complex prepared from the compound of the present invention, optically active products can be obtained in a specifically high optical yield. Moreover, the separation and recovery of the reaction products and asymmetric ligand can be easily achieved.

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