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    • 27. 发明授权
    • Branched chain olefinic alcohols, thiols, esters and ethers,
organoleptic uses thereof, processes for preparing same and
intermediates therefor
    • 支链烯烃,硫醇,酯和醚,其感官用途,制备方法及其中间体
    • US4399062A
    • 1983-08-16
    • US322841
    • 1981-11-19
    • Richard M. Boden
    • Richard M. Boden
    • A23L27/20A24B15/32C07C29/40C07C45/45C11B9/00C11D1/24C11D3/395A61K7/46
    • C11D3/3956A23L27/2026A24B15/32C07C29/40C07C45/455C11B9/0007C11D1/24
    • Described are compounds defined according to the structure: ##STR1## taken alone or in admixture wherein one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines are carbon-carbon single bonds; wherein R.sub.1 represents C.sub.1 -C.sub.4 alkyl; R.sub.2 represents C.sub.1 -C.sub.4 alkyl; Z represents oxygen or sulfur; R.sub.3 represents hydrogen, MgX, Li, C.sub.1 -C.sub.3 lower alkyl or C.sub.1 -C.sub.3 lower acyl; and wherein X represents chloro, bromo or iodo and uses thereof in augmenting or enhancing the aroma and/or taste of consumable materials such as perfume compositions, colognes, perfumed articles, e.g., solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions or dryer-added fabric softener articles, smoking tobaccos, chewing gums, chewing tobaccos, medicinal products or toothpastes. Also described are processes for preparing such compounds hereinafter described as branched chain olefinic alcohols, thiols, esters and ethers.
    • 描述的是根据以下结构定义的化合物:单独使用或混合物,其中虚线之一是碳 - 碳双键,另一个虚线中的每一个都是碳 - 碳单键; 其中R1表示C1-C4烷基; R2代表C1-C4烷基; Z表示氧或硫; R3表示氢,MgX,Li,C1-C3低级烷基或C1-C3低级酰基; 并且其中X表示氯,溴或碘,并且其用途用于增强或增强消耗材料的香气和/或味道,例如香料组合物,古龙水,加香制品,例如固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物 软化剂组合物或干燥剂添加的织物柔软剂制品,吸烟烟草,口香糖,咀嚼烟草,药用产品或牙膏。 还描述了制备这种化合物的方法,其在下文中描述为支链烯烃,硫醇,酯和醚。
    • 29. 发明授权
    • Flavoring with methyl substituted oxobicyclo-4,4,0-decane derivatives
    • 用甲基取代的氧代二环-4,4,0癸烷衍生物调理
    • US4339467A
    • 1982-07-13
    • US277130
    • 1981-06-25
    • Takao Yoshida
    • Takao Yoshida
    • C07C29/17C07C29/40C07C29/68C07C35/36C07C45/62C07C45/69C07C49/447C07C49/637C07F3/02C11B9/00A23L1/226
    • C11B9/0053C07C29/172C07C29/40C07C29/68C07C35/36C07C45/62C07C45/69C07C49/447C07C49/637C07F3/02C07C2102/28
    • Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein X represents the moieties: ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.8 and R.sub.9 represent hydrogen or methyl with the proviso that (i) at least three of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen and (ii) when the dashed line is a carbon-carbon single bond and X is: ##STR3## then one of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 is methyl and the other represents hydrogen; wherein R.sub.5 represents hydrogen, MgZ or Li; wherein Z represents chloro, bromo or iodo and wherein R.sub.6 represents hydrogen or methyl; and uses thereof as chemical reaction intermediates and/or for their organoleptic properties in augmenting or enhancing the aromas or tastes of perfumes, perfumed articles, foodstuffs, chewing gums, smoking tobaccos, toothpastes, medicinal products, chewing tobaccos and smoking tobacco articles, as well as processes for preparing same.
    • 描述的是具有通用结构的化合物:其中虚线表示碳 - 碳单键或碳 - 碳双键; 其中X表示部分:其中R 1,R 2,R 3,R 4,R 8和R 9表示氢或甲基,条件是(i)R 1,R 2,R 3和R 4中的至少3个表示氢,和(ii) 虚线是碳 - 碳单键,X是:其中R1,R2,R3或R4之一是甲基,另一个代表氢; 其中R5表示氢,MgZ或Li; 其中Z表示氯,溴或碘,并且其中R6表示氢或甲基; 以及其用作化学反应中间体和/或其感官特性以增强或增强香料,香料制品,食品,口香糖,吸烟烟草,牙膏,药用产品,咀嚼烟草和烟草制品的香味或味道,以及 作为制备方法。