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21. 发明授权

US4138298A Treatment of high-polymer materials 失效
标题翻译：高分子材料的处理
公开(公告)号：US4138298A
公开(公告)日：1979-02-06
申请号：US473303
申请日：1974-05-24
申请人： Wolfgang Bobeth , Adolf Heger , Helmar Passler , Hermann Roloff , Ellen Patitz , Adolf-Ernst Schwind , Erwin Zilinski
发明人： Wolfgang Bobeth , Adolf Heger , Helmar Passler , Hermann Roloff , Ellen Patitz , Adolf-Ernst Schwind , Erwin Zilinski
IPC分类号： D06M14/26 , C08J7/18 , C08J7/10
CPC分类号： D06M14/26 , Y10S8/12 , Y10S8/18
摘要： Two basic methods for texturizing or structurizing high-polymer materials are disclosed. One method resides in selectively irradiating a high-polymer material so as to form chemically active species in the material. The material is contacted with a treating medium which reacts with the chemically active species in such a manner as to cause shrinkage of the material. The texturizing or structurizing effects are due to the fact that the irradiated areas of the material will shrink to a different extent in dependence upon the concentration of the chemically active species and/or that the irradiated areas of the material will shrink to a different extent than the non-irradiated areas of the material.
摘要翻译：公开了用于使高分子材料进行组织化或结构化的两种基本方法。一种方法是选择性地照射高分子材料以便在材料中形成化学活性物质。该材料与处理介质接触，处理介质与化学活性物质反应，导致材料收缩。组织化或结构化效应是由于以下事实：材料的照射区域将根据化学活性物质的浓度而收缩到不同程度，和/或材料的照射区域将收缩到与材料的未照射区域。

22. 发明授权

US3022265A Compositions comprising graft copolymers of certain aminated alkenyl aromatic monomers on acrylonitrile polymer substrates and method of making 失效
标题翻译：组合物，其包含某些胺化烯基芳族单体在丙烯腈聚合物基材上的接枝共聚物及其制备方法
公开(公告)号：US3022265A
公开(公告)日：1962-02-20
申请号：US71193458
申请日：1958-01-29
申请人： DOW CHEMICAL CO
发明人： STANTON GEORGE W , TRAYLOR TEDDY G
IPC分类号： C08F265/08 , C08F283/02 , C08F283/04 , C08L77/00 , D06M14/10 , D06M14/14 , D06M14/26 , D06M14/28 , D06M14/32
CPC分类号： D06M14/10 , C08F220/34 , C08F265/08 , C08F283/02 , C08F283/04 , C10M2205/026 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/109 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10N2220/00 , C10N2220/02 , D06M14/14 , D06M14/26 , D06M14/28 , D06M14/32 , Y10S8/18 , Y10S8/927 , C08F226/06 , C08F228/00 , C08F212/14 , C08F220/38 , C08F220/54
摘要： Dye-receptive graft polymers comprise a polyester polymer substrate having graft polymerized thereto units of an ethylenically unsaturated monomer which confers dye affinity to the resulting product, e.g. (a) vinyl lactam monomers, particularly vinyl pyrrdidones; (b) sulphonated alkenyl aromatic monomers and alkali metal salts or esters thereof; (c) sulphonated olefines and alkali metal salts or esters thereof; (d) sulphonated esters of acrylic and methacrylic acids and alkali metal salts or esters thereof; (e) sulphonated N-substituted acrylamides and methacrylamides and alkali metal salts or esters thereof; (f) vinyl pyridine and lower alkyl derivatives thereof; (g) amino-substituted alkenyl aromatic monomers; (h) aminoethyl acrylate and methacrylate and N-methyl and -ethyl derivatives thereof; (i) alkenyl aromatic monomers ar-substituted by polyglycol ethers; (j) polyglycol esters of acrylic and methacrylic acids; and (k) N-vinyl-3-morpholinone. The grafting may be effected by impregnating the polyester with the monomer or a solution or dispersion thereof followed by polymerization of the monomer by means of a free radical catalyst or high energy irradiation, e.g. beta or gamma rays or the radiation from electron beam generators. The polyester substrate is preferably in shaped form, e.g. a filament. The examples describe the grafting on to a polyethylene terephthalate substrate (cloth) of N-vinyl pyrrolidone, a mixture of N-vinyl pyrrolidone and 2-sulphoethyl methacrylate, 2 -vinyl pyridine, N-vinyl-3-morpholinone and a polyglycol monoacrylate. The resulting products have good dye-receptivity. Reference has been directed by the Comptroller to Specification 805,513.

23. 发明授权

US3008918A Compositions comprising graft copolymers of certain sulfonated acrylate and acryloyl taurine type monomers on acrylonitrile polymer substrates 失效
标题翻译：组合物包括某些磺化丙烯酸酯和丙烯酰基牛磺酸型单体在丙烯腈聚合物基材上的接枝共聚物
公开(公告)号：US3008918A
公开(公告)日：1961-11-14
申请号：US71193258
申请日：1958-01-29
申请人： DOW CHEMICAL CO
发明人： STANTON GEORGE W , TRAYLOR TEDDY G
IPC分类号： C08F265/08 , C08F283/02 , C08F283/04 , C08L77/00 , D06M14/10 , D06M14/14 , D06M14/26 , D06M14/28 , D06M14/32
CPC分类号： D06M14/10 , C08F220/34 , C08F265/08 , C08F283/02 , C08F283/04 , C10M2205/026 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/109 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10N2220/00 , C10N2220/02 , D06M14/14 , D06M14/26 , D06M14/28 , D06M14/32 , Y10S8/18 , Y10S8/927 , C08F226/06 , C08F228/00 , C08F212/14 , C08F220/38 , C08F220/54
摘要： Dye-receptive graft polymers comprise a polyester polymer substrate having graft polymerized thereto units of an ethylenically unsaturated monomer which confers dye affinity to the resulting product, e.g. (a) vinyl lactam monomers, particularly vinyl pyrrdidones; (b) sulphonated alkenyl aromatic monomers and alkali metal salts or esters thereof; (c) sulphonated olefines and alkali metal salts or esters thereof; (d) sulphonated esters of acrylic and methacrylic acids and alkali metal salts or esters thereof; (e) sulphonated N-substituted acrylamides and methacrylamides and alkali metal salts or esters thereof; (f) vinyl pyridine and lower alkyl derivatives thereof; (g) amino-substituted alkenyl aromatic monomers; (h) aminoethyl acrylate and methacrylate and N-methyl and -ethyl derivatives thereof; (i) alkenyl aromatic monomers ar-substituted by polyglycol ethers; (j) polyglycol esters of acrylic and methacrylic acids; and (k) N-vinyl-3-morpholinone. The grafting may be effected by impregnating the polyester with the monomer or a solution or dispersion thereof followed by polymerization of the monomer by means of a free radical catalyst or high energy irradiation, e.g. beta or gamma rays or the radiation from electron beam generators. The polyester substrate is preferably in shaped form, e.g. a filament. The examples describe the grafting on to a polyethylene terephthalate substrate (cloth) of N-vinyl pyrrolidone, a mixture of N-vinyl pyrrolidone and 2-sulphoethyl methacrylate, 2 -vinyl pyridine, N-vinyl-3-morpholinone and a polyglycol monoacrylate. The resulting products have good dye-receptivity. Reference has been directed by the Comptroller to Specification 805,513.

24. 发明申请

US20160317696A1 A Process for Making a Hydrophilic Nonwoven Structure, a Nonwoven Structure Produced Thereby and an Article Containing the Nonwoven Structure 审中-公开
标题翻译：制造亲水性非织造织物的方法，由此生产的非织造结构和含有非织造结构的物品
公开(公告)号：US20160317696A1
公开(公告)日：2016-11-03
申请号：US15108310
申请日：2014-12-15
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： Rudolph J. Koopmans , Evren Aslan-Guerel , Gert J. Claasen
IPC分类号： A61L15/42 , D06M10/02 , A61L15/22 , A61F13/15 , A61F13/51
CPC分类号： A61L15/42 , A61F13/15658 , A61F13/15731 , A61F13/51 , A61F13/51121 , A61F2013/51023 , A61F2013/51069 , A61L15/225 , D04H1/4291 , D06M10/02 , D06M10/025 , D06M14/26 , D06M14/28
摘要： A process for making a hydrophilic nonwoven structure comprising: forming a nonwoven structure comprising fibers; and exposing the nonwoven structure to an atmospheric plasma comprising an inert gas and a substance having a polar group and which can be vaporized or made into an aerosol and which forms a free radical upon exposure to a dielectric barrier discharge is provided. Also provided are nonwoven structures produced thereby and articles containing the nonwoven structures.
摘要翻译：一种制备亲水性非织造结构的方法，包括：形成包含纤维的非织造结构; 并且将非织造结构暴露于包含惰性气体和具有极性基团的物质的大气中的等离子体等离子体中，所述物质可以蒸发或制成气溶胶，并且在暴露于介质阻挡放电时形成自由基。还提供了由此制备的非织造结构和含有非织造结构的制品。

25. 发明申请

US20160202159A1 RIGID STRUCTURAL AND LOW BACK FACE SIGNATURE BALLISTIC UD/ARTICLES AND METHOD OF MAKING 有权
标题翻译：刚性结构和低背面签名UD TIC UD UD UD / ING ING ING ING ING ING ING ING
公开(公告)号：US20160202159A1
公开(公告)日：2016-07-14
申请号：US14695972
申请日：2015-04-24
申请人： HONEYWELL INTERNATIONAL INC.
发明人： THOMAS YIU-TAI TAM , JOHN ARMSTRONG YOUNG , RONNIE MOORE , DAVID A. HURST
IPC分类号： G01N3/02 , G01N19/04 , B29B13/08 , B29C65/48 , B29C65/00 , G01N33/36 , D03D1/00
CPC分类号： G01N3/02 , B29B13/08 , B29C65/48 , B29C66/729 , B29C66/7294 , B29K2101/12 , B29K2105/0845 , B29K2105/0854 , B29K2995/0089 , B29L2031/4821 , B29L2031/4842 , B29L2031/768 , B32B37/24 , D03D1/0052 , D06M10/025 , D06M14/26 , D06M17/00 , D06M17/04 , F41H1/02 , F41H5/0485 , G01N3/32 , G01N3/40 , G01N19/00 , G01N19/04 , G01N33/365 , G01N2203/0096 , Y10T428/24058 , Y10T428/24074 , Y10T428/24124 , Y10T428/24479 , Y10T428/2495 , Y10T428/2913 , Y10T442/607
摘要： Fabrication of ballistic resistant fibrous composites having improved ballistic resistance properties. More particularly, ballistic resistant fibrous composites having enhanced a dynamic storage modulus, which correlates to low composite backface signature.
摘要翻译：具有改进防弹性能的防弹纤维复合材料的制造。更具体地，具有增强的动态储能模量的防弹性纤维复合材料，其与低复合背面签名相关。

26. 发明授权

US09091006B2 Conformal coating of polymer fibers on nonwoven substrates 有权
标题翻译：聚合物纤维在非织造基材上的共形涂层
公开(公告)号：US09091006B2
公开(公告)日：2015-07-28
申请号：US12994403
申请日：2009-06-10
申请人： Yong Zheng , Samana Roy Chowdhury , Patrick Vasconcelos Gurgel , Haiyan Liu , Ruben G. Carbonell
发明人： Yong Zheng , Samana Roy Chowdhury , Patrick Vasconcelos Gurgel , Haiyan Liu , Ruben G. Carbonell
IPC分类号： D04H1/56 , D04H1/64 , D06M10/00 , D06M10/02 , D06M14/22 , D06M14/26 , D06M14/28
CPC分类号： D04H1/56 , D04H1/565 , D04H1/587 , D04H1/64 , D04H1/641 , D06M10/001 , D06M10/025 , D06M14/22 , D06M14/26 , D06M14/28 , D06M14/32 , D06M14/34 , Y10T442/20 , Y10T442/277 , Y10T442/2861 , Y10T442/2877 , Y10T442/2885 , Y10T442/2893 , Y10T442/2902 , Y10T442/291 , Y10T442/2918 , Y10T442/60 , Y10T442/659
摘要： The present invention describes a novel process for the conformal coating of polymer fibers of nonwoven substrates. This process is based on modification of polymer fiber surfaces by controlling the degree of etching and oxidation to improve adhesion of initiators to the surface and to facilitate subsequent conformal polymer grafting. The modified fiber surfaces render new functionalities to the surface, such as increased hydrophilicity, attached ligands or changed surface energy. The invention includes the modified polymer fibers produced by the process described herein.
摘要翻译：本发明描述了一种用于非织造衬底的聚合物纤维的保形涂层的新方法。该方法基于通过控制蚀刻和氧化程度来改进聚合物纤维表面，以改善引发剂对表面的粘合性并有利于随后的共形聚合物接枝。改性的纤维表面赋予表面新的功能，例如增加的亲水性，附着的配体或改变的表面能。本发明包括通过本文所述方法生产的改性聚合物纤维。

27. 发明申请

US20140302274A1 RIGID STRUCTURAL AND LOW BACK FACE SIGNATURE BALLISTIC UD/ARTICLES AND METHOD OF MAKING 有权
标题翻译：刚性结构和低背面签名UD TIC UD UD UD / ING ING ING ING ING ING ING ING ING
公开(公告)号：US20140302274A1
公开(公告)日：2014-10-09
申请号：US13594763
申请日：2012-08-24
申请人： THOMAS YIU-TAI TAM , JOHN ARMSTRONG YOUNG , RONNIE MOORE , DAVID A. HURST
发明人： THOMAS YIU-TAI TAM , JOHN ARMSTRONG YOUNG , RONNIE MOORE , DAVID A. HURST
IPC分类号： F41H1/02 , G01N19/00 , B32B37/24
CPC分类号： G01N3/02 , B29B13/08 , B29C65/48 , B29C66/729 , B29C66/7294 , B29K2101/12 , B29K2105/0845 , B29K2105/0854 , B29K2995/0089 , B29L2031/4821 , B29L2031/4842 , B29L2031/768 , B32B37/24 , D03D1/0052 , D06M10/025 , D06M14/26 , D06M17/00 , D06M17/04 , F41H1/02 , F41H5/0485 , G01N3/32 , G01N3/40 , G01N19/00 , G01N19/04 , G01N33/365 , G01N2203/0096 , Y10T428/24058 , Y10T428/24074 , Y10T428/24124 , Y10T428/24479 , Y10T428/2495 , Y10T428/2913 , Y10T442/607
摘要： Fabrication of ballistic resistant fibrous composites having improved ballistic resistance properties. More particularly, ballistic resistant fibrous composites having enhanced a dynamic storage modulus, which correlates to low composite backface signature.
摘要翻译：具有改进防弹性能的防弹纤维复合材料的制造。更具体地，具有增强的动态储能模量的防弹性纤维复合材料，其与低复合背面签名相关。

28. 发明授权

US08414980B2 Method for hydrophobic and oleophobic modification of polymeric materials with atmospheric plasmas 失效
标题翻译：具有大气等离子体的聚合材料疏水和疏油改性的方法
公开(公告)号：US08414980B2
公开(公告)日：2013-04-09
申请号：US12545664
申请日：2009-08-21
申请人： Tien-Hsiang Hsueh , Mien-Win Wu , Chi-Fong Ai
发明人： Tien-Hsiang Hsueh , Mien-Win Wu , Chi-Fong Ai
IPC分类号： C08J7/18
CPC分类号： B05D3/142 , C08J7/18 , C08J2427/12 , D06M10/025 , D06M14/18 , D06M14/22 , D06M14/26 , D06M14/28 , D06M14/32 , D06M14/34 , D06M2200/11 , D06M2200/12
摘要： A method of fabricating hydrophobic and oleophobic polymer fabric through two stages of modification using atmospheric plasmas including (a) moving a substrate into an atmospheric plasma area, generating an atmospheric filamentary discharge plasma with a first plasma working gas to obtain a first rough surface of said substrate, (b) exposing plasma treated substrate to air to obtain highly active peroxide on said first rough surface of said substrate, (c) immersing said substrate in a solution of fluorocarbon compound and processing a first stage of graft of a fluorocarbon monomer or oligomer on said substrate to obtain a grafted fluorocarbon monomer or oligomer layer on said first rough surface of said substrate, (d) processing a second stage of graft a fluorocarbon functional group to said grafted fluorocarbon monomer or oligomer layer by generating a carbon tetrafluoride plasma from a second plasma working gas and irradiating said carbon tetrafluoride plasma on said grafted fluorocarbon monomer or oligomer layer; and (e) curing and drying said substrate.
摘要翻译：一种通过使用大气等离子体的两个阶段的修饰制造疏水和疏油聚合物织物的方法，包括：（a）将基底移动到大气等离子体区域，用第一等离子体工作气体产生大气丝状放电等离子体，以获得所述（b）将等离子体处理的基板暴露于空气中以在所述基板的所述第一粗糙表面上获得高活性过氧化物，（c）将所述基材浸入氟碳化合物溶液中，并处理氟碳单体或低聚物的第一接枝段在所述基板上在所述基板的所述第一粗糙表面上获得接枝的碳氟单体或低聚物层，（d）通过从所述基板上生成碳氟化合物单体或低聚物层，第二等离子体工作气体，并且在所述接枝的氟碳上照射所述四氟化碳等离子体单体或低聚物层; 和（e）固化和干燥所述基材。

29. 发明申请

US20100192414A1 WATERPROOF PLASMA TREATED FOOTWEAR WITH LIQUID ABSORBING FOOTBED 有权
标题翻译：防水等离子体处理鞋与液体吸收脚
公开(公告)号：US20100192414A1
公开(公告)日：2010-08-05
申请号：US12669076
申请日：2008-07-16
申请人： Stephen Coulson
发明人： Stephen Coulson
IPC分类号： A43B23/16 , A43B7/14
CPC分类号： D06M14/18 , A43B7/12 , B05D1/62 , D06M10/025 , D06M14/20 , D06M14/22 , D06M14/24 , D06M14/26 , D06M14/28 , D06M14/30 , D06M14/32 , D06M14/34 , Y10T428/31504 , Y10T428/31855
摘要： An item of footwear having a liquid-repelling polymeric coating, obtained by a plasma treatment process, provided over at least part of a surface thereof, said item also being provided at the region on the inside upon which the wearer's foot rests with a liquid-absorbing foot supporting footbed. Items of this type provide improved comfort for the wearer.
摘要翻译：一种通过等离子体处理方法获得的具有液体排斥聚合物涂层的鞋类物品，其至少部分表面上设置有所述物品，所述物品还设置在所述内部的所述区域上，吸脚支脚。这种物品为佩戴者提供了改进的舒适感。

30. 发明授权

US07390853B2 Solid reagents 失效
公开(公告)号：US07390853B2
公开(公告)日：2008-06-24
申请号：US10617025
申请日：2003-07-11
申请人： Makoto Komatsu , Kazuyoshi Takeda
发明人： Makoto Komatsu , Kazuyoshi Takeda
IPC分类号： C08F291/00 , C08J7/18
CPC分类号： D06M14/18 , C08F255/00 , C08F255/02 , C08F255/023 , C08F255/026 , C08F257/02 , C08F259/00 , C08F291/00 , D06M14/26 , D06M14/28
摘要： An object of the present invention is to provide a novel solid reagent capable of solving the problems of conventional solid reagents based on resin beads.The present invention relates to a solid reagent comprising an organic polymer base in which a polymer side chain is introduced onto the backbone of the organic polymer base via graft polymerization and a reactive functional group is introduced onto the polymer side chain. The organic polymer base is preferably in the form of a fiber, a woven or nonwoven fabric consisting of an assembly of fibers, a porous membrane or a hollow fiber membrane. The graft polymerization is preferably a radiation-induced graft polymerization. Solid reagents according to the present invention can be used in various organic synthetic reactions.

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