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    • 21. 发明授权
    • Gel comprising a phase-change material, method of preparing the gel, and thermal exchange implement comprising the gel
    • 包含相变材料的凝胶,制备凝胶的方法和包含凝胶的热交换工具
    • US09556373B2
    • 2017-01-31
    • US14036497
    • 2013-09-25
    • Cold Chain Technologies, Inc.
    • Richard M. FormatoDimitrios P. Bakllas
    • C08K5/01C08L9/06C08L15/00C09K5/06C08L9/00
    • C09K5/06C08K5/01C08L9/00C08L9/06C08L15/00C09K5/063Y02E60/147Y10T428/1334
    • Gel including a phase-change material and a gelling agent. In one embodiment, the phase-change material may be n-tetradecane, and the gelling agent may be a styrene-ethylene-butylene-styrene (SEBS) triblock copolymer. In particular, the SEBS copolymer may be a high molecular weight SEBS copolymer with a styrene:rubber ratio of about 30:70 to 33:67% by weight. The SEBS copolymer may constitute up to about 10%, by weight, of the gel, preferably less than 6%, by weight, of the gel, with n-tetradecane constituting the remainder. To form the gel, the phase-change material and the gelling agent are mixed together at an elevated temperature relative to room temperature to partially, but not completely, dissolve the gelling agent, i.e., a homogeneous solution is not formed. The mixture is then allowed to cool to room temperature. The invention is also directed at a method of preparing the gel and a thermal exchange implement including the gel.
    • 凝胶包括相变材料和胶凝剂。 在一个实施方案中,相变材料可以是正十四烷,并且胶凝剂可以是苯乙烯 - 乙烯 - 丁烯 - 苯乙烯(SEBS)三嵌段共聚物。 特别地,SEBS共聚物可以是苯乙烯:橡胶比为约30:70至33:67重量%的高分子量SEBS共聚物。 所述SEBS共聚物可以构成至多约10重量%的凝胶,优选小于6重量%的凝胶,其中正十四烷构成其余部分。 为了形成凝胶,相变材料和胶凝剂在相对于室温的升高的温度下混合在一起,部分但不完全溶解胶凝剂,即不形成均匀的溶液。 然后将混合物冷却至室温。 本发明还涉及制备凝胶的方法和包含该凝胶的热交换工具。
    • 22. 发明授权
    • Method of modulated exothermic chemical systems through phase change materials
    • 通过相变材料调制放热化学系统的方法
    • US09481821B2
    • 2016-11-01
    • US13716915
    • 2012-12-17
    • University of South Florida
    • Sermin G. SunolAydin K. Sunol
    • C09K5/06C09K5/18
    • C09K5/18C09K5/06C09K5/063
    • The chemical reactions modulation of temperature and dissipate heat through using phase change materials (PCM). Hydration of a mixture composed of encapsulated and/or non-encapsulated oxides such as calcium oxide and/or magnesium oxide and dehydrated and/or hydrated zeolite coupled with control of pH of mixture through compounds such as Citric acid, or combination exothermic mixes, such as Cao and Mg—Fe, provide sustained heat release and heat retention tailored by addition of PCMs. The modulation may include timed/controlled release from encapsulated reactants and may include particles with tailored size distribution and different burn characteristics. The phase change materials used include organics (paraffins, non paraffins and fatty acids) and inorganics (salt hydrates). The selection of PCM is based on compatibility with the reacting mix, added reacting aqueous medium, and the desired temperature the system is to be held constant or temperature range it is desired to be modulated.
    • 通过使用相变材料(PCM)的温度化学反应调制和散热。 由包封和/或未包封的氧化物如氧化钙和/或氧化镁和脱水和/或水合沸石组成的混合物的水合与通过化合物如柠檬酸或混合放热混合物混合的混合物的pH值进行偶联, 作为Cao和Mg-Fe,通过添加PCM提供持续的放热和保温。 调制可以包括来自封装的反应物的定时/控制释放,并且可以包括具有定制尺寸分布和不同燃烧特性的颗粒。 使用的相变材料包括有机物(石蜡,非石蜡和脂肪酸)和无机物(盐水合物)。 PCM的选择基于与反应混合物的相容性,添加的水性介质反应以及要保持系统的期望温度或期望调制的温度范围。
    • 25. 发明授权
    • Porous material having micropores capable of storing and releasing heat by phase change and preparation method thereof
    • 具有能够通过相变来储存和释放热的微孔的多孔材料及其制备方法
    • US09410747B2
    • 2016-08-09
    • US13706534
    • 2012-12-06
    • KOREA INSTITUTE OF CONSTRUCTION TECHNOLOGY
    • Kwang-Soo Kim
    • F28D17/00B05D5/00C09K5/06F28D20/02
    • F28D17/00B05D5/00C09K5/063F28D20/023Y02E60/145
    • The present invention provides a porous material having micropores capable of storing and releasing heat by phase change, which comprises a phase change material inserted into the micropores of a porous material medium such as activated carbon or silica gel so as to be capable of storing and releasing energy, and a preparation method thereof. The method comprises the steps of: pre-treating a porous material medium to remove impurities from the micropores of the porous material medium, thereby opening the micropores; pre-treating a phase change material to make it possible to insert the phase change material into the micropores of the porous material medium; inserting the pretreated phase change material into the pretreated porous material medium; filtering the porous material medium filled with the phase change material to remove the phase change material remaining after the insertion step; and washing the filtered material.
    • 本发明提供一种多孔材料,其具有能够通过相变来储存和释放热量的微孔,该多孔材料包括插入诸如活性炭或硅胶的多孔材料介质的微孔中的相变材料,以便能够储存和释放 能量及其制备方法。 该方法包括以下步骤:预处理多孔材料介质以从多孔材料介质的微孔中除去杂质,从而打开微孔; 预处理相变材料以使相变材料插入多孔材料介质的微孔中成为可能; 将预处理的相变材料插入预处理的多孔材料介质中; 过滤填充有相变材料的多孔材料介质以去除在插入步骤之后剩余的相变材料; 并洗涤过滤的材料。
    • 27. 发明申请
    • DIMENSIONALLY STABLE PHASE CHANGE MATERIAL AND A CONTINUOUS PROCESS FOR MAKING SAME
    • 尺寸稳定的相变材料和连续制造方法
    • US20160208155A1
    • 2016-07-21
    • US15000376
    • 2016-01-19
    • Microtek Laboratories, Inc.
    • Carl M. LentzTeresa T. VirgallitoJerry K. Lawson
    • C09K5/06
    • C09K5/063
    • Methods for producing a dimensionally stable phase change material (PCM), and dimensionally stable PCMs are disclosed. The methods include providing a porous base material, mixing a phase change material having a polar functional group with a substance that increases the polar attraction of the phase change material for the porous base material to form a mixture thereof; and, thereafter, mixing the mixture with the porous base material until a selected saturation of phase change material in the porous base material is reached. The methods may include filtering the porous base material after the selected saturation is reached to form a cake of dimensionally stable PCM and, thereafter, reducing the size of the dimensionally stable PCM to an average mean particle size of about 10 to about 50 μm, or more preferably 20 to 30 μm.
    • 公开了用于制造尺寸稳定的相变材料(PCM)的方法和尺寸稳定的PCM。 所述方法包括提供多孔基材,将具有极性官能团的相变材料与增加多孔基材的相变材料的极性吸引的物质混合形成混合物; 然后将混合物与多孔基材混合,直到达到多孔基材中相变材料的选定饱和。 所述方法可以包括在达到选择的饱和之后过滤多孔基材以形成尺寸稳定的PCM的饼,然后将尺寸稳定的PCM的尺寸减小到约10至约50μm的平均平均粒度,或 更优选为20〜30μm。