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    • 24. 发明授权
    • Vulcanizable binder dispersion composition
    • 可硫化粘合剂分散体组合物
    • US4988753A
    • 1991-01-29
    • US207258
    • 1988-06-15
    • Helmut RullmannAdolf ZellnerManfred Gebhard
    • Helmut RullmannAdolf ZellnerManfred Gebhard
    • C08J5/12C09J4/00C09J4/02C09J123/34C09J151/00C09J157/00
    • C08J5/127C09J123/34C08J2321/00
    • A bonding composition comprising an aqueous dispersion is described, which is used to bond natural and synthetic elastomers to metallic and nonmetallic substrates under vulcanizing conditions. Such dispersions contain an organic polymeric film-forming substance, an aromatic polynitroso compound, and a coactivator and optionally contain conventional adhesion promoters, fillers and processing aids. In order to widen the field of application and to ensure a high stability of the bond against corrosive influences, the coactivator particularly consists of phenylene bis-maleic acid imide, but one more of the following may be used: triallyl- cyanurate, triallylisocyanurate, diallylacrylamide, tetraallylterephthalamide, tris(1-methyl-2-propenyl) isocyanurate, trivinylisocyanurate, triallyltrimellitate, diallylphthalate, ethylene-glycoldimethacrylate, trimethylolpropanetrimethacrylate, and 1,3-butyleneglycoldimethacrylate.
    • 描述了包含水分散体的粘合组合物,其用于在天然和合成弹性体在硫化条件下将金属和非金属基材粘合。 这样的分散体含有有机高分子成膜物质,芳族多核苷酸化合物和共活化剂,并且任选地含有常规的粘合促进剂,填料和加工助剂。 为了拓宽应用领域并确保粘合剂对腐蚀性影响的高稳定性,共激活剂特别由亚苯基双马来酸酰亚胺组成,但可以使用以下一种:三烯丙基氰脲酸酯,三烯丙基异氰尿酸酯,二烯丙基丙烯酰胺 四烯丙基对苯二甲酰胺,三(1-甲基-2-丙烯基)异氰脲酸酯,三乙烯基异氰脲酸酯,三烯丙基偏苯三酸酯,邻苯二甲酸二烯丙酯,乙烯 - 甘氨酸二甲基丙烯酸酯,三羟甲基丙烷三甲基丙烯酸酯和1,3-丁二醇二十二烷基二甲基丙烯酸酯。
    • 25. 发明授权
    • Process of forming phosphate coatings on metals
    • 在金属上形成磷酸盐涂层的工艺
    • US4950339A
    • 1990-08-21
    • US305214
    • 1989-02-01
    • Horst GehmeckerWerner RauschPeter Jorns
    • Horst GehmeckerWerner RauschPeter Jorns
    • C23C22/36C23C22/78
    • C23C22/362C23C22/78
    • A process to form phosphate coatings on individual parts of metal which at least on part of their surface consists of iron or steel. The individual parts are contacted at a temperature in the range of from 60 to 100 degrees centigrade for 3 to 30 seconds with an aqueous phosphating solution which contains 10 to 80 g/l zinc, 12 to 80 g/l phosphate (calculated as P.sub.2 O.sub.5), 40 to 150 g/l nitrate and, in addition 0.1 to 10 g/l fluoride, 0.01 to 10 g/l nickel, 0.0001 to 0.1 g/l copper, and may also contain tartaric acid, citric acid and/or manganese and in which the ratio of free acid to total acid has been adjusted to (0.1 to 0.3):1 and which contains at least 80 points of total acid and is virtually free of iron(II) ions. Prior to phosphating treatment, the individual parts may be cleaned and may optionally be treated to remove rust, scale and phosphate layers and/or be activated. After the phosphating treatment they may be passivated with an after-rinse solution. Each of said process steps is carried out for 3 to 30 seconds.
    • 在金属的单个部分上形成磷酸盐涂层的方法,其至少部分表面由铁或钢组成。 使用含有10至80g / l锌,12至80g / l磷酸盐(以P2O5计算)的磷酸盐水溶液将各个部件在60至100摄氏度的温度范围内接触3至30秒, ,40〜150g / l的硝酸盐,以及0.1〜10g / l的氟化物,0.01〜10g / l的镍,0.0001〜0.1g / l的铜,也可以含有酒石酸,柠檬酸和/或锰, 其中游离酸与总酸的比例已经被调节到(0.1〜0.3):1,并且其含有至少80个总酸,实际上没有铁(II)离子。 在磷化处理之前,可以清洁各个部件,并且可以任选地处理以除去锈,鳞屑和磷酸盐层和/或被活化。 在磷化处理后,可以用冲洗液进行钝化。 每个所述处理步骤进行3至30秒。
    • 30. 发明授权
    • Process of producing phosphate coatings on metal surfaces
    • 在金属表面生产磷酸盐涂层的工艺
    • US4849031A
    • 1989-07-18
    • US92951
    • 1987-09-04
    • Dieter HauffeGisela BeegePeter MischkeWerner Rausch
    • Dieter HauffeGisela BeegePeter MischkeWerner Rausch
    • C23C22/36C23C22/77C23C22/12
    • C23C22/362C23C22/77
    • Disclosed is a process of producing phosphate coatings on surfaces which consist of aluminum or its alloys and of at least one of the materials steel and galcanized steel by spraying or by spraying and dipping. Uniform phosphate layers having a high cover factor are obtained by the use of a phosphating solution which contains about 0.4 to about 0.8 g/l Zn, about 10 to about 20 g/l P.sub.2 O.sub.5, at least one accelerator and about 80 to about 220 mg/l fluoride ("F(el)"), as determined by a fluoride-sensitive electrode immersed into the bath solution and in which the content of free acid (FA) (in points) has been adjusted to and is maintained at a value corresponding to FA=(0.5 to 1.0)+K wherein K is calculated as K=(0.002 to 0.012).times.F(el). The free acid (FA) content is preferably adjusted to and maintained at FA=(0.04 to 0.06).times.C.sub.P.sbsb.2.sub.O.sbsb.5 +K and the content of free acid (FA) is determined using K=(0.003 to 0.009).times.F(el). The process is particularly suitable for preparing the surfaces for being painted, preferably by electrophoretic dip painting.
    • 公开了一种通过喷涂或喷涂和浸渍在由铝或其合金和至少一种材料钢和镓化钢组成的表面上生产磷酸盐涂层的方法。 通过使用含有约0.4至约0.8g / l的Zn,约10至约20g / l的P 2 O 5,至少一种促进剂和约80至约220mg的磷酸盐溶液获得具有高覆盖系数的均匀磷酸盐层 /氟化物(“F(el)”),其通过浸入浴溶液中的氟化物敏感电极测定,其中游离酸(FA)的含量(以点计)已被调节并保持在值 对应于FA =(0.5〜1.0)+ K,其中K被计算为K =(0.002至0.012)×F(el)。 优选将游离酸(FA)含量调节至FA =(0.04〜0.06)×CP2O5 + K,并且使用K =(0.003〜0.009)×F(el)求出游离酸(FA)的含量。 该方法特别适于制备用于涂漆的表面,优选通过电泳浸涂。