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    • 21. 发明申请
    • POLYMER FILM COMPRISING ROUGHENING MATERIAL
    • 包含粗化材料的聚合物膜
    • US20100316843A1
    • 2010-12-16
    • US12781018
    • 2010-05-17
    • Lih-Long ChuAllen W. RossRobert L. McGee
    • Lih-Long ChuAllen W. RossRobert L. McGee
    • C09J7/00B32B27/20C09J7/02
    • C08L23/0876B32B7/06B32B27/08B32B27/18B32B27/20B32B27/306B32B27/308B32B27/32B32B2250/24B32B2264/10B32B2270/00B32B2307/50B32B2307/538B32B2307/72B32B2307/748B32B2405/00C08K3/34C08L2203/16C08L2205/025Y10T428/24372C08L23/06
    • The present invention is directed to a multilayer polymer film for application to and removal from a substrate, having controlled surface adhesion and peelably removable from a surface, the film having a layer comprising components (A) at least one polyolefin, (B) an adhesive composition in an amount equal to or greater than 3 weight percent, (C) a tackifier composition in an amount of from 1 to 12 weight percent, (D) at least one colorant in an amount from 0 to 15 weight percent, (E) anti-block additive in an amount of less than 1 weight percent, and (F) roughening material in an amount of less than or equal to 20 weight percent, each based on total weight of the adhesive layer; the components (A) through (F) with optional incidental carriers and additives being 100 percent by weight of the adhesive layer; wherein the adhesive composition consists essentially of ethylene/methyl acrylate and ethylene/acrylic acid in a weight ratio of from 60:40 to 50:15, that is, 77:23, ethylene/methyl acrylate to ethylene/acrylic acid; the tackifier is selected from a terpene phenolic resin or an acrylic hot melt resin; and the roughening material has an average particle size ranging from 20 to 60 microns.
    • 本发明涉及一种多层聚合物薄膜,其用于从基材上移除并具有可控制的表面粘附性并且可从表面剥离的薄膜,该薄膜具有包含组分(A)至少一种聚烯烃的层,(B)粘合剂 (C)1至12重量%的增粘剂组合物,(D)至少一种0至15重量%的着色剂,(E)组合物,其量为等于或大于3重量% 小于1重量%的抗阻燃添加剂,和(F)小于或等于20重量%的量的粗糙材料,各自基于粘合剂层的总重量; 具有任选附带载体和添加剂的组分(A)至(F)为粘合剂层的100重量%; 其中所述粘合剂组合物基本上由乙烯/丙烯酸甲酯和乙烯/丙烯酸组成,其重量比为60:40至50:15,即77:23,乙烯/丙烯酸甲酯至乙烯/丙烯酸; 增粘剂选自萜烯酚醛树脂或丙烯酸热熔树脂; 粗化材料的平均粒度为20〜60微米。
    • 22. 发明授权
    • Shrink labels of oriented polystyrene film containing small rubber particles and low rubber particle gel content and block copolymers
    • 收缩包含小橡胶颗粒和低橡胶颗粒凝胶含量的定向聚苯乙烯薄膜的标签和嵌段共聚物
    • US07824773B2
    • 2010-11-02
    • US12306994
    • 2006-07-27
    • Robert L. McGeeStephen J. Skapik, III
    • Robert L. McGeeStephen J. Skapik, III
    • B32B3/10G09F3/02C08L51/00
    • C08L51/003C08J5/18C08J2325/06C08L25/06C08L53/02Y10T428/24273Y10T428/24893Y10T428/268Y10T428/31909Y10T428/31924Y10T428/31931C08L2666/02C08L2666/24C08L2666/06
    • A polymer composition containing (a) a high impact polystyrene (HIPS) component with a block copolymer grafted to polystyrene, a rubbery conjugated diene content of one to seven weight percent based on HIPS weight, less than 10 weight-percent gel concentration, an average rubber particle size of between one and 0.01 micrometers, about 40 to about 90 volume percent of the rubber particles have diameters of less than about 0.4 microns and from about 10 to about 60 volume percent of the rubber particles have diameters between about 0.4 and about 2.5 microns, a majority of rubber particles with a core/shell morphology and a concentration that accounts for 10 to 70 weight-percent of the total polymer composition weight and one to five weight-percent rubbery diene based on total polymer composition weight; (b) from 10 to 70 weight percent of a general purpose polystyrene and from about 2 to about 80 weight-percent of a styrene block copolymer component, both based on total polymer composition weight. In a film, preferably oriented, wherein the polymer composition accounts for at least 95 weight-percent of the film, with the balance of the film or film composition weight being additives. Shrink labels are made from the film.
    • 一种聚合物组合物,其包含(a)具有接枝到聚苯乙烯的嵌段共聚物的高抗冲聚苯乙烯(HIPS)组分,基于HIPS重量的1至7重量%的橡胶状共轭二烯含量,小于10重量%的凝胶浓度,平均 橡胶颗粒尺寸为1至0.01微米,约40至约90体积%的橡胶颗粒具有小于约0.4微米的直径,并且约10至约60体积%的橡胶颗粒具有约0.4至约2.5的直径 基于总聚合物组合物重量,具有核/壳形态和占总聚合物组合物重量的10至70重量%和1-5重量%橡胶二烯的浓度的大多数橡胶颗粒; (b)基于总聚合物组合物重量,10至70重量%的通用聚苯乙烯和约2-约80重量%的苯乙烯嵌段共聚物组分。 在薄膜中,优选取向,其中聚合物组合物占薄膜的至少95重量%,其余的薄膜或薄膜组合物重量为添加剂。 收缩标签由电影制作。