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21. 发明授权

US4145428A Fungicidally active 2-acyloxy-1-phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butanes 失效
标题翻译：杀真菌剂2-氰基-1-苯氧基-1-（1,2,4-三唑基）-3,3-二甲基丁烷
公开(公告)号：US4145428A
公开(公告)日：1979-03-20
申请号：US753651
申请日：1976-12-21
申请人： Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/653 , A01P3/00 , C07D233/60 , C07D249/08 , C07D521/00 , A01N9/22 , A61K31/41 , C07D249/10
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： 1-Phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butanes of the formula ##STR1## in which R represents alkyl, alkenyl, alkynyl, cycloalkyl, halogenoalkyl, optionally substituted phenyl, optionally substituted phenoxyalkyl, alkylamino, dialkylamino or optionally substituted phenylamino, X represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl, amino, cyano or nitro, N represents 0, 1, 2, 3, 4 or 5, and Az represents the 1,2,4-triazolyl-1 or the 1,2,4-triazolyl-4 radical, In the form of the free base, a salt with a physiologically tolerated acid or a complex with a metal salt, which possess fungicidal properties.

22. 发明授权

US4715887A Substituted triazolyl-methyl-tert-butyl carbinol compounds and plant protection agents 失效
标题翻译：取代的三唑基 - 甲基 - 叔丁基甲醇化合物和植物保护剂
公开(公告)号：US4715887A
公开(公告)日：1987-12-29
申请号：US684178
申请日：1984-12-21
申请人： Wolfgang Kramer , Karl H. Buchel , Paul-Ernst Frohberger , Wilhelm Brandes , Klaus Lurssen
发明人： Wolfgang Kramer , Karl H. Buchel , Paul-Ernst Frohberger , Wilhelm Brandes , Klaus Lurssen
IPC分类号： A01N43/653 , A01P3/00 , C07D249/08 , C07D521/00 , A61K31/41
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New substituted triazolylmethyl tert.-butyl carbinols of the formula ##STR1## in which R represents alkyl, alkenyl, alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl or optionally substituted aralkyl,X represents hydrogen or halogen andY represents halogen,and the acid addition salts and metal salt complexes thereof, a process for the preparation of said novel compounds, their use as plant protection agents and as intermediate products for the synthesis of other plant protection agents.
摘要翻译：式（I）的新取代的三唑基甲基叔丁基甲醇，其中R表示烷基，烯基，炔基，任选取代的环烷基，任选取代的环烷基烷基或任选取代的芳烷基，X表示氢或卤素，Y表示卤素，其酸加成盐和金属盐络合物，制备所述新化合物的方法，它们作为植物保护剂的用途以及用于合成其它植物保护剂的中间产物。

23. 发明授权

US4428949A Combating fungi with fluorinated 1-azolylbutane derivatives 失效
标题翻译：用氟化1-噻唑基丁烷衍生物灭菌
公开(公告)号：US4428949A
公开(公告)日：1984-01-31
申请号：US295982
申请日：1981-08-25
申请人： Wolfgang Kramer , Karl H. Buchel , Jorg Stetter , Paul-Ernst Frohberger , Wilhelm Brandes
发明人： Wolfgang Kramer , Karl H. Buchel , Jorg Stetter , Paul-Ernst Frohberger , Wilhelm Brandes
IPC分类号： A01N43/50 , A01N43/653 , C07C45/63 , C07C45/71 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C45/63 , C07C45/71 , C07D233/56 , C07D249/08
摘要： A 4-fluoro-1-azolyl-1-phenoxy-butan-2-one or -ol of the formula ##STR1## in which Az is an imidazol-1-yl, 1,2,4-triazol-1-yl or 1,2,4-triazol-4-yl radical,B is a keto or CH(OH) group,X is a hydrogen or fluorine atom,Y is an alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio radical,Z is a halogen atom or an alkyl radical,m is 1, 2 or 3 andn is 0, 1 or 2,or an addition product thereof with a physiologically acceptable acid or a metal salt, which possesses fungicidal activity.
摘要翻译：其中A 1是咪唑-1-基，1,2,4-三唑-1-基或其中R 1，R 2，R 3，R 4，R 4， 1,2,4-三唑-4-基，B是酮或CH（OH）基，X是氢或氟原子，Y是烷氧基，烷硫基，卤代烷基，卤代烷氧基或卤代烷硫基，Z是卤素原子或烷基，m为1,2或3，n为0,1或2，或其与具有杀真菌活性的生理学上可接受的酸或金属盐的加成产物。

24. 发明授权

US4386088A Combating fungi with .alpha.-azolyl-keto derivatives 失效
标题翻译：抗真菌与α-唑基 - 酮衍生物
公开(公告)号：US4386088A
公开(公告)日：1983-05-31
申请号：US304128
申请日：1981-09-21
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/82
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： An .alpha.-azolyl-keto derivative of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxycarbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,R.sup.4 represents the grouping --O--CO--R.sup.5, --O(S)--R.sup.6 or --O--S(O).sub.n --R.sup.7, or alkylamino, dialkylamino, optionally substituted phenylamino or halogen,R.sup.5 represents alkyl, halogenoalkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,R.sup.6 represents alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.7 represents alkyl, halogenoalkyl, optionally substituted phenyl or dialkylamino,n represents 1 or 2,X.sup.1 and X.sup.2 each independently represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or a physiologically acceptable acid addition salt or metal salt complex thereof, which possesses fungicidal properties.
摘要翻译：其中R 1表示任选取代的烷基或任选取代的苯基，R 2表示分组-C X 1 X 2 R 3或烷氧基羰基，R 3表示卤素，卤代烷基或任选取代的苯基，R 4表示基团-O -CO-R 5，-O（S）-R 6或-OS（O）n -R 7或烷基氨基，二烷基氨基，任选取代的苯基氨基或卤素，R 5表示烷基，卤代烷基，烯基，炔基，环烷基，任选取代的苯基，取代的苯基烷基，烷基氨基，二烷基氨基或任选取代的苯基氨基，R 6表示烷基，烯基，炔基，环烷基，任选取代的苯基或任选取代的苄基，R 7表示烷基，卤代烷基，任选取代的苯基或二烷基氨基，n表示1或2，各自独立地表示氢或卤素，Y表示氮原子或CH基团，或生理上可接受的酸加成盐或金属盐共其复合物具有杀真菌性能。

25. 发明授权

US4364955A Combating fungi with 1-(substituted phenyl)-1-oximino-2-(1,2,4-triazol-1-yl)-ethane 失效
标题翻译：用1-（取代的苯基）-1-肟基-2-（1,2,4-三唑-1-基） - 乙烷灭菌
公开(公告)号：US4364955A
公开(公告)日：1982-12-21
申请号：US142515
申请日：1980-04-21
申请人： Wolfgang Kramer , Karl H. Buchel , Helmut Timmler , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Wolfgang Kramer , Karl H. Buchel , Helmut Timmler , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/653 , A61K31/41 , A61P31/04 , C07D249/08 , C07D521/00 , A01N43/64 , A01N55/02
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： A 1-(substituted phenyl)-1-oximino-2-(1,2,4-triazol-1-yl)-ethanes of the formula ##STR1## in which R.sup.1 is alkyl with 1 to 4 carbon atoms, benzyl, or benzyl substituted once or twice with halogen and/or alkyl with 1 to 4 carbon atoms.R.sup.2 is hydrogen, alkyl with 1 to 4 carbon atoms or halogen, andR.sup.3 is alkyl or haloalkyl with 1 to 4 carbon atoms, and when R.sup.1 is alkyl, can also be phenyl, phenoxy, halophenyl or halophenoxy,or an acid addition salt or metal salt complex thereof which is fungicidally active.
摘要翻译：其中R 1是具有1至4个碳原子的烷基的式（I）的1-（取代的苯基）-1-肟基-2-（1,2,4-三唑-1-基）苄基或被卤素和/或具有1至4个碳原子的烷基取代一次或两次的苄基。 R 2是氢，具有1至4个碳原子的烷基或卤素，并且R 3是具有1至4个碳原子的烷基或卤代烷基，并且当R 1是烷基时，也可以是苯基，苯氧基，卤代苯基或卤代苯氧基，或酸加成盐或其金属盐复合物是杀真菌活性的。

26. 发明授权

US4357338A Combating fungi with 1-phenyl-1-oximino-2-(1,2,4-triazol-1-yl)-ethanes 失效
标题翻译：将真菌与1-苯基-1-肟基-2-（1,2,4-三唑-1-基） - 乙胺
公开(公告)号：US4357338A
公开(公告)日：1982-11-02
申请号：US204986
申请日：1980-11-07
申请人： Wolfgang Kramer , Karl H. Buchel , Helmut Timmler , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Wolfgang Kramer , Karl H. Buchel , Helmut Timmler , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/653 , A61K31/41 , A61P31/04 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： A 1-phenyl,1-oximino-2-(1,2,4-triazol-1-yl)-ethane of the formula ##STR1## in which R is halogen, alkyl, alkoxy, alkylthio, alkylsulphonyl, halogenoalkyl, nitro, cyano, optionally substituted phenyl or optionally substituted phenoxy,R' is alkyl, alkenyl, alkynyl, optionally substituted benzyl or optionally substituted styryl, andn is 0, 1, 2 or 3,or a salt thereof with a physiologically acceptable acid or a metal salt complex thereof which possesses fungicidal properties.
摘要翻译：其中R为卤素，烷基，烷氧基，烷硫基，烷基磺酰基，卤代烷基，硝基，苯基，苯基，氰基，任选取代的苯基或任选取代的苯氧基，R'是烷基，烯基，炔基，任选取代的苄基或任选取代的苯乙烯基，n是0,1,2或3，或其盐与生理学上可接受的酸或金属其复合物具有杀真菌性。

27. 发明授权

US4291047A Combating fungi with .alpha.-azolyl-.beta.-hydroxy-ketones 失效
标题翻译：抗真菌与α-唑基-β-羟基酮
公开(公告)号：US4291047A
公开(公告)日：1981-09-22
申请号：US54061
申请日：1979-07-02
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： .alpha.-Azolyl-.beta.-hydroxy-ketones of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxycarbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,X.sup.1 and X.sup.2, which may be identical or different, each represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or physiologically acceptable acid-addition salts or metal-salt complexes thereof which possess fungicidal properties.
摘要翻译：其中R 1表示任选取代的烷基或任选取代的苯基，R 2表示基团-CX 1 X 2 R 3或烷氧基羰基，R 3表示卤素，卤代烷基或任选取代的苯基，X 1和X 2，其可以相同或不同，各自表示氢或卤素，Y表示具有杀真菌性质的氮原子或CH基团或其生理上可接受的酸加成盐或其金属盐络合物。

28. 发明授权

US4254132A Combating fungi with 2-acyloxy-1-azolyl-3,3-dimethyl-2-phenoxy-butanes 失效
标题翻译：用2-酰氧基-1-吡唑基-3,3-二甲基-2-苯氧基 - 丁烷灭菌
公开(公告)号：US4254132A
公开(公告)日：1981-03-03
申请号：US14771
申请日：1979-02-22
申请人： Wolfgang Kramer , Karl H. Buchel , Paul-Ernst Frohberger , Wilhelm Brandes
发明人： Wolfgang Kramer , Karl H. Buchel , Paul-Ernst Frohberger , Wilhelm Brandes
IPC分类号： A01N43/50 , A01N43/653 , A01N47/06 , A01N47/12 , A01N47/20 , A01N47/24 , A61K31/41 , A61K31/415 , A61P31/04 , C07C45/63 , C07C45/71 , C07C45/75 , C07C49/16 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , A01N47/06 , A01N47/12 , A01N47/20 , A01N47/24 , C07C45/63 , C07C45/71 , C07C45/75 , C07C49/16 , C07D233/56 , C07D249/08
摘要： A 2-acyloxy-1-azolyl-3,3-dimethyl-2-phenoxy-butane of the formula ##STR1## in which A represents a nitrogen atom or the CH group,R represents alkyl, alkenyl, alkynyl, alkoxy, alkoxyalkyl, cycloalkyl, halogenoalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, optionally substituted phenoxyalkyl, alkylamino, dialkylamino, optionally substituted phenylamino, halogenalkylamino, alkoxycarbonylamino, or alkoxyalkylamino,X represents hydrogen, halogen or alkylcarbonyloxy,Y represents halogen or alkylcarbonyloxy,Z represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl, cyano or nitro, andn represents 0, 1, 2, 3, 4 or 5, the substituents Z being selected independently of one another when n is 2 or more,and salts and complexes thereof which possess fungicidal properties.
摘要翻译：其中A表示氮原子或CH基团的式“IMAGE”的2-酰氧基-1-噻唑基-3,3-二甲基-2-苯氧基 - 丁烷，R表示烷基，烯基，炔基，烷氧基，烷氧基烷基，环烷基，卤代烷基，任选取代的苯基，任选取代的苯基烷基，任选取代的苯氧基烷基，烷基氨基，二烷基氨基，任选取代的苯基氨基，卤代烷基氨基，烷氧基羰基氨基或烷氧基烷基氨基，X表示氢，卤素或烷基羰氧基，Y表示卤素或烷基羰基氧基，Z表示卤素，，环烷基，烷氧基，卤代烷基，烷硫基，烷氧基羰基，任选取代的苯基，任选取代的苯氧基，任选取代的苯基烷基，氰基或硝基，n表示0,1,2,3,4或5，取代基Z独立地选自 n为2以上时的另一种，以及具有杀真菌性的盐及其配合物。

29. 发明授权

US4232033A Combating fungi with diastereomeric form A of 1-phenoxy-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-ols 失效
标题翻译：将真菌与1-苯氧基-3,3-二甲基-1-（1,2,4-三唑-1-基） - 丁-2-醇的非对映体形式A
公开(公告)号：US4232033A
公开(公告)日：1980-11-04
申请号：US941832
申请日：1978-09-11
申请人： Wolfgang Kramer , Karl H. Buchel , Wolf-Dietrich Pflugbeil , Paul-Ernst Frohberger , Wilhelm Brandes
发明人： Wolfgang Kramer , Karl H. Buchel , Wolf-Dietrich Pflugbeil , Paul-Ernst Frohberger , Wilhelm Brandes
IPC分类号： A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Substantially pure diastereomeric form A of 1-phenoxy-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-ols of the formula ##STR1## in which X represents halogen, optionally substituted p- or m-phenyl, substituted o-phenyl, alkyl, alkoxycarbonyl or nitro, andn represents an integer from 1 to 5,which possess fungicidal properties.
摘要翻译：基本上纯的非对映异构体形式A，其中X表示卤素，可任意选择地具有式“IMAGE”的1-苯氧基-3,3-二甲基-1-（1,2,4-三唑-1-基） - 丁-2-醇取代的对 - 或间 - 苯基，取代的邻 - 苯基，烷基，烷氧基羰基或硝基，n表示1至5的整数，具有杀真菌性。

30. 发明授权

US4134988A 2-Acyloxy-1-phenoxy-1-imidazolyl-(1)-3,3-dimethyl-butanes 失效
标题翻译： 2-乙氧基-1-苯氧基-1-咪唑并 - （1）-3,3-二甲基 - 丁烷
公开(公告)号：US4134988A
公开(公告)日：1979-01-16
申请号：US763465
申请日：1977-01-28
申请人： Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01P3/00 , C07D233/60 , C07D521/00 , A61K31/415
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： 2-Acyloxy-1-phenoxy-1-imidazolyl-(1)-3,3-dimethylbutanes of the formula ##STR1## in which R is alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, optionally substituted phenyl or phenoxyalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,X is halogen, alkyl, cycloalkyl, alkoxy, haloalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl or phenoxy, optionally substituted phenylalkyl, amino, cyano or nitro, andN is 0 or an integer from 1 to 5,Or salts or metal salt complexes thereof, which possess fungicidal and bactericidal properties.

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