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21. 发明授权

US09505943B2 Aqueous bio-renewable vinyl polymer composition 有权
标题翻译：水性生物可再生乙烯基聚合物组合物
公开(公告)号：US09505943B2
公开(公告)日：2016-11-29
申请号：US13995738
申请日：2011-12-20
申请人： Gerardus Cornelis Overbeek , Tijs Nabuurs
发明人： Gerardus Cornelis Overbeek , Tijs Nabuurs
IPC分类号： C09D133/12 , C08F265/06 , C08L33/12 , C09D151/06 , C09J151/06 , C08L51/06 , C09D11/106 , C08F220/18
CPC分类号： C09D133/12 , C08F220/18 , C08F265/06 , C08L33/12 , C08L51/06 , C09D11/106 , C09D151/06 , C09J151/06 , C08L2666/04
摘要： An aqueous polymer coating composition comprising at least: a vinyl polymer A having a wt average molecular wt Mw within the range of from 1,000 to 150,000 g/mol and an acid value >5 mgKOH/g; and a vinyl polymer B having a molecular wt Mw of at least 80,000 g/mol and an acid value
摘要翻译：一种水性聚合物涂料组合物，其至少包含：重均分子量Mw在1,000至150,000g / mol且酸值> 5mgKOH / g的乙烯基聚合物A; 和分子量Mw为至少80,000g / mol，酸值<35mgKOH / g的乙烯基聚合物B; 其中I）用于形成聚合物A和聚合物B的烯属不饱和单体的重量％为5:70至95:30，加起来为100％; II）至少20wt％的聚合物A和/或聚合物B中的至少一种衍生自至少一种生物可再生的烯属不饱和单体。

22. 发明授权

US09012027B2 Aqueous emulsion 有权
标题翻译：水乳液
公开(公告)号：US09012027B2
公开(公告)日：2015-04-21
申请号：US13516452
申请日：2010-12-17
申请人： Tijs Nabuurs , Gerardus Cornelis Overbeek , Jeffrey Stubbs
发明人： Tijs Nabuurs , Gerardus Cornelis Overbeek , Jeffrey Stubbs
IPC分类号： C09D135/02 , C08F265/04 , C08F267/06 , C08L35/02 , C08F212/08 , C08F220/18 , C08F222/14
CPC分类号： C09D135/02 , C08F212/08 , C08F220/18 , C08F222/14 , C08F265/04 , C08F267/06 , C08F2220/1808 , C08F2220/1825 , C08F2220/1833 , C08L35/02 , Y10T428/31935 , C08L2666/04 , C08L2666/02
摘要： The invention relates to an aqueous emulsion comprising at least a vinyl polymer, said vinyl polymer comprising: a) 45 to 99 wt % of itaconate ester monomers having formula (I), wherein R and R′ are independently an alkyl or an aryl group; b) 0.1 to 15 wt % of ionic or potentially ionic unsaturated monomers; c) 0 to 54 wt % of unsaturated monomers, different from a) and b); and 0.9 to 54.9 wt % by weight of total monomers of a chaser monomer composition added subsequently and polymerized after the polymerization of monomers a), b) and c); wherein a)+b)+c) and the chaser monomer composition add up to 100%; and wherein the aqueous emulsion contains less than 0.5 wt % free itaconate ester monomers of formula I based on the total weight of the aqueous emulsion.
摘要翻译：本发明涉及包含至少一种乙烯基聚合物的水乳液，所述乙烯基聚合物包含：a）45至99重量％的具有式（I）的衣康酸酯单体，其中R和R'独立地为烷基或芳基; b）0.1至15重量％的离子或潜在的不饱和单体; c）0至54重量％的不饱和单体，不同于a）和b）; 和0.9至54.9重量％的随后添加的追踪单体组合物的单体的总单体，并且在单体a），b）和c）的聚合之后聚合; 其中a）+ b）+ c）和所述追踪单体组合物总计高达100％; 并且其中基于所述水性乳液的总重量，所述水性乳液含有小于0.5重量％的式I的游离的衣康酸酯单体。

23. 发明申请

US20140058031A1 AQUEOUS BIO-RENEWABLE VINYL POLYMER COMPOSITION 有权
标题翻译：水性生物可再生的乙烯基聚合物组合物
公开(公告)号：US20140058031A1
公开(公告)日：2014-02-27
申请号：US13995738
申请日：2011-12-20
申请人： Gerardus Cornelis Overbeek , Tijs Nabuurs
发明人： Gerardus Cornelis Overbeek , Tijs Nabuurs
IPC分类号： C09D133/12
CPC分类号： C09D133/12 , C08F220/18 , C08F265/06 , C08L33/12 , C08L51/06 , C09D11/106 , C09D151/06 , C09J151/06 , C08L2666/04
摘要： An aqueous polymer coating composition comprising at least: a vinyl polymer A having a wt average molecular wt Mw within the range of from 1,000 to 150,000 g/mol and an acid value >5 mgKOH/g; and a vinyl polymer B having a molecular wt Mw of at least 80,000 g/mol and an acid value
摘要翻译：一种水性聚合物涂料组合物，其至少包含：重均分子量Mw在1,000至150,000g / mol且酸值> 5mgKOH / g的乙烯基聚合物A; 和分子量Mw为至少80,000g / mol，酸值<35mgKOH / g的乙烯基聚合物B; 其中I）用于形成聚合物A和聚合物B的烯属不饱和单体的重量％为5:70至95:30，加起来为100％; II）至少20wt％的聚合物A和/或聚合物B中的至少一种衍生自至少一种生物可再生烯烃不饱和单体。

24. 发明授权

US07247671B2 Aqueous crosslinkable coating compositions based on vinyl fluoropolymer 失效
标题翻译：基于乙烯基含氟聚合物的水性交联涂料组合物
公开(公告)号：US07247671B2
公开(公告)日：2007-07-24
申请号：US10485572
申请日：2002-07-22
申请人： Gerardus Cornelis Overbeek , Jurgen Scheerder , Tijs Nabuurs
发明人： Gerardus Cornelis Overbeek , Jurgen Scheerder , Tijs Nabuurs
IPC分类号： C08F8/00 , C08G63/91 , C08G63/48 , C08J3/02 , C08L27/12
CPC分类号： C09D175/04 , C08G18/4833 , C08G18/6279 , C08G18/706 , C08L61/20 , C09D133/16 , C08L2666/14
摘要： Aqueous crosslinkable coating composition suitable for anti-graffiti and heavy duty applications comprising: (A) an aqueous polymer emulsion comprising at least one vinyl fluoropolymer which comprises as a polymerized constituent monomer thereof (i) a fluoromonomer(s) having the formula (1) wherein R1 is CH3 or H, R2 is a per-fluorinated C1-5 alkyl group and n is 1, 2, 3 or 4, (ii) a hydroxyl functional monomer(s) and (iii) a carboxylic acid-functional monomer(s) where the vinyl fluoropolymer has a glass transition temperature Tg within the range of from −50 to 90° C. and (B) at least one hydroxyl-reactive crosslinker material
摘要翻译：适用于防涂鸦和重载应用的水性交联涂料组合物包括：（A）包含至少一种乙烯基含氟聚合物的水性聚合物乳液，其包含作为其聚合构成单体的（i）具有式（1）的含氟单体，其中R 1是CH 3或H，R 2是全氟化的C 1-5烷基和n为1,2,3或4，（ii）羟基官能单体和（iii）羧酸官能单体，其中所述乙烯基含氟聚合物的玻璃化转变温度Tg为 - 50至90℃，和（B）至少一种羟基反应性交联剂材料

25. 发明授权

US07144945B2 Aqueous coating composition comprising non-crosslinkable oligomer(s) and dispersed polymer(s) 有权
标题翻译：包含不可交联的低聚物和分散的聚合物的水性涂料组合物，
公开(公告)号：US07144945B2
公开(公告)日：2006-12-05
申请号：US10509223
申请日：2003-03-21
申请人： Emilio Martin , Jurgen Scheerder , Gerardus Cornelis Overbeek , Ronald Tennebroek , Tijs Nabuurs , Pablo Steenwinkel
发明人： Emilio Martin , Jurgen Scheerder , Gerardus Cornelis Overbeek , Ronald Tennebroek , Tijs Nabuurs , Pablo Steenwinkel
IPC分类号： C08K3/20
CPC分类号： C09D167/00 , C09D175/04 , C08L2666/04
摘要： An aqueous coating composition containing a non-crosslinkable water-dispersible oligomer(s); a dispersed polymer(s); water and optionally co-solvent wherein the composition has an open time of at least 20 minutes; a wet edge time of at least 10 minutes; a tack free time of ≦24 hours and an equilibrium viscosity of 5,000 Pa·s.
摘要翻译：含有不可交联的水分散性低聚物的水性涂料组合物; 分散的聚合物; 水和任选的共溶剂，其中组合物的开放时间为至少20分钟; 湿边缘时间至少10分钟; 无粘性时间<= 24小时，平衡粘度为5000帕。

26. 发明申请

US20140065435A1 BIO-RENEWABLE SEQUENTIAL VINYL POLYMER 有权
标题翻译：生物可再生顺序的乙烯基聚合物
公开(公告)号：US20140065435A1
公开(公告)日：2014-03-06
申请号：US13995660
申请日：2011-12-20
申请人： Gerardus Cornelis Overbeek
发明人： Gerardus Cornelis Overbeek
IPC分类号： C09D133/06
CPC分类号： C09D133/06 , C08F265/06 , C08L33/12 , C08L51/06 , C08L2201/06 , C09D5/02 , C09D11/106 , C09D133/12 , C09D151/06 , C09J151/06 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , C08L2666/04 , C08F2/08
摘要： An aqueous polymer dispersion comprising a vinyl polymer with at least two phases comprising: A) 40 to 90 wt % of a vinyl polymer A having a glass transition temperature in the range of from −50 to 30° C.; and B) 10 to 60 wt % of a vinyl polymer B having a glass transition temperature the range of from 50 to 130° C.; wherein vinyl polymer A comprises 0.1 to 10 wt % of at least one acid-functional olefinically unsaturated monomer, wherein at least 20 wt % of the monomer composition used to form vinyl polymer A and vinyl polymer B is derived from at least one bio-renewable olefinically unsaturated monomer.
摘要翻译：一种包含具有至少两相的乙烯基聚合物的含水聚合物分散体，其包含：A）40至90重量％的玻璃化转变温度为-50至30℃的乙烯基聚合物A; 和B）10〜60重量％的玻璃化转变温度为50〜130℃的乙烯基聚合物B。其中乙烯基聚合物A包含0.1至10重量％的至少一种酸官能的烯属不饱和单体，其中用于形成乙烯基聚合物A和乙烯基聚合物B的单体组合物的至少20重量％衍生自至少一个生物可再生的烯属不饱和单体。

27. 发明授权

US08337955B2 Aqueous coating composition comprising an autoxidisable amide group containing resin 有权
标题翻译：含有可自动氧化的含酰胺基的树脂的水性涂料组合物
公开(公告)号：US08337955B2
公开(公告)日：2012-12-25
申请号：US12919263
申请日：2009-03-31
申请人： Ronald Tennebroek , Gerardus Cornelis Overbeek , Michel Johannes Jan Ruts , Franciscus Adrianus Cornelis Bergman
发明人： Ronald Tennebroek , Gerardus Cornelis Overbeek , Michel Johannes Jan Ruts , Franciscus Adrianus Cornelis Bergman
IPC分类号： B05D3/02
CPC分类号： C08G18/36 , C08G18/606 , C08G18/755 , C08G73/14 , C09D175/04 , C09D179/08
摘要： An aqueous coating composition comprising an autoxidisable amide group containing resin having ≧30 wt % of fatty acid residues by weight of autoxidisable amide group containing resin; a Tg in the range of from −40 to +35° C.; ND×AV≦22 mg KOH/g; a Mw in the range of from 2,500 to 20,000 g/mol; a PDi less than 10; an amide group content of at least 10 mmoles/100 g solid; and said composition having: a co-solvent content less that 25 wt %; a N-methylpyrrolidone content 38 wt %; and when a film, a telegraphing value of less than 20 gloss units.
摘要翻译：一种水性涂料组合物，其包含可自动氧化的含酰胺基团的树脂，其具有≥30重量％的可自动氧化的含酰胺基树脂的脂肪酸残基; 在-40至+ 35℃范围内的Tg。 ND×AV＆nlE; 22mg KOH / g; 在2500至20,000g / mol范围内的Mw; PDi小于10; 至少10毫摩尔/ 100克固体的酰胺基含量; 并且所述组合物具有：小于25重量％的助溶剂含量; N-甲基吡咯烷酮含量<13重量％的固体; 固含量> 38wt％; 而当一部电影，电报值小于20光泽单位。

28. 发明申请

US20110091653A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：US20110091653A1
公开(公告)日：2011-04-21
申请号：US12920386
申请日：2009-03-31
申请人： Gerardus Cornelis Overbeek , Ilse Van Casteren , Ronald Tennebroek , Jelle Bernardus Otto Van Der Werf
发明人： Gerardus Cornelis Overbeek , Ilse Van Casteren , Ronald Tennebroek , Jelle Bernardus Otto Van Der Werf
IPC分类号： B05D3/02 , C08L63/00 , C08G59/00
CPC分类号： C09D133/14 , C08F8/14 , C08F8/44 , C08F220/28 , C08F220/32 , C08F2810/30 , C08F2810/50 , C09D133/068 , Y10T428/31855 , C08F120/06 , C08F2220/325 , C08F220/14 , C08F2220/1825 , C08F212/08
摘要： There is described (pref. non-adhesive) coating compositions (which may be either water or solvent borne) that comprise an autoxidisable vinyl polymer, the autoxidisable polymer having a vinyl polymer backbone 25% to 75% by wt of the autoxidisable polymer; fatty acid residue 25% to 75% by wt of the autoxidisable polymer; Tg from −6O° C. to +2O° C., Mw from 3500 to 50000 g/mol; and polydispersity from 2 to 10; the autoxidisable polymer obtained by a process of: (A) polymerising ethylenically unsaturated vinyl monomers comprising: at least one epoxy functional vinyl monomer 15% to 100% by wt total monomers in (A); 0 to 85% of at least one other ethylenically unsaturated vinyl monomer, (preferably other than styrenic monomers) by wt total monomers in (A); (B) reacting the epoxy functional polymer from (A) with fatty acids having an average iodine value from 30 to 250 g I2/100 g fatty acid; where composition has: a) a opt. co-solvent content ≦40% by wt of the composition; b) a solids content either ≧30% (aqueous) ≧60% (solvent based) by wt of the composition, the composition as a coating film having a telegraphing value of less than 10 gloss units (difference between an initial smooth gloss minus an initial rough gloss of the film).
摘要翻译：描述了包含可自动氧化的乙烯基聚合物的（优先非粘性）涂料组合物（其可以是水或溶剂载体），所述可自动氧化聚合物具有25重量％至75重量％的可自动氧化聚合物的乙烯基聚合物主链; 脂肪酸残基25％至75％重量的可自动氧化聚合物; Tg为-60℃至+ 20℃，Mw为3500至50000g / mol; 多分散性为2〜10; 通过以下方法获得的可自动氧化聚合物：（A）烯键式不饱和乙烯基单体的聚合，包括：（A）中至少一种15重量％至100重量％的单体的至少一种环氧官能乙烯基单体; 0至85％的（A）中的总单体的至少一种其它烯属不饱和乙烯基单体（优选不同于苯乙烯类单体）; （B）使来自（A）的环氧官能聚合物与平均碘值为30-250g I2 / 100g脂肪酸的脂肪酸反应; 其中组合有：a）选择。共溶剂含量＆nlE; 40重量％的组合物; b）以组合物重量计≥30％（水性）≥30％（水性）≥60％（溶剂基）的固体含量，具有小于10个光泽单位的透印值的涂膜的组成（初始平滑光泽度减去初始粗糙的光泽度）。

29. 发明申请

US20110064956A1 LOW NWP AQUEOUS POLYURETHANE COMPOSITION 失效
标题翻译：低NWP水性聚氨酯组合物
公开(公告)号：US20110064956A1
公开(公告)日：2011-03-17
申请号：US12943903
申请日：2010-11-10
申请人： Ilse Casteren Van , Marc Roelands , Gerardus Cornelis Overbeek , Ronald Tennebroek
发明人： Ilse Casteren Van , Marc Roelands , Gerardus Cornelis Overbeek , Ronald Tennebroek
IPC分类号： C08K5/3415 , B32B27/06 , B32B15/095 , B32B17/10 , B32B27/08 , B32B27/40
CPC分类号： C08G18/0823 , C08G18/0852 , C08G18/12 , C08G18/283 , C08G18/6692 , C08G18/724 , C08G18/7607 , C08L33/10 , C08L75/04 , Y10T428/31551 , Y10T428/31591 , Y10T428/31598 , Y10T428/31601 , Y10T428/31605 , Y10T428/31609 , C08G18/3231 , C08L2666/04
摘要： An aqueous composition with a sediment content ≦5%, comprising a polyurethane dispersion wherein the polyurethane has an acid value in the range of from 25 to 65 mgKOH/g and comprises (i) 36 to 60 wt % of at least one aromatic polyisocyanate and where the polyurethane is prepared in the presence of (a) ≦5 wt % of 1-methyl-2-pyrrolidinone by weight of the polyurethane, (b) 5 to 100 wt % of 1-ethyl-2-pyrrolidinone by weight of polyurethane and (c) water.
摘要翻译：含有沉淀物含量的水性组合物，其含量为5％，包括聚氨酯分散体，其中所述聚氨酯的酸值在25至65mgKOH / g范围内，并且包含（i）36至60wt％的至少一种芳族多异氰酸酯（a）＆nlE; 5重量％的1-甲基-2-吡咯烷酮占聚氨酯重量的情况下制备聚氨酯，（b）按重量计5-100重量％的1-乙基-2-吡咯烷酮的聚氨酯和（c）水。

30. 发明授权

US06992121B1 Aqueous, polymodal, multistage polymer emulsions 有权
标题翻译：水性，多模态，多级聚合物乳液
公开(公告)号：US06992121B1
公开(公告)日：2006-01-31
申请号：US10130479
申请日：2000-11-16
申请人： Antonius Carolus Ida Adrianus Peters , Gerardus Cornelis Overbeek
发明人： Antonius Carolus Ida Adrianus Peters , Gerardus Cornelis Overbeek
IPC分类号： C08L51/00 , C08K9/00
CPC分类号： C08F285/00 , C08F2/22 , C09D151/00
摘要： Aqueous emulsion of a polymodal multistage polymeric material, wherein: (i) at least 50% of the polymodal multistage polymeric material comprises the polymers of at least two polymerisation stages having a Tg difference of ≧20° C., more preferably ≧40° C., and most preferably ≧60° C.; (ii) at least 50% of the polymodal multistage polymeric material comprises the polymers of at least two polymerisation stages having a Dw differing by ≧50 nm, preferably ≧80 nm and more preferably ≧100 nm; and (iii) the means to form at least one of the differing Tg's in (i) and at least one of the differing Dw's in (ii) are carried out in different stages of the multistage polymerisation to form the polymeric material. The polymer emulsion is useful for protective coatings, printing inks, overprint lacquer formulations, polishes, varnishes, sealants, paint formulations and adhesives.
摘要翻译：多模态多级聚合物材料的水性乳液，其中：（i）至少50％的多模态多级聚合物材料包含Tg差≥20℃，更优选> = 40的至少两个聚合阶段的聚合物 ℃，最优选> = 60℃。（ii）至少50％的多模态多级聚合物材料包含至少两个聚合阶段的聚合物，其中Dw具有> = 50nm，优选> = 80nm，更优选> = 100nm; 和（iii）在（i）中形成不同Tg的至少一种和（ii）中不同Dw中的至少一种的方法在多段聚合的不同阶段中进行以形成聚合物材料。聚合物乳液可用于保护涂料，印刷油墨，套印漆配方，抛光剂，清漆，密封剂，涂料配方和粘合剂。

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