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21. 发明授权

US4675442A Method of making methacrylamides 失效
标题翻译：制备甲基丙烯酰胺的方法
公开(公告)号：US4675442A
公开(公告)日：1987-06-23
申请号：US709343
申请日：1985-03-06
申请人： Siegmund Besecke , Guenter Schroeder
发明人： Siegmund Besecke , Guenter Schroeder
IPC分类号： C07B61/00 , B01J31/00 , B01J31/02 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/02 , C07C233/09 , C07C233/38 , C07C102/06
CPC分类号： C07C231/02
摘要： What is disclosed is a method for making an amide of acrylic acid or of methacrylic acid by the reaction of an alkyl ester of acrylic acid or of methacrylic acid with an amine at a temperature between 50.degree. C. and 180.degree. C., whereby the reaction with the amine is carried out in the presence of a catalytic amount of a compound of a metal of Group IVB of the periodic table of the elements or of a compound of lead, zinc, or tantalum.
摘要翻译：公开的是通过丙烯酸或甲基丙烯酸的烷基酯与胺在50℃至180℃的温度下反应制备丙烯酸或甲基丙烯酸的酰胺的方法，其中与胺的反应在催化量的元素周期表第IVB族金属化合物或铅，锌或钽化合物的存在下进行。

22. 发明授权

US4492805A Polyarylene ethers containing phosphorus 失效
标题翻译：含聚磷脂的聚亚芳基醚
公开(公告)号：US4492805A
公开(公告)日：1985-01-08
申请号：US461037
申请日：1983-01-26
申请人： Siegmund Besecke , Gunter Schroder , Werner Ude , Winfried Wunderlich
发明人： Siegmund Besecke , Gunter Schroder , Werner Ude , Winfried Wunderlich
IPC分类号： C08G79/00 , C08G65/00 , C08G65/38 , C08G65/40 , C08G75/23 , C08G79/02 , C07F9/50 , C07F9/53
CPC分类号： C08G75/23 , C08G65/38 , C08G65/4006
摘要： Difficultly flammable polyarylene ether resins containing phosphorus having the structure ##STR1## and methods for making the same.
摘要翻译：含有结构“IMAGE”的磷的易燃易燃聚芳醚树脂及其制造方法。

23. 发明授权

US4373056A Aqueous artificial resin dispersions free of emulsifying agents 失效
标题翻译：水性人造树脂分散体不含乳化剂
公开(公告)号：US4373056A
公开(公告)日：1983-02-08
申请号：US295544
申请日：1981-08-24
申请人： Siegmund Besecke , Herbert Fink , Norbert Sutterlin , Gerhard Markert , Gunter Schroder , Willi Tilch
发明人： Siegmund Besecke , Herbert Fink , Norbert Sutterlin , Gerhard Markert , Gunter Schroder , Willi Tilch
IPC分类号： C08L33/00 , C08F2/22 , C08F220/58 , C08F246/00 , C08L33/02 , C08L33/04 , C08L41/00
CPC分类号： C08F246/00 , C08F220/58
摘要： An aqueous artificial resin dispersion, comprising an aqueous phase and a water-insoluble disperse phase formed from particles containing a copolymer formed in substantial part from a water insoluble or slightly soluble first monomer, wherein the copolymer additionally is formed from a second monomer of the formula ##STR1## wherein R represents hydrogen or methyl, R' represents hydrogen or an alkyl radical with 1 to 12 C-atoms, R" represents an alkyl radical with 7 to 20 C-atoms, and M represents a proton, an alkali metal ion, or an ammonium ion, with the proviso that the aqueous phase is free of low molecular weight, ionic emulsifying agents. Such dispersions are particularly well suited for continuous emulsion polymerization because of the highly stable monomer emulsions formed by mixtures produced according to the invention.
摘要翻译：一种水性人造树脂分散体，其包含水相和由非水溶性或微溶性第一单体形成的含有共聚物的颗粒形成的水不溶性分散相，其中所述共聚物另外由式其中R表示氢或甲基，R'表示氢或具有1至12个C原子的烷基，R“表示具有7至20个碳原子的烷基，M表示质子，碱金属离子或铵离子，条件是水相不含低分子量离子乳化剂。由于由根据本发明制备的混合物形成的高度稳定的单体乳液，这种分散体特别适用于连续乳液聚合。

24. 发明授权

US4652656A UV-absorbing monomer and polymers thereof 失效
标题翻译：紫外线吸收单体及其聚合物
公开(公告)号：US4652656A
公开(公告)日：1987-03-24
申请号：US851254
申请日：1986-04-14
申请人： Siegmund Besecke , Ralf Liebler , Heinz-Juergen Hohage , Guenter Schroeder
发明人： Siegmund Besecke , Ralf Liebler , Heinz-Juergen Hohage , Guenter Schroeder
IPC分类号： C08F20/00 , C07D249/20 , C08F20/52 , C08F20/60 , C08K5/3475 , C07D249/16
CPC分类号： C07D249/20 , C08K5/3475
摘要： UV absorbing compounds, susceptible to free-radical polymerization, of the formula ##STR1## wherein R is alkyl having from 4 to 12 carbon atoms of which not more than 6 are present in a linear chain, and in particular2-(2'-hydroxy-3'-methacrylamidomethyl-5'-tert-octylphenyl)benzotriazole, and polymers thereof.
摘要翻译：其中R为具有4至12个碳原子的烷基，其中不超过6个的式为“IMAGE”的易于自由基聚合的紫外线吸收化合物存在于线性链中，特别是2-（2'- 羟基-3'-甲基丙烯酰胺基甲基-5'-叔辛基苯基）苯并三唑及其聚合物。

25. 发明授权

US4576870A Method for making multilayered resin bodies having UV-protection and the resultant products 失效
标题翻译：制造具有紫外线保护性的多层树脂体的方法和所得产物
公开(公告)号：US4576870A
公开(公告)日：1986-03-18
申请号：US594326
申请日：1984-03-28
申请人： Ralf Liebler , Siegmund Besecke , Manfred Munzer
发明人： Ralf Liebler , Siegmund Besecke , Manfred Munzer
IPC分类号： B32B37/00 , B29B7/00 , B29C47/00 , B29C47/06 , B29C63/00 , B29K105/00 , B29L9/00 , B32B27/08 , B32B27/36 , B32B37/15 , B32B31/30
CPC分类号： B32B27/08 , Y10T428/31507 , Y10T428/31909
摘要： A method for making multilayered synthetic resin bodies by the coextrusion of thermoplastic molding compounds wherein at least one of the layers in the extruded body is to be protected against UV light, which comprises extruding at least one layer from a thermoplastic molding compound that is formed entirely or predominantly of a copolymer formed between monomers comprising in their molecules groups or structures which, because of their characteristic absorption of ultraviolet light, provide protection against ultraviolet light, together with other, known, monomers.
摘要翻译：通过热塑性模塑料的共挤出制备多层合成树脂体的方法，其中挤出体中的至少一层被保护免受紫外光的侵害，其包括从完全形成的热塑性模塑料中挤出至少一层或主要是由在其分子基团或结构中形成的共聚物之间形成的共聚物，其由于它们的紫外光的特征吸收而与其它已知的单体一起提供了防紫外线的保护。

26. 发明授权

US4504675A Method for making isobutyric acid or esters thereof 失效
标题翻译：制备异丁酸或其酯的方法
公开(公告)号：US4504675A
公开(公告)日：1985-03-12
申请号：US436467
申请日：1982-10-25
申请人： Siegmund Besecke , Hermann-Josef Siegert , Gunter Schroder
发明人： Siegmund Besecke , Hermann-Josef Siegert , Gunter Schroder
IPC分类号： C07C67/38 , C07C51/00 , C07C51/14 , C07C53/124 , C07C67/00 , C07C69/22
CPC分类号： C07C51/14 , C07C67/38
摘要： What is disclosed is a process for the continuous production of isobutyric acid or an alkyl ester thereof by the Koch synthesis, which process comprises reacting propylene, carbon monoxide, and water or an alkanol in the presence of hydrogen fluoride in at least one reaction space containing a liquid phase and a gas phase under high pressure, releasing said pressure at least partially, whereby a gas containing organic compounds from said synthesis evolves from said liquid phase, adding oxygen to said evolved gas and at least partially combusting the organic compounds contained therein, then contacting the evolved gas containing the at least partially combusted organic compounds with at least a portion of the water or alkanol to be reacted with said propylene and carbon monoxide, whereby at least a portion of said combusted organic compounds are absorbed by said water or alkanol, returning said water or alkanol containing the absorbed combusted organic compounds to said reaction space, and discharging any unabsorbed gas from the reaction system.
摘要翻译：所公开的是通过Koch合成连续生产异丁酸或其烷基酯的方法，该方法包括使丙烯，一氧化碳和水或链烷醇在氟化氢存在下在至少一个含有在高压下的液相和气相，至少部分地释放所述压力，由此来自所述合成的含有有机化合物的气体从所述液相中放出，向所述放出的气体中加入氧气并且至少部分地燃烧其中所含的有机化合物，然后将含有至少部分燃烧的有机化合物的进化气体与要与所述丙烯和一氧化碳反应的水或链烷醇的至少一部分接触，由此所述燃烧的有机化合物的至少一部分被所述水或链烷醇吸收将含有所吸收的燃烧的有机化合物的所述水或链烷醇返回到所述反应空间，并从反应系统排出任何未吸收的气体。

27. 发明授权

US4452999A Method for making isobutyric acid 失效
标题翻译：制备异丁酸的方法
公开(公告)号：US4452999A
公开(公告)日：1984-06-05
申请号：US380609
申请日：1982-05-21
申请人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
发明人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
IPC分类号： C07C51/14 , C07C67/38
CPC分类号： C07C51/14 , C07C67/38
摘要： What is disclosed is a continuous one-step method for the preparation of isobutyric acid or a lower alkyl ester thereof by the Koch synthesis, which method comprises reacting propylene, carbon monoxide, and water or a lower alcohol, in the gaseous and liquid phases, in the presence of hydrogen fluoride as a Koch catalyst, at a temperature between 80.degree. C. and 160.degree. C., at a dwell time of the liquid phase of less than 20 minutes, and with a high degree of backmixing, while maintaining the content of propylene in the reaction mixture at less than one percent by weight of the liquid phase, wherein all or part of the propylene, carbon monoxide, and water or lower alcohol can be replaced by binary addition compounds formed pairwise between these materials. In the alternative, isopropylformiate can be continuously rearranged in the presence of hydrogen fluoride to produce isobutyric acid.
摘要翻译：所公开的是通过Koch合成制备异丁酸或其低级烷基酯的连续一步法，该方法包括在气相和液相中使丙烯，一氧化碳和水或低级醇反应，在作为Koch催化剂的氟化氢的存在下，在80℃至160℃的温度下，在液相的停留时间小于20分钟，并具有高度的回混，同时保持反应混合物中丙烯的含量小于液相的1重量％，其中全部或部分丙烯，一氧化碳和水或低级醇可以由在这些材料之间成对形成的二元加成化合物代替。在替代方案中，异丙基甲酸酯可以在氟化氢的存在下连续重排以产生异丁酸。

28. 发明授权

US5300601A Suspension polymers based on methyl methacrylate 失效
标题翻译：基于甲基丙烯酸甲酯的悬浮聚合物
公开(公告)号：US5300601A
公开(公告)日：1994-04-05
申请号：US801293
申请日：1991-12-02
申请人： Siegmund Besecke , Wilfried Schoen , Karl-Ludwig Endlich
发明人： Siegmund Besecke , Wilfried Schoen , Karl-Ludwig Endlich
IPC分类号： C08F2/02 , C08F2/18 , C08F4/28 , C08F4/32 , C08F4/38 , C08F20/10 , C08F20/14 , C08F4/36
CPC分类号： C08F20/14
摘要： Suspension polymers ofa) from 80 to 100% by weight of methyl methacrylate andb) from 0 to 20% by weight of further monomers capable of undergoing free radical polymerization,are obtainable by polymerization at a temperature of from 100.degree. to 140.degree. C. which is virtually constant over the major part of the polymerization time by means of an initiator system consisting of two or more peroxide initiators I having different decomposition temperatures T at which in each case half of the initiator has decomposed after 1 hour, whereinthe initiator I.sub.min having the lowest decomposition temperature has a decomposition temperature T.sub.min of from 60.degree. to 100.degree. C.,the initiator I.sub.max having the highest decomposition temperature has a decomposition temperature T.sub.max of from 100.degree. to 140.degree. C., the difference between T.sub.max and T.sub.min is greater than 10.degree. C. and I.sub.max is a perketal of the general formula (1) ##STR1## where R.sup.1 and R.sup.2 are identical or different alkyl radicals of 1 to 5 carbon atoms and R.sup.1 and R.sup.2 may be bonded to form a 5-membered or 6-membered ring and R.sup.3 is tert-butyl or tert-amyl, andfurther initiators I.sub.n which, if desired, may be concomitantly used have decomposition temperatures T.sub.n of from T.sub.min to T.sub.max.
摘要翻译： a）80至100重量％的甲基丙烯酸甲酯和b）0至20重量％的能够进行自由基聚合的其它单体的悬浮聚合物可通过在100-140℃的温度下聚合获得其通过由两种或更多种具有不同分解温度T的过氧化物引发剂组成的引发剂体系在聚合时间的主要部分上几乎恒定，其中在每种情况下，引发剂的一半在1小时后分解，其中引发剂具有最低分解温度的Imin具有60至100℃的分解温度Tmin，具有最高分解温度的引发剂Imax的分解温度Tmax为100-140℃，Tmax和Tmin之间的差大于10摄氏度，而Imax为通式（1）（*化学结构*）（1）的庚缩醛，其中R1和R2相同或不同的1至5个碳原子的烷基，并且R 1和R 2可以键合以形成5元或6元环，并且R 3是叔丁基或叔戊基，以及其它引发剂，其中如果需要，可以是同时使用的分解温度Tn从Tmin到Tmax。

29. 发明授权

US4698448A Method for making aromatic phosphorus compounds 失效
标题翻译：制备芳香族磷化合物的方法
公开(公告)号：US4698448A
公开(公告)日：1987-10-06
申请号：US751625
申请日：1985-07-02
申请人： Werner Ude , Siegmund Besecke , Achim Riemann , Guenther Schroeder
发明人： Werner Ude , Siegmund Besecke , Achim Riemann , Guenther Schroeder
IPC分类号： B01J27/00 , C07B61/00 , C07F9/50 , C07F9/53 , C08G79/04 , C08G79/06
CPC分类号： C08G79/06 , C07F9/5068 , C07F9/5325 , C08G79/04
摘要： Compounds of the formula ##STR1## wherein R is lower alkyl or aryl, Y is oxygen or sulfur, m is 0 or 1, Ar is arylene, and X is halogen, methyl, or aryloxy, or polymers containing repeating units of this kind are prepared from a compound R--P(Y).sub.r Cl.sub.2, where r is 0 or 1 but is never greater than m, by reaction with one or two molar parts of a compound H--ArX in the presence of a Friedel-Crafts catalyst.
摘要翻译：其中R是低级烷基或芳基，Y是氧或硫，m是0或1，Ar是亚芳基，X是卤素，甲基或芳氧基，或含有这种重复单元的聚合物的式在一种Friedel-Crafts催化剂的存在下，通过与一个或两个摩尔份的化合物H-ArX反应，由化合物RP（Y）rCl 2制备，其中r为0或1，但不得大于m。

30. 发明授权

US4647696A Method for making isobutyric acid 失效
标题翻译：制备异丁酸的方法
公开(公告)号：US4647696A
公开(公告)日：1987-03-03
申请号：US474799
申请日：1983-03-14
申请人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
发明人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
IPC分类号： C07C51/14 , C07C67/38 , C07B53/00 , C07C53/124
CPC分类号： C07C51/14 , C07C67/38
摘要： What is disclosed is a continuous one-step method for the preparation of isobutyric acid or a lower alkyl ester thereof by the Koch synthesis, which method comprises reacting propylene, carbon monoxide, and water or a lower alcohol, in the gaseous and liquid phases, in the presence of hydrogen fluoride as a Koch catalyst, at a temperature between 80.degree. C. and 160.degree. C., at a dwell time of the liquid phase of less than 20 minutes, and with a high degree of backmixing, while maintaining the content of propylene in the reaction mixture at less than one percent by weight of the liquid phase, wherein all or part of the propylene, carbon monoxide, and water or lower alcohol can be replaced by binary addition compounds formed pairwise between these materials. In the alternative, isopropylformiate can be continuously rearranged in the presence of hydrogen fluoride to produce isobutyric acid.
摘要翻译：所公开的是通过Koch合成制备异丁酸或其低级烷基酯的连续一步法，该方法包括在气相和液相中使丙烯，一氧化碳和水或低级醇反应，在作为Koch催化剂的氟化氢的存在下，在80℃至160℃的温度下，在液相的停留时间小于20分钟，并具有高度的回混，同时保持反应混合物中丙烯的含量小于液相的1重量％，其中全部或部分丙烯，一氧化碳和水或低级醇可以由这些材料成对形成的二元加成化合物代替。在替代方案中，异丙基甲酸酯可以在氟化氢的存在下连续重排以产生异丁酸。

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