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21. 发明授权

US08236727B2 Oxygen-absorbing resin composition and oxygen-absorbing container comprising the same 有权
标题翻译：含氧吸收性树脂组合物和含有该吸收性氧吸收性树脂组合物的吸氧性容器
公开(公告)号：US08236727B2
公开(公告)日：2012-08-07
申请号：US12812931
申请日：2009-01-19
申请人： Yoshihiro Ohta , Yui Yamaguchi , Yoichi Ishizaki
发明人： Yoshihiro Ohta , Yui Yamaguchi , Yoichi Ishizaki
IPC分类号： B01J20/26
CPC分类号： C08L23/0869 , C08L23/02 , C08L23/06 , C08L23/0861 , C08L23/0892 , C08L29/02 , C08L51/06 , C08L67/00 , C08L2205/08 , C08L2207/066 , C08L2666/02 , C08L2666/06 , C08L2666/18
摘要： An oxygen-absorbing resin composition having excellent performance is provided which contains an oxygen-absorbing polyester and a polyolefin and has enhanced compatibility between the polymers to give an oxygen-absorbing layer inhibited from having a reduced cohesive force or an appearance failure such as roughness unevenness. The oxygen-absorbing resin composition is characterized by being obtained by melt-kneading the following ingredients (A) and (B) together with the following ingredient (C) as a compatibilizing agent. Ingredient (A): an oxygen-absorbing polyester; Ingredient (B): a polyolefin; and Ingredient (C): a copolymer of ethylene and a vinyl monomer having a hydroxy group or an ester bond, the copolymer having an ethylene proportion of 70-99 mol %.
摘要翻译：提供了具有优异性能的氧吸收性树脂组合物，其含有吸氧聚酯和聚烯烃，并且具有增强的聚合物之间的相容性，从而使抑制的氧吸收层具有降低的内聚力或外观破坏如粗糙度不均匀。氧吸收性树脂组合物的特征在于通过以下成分（A）和（B）与作为相容剂的以下成分（C）一起熔融捏合而得到。成分（A）：吸氧聚酯; 成分（B）：聚烯烃; 和成分（C）：乙烯与具有羟基或酯键的乙烯基单体的共聚物，所述共聚物的乙烯比例为70-99摩尔％。

22. 发明授权

US08216651B2 Plastic multi-layer structure 有权
标题翻译：塑料多层结构
公开(公告)号：US08216651B2
公开(公告)日：2012-07-10
申请号：US11507087
申请日：2006-08-18
申请人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
发明人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
IPC分类号： B32B1/06 , B32B1/08 , B32B1/00
CPC分类号： B32B27/08 , B32B25/08 , B32B25/16 , B32B27/18 , B32B27/302 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2264/102 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/7244 , B32B2307/74 , B32B2439/46 , B32B2439/70 , Y10T428/1314 , Y10T428/1317 , Y10T428/1321 , Y10T428/1352
摘要： The present invention herein provides a plastic multi-layer structure which comprises an oxygen-barrier layer (A-1), an oxygen absorptive layer (B), and a thermoplastic resin layer (C) containing a high silica type zeolite material having a silica/alumina ratio of not less than 80; and a packaging material such as bottles for accommodating foods, for instance, a beverage and medical and pharmaceutical products. The plastic multi-layer structure possesses oxidation-barrier characteristics and the structure would permit the considerable reduction of the quantity of the oxidation by-products generated from the structure, even when used under a high humidity atmosphere.
摘要翻译：本发明提供一种塑料多层结构，其包括氧阻隔层（A-1），氧吸收层（B）和含有二氧化硅的高二氧化硅型沸石材料的热塑性树脂层（C） /氧化铝比不小于80; 以及诸如用于容纳食物的瓶子的包装材料，例如饮料和医药产品。塑料多层结构具有氧化屏障特性，即使在高湿度环境下使用时，结构也能大大减少由结构产生的氧化副产物的量。

23. 发明申请

US20120001121A1 Oxygen-absorbable Solvent-soluble Resin and Oxygen-absorbable Adhesive Resin Composition 有权
标题翻译：可吸收氧化物的溶剂树脂和吸氧性粘合剂树脂组合物
公开(公告)号：US20120001121A1
公开(公告)日：2012-01-05
申请号：US13255057
申请日：2010-03-08
申请人： Yoichi Ishizaki , Yoshihiro Ohta , Yui Yamaguchi
发明人： Yoichi Ishizaki , Yoshihiro Ohta , Yui Yamaguchi
IPC分类号： C09K3/00 , C08G63/553
CPC分类号： C08G63/183 , C09J167/02 , Y02E60/324
摘要： Disclosed is an oxygen-absorbable solvent-soluble resin having both oxygen absorbability and adhesive properties. Specifically disclosed is an oxygen-absorbable solvent-soluble resin which comprises an acid component (A), an acid component (B) and a polyester having a constituent unit derived from a glycol component, wherein the ratio of the amount of the acid component (A) to the total amount of the acid components is 40 to 80 mol % and the ratio of the amount of the acid component (B) to the total amount of the acid components is 15 to 35 mol %. The acid component (A): tetrahydrophthalic acid or a derivative thereof, or tetrahydrophthalic anhydride or a derivative thereof; and the acid component (B): terephthalic acid.
摘要翻译：公开了具有氧吸收性和粘合性的氧吸收性溶剂可溶性树脂。具体公开的是可吸收氧化物的溶剂可溶性树脂，其包含酸组分（A），酸组分（B）和具有源自二醇组分的构成单元的聚酯，其中酸组分 A）相对于酸成分的总量为40〜80摩尔％，酸成分（B）与酸成分总量的比例为15〜35摩尔％。酸成分（A）：四氢邻苯二甲酸或其衍生物，或四氢邻苯二甲酸酐或其衍生物; 和酸成分（B）：对苯二甲酸。

24. 发明授权

US07709567B2 Oxygen-absorbing resin composition 有权
标题翻译：吸氧树脂组合物
公开(公告)号：US07709567B2
公开(公告)日：2010-05-04
申请号：US11351737
申请日：2006-02-10
申请人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
发明人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
IPC分类号： C06B23/00
CPC分类号： C08L23/0815 , C08L53/02 , C08L2666/24
摘要： The present invention herein provides an oxygen-absorbing resin composition which is excellent in the oxygen-absorbability and which can inhibit any deterioration through oxidation during the molding operations of the composition and does not accordingly undergo any coloration during the molding operations. The present invention thus provides an oxygen-absorbing resin composition characterized in that it comprises (A) a hydrogenated styrene-diene copolymer; (B) a thermoplastic resin including ethylenic structural units in its molecular structure; and (C) a transition metal catalyst, wherein the oxidation of the thermoplastic resin (B) proceeds while the copolymer (A) serves as a trigger and the composition thus absorbs oxygen. In this respect, the copolymer (A) comprises carbon-carbon double bonds derived from the diene in an amount ranging from 1×10.5 to 1×10.2 eq/g.
摘要翻译：本发明提供一种氧吸收性树脂组合物，其吸氧性优异，并且能够抑制组合物成型时的氧化劣化，并且在成型操作中不会发生任何着色。因此，本发明提供了一种吸氧树脂组合物，其特征在于它包含（A）氢化苯乙烯 - 二烯共聚物; （B）其分子结构中含有乙烯结构单元的热塑性树脂; 和（C）过渡金属催化剂，其中当共聚物（A）用作触发剂时，热塑性树脂（B）的氧化进行，并且组合物因此吸收氧气。在这方面，共聚物（A）包含衍生自二烯的碳 - 碳双键，其量为1×10 5〜1×10 2 eq / g。

25. 发明申请

US20080286584A1 OXYGEN-ABSORBING RESIN COMPOSITIONS 有权
标题翻译：氧吸收树脂组合物
公开(公告)号：US20080286584A1
公开(公告)日：2008-11-20
申请号：US12125991
申请日：2008-05-23
申请人： Takayuki Ishihara , Hiroaki Goto , Yoshihiro Ohta
发明人： Takayuki Ishihara , Hiroaki Goto , Yoshihiro Ohta
IPC分类号： B32B27/28
CPC分类号： B32B27/30 , B32B7/12 , B32B27/08 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/327 , B32B2250/24 , B32B2264/10 , B32B2270/00 , B32B2307/724 , B32B2307/7242 , B32B2439/70 , C08L23/04 , C08L23/0815 , C08L53/02 , C08L2205/02 , Y02E60/324 , Y10T428/25 , Y10T428/256 , Y10T428/257 , Y10T428/259 , Y10T428/31667 , Y10T428/31855 , Y10T428/31909 , C08L2666/06
摘要： The invention provides oxygen-absorbing resin compositions which are reduced in the quantity of by-product oxides and are excellent in oxygen-absorbing capacity, more specifically, an oxygen-absorbing resin composition which comprises a styrene resin, a thermoplastic resin having ethylene structure in the molecular structure, and a transition metal catalyst and in which the oxidation of the thermoplastic resin proceeds by the action of the styrene resin as a trigger to attain oxygen absorption, wherein the styrene resin comprises two kinds of styrene resins (A) and (B) different in styrene content and the styrene content of the resin (A) is higher than that of the resin (B); and an oxygen-absorbing resin composition comprising polyethylene, a resin other than polyethylene which is capable of acting as a trigger in the oxidation of polyethylene, and a transition metal catalyst, wherein the polyethylene comprises two or more kinds of polyethylenes and at least one of them is a linear low-density polyethylene obtained by copolymerizing ethylene with at least 4 wt % of a 1-alkene having 3 to 6 carbon atoms.
摘要翻译：本发明提供氧化吸收树脂组合物，其减少副产物氧化物的量并且具有优异的吸氧能力，更具体地说，是一种吸氧树脂组合物，其包含苯乙烯树脂，具有乙烯结构的热塑性树脂分子结构和过渡金属催化剂，其中热塑性树脂的氧化通过苯乙烯树脂作为触发剂的作用进行以获得氧吸收，其中苯乙烯树脂包括两种苯乙烯树脂（A）和（B ）苯乙烯含量不同，树脂（A）的苯乙烯含量高于树脂（B）的苯乙烯含量; 以及包含聚乙烯，聚乙烯以外的树脂，其能够用作聚乙烯氧化中的触发剂的氧吸收性树脂组合物和过渡金属催化剂，其中所述聚乙烯包含两种或更多种聚乙烯和至少一种它们是通过使乙烯与至少4重量％的具有3至6个碳原子的1-烯烃共聚获得的线性低密度聚乙烯。

26. 发明授权

US07427436B2 Oxygen-absorbing resin compositions 有权
标题翻译：吸氧树脂组合物
公开(公告)号：US07427436B2
公开(公告)日：2008-09-23
申请号：US11805352
申请日：2007-05-22
申请人： Takayuki Ishihara , Hiroaki Goto , Yoshihiro Ohta
发明人： Takayuki Ishihara , Hiroaki Goto , Yoshihiro Ohta
IPC分类号： B32B5/16 , B32B27/00
CPC分类号： B32B27/30 , B32B7/12 , B32B27/08 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/327 , B32B2250/24 , B32B2264/10 , B32B2270/00 , B32B2307/724 , B32B2307/7242 , B32B2439/70 , C08L23/04 , C08L23/0815 , C08L53/02 , C08L2205/02 , Y02E60/324 , Y10T428/25 , Y10T428/256 , Y10T428/257 , Y10T428/259 , Y10T428/31667 , Y10T428/31855 , Y10T428/31909 , C08L2666/06
摘要： The invention provides oxygen-absorbing resin compositions which are reduced in the quantity of by-product oxides and are excellent in oxygen-absorbing capacity, more specifically, an oxygen-absorbing resin composition which comprises a styrene resin, a thermoplastic resin having ethylene structure in the molecular structure, and a transition metal catalyst and in which the oxidation of the thermoplastic resin proceeds by the action of the styrene resin as a trigger to attain oxygen absorption, wherein the styrene resin comprises two kinds of styrene resins (A) and (B) different in styrene content and the styrene content of the resin (A) is higher than that of the resin (B); and an oxygen-absorbing resin composition comprising polyethylene, a resin other than polyethylene which is capable of acting as a trigger in the oxidation of polyethylene, and a transition metal catalyst, wherein the polyethylene comprises two or more kinds of polyethylenes and at least one of them is a linear low-density polyethylene obtained by copolymerizing ethylene with at least 4 wt % of a 1-alkene having 3 to 6 carbon atoms.
摘要翻译：本发明提供氧化吸收树脂组合物，其减少副产物氧化物的量并且具有优异的吸氧能力，更具体地说，是一种吸氧树脂组合物，其包含苯乙烯树脂，具有乙烯结构的热塑性树脂分子结构和过渡金属催化剂，其中热塑性树脂的氧化通过苯乙烯树脂作为触发剂的作用进行以获得氧吸收，其中苯乙烯树脂包括两种苯乙烯树脂（A）和（B ）苯乙烯含量不同，树脂（A）的苯乙烯含量高于树脂（B）的苯乙烯含量; 以及包含聚乙烯，聚乙烯以外的树脂，其能够用作聚乙烯氧化中的触发剂的氧吸收性树脂组合物和过渡金属催化剂，其中所述聚乙烯包含两种或更多种聚乙烯和至少一种它们是通过使乙烯与至少4重量％的具有3至6个碳原子的1-烯烃共聚获得的线性低密度聚乙烯。

27. 发明申请

US20070042145A1 Plastic multi-layer structure 有权
标题翻译：塑料多层结构
公开(公告)号：US20070042145A1
公开(公告)日：2007-02-22
申请号：US11507087
申请日：2006-08-18
申请人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
发明人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
IPC分类号： C03C17/32 , B29D22/00 , B28B23/00
CPC分类号： B32B27/08 , B32B25/08 , B32B25/16 , B32B27/18 , B32B27/302 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2264/102 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/7244 , B32B2307/74 , B32B2439/46 , B32B2439/70 , Y10T428/1314 , Y10T428/1317 , Y10T428/1321 , Y10T428/1352
摘要： The present invention herein provides a plastic multi-layer structure which comprises an oxygen-barrier layer (A-1), an oxygen absorptive layer (B), and a thermoplastic resin layer (C) containing a high silica type zeolite material having a silica/alumina ratio of not less than 80; and a packaging material such as bottles for accommodating foods, for instance, a beverage and medical and pharmaceutical products. The plastic multi-layer structure possesses oxidation-barrier characteristics and the structure would permit the considerable reduction of the quantity of the oxidation by-products generated from the structure, even when used under a high humidity atmosphere.
摘要翻译：本发明提供一种塑料多层结构，其包括氧阻隔层（A-1），氧吸收层（B）和含有二氧化硅的高二氧化硅型沸石材料的热塑性树脂层（C） /氧化铝比不小于80; 以及诸如用于容纳食物的瓶子的包装材料，例如饮料和医药产品。塑料多层结构具有氧化屏障特性，即使在高湿度环境下使用时，结构也能大大减少由结构产生的氧化副产物的量。

28. 发明申请

US20060211811A1 Oxygen-absorbing resin composition 有权
标题翻译：吸氧树脂组合物
公开(公告)号：US20060211811A1
公开(公告)日：2006-09-21
申请号：US11351737
申请日：2006-02-10
申请人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
发明人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
IPC分类号： C09B67/00
CPC分类号： C08L23/0815 , C08L53/02 , C08L2666/24
摘要： The present invention herein provides an oxygen-absorbing resin composition which is excellent in the oxygen-absorbability and which can inhibit any deterioration through oxidation during the molding operations of the composition and does not accordingly undergo any coloration during the molding operations. The present invention thus provides an oxygen-absorbing resin composition characterized in that it comprises (A) a hydrogenated styrene-diene copolymer; (B) a thermoplastic resin including ethylenic structural units in its molecular structure; and (C) a transition metal catalyst, wherein the oxidation of the thermoplastic resin (B) proceeds while the copolymer (A) serves as a trigger and the composition thus absorbs oxygen. In this respect, the copolymer (A) comprises carbon-carbon double bonds derived from the diene in an amount ranging from 1×10−5 to 1×10−2 eq/g.
摘要翻译：本发明提供一种氧吸收性树脂组合物，其吸氧性优异，并且能够抑制组合物成型时的氧化劣化，并且在成型操作中不会发生任何着色。因此，本发明提供了一种吸氧树脂组合物，其特征在于它包含（A）氢化苯乙烯 - 二烯共聚物; （B）其分子结构中含有乙烯结构单元的热塑性树脂; 和（C）过渡金属催化剂，其中当共聚物（A）用作触发剂时，热塑性树脂（B）的氧化进行，并且组合物因此吸收氧气。在这方面，共聚物（A）包含衍生自二烯的碳 - 碳双键，其量为1×10 -5至1×10 -2 eq / g。

29. 发明授权

US4390747A Speech analyzer 失效
标题翻译：语音分析仪
公开(公告)号：US4390747A
公开(公告)日：1983-06-28
申请号：US191294
申请日：1980-09-26
申请人： Tohru Sampei , Akihiro Asada , Yoshihiro Ohta , Syunji Iwasaki
发明人： Tohru Sampei , Akihiro Asada , Yoshihiro Ohta , Syunji Iwasaki
IPC分类号： G10L11/00 , G10L11/04 , G10L1/00
CPC分类号： G10L25/90 , G10L25/00
摘要： A speech analyzer for extracting spectrum information and pitch information from natural speech wherein an accuracy of pitch extraction is enhanced by sampling pitch at a sampling frequency which is higher than a sampling frequency for analyzing the spectrum information.
摘要翻译：一种用于从自然语音提取频谱信息和音调信息的语音分析器，其中通过以高于用于分析频谱信息的采样频率的采样频率采样音调来增强音高提取的精度。

30. 发明授权

US4388491A Speech pitch period extraction apparatus 失效
标题翻译：语音音调周期提取装置
公开(公告)号：US4388491A
公开(公告)日：1983-06-14
申请号：US191291
申请日：1980-09-26
申请人： Yoshihiro Ohta , Akira Ichikawa
发明人： Yoshihiro Ohta , Akira Ichikawa
IPC分类号： G10L11/00 , G10L11/04 , G10L1/00
CPC分类号： G10L25/90
摘要： A speech pitch period extracting apparatus includes an amplitude classifying and coding circuit for classifying and coding the amplitude of a selected frame of a speech waveform signal to be analyzed into at least three levels of coded data, and a coincidence circuit for detecting the number of coincidences which occur between sets of coded data signals from said selected frame separated by different arbitrary time intervals, thereby to determine that time interval for which the maximum number of code coincidences between data signals occurs and to identify that time interval as the pitch period of the speech waveform signal. In addition, there may be provided a circuit for normalizing the speech waveform signal included in the frame to be analyzed, in accordance with the maximum peak value of the speech waveform, the speech waveform signal after being normalized is applied to the classifying and coding circuit.
摘要翻译：语音音调周期提取装置包括：振幅分类和编码电路，用于将要分析的语音波形信号的所选帧的幅度分类和编码为至少三个编码数据级别;以及用于检测重合次数的符合电路其发生在由不同的任意时间间隔分隔的所述所选帧的编码数据信号组之间，从而确定发生数据信号之间最大数量的符号的时间间隔，并将该时间间隔识别为语音的音调周期波形信号。此外，可以提供一种用于根据语音波形的最大峰值对包括在待分析帧中的语音波形信号进行归一化的电路，将归一化后的语音波形信号应用于分类和编码电路。

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