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21. 发明授权

US09221723B2 Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1 有权
标题翻译：用于烃转化的催化剂，其制备方法及其使用方法 - 掺入-1
公开(公告)号：US09221723B2
公开(公告)日：2015-12-29
申请号：US12125796
申请日：2008-05-22
申请人： Alla K. Khanmamedova , Scott A. Stevenson , Scott F. Mitchell , Dustin B. Farmer , Jim Vartuli
发明人： Alla K. Khanmamedova , Scott A. Stevenson , Scott F. Mitchell , Dustin B. Farmer , Jim Vartuli
IPC分类号： B01J29/06 , C07C2/00 , C07C1/20 , B01J29/86 , B01J29/04 , B01J29/40 , B01J29/44 , C07C2/24 , C07C2/66 , C07C2/76 , C07C6/08 , C07C6/12 , C10G1/04 , C10G11/05 , C10G25/03 , C10G35/085 , C10G35/095 , C10G45/00 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/18 , C10G50/00
CPC分类号： C07C1/20 , B01J29/047 , B01J29/405 , B01J29/44 , B01J29/86 , B01J2229/183 , B01J2229/186 , C07C2/24 , C07C2/66 , C07C2/76 , C07C6/08 , C07C6/123 , C07C6/126 , C07C2521/02 , C07C2523/04 , C07C2523/14 , C07C2523/58 , C07C2523/62 , C07C2529/44 , C07C2529/86 , C10G1/04 , C10G11/05 , C10G25/03 , C10G35/085 , C10G35/095 , C10G45/00 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/18 , C10G50/00 , C10G2400/20 , C10G2400/30 , Y02P30/42 , C07C15/02
摘要： This invention is for a catalyst for conversion of hydrocarbons. The catalyst contains a zeolite having germanium and at least one selected from the group consisting of tin and boron incorporated into the zeolite framework and at least one metal selected from Group 10 deposited on the zeolite. The catalyst is prepared by synthesizing a zeolite having germanium and at least one selected from the group consisting of tin and boron incorporated into the zeolite framework; depositing the metal; and calcining after preparation of the zeolite and before or after depositing the metal. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with alkanes having 2 to 12 carbon atoms per molecule and recovering the product.
摘要翻译：本发明是用于烃转化的催化剂。催化剂含有具有锗的沸石和选自掺入沸石骨架中的锡和硼中的至少一种和选自沉积在沸石上的组10中的至少一种金属。通过合成具有锗的沸石和掺入沸石骨架中的选自锡和硼中的至少一种的沸石来制备催化剂; 沉积金属; 并在制备沸石之后和在沉积金属之前或之后煅烧。催化剂可用于通过使催化剂与每分子具有2至12个碳原子的烷烃接触并回收产物来将烃类如丙烷转化成芳族化合物的方法。

22. 发明授权

US09192925B2 Catalyst for conversion of hydrocarbons, process of making and process of using thereof 有权
标题翻译：用于烃转化的催化剂，其制备方法及其使用方法
公开(公告)号：US09192925B2
公开(公告)日：2015-11-24
申请号：US13961147
申请日：2013-08-07
申请人： Scott F. Mitchell , Alla K. Khanmamedova , Scott A. Stevenson , Jim Vartuli
发明人： Scott F. Mitchell , Alla K. Khanmamedova , Scott A. Stevenson , Jim Vartuli
IPC分类号： B01J29/89 , B01J29/46 , B01J29/48 , B01J29/82 , B01J29/83 , B01J29/84 , B01J29/85 , B01J29/04 , B01J29/068 , B01J29/064 , B01J29/072 , B01J29/42 , B01J29/40 , B01J29/44 , B01J29/86 , C07C1/20 , C07C2/24 , C07C2/66 , C07C2/76 , C07C6/12 , C10G11/05 , C10G25/03 , C10G35/06 , C10G35/085 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/16 , C10G47/18 , C10G50/00 , C10G3/00 , B01J29/88
CPC分类号： B01J29/89 , B01J29/047 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/405 , B01J29/42 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/82 , B01J29/83 , B01J29/84 , B01J29/85 , B01J29/86 , B01J29/88 , B01J2229/18 , B01J2229/186 , C07C1/20 , C07C2/24 , C07C2/66 , C07C2/76 , C07C6/123 , C07C6/126 , C07C2529/44 , C10G3/47 , C10G3/49 , C10G11/05 , C10G25/03 , C10G35/065 , C10G35/085 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/16 , C10G47/18 , C10G50/00 , C10G2300/1081 , C10G2300/1088 , C10G2400/20 , C10G2400/30 , C07C15/02
摘要： This invention is for a catalyst for conversion of hydrocarbons. The catalyst contains a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework. At least one Group 10 metal, such as platinum, is deposited on the zeolite. Examples of the elements in the framework are tin, boron, iron or titanium. The catalyst is prepared by synthesizing a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework; depositing the metal; and calcining after preparation of the zeolite and before or after depositing the metal. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with alkanes having 2 to 12 carbon atoms per molecule and recovering the product.
摘要翻译：本发明是用于烃转化的催化剂。催化剂含有沸石，沸石具有来自第13族，第14族或第一系列过渡金属的一种元素，和任选的在沸石骨架中的锗和/或铝。在沸石上沉积至少一种第10族金属，例如铂。框架中的元素的实例是锡，硼，铁或钛。通过在沸石骨架中合成具有来自第13族，第14族或第一系列过渡金属和任选的锗和/或铝的一种元素的沸石来制备催化剂; 沉积金属; 并在制备沸石之后和在沉积金属之前或之后煅烧。催化剂可用于通过使催化剂与每分子具有2至12个碳原子的烷烃接触并回收产物来将烃类如丙烷转化成芳族化合物的方法。

23. 发明授权

US08993468B2 Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites 有权
标题翻译：用于烃转化的催化剂，其制备方法及其使用方法-Ge沸石
公开(公告)号：US08993468B2
公开(公告)日：2015-03-31
申请号：US12125868
申请日：2008-05-22
申请人： Scott A. Stevenson , Alla K. Khanmamedova , Dustin B. Farmer , Scott F. Mitchell , Jim Vartuli
发明人： Scott A. Stevenson , Alla K. Khanmamedova , Dustin B. Farmer , Scott F. Mitchell , Jim Vartuli
IPC分类号： B01J29/06 , C07C6/12 , B01J29/04 , B01J29/83 , C07C2/76 , C07C1/20 , C07C2/66 , B01J29/85 , C07C2/24 , C10G35/095
CPC分类号： C07C1/20 , B01J29/047 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/186 , C07C2/12 , C07C2/24 , C07C2/42 , C07C2/66 , C07C2/76 , C07C5/31 , C07C5/367 , C07C5/412 , C07C5/417 , C07C6/123 , C07C6/126 , C07C2529/064 , C07C2529/44 , C07C2529/70 , C07C2529/74 , C07C2529/83 , C07C2529/85 , C10G35/085 , C10G35/09 , C10G35/095 , Y02P20/52 , C07C15/02
摘要： This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes having 2 to 12 carbon atoms per molecule and recovering the product.
摘要翻译：本发明是用于烃转化的催化剂。催化剂是中孔锗沸石，磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）。选自组10中的至少一种金属沉积在中孔沸石上，并且任选地沉积在磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）上。催化剂是通过合并中孔沸石，磷酸铝（AlPO）或硅铝磷酸盐（SAPO）与掺入骨架中的锗并煅烧中孔锗沸石，磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）来制备的。可以在锗沸石，磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）上沉积至少一种金属。该催化剂可用于通过使催化剂与含有每分子具有2至12个碳原子的烷烃的烃物流接触并回收产物来将烃类如丙烷转化为芳族化合物的方法。

24. 发明申请

US20120122662A1 CATALYST FOR CONVERSION OF HYDROCARBONS, PROCESS OF MAKING AND PROCESS OF USING THEREOF - BIMETALLIC DEPOSITION 审中-公开
标题翻译：碳氢化合物转化催化剂，其制备方法及其使用方法 - 双金属沉积
公开(公告)号：US20120122662A1
公开(公告)日：2012-05-17
申请号：US13110157
申请日：2011-05-18
申请人： Alla K. Khanmamedova , Scott F. Mitchell , Scott A. Stevenson , Gopalakrishnan G. Juttu
发明人： Alla K. Khanmamedova , Scott F. Mitchell , Scott A. Stevenson , Gopalakrishnan G. Juttu
IPC分类号： B01J29/04 , C07C7/148 , B01J37/08 , C07C29/00 , C07C51/00 , C07C67/00 , C07C4/06 , C10G47/02
CPC分类号： C07C1/20 , B01J29/047 , B01J29/405 , B01J29/44 , B01J2229/186 , C07C2/12 , C07C2/24 , C07C2/66 , C07C2/76 , C07C4/06 , C07C5/2708 , C07C5/2754 , C07C6/123 , C07C6/126 , C07C2529/44 , C07C2529/62 , C07C2529/74 , C10G35/095 , C10G47/18 , C10G2300/1081 , C10G2300/1088 , Y02P20/52 , C07C15/02
摘要： This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a non-acidic germanium zeolite, such as Ge-ZSM-5, on which at least two metals, platinum and at least one other metal selected from Group 7, Group 8, Group 9, Group 10 and tin, are deposited on the germanium zeolite. Examples of the other metal are iridium, rhenium, palladium, ruthenium, rhodium, iron, cobalt and tin. The catalyst is prepared by synthesizing a germanium zeolite; depositing platinum and at least one other metal on the germanium zeolite; and calcining after preparation of the zeolite, before depositing the metals or after depositing the metals. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes, olefins and mixtures thereof having 2 to 12 carbon atoms per molecule and recovering the product.
摘要翻译：本发明是用于烃转化的催化剂。催化剂是诸如Ge-ZSM-5的非酸性锗沸石，其上沉积了至少两种金属，铂和选自第7组，第8组，第9组，第10组和锡中的至少一种其他金属在锗沸石上。其他金属的实例是铱，铼，钯，钌，铑，铁，钴和锡。催化剂是通过合成锗沸石制备的; 在锗沸石上沉积铂和至少一种其他金属; 并在制备沸石之后，在沉积金属之前或在沉积金属之后进行煅烧。催化剂可用于通过使催化剂与含有每分子具有2至12个碳原子的烷烃，烯烃和其混合物的烃流接触并回收产物来将烃如丙烷转化为芳族化合物的方法。

25. 发明授权

US07902413B2 Aromatization of alkanes using a germanium-zeolite catalyst 有权
标题翻译：使用锗 - 沸石催化剂的烷烃芳构化
公开(公告)号：US07902413B2
公开(公告)日：2011-03-08
申请号：US11786590
申请日：2007-04-12
申请人： Scott A. Stevenson , Dustin B. Farmer , Scott F. Mitchell , Gopalakrishnan G. Juttu , Alla K. Khanmamedova , Paul E. Ellis
发明人： Scott A. Stevenson , Dustin B. Farmer , Scott F. Mitchell , Gopalakrishnan G. Juttu , Alla K. Khanmamedova , Paul E. Ellis
IPC分类号： C07C2/76
CPC分类号： C07C5/415 , B01J23/42 , B01J29/04 , B01J29/047 , B01J2229/18 , B01J2229/186 , C07C5/417 , C07C2529/44 , C10G45/68 , C10G45/70 , Y02P20/52 , C07C15/06
摘要： This invention relates to a process for the aromatization of C6 to C12 alkanes, such as hexane, heptane and octane, to aromatics, such as benzene, ethyl benzene, toluene and xylenes, with a germanium-containing zeolite catalyst. The catalyst is a non-acidic aluminum-silicon-germanium zeolite on which a noble metal, such as platinum, has been deposited. The zeolite structure may be of MFI, BEA, MOR, LTL or MTT. The zeolite is made non-acidic by being base-exchanged with an alkali metal or alkaline earth metal, such as cesium, potassium, sodium, rubidium, barium, calcium, magnesium and mixtures thereof, to reduce acidity. The catalyst is sulfur tolerant and may be pretreated with a sulfur compound, i.e., sulfided. The hydrocarbon feed may contain sulfur up to 1000 ppm. The present invention could be applicable to a feedstream which is predominantly paraffinic and/or low in naphthenes. Lowering the hydrogen to hydrocarbon ratio increases conversion and aromatics selectivity.
摘要翻译：本发明涉及一种使用含锗沸石催化剂将C6至C12烷烃如己烷，庚烷和辛烷芳构化成芳族化合物如苯，乙苯，甲苯和二甲苯的方法。催化剂是沉积贵金属如铂的非酸性铝硅锗沸石。沸石结构可以是MFI，BEA，MOR，LTL或MTT。沸石通过与碱金属或碱土金属如铯，钾，钠，铷，钡，钙，镁及其混合物进行碱交换而制成非酸性，以降低酸度。催化剂是耐硫的，并且可以用硫化合物预处理，即硫化。烃进料可含有高达1000ppm的硫。本发明可以应用于主要是石蜡和/或低环烷烃的进料流。降低氢气与烃的比例会提高转化率和芳烃选择性。

26. 发明申请

US20080293990A1 Catalyst for Conversion of Hydrocarbons, Process of Making and Process of Using Thereof - Ge Zeolites 有权
标题翻译：烃转化催化剂，其制备方法及其使用方法 - Ge沸石
公开(公告)号：US20080293990A1
公开(公告)日：2008-11-27
申请号：US12125868
申请日：2008-05-22
申请人： Scott A. Stevenson , Alla K. Khanmamedova , Dustin B. Farmer , Scott F. Mitchell , Jim Vartuli
发明人： Scott A. Stevenson , Alla K. Khanmamedova , Dustin B. Farmer , Scott F. Mitchell , Jim Vartuli
IPC分类号： C07C1/00 , B01J29/04 , C01B39/00 , C01B39/06 , B05D3/10
CPC分类号： C07C1/20 , B01J29/047 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/186 , C07C2/12 , C07C2/24 , C07C2/42 , C07C2/66 , C07C2/76 , C07C5/31 , C07C5/367 , C07C5/412 , C07C5/417 , C07C6/123 , C07C6/126 , C07C2529/064 , C07C2529/44 , C07C2529/70 , C07C2529/74 , C07C2529/83 , C07C2529/85 , C10G35/085 , C10G35/09 , C10G35/095 , Y02P20/52 , C07C15/02
摘要： This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes having 2 to 12 carbon atoms per molecule and recovering the product.
摘要翻译：本发明是用于烃转化的催化剂。催化剂是中孔锗沸石，磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）。选自组10中的至少一种金属沉积在中孔沸石上，并且任选地沉积在磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）上。催化剂是通过合并中孔分子筛，铝磷酸盐（AlPO）或硅铝磷酸盐（SAPO）与掺入骨架中的锗并煅烧中孔锗沸石，磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）来制备的。可以在锗沸石，磷酸铝铝（AlPO）或锗硅铝磷酸盐（SAPO）上沉积至少一种金属。该催化剂可用于通过使催化剂与含有每分子具有2至12个碳原子的烷烃的烃物流接触并回收产物来将烃类如丙烷转化为芳族化合物的方法。

27. 发明授权

US5734066A Supression of autoignition in maleic anhydride production 失效
标题翻译：抑制马来酸酐生产中的自燃
公开(公告)号：US5734066A
公开(公告)日：1998-03-31
申请号：US835152
申请日：1992-02-13
申请人： Robert A. Keppel , Scott F. Mitchell , Michael J. Mummey
发明人： Robert A. Keppel , Scott F. Mitchell , Michael J. Mummey
IPC分类号： B01J27/198 , C07C51/215 , C07C51/225 , C07C57/145 , C07D307/60
CPC分类号： C07C51/215
摘要： An improved process for the manufacture of maleic anhydride by catalytic oxidation of n-butane in which the feed flow channel to the catalytic reactor contains an autoignition suppression agent containing acid sites or trivalent phosphorus as an ignition inhibiting component. The autoignition suppression agent may also be used in other gas/liquid containment envelopes for flammable mixtures of hydrocarbons and oxygen. A novel apparatus and method are disclosed for assessing the influence of system conditions on autoignition of hydrocarbon/oxygen mixtures.
摘要翻译：通过正丁烷的催化氧化制备马来酸酐的改进方法，其中向催化反应器的进料流动通道含有含有酸性位点或三价磷作为点火抑制组分的自燃抑制剂。自燃抑制剂也可以用于其它气体/液体容纳包封，用于可燃的烃和氧混合物。公开了一种用于评估系统条件对烃/氧混合物的自燃的影响的新颖的装置和方法。

28. 发明授权

US5641722A High performance VPO catalyst and process of preparation thereof 失效
标题翻译：高性能VPO催化剂及其制备方法
公开(公告)号：US5641722A
公开(公告)日：1997-06-24
申请号：US306489
申请日：1994-09-15
申请人： Scott F. Mitchell , Robert A. Keppel , Michael J. Mummey
发明人： Scott F. Mitchell , Robert A. Keppel , Michael J. Mummey
IPC分类号： C07D307/60 , B01J27/198 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/08 , C07B61/00 , C07C51/21 , C07C51/215 , C07C51/25
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , B01J37/0018 , C07C51/215 , C07C51/25 , B01J2523/00 , B01J35/0026 , B01J35/1014 , B01J35/108 , B01J37/08
摘要： An activated porous phosphorus/vanadium oxide catalyst adapted for the catalytic oxidation of a hydrocarbon to produce a carboxylic acid anhydride. The catalyst comprises a shaped body having a volume of at least about 0.02 cc, a phosphorus content of between about 1.05 and about 1.20, a B.E.T. surface area of at least about 15 m.sup.2 /g, an average vanadium oxidation state of between about 4.06 and about 4.3, a total pore volume of at least about 0.15 cc/g, a normalized apparent shaped body density of between about 1.0 and about 2.0 g/cc, and a crush strength of at least about 4 pounds. At least about 20% of the pore volume of the catalyst is constituted of pores having a diameter between about 0.1 and about 3.3 .mu.M, and at least about 40% of the pore volume is constituted of pores having a diameter of less than about 0.1 .mu.M. The catalyst is prepared by mixing a particulate phosphorus/vanadium oxide precursor with a pore modification agent to produce a modified catalyst precursor composition, forming the modified precursor composition into a predetermined shape, and removing the pore modification agent substantially at a temperature below 300.degree. C., preferably using air as a stripping gas.
摘要翻译：一种活化的多孔磷/氧化钒催化剂，适于催化氧化烃以产生羧酸酐。催化剂包括具有至少约0.02cc的体积，约1.05至约1.20的磷含量的成形体，B.E.T. 表面积至少约15m 2 / g，平均钒氧化态在约4.06与约4.3之间，总孔体积至少约0.15cc / g，归一化表观体密度在约1.0至约2.0之间 g / cc，压碎强度至少约4磅。催化剂的孔体积的至少约20％由直径在约0.1至约3.3μm之间的孔构成，并且至少约40％的孔体积由直径小于约0.1的孔构成通过将颗粒状磷/钒氧化物前体与孔改性剂混合以制备改性催化剂前体组合物，将改性前体组合物形成预定形状并基本上在低于下述温度下除去孔改性剂来制备催化剂 300℃，优选使用空气作为汽提气体。

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