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21. 发明授权

US06777582B2 Process for producing propylene and hexene from C4 olefin streams 失效
标题翻译：从C4烯烃流中生产丙烯和己烯的方法
公开(公告)号：US06777582B2
公开(公告)日：2004-08-17
申请号：US10093322
申请日：2002-03-07
申请人： Robert J. Gartside , Marvin I. Greene , Quincy J. Jones
发明人： Robert J. Gartside , Marvin I. Greene , Quincy J. Jones
IPC分类号： C07C604
CPC分类号： C07C11/107 , C07C5/2512 , C07C6/04 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/16 , C07C2523/24 , C07C2523/30 , C07C2523/32 , C07C2529/06
摘要： A C3 to C6 hydrogen cut from a cracking unit is processed for the conversion of olefins to propylene and hexene via autometathesis. The autometathesis of a mixed normal butenes feed in the presence of a metathesis catalyst operates without any ethylene in the feed mix to the metathesis reactor. Some fraction of the 2-butene feed may be isomerized to 1-butene and the 1-butene formed plus the 1-butene in the feed react rapidly with the 2-butene to form propylene and 2-pentene. The feed to the reactor also includes the recycle of the 2-pentene formed in the reactor with unreacted butenes to simultaneously form additional propylene and hexene. In one embodiment, some or all of the 3-hexene formed in the reaction is isomerized to 1-hexene. In another embodiment, some portion of the 3-hexene produced in the main metathesis reaction is reacted with ethylene to produce 1-butene without the need for superfractionation. In another embodiment, the 3-hexene product is hydrogenated and recycled back to the cracking heaters.
摘要翻译：处理从裂化装置切割的C 3至C 6氢气经由自动化将烯烃转化为丙烯和己烯。在复分解催化剂存在下，混合的正丁烯进料的自动化在进料混合物中没有任何乙烯运行到复分解反应器。 2-丁烯进料的一部分可以异构化成1-丁烯，并且进料中形成的1-丁烯加上1-丁烯与2-丁烯快速反应形成丙烯和2-戊烯。反应器的进料还包括在反应器中形成的2-戊烯与未反应的丁烯循环，以同时形成另外的丙烯和己烯。在一个实施方案中，在反应中形成的部分或全部3-己烯异构化为1-己烯。在另一个实施方案中，在主复分解反应中产生的一部分3-己烯与乙烯反应生成1-丁烯，而不需要超分级。在另一个实施方案中，将3-己烯产物氢化并再循环回裂化加热器。

22. 发明授权

US06727396B2 Process for the production of linear alpha olefins and ethylene 有权
标题翻译：生产线性α-烯烃和乙烯的方法
公开(公告)号：US06727396B2
公开(公告)日：2004-04-27
申请号：US10055126
申请日：2002-01-23
申请人： Robert J. Gartside
发明人： Robert J. Gartside
IPC分类号： C07C604
CPC分类号： C07C11/107 , C07C5/25 , C07C6/04 , C07C11/02 , C07C11/04 , C07C2521/08 , C07C2523/28 , C07C2523/30 , C07C2523/36 , Y02P20/52
摘要： Ethylene and hexene-1 are produced from butene-1 by metathesis of butene-1 and isomerization of the hexene-3 produced therein to hexene-1. The initial starting material is a mixed butene stream wherein butene-1 is isomerized to butene-2 with isobutylene being separated therefrom, followed by isomerization of butene-2 to butene-1, with the butene-1 being the feed to the metathesis.
摘要翻译：乙烯和己烯-1通过丁烯-1的复分解和丁烯-1的己烯-3的异构化生成己烯-1，由丁烯-1制备。初始原料是一种混合丁烯流，其中丁烯-1异构化为丁烯-2，异丁烯与其分离，随后将丁烯-2异构化为丁烯-1，丁烯-1为复分解料的进料。

23. 发明授权

US06425757B1 Pyrolysis heater with paired burner zoned firing system 失效
标题翻译：热解加热器配对燃烧器分区射击系统
公开(公告)号：US06425757B1
公开(公告)日：2002-07-30
申请号：US09880588
申请日：2001-06-13
申请人： Paul J. Chapman , Erwin M. J. Platvoet , Robert J. Gartside
发明人： Paul J. Chapman , Erwin M. J. Platvoet , Robert J. Gartside
IPC分类号： F27B900
CPC分类号： C10G9/20
摘要： A pyrolysis heater has the inlet sections of the process coils grouped together and the outlet sections of these same process coils also grouped together. High heat liberation hearth burners are located adjacent to the inlet sections of the coils and lower heat liberation burners are located adjacent to the outlet sections. The secondary fuel tips of the burners are inclined toward the adjacent heater wall. The high heat liberation hearth burners adjacent to the inlet coils are arranged in spaced apart pairs with the secondary burner tips of each of the pair being inclined toward the other burner of the pair.
摘要翻译：热解加热器将过程线圈的入口部分组合在一起，并且这些相同过程线圈的出口部分也被组合在一起。高放热炉底燃烧器邻近线圈的入口部分定位，下部放热燃烧器位于出口部分附近。燃烧器的二次燃料尖端朝向相邻的加热器壁倾斜。与入口线圈相邻的高热释放炉膛燃烧器以间隔开的对布置，其中每对的二次燃烧器尖端朝着该对的另一个燃烧器倾斜。

24. 发明授权

US5780683A Cyclohexane oxidation 失效
标题翻译：环己烷氧化
公开(公告)号：US5780683A
公开(公告)日：1998-07-14
申请号：US712478
申请日：1996-09-11
申请人： Marvin I. Greene , Charles Sumner , Robert J. Gartside
发明人： Marvin I. Greene , Charles Sumner , Robert J. Gartside
IPC分类号： C07C29/50 , C07C45/33
CPC分类号： C07C29/50 , C07C45/33 , C07C2101/14
摘要： Cyclohexane is catalytically oxidized to produce cyclohexanol and cyclohexanone and precursors of these products. The product is then catalytically hydrogenated while the product is still at reaction temperature to produce additional cyclohexanol and cyclohexanone from the precursors. The oxidation is carried out in a liquid oxidation reactor at high oxygen concentrations (greater than 30% and preferably greater than 90% oxygen concentration) and at relatively low temperatures (less than 160.degree. C.). The use of the liquid oxidation reactor permits the use of these high oxygen concentrations without forming dangerously high levels of oxygen in the overhead gas phase. The result is an increased yield and selectivity of the desired products. The hydrogenation is carried out in a reactor using a catalyst of palladium supported on carbon.
摘要翻译：催化氧化环己烷以产生环己醇和环己酮以及这些产物的前体。然后将产物催化氢化，同时产物仍处于反应温度以从前体产生另外的环己醇和环己酮。在高氧浓度（大于30％，优选大于90％氧气浓度）和相对低的温度（小于160℃）的液体氧化反应器中进行氧化。使用液体氧化反应器允许使用这些高氧浓度，而不会在塔顶气相中形成危险的高水平的氧。结果是所需产物的产率和选择性提高。氢化在反应器中使用负载在碳上的钯催化剂进行。

25. 发明授权

US5510557A Endothermic catalytic dehydrogenation process 失效
标题翻译：吸热催化脱氢工艺
公开(公告)号：US5510557A
公开(公告)日：1996-04-23
申请号：US202835
申请日：1994-02-28
申请人： Robert J. Gartside , Cemal Ercan , Kandasamy M. Sundaram
发明人： Robert J. Gartside , Cemal Ercan , Kandasamy M. Sundaram
IPC分类号： C07B35/04 , C07C5/32 , C07C5/333
CPC分类号： C07C5/3332 , C07B35/04 , C07C5/321 , Y02P20/584
摘要： Catalytic dehydrogenation wherein feed is passed in one direction through the bed in a first cycle and heating gas is passed in an opposite direction in a second cycle to provide the endothermic heat of reaction and regenerate catalyst. The operation is controlled to balance properly heat absorbed during dehydrogenation and heat input during regeneration; e.g., by having catalyst of different activities over the length of the bed.
摘要翻译：催化脱氢，其中进料在第一循环中沿一个方向通过床，并且加热气体在第二循环中沿相反方向通过，以提供反应的吸热热并再生催化剂。控制操作以平衡在再生期间脱氢和热输入期间吸收的适当热量; 例如通过在床的长度上具有不同活性的催化剂。

26. 发明授权

US5314610A Staged catalytic cracking process 失效
标题翻译：分阶段催化裂化过程
公开(公告)号：US5314610A
公开(公告)日：1994-05-24
申请号：US890196
申请日：1992-05-29
申请人： Robert J. Gartside
发明人： Robert J. Gartside
IPC分类号： C10G11/18 , C10G51/06 , C10G11/00
CPC分类号： C10G11/18
摘要： A staged catalytic cracking process and apparatus is disclosed where each stage has a catalyst to oil ratio of at least 15 and there are individual hydrocarbon feeds to each stage and product removal from each stage. There is a residence time profile with the first stage having a short residence time and the successive stages having progressively longer residence times. Further, there is a feed profile with the lighter components of the total feed going to the first stage and the heavier components being fed to the later stages. The apparatus has a generally vertical orientation which permits it to be incorporated into existing cracking units for upgrading and also easily provides for both short and long residence times.
摘要翻译：公开了分阶段的催化裂化方法和装置，其中每个阶段的催化剂油比至少为15，并且每个阶段有单独的烃进料和从每个阶段除去产物。存在停留时间曲线，第一阶段具有短停留时间，并且连续阶段具有逐渐更长的停留时间。此外，存在进料曲线，其中总进料的较轻组分进入第一阶段，较重的组分进料到后期。该装置具有大致垂直的取向，其允许将其并入现有的用于升级的裂解装置，并且还容易地提供短停留时间和长停留时间。

27. 发明授权

US4433984A Low residence time solid-gas separation device and system 失效
标题翻译：低停留时间固体气体分离装置和系统
公开(公告)号：US4433984A
公开(公告)日：1984-02-28
申请号：US299587
申请日：1981-09-04
申请人： Robert J. Gartside , Herman N. Woebcke
发明人： Robert J. Gartside , Herman N. Woebcke
IPC分类号： B01D45/06 , B01D50/00
CPC分类号： B01D45/06
摘要： This invention relates to an apparatus and method for rapidly separating particulate solids from a mixed phase solids-gas stream which may be at velocities up to 150 ft./sec. and at high temperature. Specifically, the device is designed for incorporation at the discharge of solid-gas reacting systems having low residence time requirements and carried out in tubular type reactors. Separation is effected by projecting solids by centrifugal force against a bed of solids as the gas phase makes a 180.degree. directional change, said solids changing direction only 90.degree. relative to the incoming stream.
摘要翻译：本发明涉及一种从混合相固体 - 气体流快速分离颗粒固体的装置和方法，混合相固体 - 气流的速度可达150英尺/秒。并在高温下。具体地说，该装置被设计用于在具有低停留时间要求的固体气体反应系统的排放中并入并在管式反应器中进行。通过离心力将固体投射到固体床上进行分离，当气相进行180°方向改变时，所述固体改变方向相对于进入流仅90度。

28. 发明授权

US4351275A Solids quench boiler and process 失效
标题翻译：固体淬火锅炉和工艺
公开(公告)号：US4351275A
公开(公告)日：1982-09-28
申请号：US82162
申请日：1979-10-05
申请人： Arju H. Bhojwani , Robert J. Gartside , Herman N. Woebcke
发明人： Arju H. Bhojwani , Robert J. Gartside , Herman N. Woebcke
IPC分类号： B01J8/00 , C10G9/00 , C10G9/18 , C10G9/32 , C10G51/02 , F28C3/16 , F22D1/00
CPC分类号： C10G9/002 , B01J8/003 , C10G9/00 , C10G9/32 , C10G2400/20
摘要： Apparatus and process for quenching and cooling reactor effluent. The apparatus includes a section for introducing relatively cool particulate solids into a hot effluent stream to effect initial quenching and a section to further cool the composite quenched effluent and solids. The process employs relatively cool particulate solids to quench hot effluent and indirect heat exchange between water and the quenched effluent-solids mix to generate high pressure steam and further cool the mix.
摘要翻译：用于淬火和冷却反应器流出物的装置和方法。该装置包括用于将相对较冷的颗粒固体引入热流出物流以实现初始淬火的部分和用于进一步冷却复合淬火流出物和固体的部分。该方法采用相对较冷的颗粒固体来猝灭热流出物和水与骤冷的流出物 - 固体混合物之间的间接热交换以产生高压蒸汽并进一步冷却混合物。

29. 发明授权

US4338187A Solids feeding device and system 失效
标题翻译：固体饲养装置和系统
公开(公告)号：US4338187A
公开(公告)日：1982-07-06
申请号：US86951
申请日：1979-10-22
申请人： Robert J. Gartside , Herman N. Woebcke
发明人： Robert J. Gartside , Herman N. Woebcke
IPC分类号： B01J4/00 , B01J8/00 , C10G9/00 , C10G9/18 , C10G9/32 , C10G51/02 , C10G9/30
CPC分类号： C10G9/32 , B01J8/003 , C10G9/00 , C10G2400/20
摘要： An apparatus and process for delivering fluidization gas to a bed of particulate solids to selectively locally fluidize the solids above a delivery conduit in communication with a reaction chamber. Also an apparatus and process for intimately mixing hydrocarbon feed with the particulate solids at the end of the delivery conduit in the reaction chamber.
摘要翻译：用于将流化气体输送到颗粒固体床以选择性地使固体在与反应室连通的输送管道上流化的装置和方法。还有一种用于将烃进料与反应室中输送管道末端的颗粒固体充分混合的装置和方法。

30. 发明授权

US08314280B2 Process for the production of olefins 有权
标题翻译：烯烃生产工艺
公开(公告)号：US08314280B2
公开(公告)日：2012-11-20
申请号：US12720975
申请日：2010-03-10
申请人： Robert J. Gartside , Robert Haines
发明人： Robert J. Gartside , Robert Haines
IPC分类号： C07C4/06
CPC分类号： C07C4/02 , C07C4/06 , Y02P20/127 , Y02P20/584 , C07C11/04 , C07C11/06
摘要： Disclosed is a process for the production of C2 to C3 olefins via the catalytic cracking of feedstocks including C4 and heavier olefins in an integrated reaction/regeneration system.
摘要翻译：公开了通过在一体化反应/再生系统中通过催化裂化包括C4和较重烯烃的原料来生产C 2至C 3烯烃的方法。

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