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21. 发明授权

US4517128A Two-tailed surfactants having one aromatic containing tail and their use in chemical waterflooding 失效
公开(公告)号：US4517128A
公开(公告)日：1985-05-14
申请号：US413576
申请日：1982-08-31
申请人： Kirk D. Schmitt
发明人： Kirk D. Schmitt
IPC分类号： C07C33/20 , C07C309/09 , C09K8/584 , C07C141/02 , C07C143/42
CPC分类号： C07C309/00 , C07C33/20 , C09K8/584 , Y10S507/936
摘要： (Branched alkyl)-polyethoxyalkyl sulfonates, and similar compounds wherein the alkyl sulfonate moiety is replaced by a sulfate moiety, having an aromatic group on one of the branches of the branched alkyl group are provided. These compounds are surfactants which are particularly useful for chemical waterflooding, especially in high brine environments.

22. 发明授权

US4487837A Radiation method for determining brine tolerant surfactants in complex mixtures 失效
标题翻译：用于测定复杂混合物中盐水耐受性表面活性剂的辐射方法
公开(公告)号：US4487837A
公开(公告)日：1984-12-11
申请号：US329479
申请日：1981-12-10
申请人： Kirk D. Schmitt
发明人： Kirk D. Schmitt
IPC分类号： C09K8/584 , E21B43/20
CPC分类号： C09K8/584 , E21B43/20
摘要： This invention provides a method for determining the concentration of a brine tolerant sulfonate surfactant in a complex mixture containing, in addition to said brine tolerant sulfonate surfactant, lignosulfonates, crude oil, salts, and water and, optionally, petroleum sulfonates and alcohols, that comprises incorporating into the brine tolerant sulfonate surfactant molecule a small amount of tritium prior to addition to the complex mixture and determining the concentration of the brine tolerant sulfonate surfactant by measuring its radioactivity.
摘要翻译：本发明提供了一种用于确定复合混合物中盐水耐受性磺酸盐表面活性剂浓度的方法，该混合物除了所述耐盐磺酸盐表面活性剂，木素磺酸盐，原油，盐和水以及任选的石油磺酸盐和醇之外，还包含在加入复杂混合物之前将少量氚掺入盐水耐受性磺酸盐表面活性剂分子中，并通过测定其放射性来测定耐盐磺酸盐表面活性剂的浓度。

23. 发明授权

US4469607A Pyrrolidinium methane sulfonates as surfactants in enhanced oil recovery 失效
标题翻译：吡咯烷鎓甲烷磺酸盐作为表面活性剂在提高采收率
公开(公告)号：US4469607A
公开(公告)日：1984-09-04
申请号：US373551
申请日：1982-04-30
申请人： Kirk D. Schmitt
发明人： Kirk D. Schmitt
IPC分类号： C07D333/18 , C07C67/00 , C07C301/00 , C07C303/20 , C07C309/01 , C07C309/19 , C07D207/08 , C07D307/10 , C07D333/06 , C07F9/53 , C07F9/6568 , C09K8/58 , E21B43/22
CPC分类号： C09K8/584 , C07D207/08 , C07D307/10 , C07D333/06 , C07F9/65681 , C07F9/65685 , Y10S507/936
摘要： There are provided pyrrolidinium methane sulfonates as surfactants in enhanced oil recovery.
摘要翻译：提供吡咯烷鎓甲烷磺酸盐作为增强油采收中的表面活性剂。

24. 发明授权

US4303411A Fluorine-containing tracers for subterranean petroleum and mineral containing formations 失效
标题翻译：含有地下石油和含矿物地层的含氟示踪剂
公开(公告)号：US4303411A
公开(公告)日：1981-12-01
申请号：US221608
申请日：1980-12-31
申请人： Catherine S. H. Chen , Yuhshi Luh , Kirk D. Schmitt
发明人： Catherine S. H. Chen , Yuhshi Luh , Kirk D. Schmitt
IPC分类号： G01R33/28 , G01N24/08
CPC分类号： G01R33/281 , E21B47/1015 , Y10T436/13
摘要： There is disclosed a method for determining flow patterns within a subterranean formation by injecting as a tracer a water soluble alkaline metal salt of inorganic or organic compounds having fluorine in the anion. The tracer compounds of the invention are identified by FNMR spectroscopy.
摘要翻译：公开了一种通过在阴离子中注入具有氟的无机或有机化合物的水溶性碱金属盐作为示踪剂来确定地层内的流动模式的方法。本发明的示踪剂化合物通过FNMR光谱鉴定。

25. 发明授权

US4198355A Preparation of tertiary alkylphosphorodichloridite derivatives 失效
标题翻译：叔烷基磷酸二氯化物衍生物的制备
公开(公告)号：US4198355A
公开(公告)日：1980-04-15
申请号：US922873
申请日：1978-07-10
申请人： Kirk D. Schmitt
发明人： Kirk D. Schmitt
IPC分类号： C07F9/145 , C07F9/146 , C07F9/141
CPC分类号： C07F9/146 , C07F9/145
摘要： Tertiary alkylphosphorodichloridites, characterized by the formula: ##STR1## where R.sup.1, R.sup.2 and R.sup.3 may be alkyl having from about 1 to about 4 carbon atoms, aryl having from about 6 to about 8 carbon atoms, or aralkyl having from about 7 to about 10 carbon atoms, however, at least one of R.sup.1, R.sup.2 and R.sup.3 must be alkyl, as new compounds, and synthesis thereof by reacting, at temperatures of 0.degree. C. or less, a tertiary alcohol, a tertiary amine scavenger, and phosphorus trichloride, the PCl.sub.3 being employed in amounts in excess of the stoichiometric amount needed to react with the alcohol are provided. Both chlorides of the tertiary alkylphosphorodichloridites so produced may be replaced by RX.sup.- groups from alcohols (ROH), thiols (RSH), or amines (RR.sup.6 NH) in order that tri-substituted phosphite compounds of the formula: ##STR2## are produced. Disubstituted phosphorus acids of the formula: ##STR3## may be produced by heating the trisubstituted phosphite compounds. The RX.sup.- groups are retained as the substituents of the phosphorus acid compound. Such phosphorus acids are extremely useful in lubricating media as antiwear agents, in insecticides and as additives in rubber.
摘要翻译：特征为下式的化合物：其中R 1，R 2和R 3可以是具有约1至约4个碳原子的烷基，具有约6至约8个碳原子的芳基或具有约7至约10个碳原子的芳烷基的叔烷基磷酸二氯化物碳原子，然而，R 1，R 2和R 3中的至少一个必须是烷基，作为新的化合物，以及通过在0℃或更低的温度下，叔醇，叔胺清除剂和三氯化磷提供的PCl3的用量超过与醇反应所需的化学计量量。所制备的叔烷基二磷代二氯酸酯的两种氯化物可以由醇（ROH），硫醇（RSH）或胺（RR6NH））的RX-基团代替，以便产生下式的三取代亚磷酸酯化合物：。可以通过加热三取代的亚磷酸酯化合物来制备下式的二取代的磷酸：。 RX-基保留为磷酸化合物的取代基。这种磷酸在作为抗磨剂，杀虫剂和橡胶中的添加剂的润滑介质中非常有用。

26. 发明授权

US08367028B2 Amorphous acidic materials, their synthesis and use 有权
标题翻译：无定形酸性材料，其合成与使用
公开(公告)号：US08367028B2
公开(公告)日：2013-02-05
申请号：US12592921
申请日：2009-12-04
申请人： Robert C. Lemon , Gordon J. Kennedy , Michael C. Kerby , Kirk D. Schmitt , James C. Vartuli , Kun Wang
发明人： Robert C. Lemon , Gordon J. Kennedy , Michael C. Kerby , Kirk D. Schmitt , James C. Vartuli , Kun Wang
IPC分类号： C01B33/26
CPC分类号： B01J35/002 , B01J21/12 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/108 , B01J37/038 , B01J37/10 , C01B33/26 , C01B39/00
摘要： A porous material comprises oxides of silicon and aluminum and is substantially free of X-ray diffraction peaks in its calcined form. The material is characterized by the following properties: (a) a Bronsted acid site density as measured by temperature programmed ammonia adsorption of at least 0.005 mmol/g; (b) an alpha value of at least 0.5; (c) a specific surface area of about 50 to about 160 m2 g−1; (d) a total pore volume of about 0.14 to about 1.0 cm3 g−1; and (d) a micropore volume of about 0.001 to about 0.015 cm3 g−1.
摘要翻译：多孔材料包括硅和铝的氧化物，并且其煅烧形式基本上不含X射线衍射峰。该材料的特征在于以下性质：（a）通过温度程序氨吸附测定的布朗斯台德酸位点密度为至少0.005mmol / g; （b）α值至少为0.5; （c）约50至约160m2 g-1的比表面积; （d）总孔体积为约0.14至约1.0cm 3 g -1; 和（d）约0.001至约0.015cm 3 g -1的微孔体积。

27. 发明申请

US20080168014A1 Catalyst discovery through pattern recognition-based modeling and data analysis 审中-公开
标题翻译：通过基于模式识别的建模和数据分析的催化剂发现
公开(公告)号：US20080168014A1
公开(公告)日：2008-07-10
申请号：US12001906
申请日：2007-12-13
申请人： Phiroz M. Bhagat , Kirk D. Schmitt
发明人： Phiroz M. Bhagat , Kirk D. Schmitt
IPC分类号： G06F15/18
CPC分类号： G06N3/02 , G16C20/30 , G16C20/70
摘要： The present invention is a method to determine catalyst structures by correlating experimental conditions and directing agent characteristics to catalyst products. The correlating step is carried out by a performance model such as a neural net.
摘要翻译：本发明是通过将实验条件和引导剂特性与催化剂产物相关来确定催化剂结构的方法。相关步骤通过诸如神经网络的性能模型进行。

28. 发明授权

US5405596A Synthesis of crystalline ZSM-23 失效
标题翻译：结晶ZSM-23的合成
公开(公告)号：US5405596A
公开(公告)日：1995-04-11
申请号：US83241
申请日：1993-06-29
申请人： Ahmad Moini , Kirk D. Schmitt
发明人： Ahmad Moini , Kirk D. Schmitt
IPC分类号： B01J29/04 , B01J29/70 , C01B39/48 , C01B33/26
CPC分类号： B01J29/04 , B01J29/70 , C01B39/48
摘要： This invention relates to a new form of crystalline material identified as having the structure of ZSM-23, to a new and useful method for synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g., hydrocarbon compound, conversion.
摘要翻译：本发明涉及一种被认为具有ZSM-23结构的新形式的结晶材料，用于合成所述结晶材料的新的和有用的方法以及使用根据本文制备的所述结晶材料作为有机化合物的催化剂，例如，烃化合物，转化。

29. 发明授权

US5110572A Synthesis of mesoporous crystalline material using organometallic reactants 失效
标题翻译：使用有机金属反应物合成介孔结晶材料
公开(公告)号：US5110572A
公开(公告)日：1992-05-05
申请号：US720105
申请日：1991-06-24
申请人： David C. Calabro , Kirk D. Schmitt , James C. Vartuli
发明人： David C. Calabro , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/16 , B01J20/18 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42 , Y10S423/30
摘要： This invention relates to a method for synthesizing ultra-large pore crystalline material which can be used as a sorbent or catalyst component for conversion of organic and inorganic compounds. A dialkoxyaluminoxytrialkoxysilane is added to the reaction mixture as a metal oxide source.
摘要翻译：本发明涉及一种合成超大孔结晶材料的方法，该方法可用作转化有机和无机化合物的吸附剂或催化剂组分。将二烷氧基氧基三烷氧基硅烷作为金属氧化物源加入到反应混合物中。

30. 发明授权

US4545912A Two-tailed surfactants having one aromatic containing tail and their use in chemical waterflooding 失效
标题翻译：具有一个芳香族尾巴的双尾表面活性剂及其在化学注水中的应用
公开(公告)号：US4545912A
公开(公告)日：1985-10-08
申请号：US585960
申请日：1984-03-05
申请人： Kirk D. Schmitt
发明人： Kirk D. Schmitt
IPC分类号： C07C33/20 , C09K8/58 , E21B43/22
CPC分类号： C07C309/00 , C07C33/20 , C09K8/58 , Y10S507/936
摘要： (Branched alkyl)-polyethoxyalkyl sulfonates, and similar compounds wherein the alkyl sulfonate moiety is replaced by a sulfate moiety, having an aromatic group on one of the branches of the branched alkyl group are provided. These compounds are surfactants which are particularly useful for chemical waterflooding, especially in high brine environments.
摘要翻译：（支链烷基） - 聚乙氧基烷基磺酸盐，以及类似的化合物，其中烷基磺酸盐部分被硫分子替代，在支链烷基的一个支链上具有芳基。这些化合物是特别适用于化学注水的表面活性剂，特别是在高盐水环境中。

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