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21. 发明授权

US07811967B2 Method of preparing catalyst support from a waste catalyst 失效
标题翻译：从废催化剂制备催化剂载体的方法
公开(公告)号：US07811967B2
公开(公告)日：2010-10-12
申请号：US11793461
申请日：2005-12-21
申请人： Marinus Johannes Reynhout , Guy Lode Magda Maria Verbist
发明人： Marinus Johannes Reynhout , Guy Lode Magda Maria Verbist
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00 , B01J29/00 , B01J37/00
CPC分类号： B01J35/0006 , B01J21/063 , B01J23/8892 , B01J23/94 , B01J37/0201 , B01J38/68 , C10G2/33
摘要： A method of preparing, preferably recycling, a catalyst support material is disclosed and is particularly applicable to recycling a titania support. The invention includes crushing the used catalyst support that is obtained by leaching catalytic components from a used supported catalyst and preferably combining it with new catalyst support in order to provide the required average particle size and ratio of crystal phases. The invention has a number of benefits including making use of used catalyst support materials which have been conventionally disposed of and also providing a method to more efficiently recycle the active component. Where the support is recycled for a similar application, less promoter may be required.
摘要翻译：公开了制备，优选地回收催化剂载体材料的方法，并且特别适用于回收二氧化钛载体。本发明包括将所使用的催化剂载体粉碎，所用的催化剂载体是通过从所使用的负载型催化剂中浸出催化组分而获得的，优选将其与新的催化剂载体结合，以提供所需的平均粒度和结晶相的比例。本发明具有许多益处，其中包括使用常规处理的用过的催化剂载体材料，并提供一种更有效地回收活性组分的方法。如果支持被回收用于类似的应用，则可能需要较少的启动子。

22. 发明授权

US07811963B2 Elongated shaped particles use as a catalyst or support thereof 有权
标题翻译：细长形状的颗粒用作催化剂或其载体
公开(公告)号：US07811963B2
公开(公告)日：2010-10-12
申请号：US10533775
申请日：2003-11-03
申请人： Hilbrand Klaver , Carolus Matthias Anna Maria Mesters , Gerardus Petrus Lambertus Niesen , Guy Lode Magda Maria Verbist
发明人： Hilbrand Klaver , Carolus Matthias Anna Maria Mesters , Gerardus Petrus Lambertus Niesen , Guy Lode Magda Maria Verbist
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00 , B01J29/00 , B01J37/00
CPC分类号： C10G49/04 , B01J21/06 , B01J21/063 , B01J23/74 , B01J23/8892 , B01J32/00 , B01J35/026 , B01J37/0009 , C10G2/32 , C10G2/332
摘要： An elongated-shaped particle having two protrusions; each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, in which each of the six circles touches two neighboring circles and two alternating circles are equidistant to the central circle and may be attached to the central circle, and the two circles adjacent to the two alternating circles (but not the common circle) touching the central circle, minus the space occupied by the four remaining outer circles and including four remaining interstitial regions.
摘要翻译：具有两个突起的细长形状的颗粒; 每个从中心位置延伸并附接到中心位置，其中中心位置沿着颗粒的纵向轴线对准，颗粒的横截面占据由围绕中心圆的六个圆的外边缘包围的空间，其中每个六个圆的接触两个相邻的圆，两个交替的圆与中心圆等距，并且可以附接到中心圆，并且与两个交替的圆（但不是共同的圆）相邻的两个圆接触中心圆，减去四个剩余外圆占据的空间，其中包括四个剩余的间隙区域。

23. 发明申请

US20090134062A1 CATALYST SUPPORT 失效
标题翻译：催化剂支持
公开(公告)号：US20090134062A1
公开(公告)日：2009-05-28
申请号：US12277684
申请日：2008-11-25
申请人： Coen Willem Johannes PIETERSE , Guy Lode Magda Maria Verbist
发明人： Coen Willem Johannes PIETERSE , Guy Lode Magda Maria Verbist
IPC分类号： C10G11/18 , F16M13/00
CPC分类号： B01J32/00 , B01J35/00 , B01J35/0006 , B01J35/023 , B01J35/026 , C10G2/33
摘要： A catalyst support in the shape of a non-planar ring having a bore; wherein there is no rotational symmetry around the axis extending through the centre of the bore defined by the ring, and wherein the ratio of the thickness of the ring to the outer diameter of the ring is less than 0.5. The catalyst support shape is especially advantageous to pack within a fixed bed multitubular reactor such as that used for Fischer-Tropsch reactions. The packing of such shapes can reduce the pressure drop across the tubes with little or no difference in the porosity.
摘要翻译：具有孔的非平面环形状的催化剂载体; 其中围绕延伸穿过由环限定的孔的中心的轴线没有旋转对称，并且其中环的厚度与环的外径的比率小于0.5。催化剂载体形状特别有利于包装在诸如用于费 - 托反应的固定床多管反应器中。这种形状的包装可以减少管上的压降，孔隙度几乎没有差异或没有差异。

24. 发明授权

US09017472B2 Process for preparing a sulphur cement product 有权
标题翻译：硫磺水泥制品的制备方法
公开(公告)号：US09017472B2
公开(公告)日：2015-04-28
申请号：US13321277
申请日：2010-05-18
申请人： Paul de Boer , Yiu Chung Cheng , Michael David Lankshear , Catherine Frances Smura , Guy Lode Magda Maria Verbist , Willem Posthumus
发明人： Paul de Boer , Yiu Chung Cheng , Michael David Lankshear , Catherine Frances Smura , Guy Lode Magda Maria Verbist , Willem Posthumus
IPC分类号： C04B28/36 , C04B20/10
CPC分类号： C04B28/36 , C04B20/1051 , C04B24/40 , C04B24/42 , C04B14/06 , C04B14/28 , C04B14/30 , C04B22/02 , C04B24/2623 , C04B24/36
摘要： A process for the preparation of a sulphur cement product is disclosed. Sulphur is mixed with a coupling agent and with a particulate inorganic material at a temperature at which sulphur is molten to obtain a molten sulphur cement product, which is solidified. The coupling agent is supplied as a solid composition comprising the coupling agent and at least 10 wt %, based upon the weight of the solid composition, of carrier material selected from one or more of wax, inorganic filler and polymer. The coupling agent is chosen from the group of organosilanes and organotitanates.
摘要翻译：公开了一种制备硫磺水泥产品的方法。将硫与偶联剂和颗粒状无机材料在硫熔融的温度下混合，得到固化的熔融硫磺水泥产品。偶联剂以包含偶联剂的固体组合物的形式提供，并且基于固体组合物的重量至少10重量％，选自蜡，无机填料和聚合物中的一种或多种的载体材料。偶联剂选自有机硅烷和有机钛酸酯。

25. 发明授权

US08535433B2 Sulphur cement pre-composition and process for preparing such sulphur cement pre-composition 失效
标题翻译：硫磺水泥预处理和制备这种硫磺水泥预处理的方法
公开(公告)号：US08535433B2
公开(公告)日：2013-09-17
申请号：US12602838
申请日：2008-06-04
申请人： Jochem Okke Boer , Cornelis Hamelink , Guy Lode Magda Maria Verbist
发明人： Jochem Okke Boer , Cornelis Hamelink , Guy Lode Magda Maria Verbist
IPC分类号： C09D1/00
CPC分类号： C04B28/365 , C04B2111/0075 , C04B24/42 , C04B40/0085
摘要： The present invention provides a sulphur cement precomposition, comprising sulphur and at least a polysulphide-containing organosilane in an amount of at least 0.3 wt % based on the weight of the total composition, which polysulphide-containing organosilane is of the general molecular formula: (X3Si)mH(2n+l−m)Cn-Sa-Cn′H(2n′+l−m′)(SiX′3)m′ wherein a is an integer in the range of from 2 to 8, X and X′ each are, independently, a hydrolysable group, n and n′ each are, independently, an integer in the range of from 1 to 4, and m and m′ each are, independently, an integer in the range of from 1 to (2n+1).
摘要翻译：本发明提供一种硫磺水泥预组合物，其包含硫和至少含有多硫化物的有机硅烷，其含量为总组合物重量的至少0.3重量％，该多硫化物的有机硅烷具有以下通式：（ X3Si）mH（2n + 1m）Cn-Sa-Cn'H（2n'+ 1-m'）（SiX'3）m'其中a是2至8范围内的整数，X和X' 独立地是可水解基团，n和n'各自独立地为1至4的整数，m和m'各自独立地为1至（2n + 1）。

26. 发明申请

US20120149835A1 SULPHUR CEMENT PRE-COMPOSITION AND SULPHUR CEMENT PRODUCT 审中-公开
标题翻译：硫磺水泥预组合物和硫酸钙产品
公开(公告)号：US20120149835A1
公开(公告)日：2012-06-14
申请号：US13381440
申请日：2010-06-29
申请人： Michael David Lankshear , Guy Lode Magda Maria Verbist
发明人： Michael David Lankshear , Guy Lode Magda Maria Verbist
IPC分类号： C04B16/04 , C04B12/00
CPC分类号： C04B28/36 , C04B40/0039 , Y02W30/92 , C04B14/06 , C04B18/08 , C04B24/42 , C04B26/22 , C04B26/26 , C04B24/34 , C04B24/36
摘要： A sulphur cement pre-compositionr comprising sulphur and a polysiloxane is disclosed. The polysiloxane comprises a sulphur reactive functional group and/or a hydrolysable group. Sulphur cement products, wax-based pre-compositions, processes for preparing sulphur cement pre-compositions and processes for preparing sulphur cement products are also disclosed.
摘要翻译：公开了包含硫和聚硅氧烷的硫磺水泥预组合物。聚硅氧烷包含硫反应性官能团和/或可水解基团。还公开了硫磺水泥产品，蜡基预组合物，硫磺水泥预制剂的制备方法和硫磺水泥产品的制备方法。

27. 发明申请

US20110186774A1 PROCESSES FOR PREPARING SULPHUR COMPOSITES AND ORGANOSILANE COUPLING AGENTS 审中-公开
标题翻译：制备硫磺复合材料和有机硅偶联剂的方法
公开(公告)号：US20110186774A1
公开(公告)日：2011-08-04
申请号：US13056742
申请日：2009-07-15
申请人： Michael David Lankshear , Jan Hermen Hendric Meurs , Willem Posthumus , Guy Lode Magda Maria Verbist , Marioes Verbruggen
发明人： Michael David Lankshear , Jan Hermen Hendric Meurs , Willem Posthumus , Guy Lode Magda Maria Verbist , Marioes Verbruggen
IPC分类号： C09K3/00
CPC分类号： C04B28/36 , C04B20/1051 , C04B40/0039 , C04B22/14 , C04B24/42 , C04B40/0085 , C04B12/00
摘要： A process for preparing sulphur composites is disclosed. Molten sulphur is combined with filler and/or aggregate, with a compound of formula (I) wherein R1, R2 and R3 are independently chosen from alkoxy, acyloxy, aryloxy, alkyl, aryl and halogen, wherein R4 is alkylene and wherein X is a leaving group; and with a compound of formula (II): MmSn wherein M is a nitrogen-containing cation, a phosphorus-containing cation or a metal atom, m is 1 or 2 and n is from 1 to 8, or M is hydrogen, i is 2 and n is 1, The invention yet further relates to a process for preparing an organosilane coupling agent.
摘要翻译：公开了制备硫化合物的方法。熔融的硫与填料和/或聚集体与式（I）化合物结合，其中R 1，R 2和R 3独立地选自烷氧基，酰氧基，芳氧基，烷基，芳基和卤素，其中R 4是亚烷基，其中X是离开组和式（II）化合物：MmSn其中M是含氮阳离子，含磷阳离子或金属原子，m为1或2，n为1至8，或M为氢，i为 2，n为1，本发明还涉及一种制备有机硅烷偶联剂的方法。

28. 发明授权

US07811966B2 Catalyst, catalyst precursor, and catalyst carrier 有权
标题翻译：催化剂，催化剂前体和催化剂载体
公开(公告)号：US07811966B2
公开(公告)日：2010-10-12
申请号：US12016692
申请日：2008-01-18
申请人： Hans Peter Alexander Calis , Guy Lode Magda Maria Verbist
发明人： Hans Peter Alexander Calis , Guy Lode Magda Maria Verbist
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00 , B01J29/00 , B01J37/00
CPC分类号： B01J35/026 , B01J21/06 , B01J21/063 , B01J23/40 , B01J23/74 , B01J23/745 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J37/0009 , C10G2/332 , C10G47/02 , Y10T428/2982
摘要： A catalyst, catalyst precursor, or catalyst carrier formed as an elongated shaped particle having a cross section comprising three protrusions each extending from and attached to a central position. The central position is aligned along the longitudinal axis of the particle. The cross-section of the particle occupies the space encompassed by the outer edges of six outer circles around a central circle, each of the six outer circles contacting two neighbouring outer circles, the particle occupying three alternating outer circles equidistant to the central circle and the six interstitial regions, the particle not occupying the three remaining outer circles which are between the alternating occupied outer circles. The ratio of the diameter of the central circle to the diameter of the outer occupied circle is more than 1, and the ratio of the diameter of the outer unoccupied circle to the diameter of the outer occupied circle is more than 1. The ratio of the diameter of the outer unoccupied circle to the diameter of the outer occupied circle is more than the ratio of the diameter of the central circle to the diameter of the outer occupied circle.
摘要翻译：形成为细长形状的颗粒的催化剂，催化剂前体或催化剂载体，其具有包括从中心位置延伸并连接到中心位置的三个突起的横截面。中心位置沿着颗粒的纵向轴线排列。颗粒的横截面占据围绕中心圆的六个外圆的外边缘包围的空间，六个外圆中的每一个与两个相邻的外圆接触，颗粒占据与中心圆等距的三个交替的外圆，并且六个间隙区域，颗粒不占据交替占据的外圆之间的三个剩余的外圆。中心圆的直径与外部占有圆的直径之比大于1，外部未占据圆的直径与外部占有圆的直径之比大于1.比例外部未占据圆的直径与外部占有圆的直径大于中心圆的直径与外部占有圆的直径的比率。

29. 发明申请

US20080171655A1 PROCESS FOR PREPARING A CATALYST 审中-公开
标题翻译：制备催化剂的方法
公开(公告)号：US20080171655A1
公开(公告)日：2008-07-17
申请号：US11954346
申请日：2007-12-12
申请人： Edward Julius Creyghton , Carolus Matthias Anna Maria Mesters , Marinus Johannes Reynhout , Guy Lode Magda Maria Verbist
发明人： Edward Julius Creyghton , Carolus Matthias Anna Maria Mesters , Marinus Johannes Reynhout , Guy Lode Magda Maria Verbist
IPC分类号： C07C1/02 , B01J23/75 , B01J23/34
CPC分类号： B01J23/8472 , B01J21/063 , B01J23/75 , B01J23/8892 , B01J37/0009 , B01J37/0201 , B01J37/0215 , B01J37/04 , C10G2/332
摘要： A process for the preparation of a catalyst precursor for use in a reactor, comprising the steps of: (a) coating one or more promoter(s) and/or one or more co-catalyst(s) onto a carrier material to form a coated carrier material; (b) combining a catalyst material with the coated carrier material of step (a); and (c) calcining the material of step (b).
摘要翻译：一种用于制备用于反应器的催化剂前体的方法，包括以下步骤：（a）将一种或多种助催化剂和/或一种或多种助催化剂涂覆到载体材料上以形成涂层载体材料; （b）将催化剂材料与步骤（a）的涂覆的载体材料组合; 和（c）煅烧步骤（b）的材料。

30. 发明授权

US09174872B2 Sulphur cement products 有权
标题翻译：硫磺水泥制品
公开(公告)号：US09174872B2
公开(公告)日：2015-11-03
申请号：US13981110
申请日：2012-01-24
申请人： Willem Posthumus , Catherine Frances Smura , Guy Lode Magda Maria Verbist
发明人： Willem Posthumus , Catherine Frances Smura , Guy Lode Magda Maria Verbist
IPC分类号： C04B28/36 , C04B24/42 , C04B14/06 , C04B40/00
CPC分类号： C04B24/42 , C04B14/06 , C04B28/36 , C04B40/0039 , C04B20/0076 , C04B40/0085 , C04B14/022 , C04B14/28 , C04B24/08 , C04B24/34
摘要： A sulphur cement product comprising sulphur, filler, sand having a surface area of greater than 0.5 m2/g, and an organosilane having at least one amino functional group is disclosed. Further, a process for the preparation of such cement sulphur product is disclosed.
摘要翻译：公开了包含表面积大于0.5m 2 / g的硫，填料，砂的硫磺水泥产品和具有至少一个氨基官能团的有机硅烷。此外，公开了制备这种水泥硫产品的方法。

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