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21. 发明授权

US5104443A Heterocyclic 2-alkoxyphenoxysulfonylureas and the use thereof as herbicides or plant growth regulators 失效
标题翻译：杂环二烷氧基甲硅烷氧基化合物及其作为除草剂或植物生长调节剂的用途
公开(公告)号：US5104443A
公开(公告)日：1992-04-14
申请号：US352167
申请日：1989-05-15
申请人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/34 , A01N47/36 , A01P13/00 , C07D239/34 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D239/70 , C07D249/14 , C07D251/26 , C07D471/04 , C07D473/32 , C07D475/00 , C07D487/04 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula I or salts thereof ##STR1## where R.sup.1 is ethyl, propyl or isopropyl,R.sup.2 is halogen, NO.sub.2, CF.sub.3, CN, alkyl, alkoxy, alkylthio or alkoxycarbonyl,n is 0, 1, 2 or 3, Y is O or S,R.sup.3 is hydrogen, alkyl, alkenyl, alkynyl or alkoxy;R.sup.4 is a heterocyclic radical of the formulae ##STR2## E is CH or N; G is O or CH.sub.2, R.sup.5 and R.sup.6 are hydrogen, halogen, or are alkyl, alkoxy or alkylthio, which are optionally substituted by halogen, alkoxy or alkylthio, or are --NR.sup.12 R.sup.13, --OCHR.sup.7 --CO.sub.2 R.sup.12, (C.sub.3 -C.sub.6 cycloalkyl, (C.sub.3 -C.sub.5)alkenyl, (C.sub.2 -C.sub.4) -alkynyl, (C.sub.3 -C.sub.5)alkenyloxy or (C.sub.3 -C.sub.5 (alkynyloxy; R.sup.7 is hydrogen or alkyl, R.sup.8 is alkyl, --CHF.sub.2 or --CH.sub.2 CF.sub.3 ; R.sup.9 and R.sup.10 are hydrogen, alkyl, alkoxy or halogen; R.sup.11 is hydrogen, alkyl, --CHF.sub.2 or CH.sub.2 CF.sub.3 ; R.sup.12 and R.sup.13 independently of one another are hydrogen, alkyl, alkenyl or alkynyl, possess outstanding herbicidal and plant growth-regulating properties.
摘要翻译：丙基或异丙基，R 2为卤素，NO 2，CF 3，CN，烷基，烷氧基，烷硫基或烷氧基羰基，n为0,1,2或3 Y是O或S，R3是氢，烷基，烯基，炔基或烷氧基; R4是下式的杂环基：E是CH或N; G是O或CH 2，R 5和R 6是氢，卤素或烷基，烷氧基或烷硫基，其任选被卤素，烷氧基或烷硫基取代，或者是-NR 12 R 13，-OCHR 7 -CO 2 R 12，（C 3 -C 6环烷基，（C 3 -C 5）烯基，（C 2 -C 4） - 炔基，（C 3 -C 5）链烯氧基或（C 3 -C 5炔氧基; R 7为氢或烷基，R 8为烷基，-CHF 2或-CH 2 CF 3; R 9和R 10为氢，烷基，烷氧基或卤素; R 11是氢，烷基，-CHF 2或CH 2 CF 3; R 12和R 13彼此独立地是氢，烷基，烯基或炔基，具有优异的除草和植物生长调节性质。

22. 发明授权

US5102443A Heterocyclically substituted phenoxysulfonylureas, and the use thereof as herbicides or plant growth regulators 失效
公开(公告)号：US5102443A
公开(公告)日：1992-04-07
申请号：US351958
申请日：1989-05-15
申请人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/34 , A01N47/36 , A01P13/00 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D249/14 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/26 , C07D251/46 , C07D251/50 , C07D251/52 , C07D251/70 , C07D471/04 , C07D473/32 , C07D475/00 , C07D487/04 , C07D491/044 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Heterocyclically substituted phenoxysulfonylureas, processes for the preparation thereof, and the use thereof as herbicides or plant growth regulators. Compounds of the formula I or the salts thereof ##STR1## where R.sup.1 is (C.sub.1 -C.sub.8)alkyl, (C.sub.2 -C.sub.8)alkenyl or (C.sub.2 -C.sub.8)alkynyl, these radicals being substituted by halogen, saturated or unsaturated (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, -sulfinyl or -sulfonyl, (C.sub.1 -C.sub.6)alkoxycarbonyl, NO.sub.2, CN or phenyl; furthermore is (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl or (C.sub.3 -C.sub.8)cycloalkyl, which can be substituted by halogen or by alkoxy or alkylthio; (C.sub.5 -C.sub.8)cycloalkenyl, cyclopropylmethyl, epoxypropyl; furfuryl, tetrahydrofurfuryl or phenoxy (C.sub.1 -C.sub.4)alkyl, it being possible for the last three substituents mentioned to be substituted by halogen, alkyl or alkoxy; or phenyl which can be substituted by halogen, alkyl, alkoxy, NO.sub.2, CF.sub.3, CN or OCHF.sub.2 ; or, in the event that R.sup.2 is alkenyl, alkynyl, phenyl or phenoxy, each of which can be substituted as indicated below, alkylsulfonyl or alkylsulfinyl and n.noteq., R.sup.1 is also (C.sub.1 -C.sub.8)alkyl,R.sup.2 radicals independently of one another are (C.sub.1 -C.sub.8)-alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, phenyl, phenoxy, (C.sub.1 -C.sub.4)alkoxy, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)-alkoxycarbonyl, (C.sub.2 -C.sub.4)alkenyloxycarbonyl, (C.sub.2 - C.sub.4)alkynyloxycarbonyl, it being possible for all the abovementioned radicals to be substituted by halogen, (C.sub.1 -C.sub.4)alkoxy or (C.sub.1 -C.sub.4)alkylthio; furthermore halogen, NO.sub.2, (C.sub.1 -C.sub.4)alkylsulfonyl or (C.sub.1 -C.sub.4)alkylsulfinyl;n is 0, 1, 2 or 3; y is O or S;R.sup.3 is hydrogen, (C.sub.1 -C.sub.8)alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.3 -C.sub.8)-alkynyl or (C.sub.1 -C.sub.4)alkoxy;R.sup.4 is a heterocyclic radical of the formulae ##STR2## E is CH or N, G is O or CH.sub.2,R.sup.5 and R.sup.6 are hydrogen, halogen, alkyl, alkoxy or alkylthio, it being possible for the abovementioned alkyl-containing radicals to be substituted by halogen, alkoxy or alkylthio, furthermore a radical of the formula --NR.sup.12 R.sup.13, --OCHR.sup.7 --CO.sub.2 R.sup.12, cycloalkyl, alkenyl, alkynyl, alkenyloxy or alkynyloxy,R.sup.7 is hydrogen or alkyl; R.sup.8 is alkyl, --CHF.sub.2 or --CH.sub.2 CF;R.sup.9 and R.sup.10 are hydrogen, alkyl, alkoxy or halogen, R.sup.11 is hydrogen, alkyl, --CHF.sub.2 or CH.sub.2 CF.sub.3, and R.sup.12 and R.sup.13 are hydrogen, alkyl, alkenyl or alkynyl, have outstanding herbicidal and plant growth-regulating properties.

23. 发明授权

US06239306B1 Phenylsulfonylureas, processes for their preparation, and their use as herbicides and plant growth regulations 有权
标题翻译：苯磺酰脲，其制备方法，以及它们作为除草剂和植物生长条件的用途
公开(公告)号：US06239306B1
公开(公告)日：2001-05-29
申请号：US09241213
申请日：1999-02-01
申请人： Klaus Lorenz , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Klaus Lorenz , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07C32716
CPC分类号： C07D521/00 , A01N47/36 , C07C311/46
摘要： Compounds of the formula (I) and their salts as defined in claim 1, in which R1 is CO—Q—R8, where R8=H or R R2 and R3 are H or (C1-C4)alkyl, R4 is H, R, RO, OH, RCO, RSO2, PhSO2 R5 is RSO2, PhSO2, PhCO, RNHSO2, R2NSO2, RCO, CHO, COCOR′, CW—T—R9, CW—NR10R11, CW—N(R12)2 or R4 and R5 together are the chain (CH2)mB or —B1—(CH2)m1B— where B=SO2, m=3, 4; m1=2, 3; T and W=O, S; Q=O, S, NR13 where R13=H, R; R6=H, R, RO, RCO, ROCO, Hal, NO2, CN; R7=H, CH3; R9=R; R10, R11=H, R; N(R12)2=heterocycle A=pyrimidinyl and triazinyl radical or an analog thereof, where R=(substituted) aliphatic hydrocarbon radical, are suitable as selective herbicides. They are prepared by analogous processes via sulfonamides, some of which are new, of the formula (II) (see claim 4).
摘要翻译：式（I）的化合物及其盐如权利要求1所定义，其中R 1为CO-Q-R 8，其中R 8 = H或R 2，R 3为H或（C 1 -C 4）烷基，R 4为H，R ，OH，RCO，RSO2，PhSO2R5是RSO2，PhSO2，PhCO，RNHSO2，R2NSO2，RCO，CHO，COCOR'，CW-T-R9，CW-NR10R11，CW-N（R12）2或R4和R5一起是链（CH2）mB或-B1-（CH2）m1B-，其中B = SO2，m = 3,4; m1 = 2,3; T和W = O，S; Q = O，S，NR 13其中R 13 = H，R; R 6 = H，R，RO，RCO，ROCO，Hal，NO 2，CN; R 7 = H，CH 3; R9 = R; R10，R11 = H，R; N（R 12）2 =杂环A =嘧啶基和三嗪基或其类似物，其中R =（取代的）脂族烃基适合作为选择性除草剂。它们通过磺酰胺类似的方法制备，其中一些是新的式（II）（参见权利要求4）。

24. 发明授权

US06235680B1 N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use 失效
标题翻译： N-酰基磺酰胺，除草剂和解毒剂的新型混合物及其用途
公开(公告)号：US06235680B1
公开(公告)日：2001-05-22
申请号：US08863476
申请日：1997-05-27
申请人： Frank Ziemer , Klaus Haaf , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Frank Ziemer , Klaus Haaf , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N2532
CPC分类号： C07D333/38 , A01N25/32 , C07C311/51 , C07C311/53 , C07C323/62 , C07C333/08 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D307/68 , C07F9/4006
摘要： Novel N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use Safeners against phytotoxic side effects of pesticides in crop plants are compounds of the formula (I) and salts thereof where R1 is hydrogen, a hydrocarbon radical, a hydrocarbonoxy radical, a hydrocarbonthio radical or a heterocyclyl radical, each of the last-mentioned 4 radicals being unsubstituted or substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, carboxyl, formyl, carboxamide, sulfonamide and radicals of the formula —Za—Ra R2 is hydrogen or (C1-C4)-alkyl or R1 and R2 together with the group of the formula —CO—N— are the radical of a 3- to 8-membered saturated or unsaturated ring and R3 to R5, n and m are as defined in claim 1. The compounds can be prepared by the process of claim 8.
摘要翻译：新型N-酰基磺酰胺，除草剂和解毒剂的新型混合物及其用途农药对作物植物的植物毒副作用的安全剂是式（I）化合物及其盐，其中R 1是氢，烃基，烃氧基，烃硫基或杂环基，每个最后提到的4个基团是未取代的或被一个或多个选自卤素，氰基，硝基，氨基，羟基，羧基，甲酰基，甲酰胺，磺酰胺和基团的相同或不同的基团取代式-Za-RaR2是氢或（C1-C4） - 烷基或R1和R2与式-CO-N-的基团是3-至8-元饱和或不饱和环的基团和R3至R5 ，n和m如权利要求1所定义。化合物可以通过权利要求8的方法制备。

25. 发明授权

US5700758A Pyrazolines for protecting crop plants against herbicides 失效
标题翻译：用于保护作物对抗除草剂的吡唑啉
公开(公告)号：US5700758A
公开(公告)日：1997-12-23
申请号：US468850
申请日：1995-06-06
申请人： Wolfgang Rosch , Erich Sohn , Klaus Bauer , Hermann Bieringer
发明人： Wolfgang Rosch , Erich Sohn , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , C07D231/06 , C07D231/54 , C07F7/08 , C07F7/18 , A01N43/56 , A01N43/86
CPC分类号： C07F7/1896 , A01N25/32 , C07D231/06 , C07D231/54 , C07F7/0812
摘要： Compounds of the formula (I) ##STR1## where X, n, R.sup.1, R.sup.2 and R.sup.3 are as defined in claim 1 are suitable as antidotes against phytotoxic secondary effects of herbicides in crop plants without adversely affecting the action of the herbicides against harmful plants.
摘要翻译：其中X，n，R 1，R 2和R 3如权利要求1中所定义的式（I）化合物适合作为除草剂在作物中对植物毒性次要作用的解毒剂，而不会不利地影响除草剂对有害植物的作用。

26. 发明授权

US5318947A Method for controlling harmful plants in rice with 2-benzoyl-1,3-cyclohexanedione derivatives 失效
标题翻译：用2-苯甲酰基-1,3-环己二酮衍生物控制水稻有害植物的方法
公开(公告)号：US5318947A
公开(公告)日：1994-06-07
申请号：US856170
申请日：1992-06-09
申请人： Oswald Ort , Lothar Willms , Hans-Joachim Zeiss , Klaus Bauer , Hermann Bieringer
发明人： Oswald Ort , Lothar Willms , Hans-Joachim Zeiss , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N35/06 , A01N37/34 , A01N41/10 , A01N37/22
CPC分类号： A01N41/10 , A01N35/06
摘要： Compounds of the formula I ##STR1## where R.sup.1 to R.sup.9 are as defined in claim 1 are known as herbicides. When these compounds are applied in traditionally used amounts, this often results in damage to crop plants in the crops, when it is desired to achieve sufficient action against weeds typically occurring therein. However, according to the invention it is possible to reduce the application rates to 0.001 to 0.5 kg of a.i./ha in rice growing, and the action obtained against important harmful plants in rice from the species Sagittaria, Cyperus and Scirpus Eleocharis is nevertheless sufficient.
摘要翻译： PCT No.PCT / EP90 / 01721 Sec。 371日期：1992年6月9日 102（e）日期1992年6月9日PCT提交1990年10月12日PCT公布。出版物WO91 / 05470 日本1991年5月2日。式I的化合物（I）其中R1至R9如权利要求1中所定义，作为除草剂是已知的。当这些化合物以传统使用的量施用时，当期望通过其中通常发生的杂草达到足够的作用时，这通常导致作物对作物的损害。然而，根据本发明，可以将水稻种植中的施用率降低至0.001至0.5kg的a.i./ha，而对于来自S the属（Sagittaria），莎草（Scperus）和Ele the属（Scirpus Eleocharis）的水稻中重要的有害植物所获得的作用仍然足够。

27. 发明授权

US5186736A Heterocyclic N-acylsulfonamides and their use as herbicides or growth regulators 失效
标题翻译：杂环N-酰基磺酰胺及其作为除草剂或生长调节剂的用途
公开(公告)号：US5186736A
公开(公告)日：1993-02-16
申请号：US728632
申请日：1991-07-11
申请人： Oswald Ort , Lothar Willms , Klaus Bauer , Hermann Bieringer , Arno Schulz
发明人： Oswald Ort , Lothar Willms , Klaus Bauer , Hermann Bieringer , Arno Schulz
IPC分类号： A01N43/54 , C07D239/28 , C07D239/34 , C07D239/52 , C07D249/12 , C07D251/16 , C07D251/22 , C07D251/24 , C07D251/26 , C07D401/12 , C07D403/12 , C07D409/12 , C07D473/00 , C07D491/04
CPC分类号： C07D239/28 , A01N43/54 , C07D239/34 , C07D239/52 , C07D249/12 , C07D251/16 , C07D251/22 , C07D251/24 , C07D251/26 , C07D401/12 , C07D403/12 , C07D409/12 , C07D473/00 , C07D491/04
摘要： Compounds of the formula I or salts thereof ##STR1## where R.sup.1 is H or an aliphatic radical; R.sup.2 and R.sup.3 are H, alkyl or phenyl; W is O, S, NR.sup.4 or NOR.sup.4 ; X is CHR.sup.2, O or NR.sup.4 ; L is a (substituted) phenyl, naphthyl or monocyclic heteroaryl radical, A is a (substituted) pyrimidyl, triazinyl, triazolyl or bicyclic heteroaryl radical, and m and n are 0 or 1, have advantageously herbicidal or plant growth-regulating properties.
摘要翻译：式I化合物或其盐，其中R 1为H或脂族基; R2和R3是H，烷基或苯基; W是O，S，NR4或NOR4; X是CHR 2，O或NR 4; L是（取代的）苯基，萘基或单环杂芳基，A是（取代的）嘧啶基，三嗪基，三唑基或双环杂芳基，m和n是0或1，具有有利的除草或植物生长调节性质。

28. 发明授权

US5103017A Pyrazolines and their use as safeners 失效
标题翻译： PYRAZOLINES及其作为SAFENERS使用
公开(公告)号：US5103017A
公开(公告)日：1992-04-07
申请号：US722534
申请日：1991-06-27
申请人： Erich Sohn , Wolfgang Rosch , Klaus Bauer , Hermann Bieringer
发明人： Erich Sohn , Wolfgang Rosch , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N43/56 , C07D231/08
CPC分类号： C07D231/08
摘要： Compounds of the formula (I) ##STR1## where X.sup.1 and X.sup.2 independently of one another are halogen or haloalkyl,R.sup.1 is hydrogen, alkyl or alkyloxyalkyl,R.sup.2 is alkyl or haloalkyl, andR.sup.3 is hydrogen, alkyl, alkenyl or alkynyl,can reduce, or entirely compensate, phytotoxic secondary effects of herbicides on crop plants and are therefore suitable as agents for the selective use of herbicides.

29. 发明授权

US5082949A Phenylpyrazolecarboxylic acid derivative preparation 失效
标题翻译：苯基吡啶羧酸衍生物的制备
公开(公告)号：US5082949A
公开(公告)日：1992-01-21
申请号：US429384
申请日：1989-10-31
申请人： Erich Sohn , Reinhard Handte , Hilmar Mildenberger , Helmut Burstell , Klaus Bauer , Hermann Bieringer
发明人： Erich Sohn , Reinhard Handte , Hilmar Mildenberger , Helmut Burstell , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N43/56 , A01N43/836 , A01N55/10 , C07D231/14 , C07D231/16 , C07D231/24 , C07D403/04 , C07D403/06 , C07D403/10 , C07D405/04 , C07D413/04
CPC分类号： C07D403/04 , A01N25/32 , A01N43/56 , C07D231/14 , C07D231/16 , C07D403/06 , C07D403/10 , C07D413/04
摘要： Compounds of the formula I ##STR1## in which R denotes halogen, hydroxyl, cyano, nitro, (substituted) alkyl, (substituted) alkoxy, (halo)alkylthio, carboxyl, alkoxycarbonyl; (halo)alkylsulf(inyl) (onyl) or -(onyloxy); (halo)phenyl or (halo)phenoxy; X in the 3- or 5-position denotes a (thio)carboxylic acid--or an optionally heterocyclic radical which is derived therefrom; Y denotes halogen, m denotes the number 0 or 1, and n denotes a number from 0 to 5, have valuable plant growth-regulating properties and are suitable, in addition, as safeners for protecting crop plants against phytotoxic side effects of herbicides.

30. 发明授权

US4747868A Growth-regulating, fungicidal, and herbicidal cyclohexylimidazole and cyclohexenylimidazole derivatives, compositions, and methods of use therefor 失效
标题翻译：生长调节，杀真菌和除草环己基咪唑和环己烯基咪唑衍生物，组合物及其使用方法
公开(公告)号：US4747868A
公开(公告)日：1988-05-31
申请号：US853018
申请日：1986-04-17
申请人： Roland Schmierer , Hilmar Mildenberger , Reinhard Handte , Helmut Burstell , Burkhard Sachse , Klaus Bauer , Hermann Bieringer
发明人： Roland Schmierer , Hilmar Mildenberger , Reinhard Handte , Helmut Burstell , Burkhard Sachse , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D413/04 , A01N43/50 , A01N43/82 , A01N43/836 , A01N55/10 , A01N57/24 , C07D233/54 , C07D233/64 , C07D233/66 , C07D233/90 , C07D403/04 , C07D403/06 , C07D403/12 , C07D521/00 , A61K31/415 , C07D231/12
CPC分类号： C07D233/64 , A01N43/50 , A01N43/82 , C07D231/12 , C07D233/56 , C07D233/90 , C07D249/08 , C07D403/04 , C07D403/12
摘要： The new compounds of the formula I or salts thereof ##STR1## in which R denotes a (substituted) cyclohexyl radical or a (substituted) cyclohexenyl radical; and Y denotes cyano, a (substituted) (di)(thio)carboxylic acid (ester), carboxamide or acetal radical, a keto or oxime radical or a heterocyclic radical, possess an advantageous action as plant growth-regulators and, in addition, have favorable herbicidal and fungicidal properties.
摘要翻译：式I的新化合物或其盐，其中R表示（取代的）环己基或（取代的）环己烯基; 并且Y表示氰基，（取代的）（二）（硫代）羧酸（酯），羧酰胺或缩醛基，酮或肟基或杂环基，具有作为植物生长调节剂的有利作用，具有良好的除草和杀真菌性能。

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