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    • 25. 发明授权
    • Developer-soluble materials and methods of using the same in via-first dual damascene applications
    • 显影剂可溶性材料及其在通孔 - 第一双镶嵌应用中的使用方法
    • US07364835B2
    • 2008-04-29
    • US10966909
    • 2004-10-15
    • Mandar BhaveCarlton A. WashburnRama PuligaddaKevin Edwards
    • Mandar BhaveCarlton A. WashburnRama PuligaddaKevin Edwards
    • G03C5/00G03F7/00
    • H01L21/02118G03F7/091H01L21/312H01L21/76808
    • Wet-recess (develop) gap-fill and bottom anti-reflective coatings based on a polyamic acid or polyester platform are provided. The polyamic acid platform allows imidization to form a polyimide when supplied with thermal energy. The gap-fill and bottom anti-reflective coatings are soluble in standard aqueous developers, and are useful for patterning via holes and trenches on semiconductor substrates in a dual damascene patterning scheme. In one embodiment, compositions composed of polyamic acids can be used as gap-filling (via-filling) materials having no anti-reflective function in a copper dual damascene process to improve iso-dense fill bias across different via arrays. In another embodiment, the same composition can be used for anti-reflective purposes, wherein the photoresist can be directly coated over the recessed surface, while it also acts as a fill material to planarize via holes on the substrate. The compositions described here are particularly suitable for use at exposure wavelengths of less than about 370 nm.
    • 提供了基于聚酰胺酸或聚酯平台的湿式凹陷(开发)间隙填充和底部抗反射涂层。 当提供热能时,聚酰胺酸平台允许酰亚胺化形成聚酰亚胺。 间隙填充和底部抗反射涂层可溶于标准含水显影剂,并且可用于在双镶嵌图案化方案中图案化半导体衬底上的通孔和沟槽。 在一个实施方案中,由聚酰胺酸组成的组合物可用作在铜双镶嵌工艺中不具有抗反射功能的间隙填充(通孔填充)材料,以改善穿过不同通孔阵列的等密度填充偏压。 在另一个实施方案中,相同的组合物可以用于抗反射目的,其中光致抗蚀剂可以直接涂覆在凹陷表面上,同时它也用作平坦化基底上的通孔的填充材料。 这里描述的组合物特别适用于小于约370nm的曝光波长。
    • 29. 发明授权
    • Anti-reflective coating compositions comprising polymerized aminoplasts
    • 包含聚合的氨基塑料的抗反射涂料组合物
    • US06399686B1
    • 2002-06-04
    • US09691774
    • 2000-10-18
    • Rama PuligaddaRunhui Huang
    • Rama PuligaddaRunhui Huang
    • B05D302
    • G02B1/111C08L61/28Y10T428/31504Y10T428/31667Y10T428/31862Y10T428/31942
    • Improved anti-reflective coating compositions for use in integrated circuit manufacturing processes and methods of forming these compositions are provided. Broadly, the compositions are formed by heating a solution comprising a compound including specific compounds (e.g., alkoxy alkyl melamines, alkoxy alkyl benzoguanamines) under acidic conditions so as to polymerize the compounds and form polymers having an average molecular weight of at least about 1,000 Daltons. The monomers of the resulting polymers are joined to one another via linkage groups (e.g., —CH2—,—CH2—O—CH2—) which are bonded to nitrogen atoms on the respective monomers. The polymerized compound is mixed with a solvent and applied to a substrate surface after which it is baked to form an anti-reflective layer. The resulting layer has high k values and can be formulated for both conformal and planar applications.
    • 提供用于集成电路制造工艺的改进的抗反射涂料组合物和形成这些组合物的方法。 广泛地,通过在酸性条件下加热包含特定化合物(例如,烷氧基烷基三聚氰胺,烷氧基烷基苯胍胺)的化合物的溶液来形成组合物,以便使化合物聚合并形成平均分子量为至少约1,000道尔顿的聚合物 。 所得聚合物的单体通过与各单体上的氮原子键合的连接基团(例如-CH 2 - , - CH 2 -O-CH 2 - )彼此连接。 将聚合的化合物与溶剂混合并施加到基材表面,然后将其烘焙以形成抗反射层。 所得到的层具有高k值,并且可以适用于共形和平面应用。