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21. 发明授权

US4957962A Fiber composites 失效
标题翻译：纤维复合材料
公开(公告)号：US4957962A
公开(公告)日：1990-09-18
申请号：US271238
申请日：1988-11-14
申请人： Matthias Winkler , Peter Ittemann , Gerhard Heinz
发明人： Matthias Winkler , Peter Ittemann , Gerhard Heinz
IPC分类号： C08J5/04 , C08K7/02 , C08L71/00 , C08L71/08 , C08L81/04 , C08L81/06
CPC分类号： C08J5/04 , C08J5/042 , C08J5/043 , C08L71/00 , C08L81/06 , C08J2371/10 , C08J2381/06
摘要： Fiber composite useful in automotive construction and the aerospace industry are composed of a plastics matrix and reinforcing fibers, this plastics matrix comprising a mixture of from 90 to 40% by weight of polyether sulfone and 10 to 60% by weight of polyether ketone.
摘要翻译：用于汽车结构和航空航天工业的纤维复合材料由塑料基质和增强纤维组成，该塑料基质包含90至40重量％的聚醚砜和10至60重量％的聚醚酮的混合物。

22. 发明授权

US5227455A Polymer granules having improved processability 失效
标题翻译：聚合物颗粒具有改善的加工性能
公开(公告)号：US5227455A
公开(公告)日：1993-07-13
申请号：US939440
申请日：1992-09-04
申请人： Peter Ittemann , Gerhard Heinz
发明人： Peter Ittemann , Gerhard Heinz
IPC分类号： C08K5/07 , C08K5/3417 , C08K5/41 , C08L71/00 , C08L79/08
CPC分类号： C08L79/08 , C08K5/07 , C08K5/3417 , C08K5/41 , C08L71/00
摘要： Premix for the production of mouldings, containingA) from 40-99.95% by weight of polymer granules A based on a polyaryl ether sulfone, polyaryl ether ketone, polyimide, polyamide imide or polyether imide, or a mixture thereof,B) up to 50% by weight of fillers B in fiber or particle form, or a mixture thereof,C) from 0.05-10% by weight of a compound C ether of the general formula X ##STR1## where A1 to A7 are identical or different and, independently of one another, are a radical of the formula --CO--, --O--, --S--, --SO.sub.2 --, --C(CH.sub.3).sub.2 --, a chemical bond, ##STR2## and k, l, m, n, p and q are each 0 or 1, or a C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy or cyano derivative thereof which is substituted on the aromatic ring, or of the general formula Y ##STR3## where R is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy or cyano, A8 to A11 are as defined for A1 to A7, r, s and t are 0 or 1, and x is 2, 3 or 4, or a mixture thereof,is described.
摘要翻译：用于生产模制品的预混料，含有A）40-99.95重量％的基于聚芳基醚砜的聚合物颗粒A，聚芳基醚酮，聚酰亚胺，聚酰胺酰亚胺或聚醚酰亚胺，或其混合物，B）最多50 纤维或颗粒形式的填料B的重量％，或其混合物，C）0.05-10重量％的通式X（X）的化合物C醚，其中A1至A7为相同或不同并且彼此独立地是式-CO - ， - O - ， - S - ， - SO 2 - ， - C（CH 3）2 - ，化学键， l，m，n，p和q各自为0或1，或其在芳环上被取代的C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基或氰基衍生物，或通式Y 其中R为C1-C8-烷基，C1-C8-烷氧基或氰基，A8至A11如A1至A7所定义，r，s和t分别为0或1，x为2,3或 4或其混合物。

23. 发明授权

US4798855A Thermoplastic molding materials 失效
标题翻译：热塑性成型材料
公开(公告)号：US4798855A
公开(公告)日：1989-01-17
申请号：US49226
申请日：1987-05-13
申请人： Dietrich Lausberg , Gerd Blinne , Peter Ittemann , Gerhard Heinz , Erhard Seiler , Manfred Knoll
发明人： Dietrich Lausberg , Gerd Blinne , Peter Ittemann , Gerhard Heinz , Erhard Seiler , Manfred Knoll
IPC分类号： C08K3/00 , C08G65/48 , C08L3/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L71/00 , C08L77/00 , C08L81/04 , C08L81/06 , C08L101/00 , C08L63/02
CPC分类号： C08L71/00 , C08G65/48 , C08L77/00 , C08L81/06 , Y10S525/906 , Y10S525/93
摘要： Thermoplastic molding materials contain, as essential components,(A) from 2 to 97.9% by weight of a nylon,(B) from 2 to 97.9% by weight of a polyaryl ether sulfone(C) from 0.1 to 30% by weight of a polymeric component having hydroxyl groupsand in addition(D) from 0 to 50% by weight of a rubber impact modifier and(E) from 0 to 60% by weight of reinforcing fillers.
摘要翻译：热塑性成型材料作为必要成分含有（A）2〜97.9重量％的尼龙，（B）2〜97.9重量％的聚芳醚醚（C），0.1〜30重量％具有羟基的聚合物组分，以及（D）0至50重量％的橡胶抗冲改性剂和（E）0至60重量％的增强填料。

24. 发明授权

US5081215A Preparation of polyaryleneetherketones 失效
标题翻译：聚乙二醇的制备
公开(公告)号：US5081215A
公开(公告)日：1992-01-14
申请号：US393793
申请日：1989-08-15
申请人： Juergen Koch , Wolfgang Stegmaier , Gerhard Heinz
发明人： Juergen Koch , Wolfgang Stegmaier , Gerhard Heinz
IPC分类号： C08G65/40 , C08G61/12
CPC分类号： C08G61/127
摘要： Polyaryleneetherketones are prepared by a quasicontinuous process, by Friedel-Crafts polycondensation of a reaction mixture containingA. a monomer system of(a)(1) an aromatic dicarboxylic acid chloride or phosgene and(2) a polynuclear aromatic having two exchangeable hydrogen atoms and/or(b) a polynuclear aromatic carboxylic acid chloride having one exchangeable hydrogen atom,B. a Lewis acid,C. if necessary, a Lewis base andD. an inert solvent.The reaction mixture is subjected to polycondensation in a first zone, with stirring, to a viscosity of not more than 2,000 mPa.s, then conveyed through a second, vertical, unstirred zone with plug flow by means of gas pressure, where the polycondensation is completed, and is finally discharged continuously.
摘要翻译：聚芳醚醚通过准连续法制备，通过Frieder-Crafts缩聚反应混合物，该反应混合物含有（a）（1）芳族二羧酰氯或光气的单体体系，和（2）具有两个可交换氢原子的多核芳烃和 /或（b）具有一个可交换氢原子的多核芳族羧酰氯，B.路易斯酸，C.如果需要，路易斯碱和D.惰性溶剂。反应混合物在搅拌下在第一区域进行缩聚，粘度不大于2,000mPa.s，然后通过气体压力通过气流压力输送通过第二垂直的未搅拌区域，其中缩聚反应完成，终于不停地出院。

25. 发明授权

US4940629A Fiber reinforced thermoplastic integral skin foams and manufacture thereof 失效
标题翻译：纤维增强热塑性整体皮肤泡沫及其制造
公开(公告)号：US4940629A
公开(公告)日：1990-07-10
申请号：US342143
申请日：1989-04-24
申请人： Heinz Weber , Gerhard Bleckmann , Gerhard Dembek , Gerd Ehrmann , Gerhard Heinz , Lothar Schlemmer
发明人： Heinz Weber , Gerhard Bleckmann , Gerhard Dembek , Gerd Ehrmann , Gerhard Heinz , Lothar Schlemmer
IPC分类号： C08J9/12 , C08J9/00 , C08J9/34 , C08J9/36 , B32B7/02 , B32B3/26
CPC分类号： C08J9/34 , C08J9/0085 , C08J9/36 , Y10T428/2495 , Y10T428/24992 , Y10T428/249953 , Y10T428/249988 , Y10T428/249989 , Y10T442/652
摘要： Fiber reinforced thermoplastic integral skin foams of density 50-500 kg/m.sup.3 have an outer skin 0.05 to 1.5 mm in thickness and contain from 2 to 60% by weight of reinforcing fibers.
摘要翻译：密度为50-500kg / m 3的纤维增强热塑性整体皮肤泡沫具有厚度为0.05至1.5mm的外皮，并含有2至60重量％的增强纤维。

26. 发明授权

US4925910A Heat-stable copolycondensate molding materials 失效
标题翻译：热稳定共缩聚成型材料
公开(公告)号：US4925910A
公开(公告)日：1990-05-15
申请号：US36446
申请日：1987-04-09
申请人： Gerhard Heinz
发明人： Gerhard Heinz
IPC分类号： C08G65/40 , C08G75/00 , C08G75/20 , C08G75/23 , C08L71/00 , H05K1/03
CPC分类号： C08G75/23 , C08G65/4012 , C08G75/20 , C08L71/00 , C08L2205/05 , H05K1/0333 , H05K1/0373
摘要： Copolycondensate molding materials are obtainable by polycondensation offrom 2 to 98 mol % of 2,2-di-(4'-hydroxyphenyl)-propane (A),from 2 to 98 mol % of 4,4'-dihydroxydiphenyl sulfone (B) andfrom 0 to 96 mol % of (C) ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy, X is a chemical bond, --S--, --O--, --CO--, CR.sup.3 R.sup.4 (where R.sup.3 and R.sup.4 are different when n and p are each 0), or SO.sub.2 -- only when n or p is 0), R.sup.3 and R.sup.4 are each H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl or halogen-substituted alkyl of 1 to 4 carbon atoms, m is 0 or 1, and n and p are each 0, 1, 2, 3, or 4,with from 1 to 100 mol % of (D) ##STR2## where R.sup.5 and R.sup.6 have the same meaning as R.sup.1 and R.sup.2, and v and w are each 0, 1, 2, 3 or 4, and from 0 to 99 mol % of (E) ##STR3## where R.sup.7 -R.sup.10 are each Cl or F or have the same meanings as R.sup.1 and R.sup.2, q is 0 or 1, r, s, t and n are each 0, 1, 2, 3 or 4, Z.sub.1 is --SO.sub.2 -- or --CO-- and Z.sub.2 is --O--, --S--, --SO.sub.2 --, --CO-- or a chemical bond,with the proviso that one or more of the components C and E are present and the molar ratio of B to the sum of A and C is not greater than 1.
摘要翻译：共缩聚成型材料可以通过2〜98摩尔％的2,2-二（4'-羟基苯基） - 丙烷（A），2〜98摩尔％的4,4'-二羟基二苯基砜（B）的缩聚得到，和0至96摩尔％的（C）其中R 1和R 2各自为H，C 1 -C 6烷基或C 1 -C 6 - 烷氧基，X为化学键，-S - ， - O - ， - CO - ，CR 3 R 4（其中当n和p各自为0时，R 3和R 4不同）或者仅在n或p为0时为SO 2），R 3和R 4各自为H，C 1 -C 6烷基，C 1 -C 6 - 烷氧基， 1至4个碳原子的芳基或卤素取代的烷基，m为0或1，n和p各自为0,1,2,3或4，其中（D）为1至100摩尔％其中R 5和R 6具有与R 1和R 2相同的含义，v和w各自为0,1,2,3或4，和0至99mol％的（E），其中R 7 -R 10各自为Cl 或F或具有与R 1和R 2相同的含义，q为0或1，r，s，t和n各自为0,1,2,3或4，Z 1为-SO 2 - 或-CO-，Z 2为 - O-，-S-，-SO 2 - ， - CO-或化学键，条件是组分C和E中的一种或多种并且B与A和C之和的摩尔比不大于1。

27. 发明授权

US4837296A Preparation of polyaryl ether ketones 失效
标题翻译：聚芳醚酮的制备
公开(公告)号：US4837296A
公开(公告)日：1989-06-06
申请号：US141726
申请日：1988-01-11
申请人： Gerhard Heinz , Juergen Koch , Manfred Eggersdorfer , Jochem Henkelmann
发明人： Gerhard Heinz , Juergen Koch , Manfred Eggersdorfer , Jochem Henkelmann
IPC分类号： C08G65/40
CPC分类号： C08G65/4087 , C08G65/4012
摘要： Polyaryl ether ketones are prepared by reacting aromatic dihydroxy compounds with aromatic dihalogen compounds in polar aprotic solvents in the presence of alkali metal carbonates, in particular by reacting aromatic dihydroxy compounds I ##STR1## or ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof, n and m each being 0 or 1, with aromatic dihalogen compounds ##STR2## or ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof, r and s each being 0 or 1, A being oxygen or a chemical bond and X being chlorine or fluorine.
摘要翻译：聚芳基醚酮通过芳族二羟基化合物与芳族二卤代化合物在极性非质子溶剂中在碱金属碳酸盐存在下反应来制备，特别是通过使芳族二羟基化合物（I）和/或环取代的C1-C8 - 烷基，C 1 -C 8 - 烷氧基，芳基，氯或氟衍生物，n和m各自为0或1，与芳族二卤化合物（II）或环取代的C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基，芳基，氯或氟衍生物，r和s各自为0或1，A为氧或化学键，X为氯或氟。

28. 发明授权

US4418180A Preparation of branched block copolymers 失效
公开(公告)号：US4418180A
公开(公告)日：1983-11-29
申请号：US296849
申请日：1981-08-27
申请人： Gerhard Heinz , Burghard Schmitt , Ingo H. Dorn , Hermann Gausepohl , Karl Gerberding , Rudolf H. Jung , Hans Mittnacht , Jurgen Pohrt , Paul Witimer
发明人： Gerhard Heinz , Burghard Schmitt , Ingo H. Dorn , Hermann Gausepohl , Karl Gerberding , Rudolf H. Jung , Hans Mittnacht , Jurgen Pohrt , Paul Witimer
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： A process for the preparation of branched block copolymers of from 60 to 95% by weight of a monovinyl-aromatic monomer and from 40 to 5% by weight of a conjugated diene by polymerizing the monomers in an inert solvent in the presence of a monolithium-hydrocarbon as the initiator, wherein, in a first process stage (a), from 50 to 80, or where necessary at most 90, % by weight of the total amount of monovinyl-aromatic compound are polymerized to virtually complete conversion in the presence of a relatively small amount of the monolithium-hydrocarbon. This stage is carried out by starting with from 30 to 70% by weight of the vinyl-aromatic monomer and adding from 70 to 30% by weight in the feed, during the polymerization, in such a way that the polymerization temperature, which at the start of the polymerization is from 30.degree. to 40.degree. C., is kept at from 45.degree. to 70.degree. C., with use of reflux cooling. After all the monomer feed has been added, the reaction temperature is lowered to 30.degree.-40.degree. C. by evaporative cooling. In a second process stage (b), an additional amount of initiator is added to the reaction solution, after which from 1 to 30% by weight of the total amount of monovinyl-aromatic monomer can be added, the sum of the amounts of monovinyl-aromatic monomer added in the first and second process stages being at most 90% by weight of the total amount of monovinyl-aromatic monomer. The monovinyl-aromatic monomer added in the second process stage is polymerized to virtually complete conversion, employing the temperature profile described for stage (a). In process stage (c), the remainder of the monovinyl-aromatic monomer and all of the conjugated diene are added, at least predominantly in the form of a mixture, and polymerized so that the reaction temperature does not rise above 90.degree.-110.degree. C. Finally, after virtually complete conversion of the monomers, and preferably without prior cooling, a suitable liquid polyfunctional coupling agent is run in undiluted and the mixture of the linear block copolymers obtained, which still contain active terminal lithium-carbon bonds, is coupled, with stirring, to form branched block copolymers. The products prepared according to the invention are used for injection molding.

29. 发明授权

US4251411A Process for the manufacture of organic polymer polyol 失效
标题翻译：制备有机聚合物多元醇的方法
公开(公告)号：US4251411A
公开(公告)日：1981-02-17
申请号：US941285
申请日：1978-09-11
申请人： Gerhard Heinz , Hermann Dikow , Wolfgang Jarre , Dietmar Nissen , Klaus Matthias , Hanshelmut Kaeppel
发明人： Gerhard Heinz , Hermann Dikow , Wolfgang Jarre , Dietmar Nissen , Klaus Matthias , Hanshelmut Kaeppel
IPC分类号： C08G18/08 , C08G18/62 , C08G18/63 , C08J3/09 , C08J9/00 , C08K5/05
CPC分类号： C08J3/09 , C08G18/14 , C08G18/62 , C08G18/635 , C08J9/0061
摘要： A process for the manufacture of partially dehydrated organic polymer polyol dispersions from the reaction of polyhydroxyl compounds and aqueous polymer dispersions wherein the problem of excessive viscosity is overcome by mixing the reactants with a recycled partially dehydrated polyol polymer dispersion, removing water from the reaction mixture, removing a portion of the partially dehydrated polyol polymer dispersion, and recycling the remainder.
摘要翻译：从多羟基化合物和聚合物水分散体的反应制备部分脱水的有机聚合物多元醇分散体的方法，其中通过将反应物与循环的部分脱水多元醇聚合物分散体混合来克服过度粘度的问题，从反应混合物中除去水，除去部分脱水的多元醇聚合物分散体的一部分，并循环剩余部分。

30. 发明授权

US07419740B2 Membrane electrode unit for polymer electrolyte fuel cells and a process for the production thereof 有权
标题翻译：用于聚合物电解质燃料电池的膜电极单元及其制造方法
公开(公告)号：US07419740B2
公开(公告)日：2008-09-02
申请号：US09907961
申请日：2001-07-19
申请人： Matthias Binder , Ralf Zuber , Markus Vogt , Gerhard Heinz
发明人： Matthias Binder , Ralf Zuber , Markus Vogt , Gerhard Heinz
IPC分类号： H01M4/90 , H01M4/86 , H01M4/88 , H01M8/02 , H01M8/10
CPC分类号： H01M4/926 , H01M4/881 , H01M4/8828 , H01M4/92 , H01M4/921 , H01M8/1004 , Y02P70/56
摘要： A membrane electrode assembly for polymer electrolyte fuel cells consisting of a polymer electrolyte membrane, both faces of which are in contact with porous reaction layers and gas distributor layers. The reaction layers contain noble metal catalysts supported on carbon and a proton-conducting polymer, a so-called ionomer. At least one of the two reaction layers also contains a noble metal black.
摘要翻译：一种用于聚合物电解质燃料电池的膜电极组件，其由聚合物电解质膜组成，其两面都与多孔反应层和气体分配器层接触。反应层含有负载在碳上的贵金属催化剂和质子传导性聚合物，即所谓的离聚物。两个反应层中的至少一个还含有贵金属黑色。

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