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21. 发明授权

US5869627A Stabilised dye composition 失效
标题翻译：稳定的染料组成
公开(公告)号：US5869627A
公开(公告)日：1999-02-09
申请号：US981645
申请日：1998-01-08
申请人： Peter Gregory , Ronald Wynford Kenyon , Paul Wight
发明人： Peter Gregory , Ronald Wynford Kenyon , Paul Wight
IPC分类号： C09B31/072 , C09B31/08 , C09B67/24 , C09B67/42 , C09B67/26
CPC分类号： C09B31/08 , C09B67/0072
摘要： A composition of a water-soluble bis-azo dye of the Formula (1) and an oxidising agent. ##STR1## wherein A is optionally substituted phenyl or optionally substituted naphthyl;B is optionally substituted phenylene or optionally substituted naphthylene;R.sup.1 is H or sulpho;R.sup.2 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl;R.sup.3 is H, optionally substituted aryl, optionally substituted alkyl or a group, -D-E,D is optionally substituted C.sub.2-6 -alkylene; andE is a group of the Formula (1a): ##STR2## R.sup.4 & R.sup.5 each independently is H or optionally substituted alkyl; andR.sup.6 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl.
摘要翻译： PCT No.PCT / GB96 / 01561 Sec。 371日期1998年1月8日 102（e）1998年1月8日PCT PCT 1996年6月28日PCT公布。出版物WO97 / 03132 日本1997年1月30日为式（1）的水溶性双偶氮染料和氧化剂的组合物。（1）其中A是任选取代的苯基或任选取代的萘基; B是任选取代的亚苯基或任选取代的亚萘基; R1是H或磺基; R2是H，任选取代的烷基，任选取代的芳基或任选取代的酰基; R3是H，任选取代的芳基，任选取代的烷基或基团，-D-E，D是任选取代的C 2-6 - 亚烷基; 和E是式（1a）的基团：或任选取代的烷基; 并且R 6是H，任选取代的烷基，任选取代的芳基或任选取代的酰基。

22. 发明授权

US5843218A Bisazo inkjet dyes 失效
标题翻译：双偶氮喷墨染料
公开(公告)号：US5843218A
公开(公告)日：1998-12-01
申请号：US947865
申请日：1997-10-09
申请人： Peter Gregory , Prahalad Manibhai Mistry , Roy Bradbury , Paul Wight
发明人： Peter Gregory , Prahalad Manibhai Mistry , Roy Bradbury , Paul Wight
IPC分类号： C09B31/08 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B31/08
摘要： A bisazo dye of Formula (1) and salts thereof: ##STR1## wherein: R.sub.1 and R.sub.2 together with the carbon atoms to which they are attached form a 5- or 6- membered carbocyclic ring which is optionally substituted by SO.sub.3 H; R.sub.3 and R.sub.4 are each independently H or C.sub.1-4 -alkyl; y is 1, 2, 3 or 4; and n is 1, 2 or 3. The dyes are useful for ink jet printing.
摘要翻译：式（1）的双偶氮染料及其盐：式（1）其中：R1和R2与它们所连接的碳原子一起形成5-或6-元碳环，其任选被SO 3 H取代 ; R 3和R 4各自独立地为H或C 1-4 - 烷基; y为1,2,3或4; 并且n为1,2或3.染料可用于喷墨印刷。

23. 发明授权

US5779778A Ink composition containing a mixture of benzodifuranone dyes 失效
标题翻译：含有苯并呋喃酮染料混合物的油墨组合物
公开(公告)号：US5779778A
公开(公告)日：1998-07-14
申请号：US831935
申请日：1997-04-02
申请人： Peter Gregory , Alan Thomas Leaver
发明人： Peter Gregory , Alan Thomas Leaver
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C07D493/04 , C09B57/00 , C09D11/00 , D06P5/00 , D06P5/30 , G03G9/09 , C09D11/02
CPC分类号： C09D11/328 , D06P5/30 , G03G9/0906 , G03G9/0912
摘要： An ink composition comprising: (i) a medium comprising a low melting point solid, an organic solvent, or a mixture of water and one or more water-soluble organic solvent(s); and (ii) from 0.5 to 20% based on the total weight of the ink composition of at least one dye selected from a dye of Formula (1), a dye of Formula (2) and a dye of Formula (3) or a mixture thereof: ##STR1## wherein: R and R.sup.1 each independently represent an alkylene group; andR.sup.2 and R.sup.3 each independently represent an alkyl group. Also claimed is a process for ink jet printing of textiles using the inks, a process for ink jet printing a substrate with the inks and a toner resin composition containing a dye of Formula (1), (2) or (3) or a mixture thereof.
摘要翻译：一种油墨组合物，其包含：（i）包含低熔点固体，有机溶剂或水与一种或多种水溶性有机溶剂的混合物的介质; 和（ii）基于油墨组合物的至少一种选自式（1）的染料，式（2）的染料和式（3）的染料或式（3）的染料的染料的总重量的0.5至20％式（1）其中：R 1和R 2各自独立地表示亚烷基; 并且R 2和R 3各自独立地表示烷基。还要求保护的是使用油墨的纺织品喷墨印刷的方法，用油墨喷射印刷基材的方法和含有式（1），（2）或（3）的染料的调色剂树脂组合物或混合物其中。

24. 发明授权

US5756692A Chemical compounds 失效
标题翻译：化合物
公开(公告)号：US5756692A
公开(公告)日：1998-05-26
申请号：US768941
申请日：1996-12-18
申请人： Peter Gregory , Ronald Wynford Kenyon , Paul Wight
发明人： Peter Gregory , Ronald Wynford Kenyon , Paul Wight
IPC分类号： B41J2/01 , C07D251/52 , C07D251/70 , C09B33/10 , C09B43/16 , C09D11/00 , C09D11/02 , D06P5/00 , D06P5/30 , D06P1/06
CPC分类号： C09D11/328 , C09B43/16 , D06P5/30
摘要： A bisazo compound of the Formula (1) and salts thereof: ##STR1## wherein the variables are as defined in the specification, the compounds of Formula (1) being free from fibre-reactive groups and any carboxyl substituents present in the compounds being attached in the form of one or more residue of the following formulae: ##STR2## Also claimed are ink compositions comprising the above compound; a precess for printing substrates with the ink compositions using an ink-jet printer; paper, project slides and textile materials printed with the ink compositions; and a process for coloration of textile materials with the ink compositions.
摘要翻译：式（1）的双偶氮化合物及其盐：其中变量如说明书中所定义，式（1）的化合物不含纤维反应性基团和任何羧基取代基存在于化合物以一种或多种下式的残基的形式连接：还涉及包含上述化合物的油墨组合物; 使用喷墨打印机用油墨组合物印刷基材的进程; 纸，项目幻灯片和用油墨组合物印刷的纺织材料; 以及用油墨组合物着色纺织材料的方法。

25. 发明授权

US5755862A Monoazo dyes useful in ink compositions for printing on substrates by ink-jet printing 失效
标题翻译：可用于通过喷墨印刷在基材上印刷的油墨组合物中的单偶氮染料
公开(公告)号：US5755862A
公开(公告)日：1998-05-26
申请号：US831951
申请日：1997-04-02
申请人： Peter Gregory , Prakash Patel
发明人： Peter Gregory , Prakash Patel
IPC分类号： C09D11/00 , G03G9/09 , C09D11/02
CPC分类号： C09D11/328 , G03G9/091
摘要： An ink composition comprising (i) a medium comprising a mixture of water and one or more water-soluble organic solvent(s), an organic solvent, or a low melting point solid; and (ii) a dye of Formula (1) or salt thereof: ##STR1## wherein: each X.sup.1 independently is a labile or non-labile substituent;each T independently is --O--, --S-- or --NR.sup.1 --; each L.sup.1 independently is a divalent organic linker group; each V.sup.1 independently is a group which is capable of undergoing an addition reaction or an elimination and addition reaction; each R.sup.1 independently is H or optionally substituted alkyl; Z is the residue of a coupling component; and m and n are each independently 0 or 1. Also claimed is a composition comprising the ink and a nucleophilic agent; a process for ink jet printing of a substrate wherein the ink is applied to the substrate using an ink jet printer together with a nucelophilic agent and heating and/or basifying the ink and nucelophilic agent thereby causing the dye present in the ink and the nucleophilic agent to react together; and a toner resin composition comprising a toner resin and a dye of Formula (1).
摘要翻译：一种油墨组合物，其包含（i）包含水和一种或多种水溶性有机溶剂，有机溶剂或低熔点固体的混合物的介质; 式（1）所示的染料或其盐：其中：每个X1独立地是不稳定或非不稳定的取代基; 每个T独立地是-O - ， - S-或-NR1-; 每个L1独立地是二价有机连接基团; 每个V1独立地是能够进行加成反应或消除和加成反应的基团; 每个R 1独立地是H或任选取代的烷基; Z是偶联组分的残基; 并且m和n各自独立地为0或1.还要求保护的是包含油墨和亲核剂的组合物; 用于喷墨印刷基材的方法，其中使用喷墨打印机将油墨与难溶性剂一起施加到基材上，并且加热和/或使油墨和纳米脂质体碱化，从而使存在于油墨中的染料和亲核剂一起反应以及包含调色剂树脂和式（1）的染料的调色剂树脂组合物。

26. 发明授权

US5423906A Trisazo dyes, inks comprising same and their use in ink jet printing 失效
标题翻译：三唑系染料，包含其的油墨及其在喷墨印刷中的用途
公开(公告)号：US5423906A
公开(公告)日：1995-06-13
申请号：US108425
申请日：1993-08-19
申请人： Peter Gregory , Prahalad M. Mistry
发明人： Peter Gregory , Prahalad M. Mistry
IPC分类号： B41M5/00 , C09B35/46 , C09B67/22 , C09D11/00 , C09D11/02 , D06P5/00
CPC分类号： C09D11/328 , C09B35/461 , Y10T428/31993
摘要： A compound of Formula (1) or salt thereof: ##STR1## wherein: R.sup.1 is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, CO.sub.2 H, SO.sub.3 H or --NR.sup.3 R.sup.4 ;R.sup.2 is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, CO.sub.2 H or SO.sub.3 H;R.sup.3 and R.sup.4 are each independently H, C.sub.1-18 -alkyl or R.sup.3 and R.sup.4, together with the nitrogen atom to which they are attached, form an optionally substituted 5- or 6-membered ring;W is --OH and X is --NH.sub.2, or W is --NH.sub.2 and X is --OH; andY and Z are each independently --OH or --NR.sup.3 R.sup.4.The compound is suitable for use as a black component of ink jet printing inks.
摘要翻译：式（1）的化合物或其盐：其中：R 1是H，C 1-4 - 烷基，C 1-4 - 烷氧基，CO 2 H，SO 3 H或-NR 3 R 4; R2是H，C1-4 - 烷基，C1-4 - 烷氧基，CO2H或SO3H; R 3和R 4各自独立地为H，C 1-18 - 烷基或R 3和R 4与它们所连接的氮原子一起形成任选取代的5-或6-元环; W是-OH，X是-NH 2，或W是-NH 2，X是-OH; Y和Z各自独立地为-OH或-NR 3 R 4。该化合物适合用作喷墨印刷油墨的黑色组分。

27. 发明授权

US5374301A Inks suitable for use in ink jet printing 失效
标题翻译：油墨适用于喷墨打印
公开(公告)号：US5374301A
公开(公告)日：1994-12-20
申请号：US983170
申请日：1992-11-30
申请人： Peter Gregory , Ronald W. Kenyon
发明人： Peter Gregory , Ronald W. Kenyon
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： An ink comprising a liquid medium and a compound of Formula (1) or salt thereof: ##STR1## provided (i) if the compound of Formula (1) has no --SO.sub.3 H groups then it has at least two groups selected from --COOH and --COSH; and (ii) the compound of Formula (1) has at least as many groups selected from --COOH and --COSH as --SO.sub.3 H groups. The inks are useful for ink-jet printing.
摘要翻译：包含液体介质和式（1）化合物或其盐的油墨：（i）如果式（1）的化合物不具有-SO 3 H基团，则其具有至少两个选自以下的基团： -COOH和-COSH; 和（ii）式（1）的化合物具有至少一个选自-COOH和-COSH的基团作为-SO 3 H基团。这些油墨可用于喷墨打印。

28. 发明授权

US5234887A Thermal transfer printing 失效
标题翻译：热转印
公开(公告)号：US5234887A
公开(公告)日：1993-08-10
申请号：US791903
申请日：1991-07-10
申请人： Peter Gregory , Raymond White , Geoffrey Rothwell , Roy Porter
发明人： Peter Gregory , Raymond White , Geoffrey Rothwell , Roy Porter
IPC分类号： B41M5/035 , B41M5/26 , B41M5/388
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914 , Y10T428/265
摘要： A thermal transfer printing sheet comprising a substrate having a coating comprising a dye of the formula:A--N.dbd.N--EwhereinA is a phenyl group substituted by at least one electron-withdrawing group selected from NO.sub.2, CN, CF.sub.3, halogen, --SO.sub.2 --C.sub.1-4 -alkyl, --SO.sub.2 F, --SO.sub.2 CF.sub.3, --SO.sub.2 NRR.sup.1, --CONRR.sup.1, --COOR, --CO--CO--R, wherein R and R.sup.1 are independently selected from H and C.sub.1-4 alkyl, provided that where A carries only two halogen atoms these are not in the 2- and 6- positions in relation to the azo link;and E is the radical of an aniline, a tetrahydroquinoline, a lilolidine or a julolidine coupling component, and a thermal transfer printing process for the coloration of a polymeric substrate using the thermal transfer printing sheet.
摘要翻译：一种热转印片，其包含具有下式染料的涂层的基材：AN = NE，其中A是被至少一个选自NO 2，CN，CF 3，卤素，-SO 2 -C 1的吸电子基团取代的苯基其中R和R 1独立地选自H和C 1-4烷基，条件是其中A仅携带两个卤素，其中R 1和R 2独立地选自H和C 1-4烷基，原子相对于偶氮键不在2-和6-位; E是苯胺，四氢喹啉，左旋兰碱或久洛尼定偶联组分的基团，以及使用热转印印刷片对聚合物基材着色的热转印印刷方法。

29. 发明授权

US4829048A Thermal transfer printing 失效
公开(公告)号：US4829048A
公开(公告)日：1989-05-09
申请号：US252988
申请日：1988-10-04
申请人： Peter Gregory , Richard A. Hann
发明人： Peter Gregory , Richard A. Hann
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52
CPC分类号： B41M5/3858 , B41M5/3852 , B41M5/388 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer printing sheet comprising a substrate having a coating comprising:(1) an anthraquinone dye of the formula: ##STR1## wherein each of R.sup.1 and R.sup.2, independently, represents hydrogen or C.sub.1-4 -alkyl and rings A and B are optionally substituted in the free positions by non-ionic groups, and(2) a monoazo dye of the formula: ##STR2## wherein each of R.sup.3 and R.sup.4, independently, represents C.sub.1-4 -alkyl optionally substituted by halogen, cyano, phenyl, C.sub.1-4 -alkoxy, C.sub.1-4 -alkoxycarbonyl, C.sub.1-4 -alkylcarbonyloxy, R.sup.6 CONH--, R.sup.6 NHCO-- or R.sup.6 NHCOO-- in which R.sup.6 represents C.sub.1-4 -alkyl or optionally substituted aryl;R.sup.5 represents hydrogen, halogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C.sub.1-4 -alkylthio, beta-cyanoethyl, C.sub.1-4 -alkylcarbonylamino or C.sub.1-4 -alkylsulphonylamino; andQ represents a heterocyclic radical selected from radicals of the formula: ##STR3## wherein V represents hydrogen or methyl, ##STR4## wherein X represents halogen, methyl or methoxy and each of Y and Z, independently, represents cyano, nitro, methylaminocarbonyl, C.sub.1-4 -alkylcarbonyl or C.sub.1-4 -alkoxycarbonyl, the combination of these substituents being such that the dye has a magenta shade, ##STR5## wherein R.sup.7 represents C.sub.1-4 -alkyl optionally substituted by halogen, cyano, C.sub.1-4 -alkylcarbonyl or C.sub.1-4 -alkoxycarbonyl, andn represents 0, 1 or 2.

30. 发明授权

US4217271A Basic azo dyestuffs containing a n-picolinium alkylene amino phenyl group 失效
标题翻译：碱性偶氮染料含有n-吡啶鎓亚烷基氨基苯基
公开(公告)号：US4217271A
公开(公告)日：1980-08-12
申请号：US891384
申请日：1978-03-29
申请人： Peter Gregory , Edwin D. Harvey
发明人： Peter Gregory , Edwin D. Harvey
IPC分类号： C09B29/08 , C09B43/00 , C09B44/04 , D06P1/08 , D06P1/16 , D06P5/28 , C09B29/36
CPC分类号： D06P5/006 , C09B44/04 , D06P1/08
摘要： Basic azo dyestuffs devoid of sulphonic acid and carboxylic acid groups and of the formula ##STR1## wherein A is an optionally substituted aromatic carboxylic or heterocyclic radical, R is an optionally substituted lower alkyl, aralkyl or cycloalkyl radical, Y is an optionally substituted alkylene radical of 1 to 4 carbon atoms, Z.sup..sym. is a 3- or 4-methylpyridinium group, X is an anion and the ring B may be further substituted, useful for dyeing synthetic polymeric materials especially polymers and copolymers of acrylonitrile.
摘要翻译：碱性偶氮染料不含磺酸和羧酸基团，其结构式为：其中A为任选取代的芳族羧酸或杂环基，R为任选取代的低级烷基，芳烷基或环烷基，Y为任选取代的亚烷基 1〜4个碳原子，Z（+）为3-或4-甲基吡啶基，X为阴离子，环B可进一步取代，可用于染色合成聚合物，特别是丙烯腈的聚合物和共聚物。

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