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21. 发明授权

US5143979A Molding material 失效
标题翻译：模具材料
公开(公告)号：US5143979A
公开(公告)日：1992-09-01
申请号：US540727
申请日：1990-06-20
申请人： Yoshikatsu Nishi , Masayoshi Oshima , Tadao Natsuume , Teiji Kohara
发明人： Yoshikatsu Nishi , Masayoshi Oshima , Tadao Natsuume , Teiji Kohara
IPC分类号： G02B1/04 , C08F32/08 , C08G61/06 , C08G61/08 , C08J5/18 , C08L65/00 , G11B7/24 , G11B7/253 , G11B7/26
CPC分类号： C08G61/08 , G11B7/253 , G11B7/26 , G11B7/263
摘要： A molding material suitable as an optical material and an optical recording medium formed of the molding material are disclosed. The molding material comprises a hydrogenated product of a polymer formed by ring-opening polymerization of a norbornene-type monomer, the hydrogenated product having a number average molecular weight (Mn) of 20,000 to 50,000, a weight average molecular weight (Mw) of 40,000 to 80,000 and a molecular distribution (Mw/Mn) of not more than 2.5 and having a volatile content of not more than 0.3% by weight.

22. 发明授权

US5034482A Process for producing polymer by ring-opening polymerization 失效
标题翻译：通过开环聚合制备聚合物的方法
公开(公告)号：US5034482A
公开(公告)日：1991-07-23
申请号：US553849
申请日：1990-07-18
申请人： Teiji Kohara , Toshihide Murakami , Masayoshi Oshima , Tadao Natsuume
发明人： Teiji Kohara , Toshihide Murakami , Masayoshi Oshima , Tadao Natsuume
IPC分类号： C08G61/06 , C08F4/44 , C08F4/60 , C08G61/08 , G02B1/04 , G11B7/253
CPC分类号： C08G61/08
摘要： A process for producing a polymer by ring-opening polymerization of a norbornene-type monomer, which comprises starting the ring-opening polymerization in the presence of a Ziegler-type catalyst consisting essentially of an organometallic compound of a metal belonging to the groups I to III of the periodic table and titanium tetrahalide, carrying out the ring-opening polymerization until the norbornene-type monomer shows a conversion ratio of not less than 60%, and then adding a tungsten and/or molybdenum-based metathesis catalyst to the polymerization reaction system to continue the ring-opening polymerization.

23. 发明授权

US5539060A Method for hydrogenation of metathesis polymers 失效
标题翻译：复分解聚合物的氢化方法
公开(公告)号：US5539060A
公开(公告)日：1996-07-23
申请号：US542654
申请日：1995-10-13
申请人： Yasuo Tsunogae , Hideharu Mizuno , Teiji Kohara , Tadao Natsuume
发明人： Yasuo Tsunogae , Hideharu Mizuno , Teiji Kohara , Tadao Natsuume
IPC分类号： C08G61/08 , C08F8/04
CPC分类号： C08G61/08
摘要： The present invention provides a method for hydrogenating a metathesis polymer solution obtained by polymerization in the presence of a metathesis polymerization catalyst comprising (a) the catalyst component of a transition metal compound and (b) the co-catalyst component of a metal compound by bringing the above solution into contact with hydrogen, without adding an inactivating agent for the metathesis polymerization catalyst, that is, with the solution left to contain the catalyst, in the presence of a hydrogenation catalyst comprising a transition metal compound (c) and a reductive metal compound (d) and if necessary by adding an acid-binding compound. According to this method, both addition of the inactivating agent and removal of the metathesis polymerization catalyst are not necessary, and also the hydrogenation can be carried out at a lower temperature and under a lower pressure than in hydrogenation with a supported-type catalyst, so that the efficiency of production of the hydrogenated product is excellent. Besides, even if tungsten hexachloride (WCl.sub.6), etc. are used as the catalyst component, an effect of preventing a hydrogenation reactor from corrosion by a hydrogen halide, can be obtained.
摘要翻译：本发明提供一种在易位聚合催化剂存在下，通过聚合反应得到的复分解聚合物溶液的氢化方法，所述分解聚合催化剂包含（a）过渡金属化合物的催化剂组分和（b）金属化合物的助催化剂组分，在含有过渡金属化合物（c）和还原性金属（c）的氢化催化剂的存在下，将上述溶液与氢接触，而不添加用于易位聚合催化剂的灭活剂，即溶液含有催化剂化合物（d），如果需要，加入酸结合化合物。根据该方法，不需要添加灭活剂和去除复分解聚合催化剂，并且在与负载型催化剂的氢化相比，在较低的温度和低的压力下氢化可以进行，因此氢化产物的生产效率优异。此外，即使使用六氯化钨（WCl 6）等作为催化剂成分，也可以得到防止氢化反应器被卤化氢腐蚀的效果。

24. 发明授权

US5462995A Hydrogenated products of thermoplastic norbornene polymers, their production, substrates for optical elements obtained by molding them, optical elements and lenses 失效
标题翻译：热塑性降冰片烯聚合物的氢化产物，它们的生产，通过模制它们获得的光学元件的基底，光学元件和透镜
公开(公告)号：US5462995A
公开(公告)日：1995-10-31
申请号：US146101
申请日：1993-11-16
申请人： Tohru Hosaka , Hideharu Mizuno , Yuji Koushima , Teiji Kohara , Tadao Natsuume
发明人： Tohru Hosaka , Hideharu Mizuno , Yuji Koushima , Teiji Kohara , Tadao Natsuume
IPC分类号： C08F8/04 , G11B7/253 , B32B3/00 , C08F32/00
CPC分类号： G11B7/253 , C08F8/04 , Y10S428/913 , Y10S430/146
摘要： The present invention provides the hydrogenated product of a thermoplastic norbornene polymer excellent in characteristics as optical materials by reducing the residual amounts of the transition metal atoms originating from the polymerization catalyst used at the polymerization to 1 ppm or less of the hydrogenated product.Reduction of the residual amounts to below the desired level is attained by treating the reaction solution with the adsorbent during or after production of the hydrogenated product from the thermoplastic norbornene polymer.The hydrogenated product of the thermoplastic norbornene polymer thus obtained in which the residual amounts of the transition metal atoms are 1 ppm or less, has a wide utilization field, including a material for optical articles having excellent utilization characteristics such as substrates for optical elements, lenses and the like.
摘要翻译： PCT No.PCT / JP92 / 00737 371日期：1993年11月16日 102（e）日期1993年11月16日PCT提交1992年6月9日PCT公布。公开号WO92 / 22590 日本1992年12月23日。本发明通过将聚合时使用的聚合催化剂的过渡金属原子的残留量减少到1ppm以下，提供作为光学材料的特性优异的热塑性降冰片烯聚合物的氢化物，氢化产物。通过在热塑性降冰片烯聚合物制备氢化产物期间或之后用吸附剂处理反应溶液可以将残余物还原到所需水平以下。由此获得的过渡金属原子的残留量为1ppm以下的热塑性降冰片烯类聚合物的氢化物具有广泛的利用场，包括具有优异的利用特性的光学制品的材料，例如光学元件用基材，透镜等等。

25. 发明授权

US5063096A Optical disk 失效
标题翻译：光盘
公开(公告)号：US5063096A
公开(公告)日：1991-11-05
申请号：US534215
申请日：1990-06-07
申请人： Teiji Kohara , Masayoshi Oshima , Tadao Natsuume
发明人： Teiji Kohara , Masayoshi Oshima , Tadao Natsuume
IPC分类号： G11B7/24047 , G11B7/2533 , G11B7/258
CPC分类号： G02B5/0833 , Y10S428/913 , Y10S430/146 , Y10S430/165 , Y10T428/31504 , Y10T428/31678 , Y10T428/31692
摘要： There is disclosed an optical disk having an optical reflectivity of 70% or above which comprises a substrate made of a thermoplastic saturated norbornene type polymer having a glass transition temperature of 100.degree. C. or above and a light reflecting layer formed by laminating, on said substrate, a multi-layer film constituted of at least one compound selected from the group consisting of metallic oxides and metallic fluorides.
摘要翻译：公开了具有70％以上的光反射率的光盘，其包括由玻璃化转变温度为100℃以上的热塑性饱和降冰片烯类聚合物构成的基板和通过层压所述光反射层而形成的光反射层基材，由选自金属氧化物和金属氟化物中的至少一种化合物构成的多层膜。

26. 发明申请

US20130008506A1 RESIN COMPOSITION FOR ENCAPSULATING SOLAR CELL AND SOLAR MODULE 审中-公开
标题翻译：用于封装太阳能电池和太阳能模块的树脂组合物
公开(公告)号：US20130008506A1
公开(公告)日：2013-01-10
申请号：US13520715
申请日：2011-02-01
申请人： Naoki Tanahashi , Teiji Kohara
发明人： Naoki Tanahashi , Teiji Kohara
IPC分类号： C08L79/02 , C08K5/3475 , C08K5/52 , C08K5/3435 , H01L31/0203 , C08F257/02
CPC分类号： C08L53/025 , C08K5/005 , C08K5/3475 , C08K5/3492 , C08K5/523 , C09J153/025 , H01L31/0481 , Y02E10/50
摘要： A resin composition comprising a hydrogenated block copolymer which is used for a resin composition for encapsulating a solar cell is provided. The hydrogenated block copolymer can be obtained by hydrogenating 90% or more of the total unsaturated bonds of block copolymers which comprise at least two polymer blocks [A] having an aromatic vinyl compound-origin repeating unit as the main component and at least one polymer block [B] comprising a chain-type conjugated diene compound-origin repeating unit as the main component and in which the ratio (wA:wB) of the weight fraction (wA) of the total polymer blocks [A], relative to the total block copolymer, to the weight fraction (wB) of the total polymer block [B] is 20:80 to 60:40. The resin composition has a tensile elasticity (at 23° C.) of 1.0-500 MPa and is excellent in low hygroscopicity, non-hydrolyzablity, weather resistance, transparency, adhesiveness, flexibility, and adhesive properties with glass, and can be used for encapsulating a solar cell without providing special impermeable treatment. Also provided is a solar module in which a solar cell is encapsulated with the resin composition.
摘要翻译：提供一种包含用于封装太阳能电池的树脂组合物的氢化嵌段共聚物的树脂组合物。氢化嵌段共聚物可以通过将含有至少两个具有芳香族乙烯基化合物起始重复单元的聚合物嵌段[A]作为主要成分的嵌段共聚物的总不饱和键的90％以上的氢化，以及至少一种聚合物嵌段 [B]包含链型共轭二烯化合物起始重复单元作为主要成分，其中总聚合物嵌段[A]的重量分数（wA）的比（wA：wB）相对于总嵌段共聚物与总聚合物嵌段[B]的重量分数（wB）为20:80至60:40。该树脂组合物的拉伸弹性（23℃）为1.0-500MPa，并且具有优异的低吸湿性，非水解性，耐候性，透明性，粘合性，柔韧性和与玻璃的粘合性，并且可用于封装太阳能电池而不提供特殊的不渗透处理。还提供了一种太阳能组件，其中太阳能电池被树脂组合物包封。

27. 发明申请

US20100076396A1 HYDROGENATED NORBORNENE-BASED RING-OPENING POLYMERIZATION POLYMER, RESIN COMPOSITION, AND MOLDED OBJECT 审中-公开
标题翻译：基于NORBORNENE的开环聚合聚合物，树脂组合物和模塑对象
公开(公告)号：US20100076396A1
公开(公告)日：2010-03-25
申请号：US12439360
申请日：2007-08-31
申请人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： A61J1/10 , C08F132/08 , C08L55/00 , B32B27/08 , B32B1/00
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening polymerization of 2-norbornene is disclosed. The hydrogenated norbornene ring-open polymer has a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution (Mw/Mn) of 1.5 to 10.0, and a melting point of 110 to 145° C. Also disclosed is a hydrogenated norbornene ring-open polymer (hydrogenated polymer) obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. The hydrogenated ring-open polymer has a melting point of 110 to 145° C. A resin composition and a molding material containing these hydrogenated polymers, a molded article, a resin film, a resin sheet, a multilayer laminate, a packing material, a molded article for medical supplies, a blister molding sheet, a blister molded article, and a multilayer blow-molded container made of these hydrogenated polymers are also disclosed.
摘要翻译：公开了通过2-取代降冰片烯的开环聚合获得的开环聚合物的80％以上的主链碳 - 碳双键氢化得到的氢化降冰片烯开环聚合物。氢化降冰片烯开环聚合物通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为50,000〜200,000，分子量分布（Mw / Mn）为1.5〜10.0，熔点为110〜 145℃。还公开了通过将通过2-降冰片烯的开环共聚获得的开环聚合物的80％以上的碳 - 碳双键氢化得到的氢化降冰片烯开环聚合物（氢化聚合物）和含有取代基的降冰片烯单体，其中，来自2-降冰片烯的重复单元（A）相对于所有重复单元的比例为90〜99重量％，衍生自取代基的降冰片烯的重复单元（B）含有降冰片烯单体相对于所有重复单元为1〜10重量％。氢化开环聚合物的熔点为110〜145℃。树脂组合物和含有这些氢化聚合物的成型材料，模塑制品，树脂膜，树脂片，多层压板，包装材料，还公开了用于医疗用品的模制品，泡罩成型片，泡罩模制品和由这些氢化聚合物制成的多层吹塑容器。

28. 发明授权

US06630234B1 Polymeric film and film capacitor 有权
标题翻译：聚合物膜和薄膜电容器
公开(公告)号：US06630234B1
公开(公告)日：2003-10-07
申请号：US09446309
申请日：1999-12-20
申请人： Hajime Tanisho , Yuichiro Konishi , Teiji Kohara
发明人： Hajime Tanisho , Yuichiro Konishi , Teiji Kohara
IPC分类号： B32B516
CPC分类号： C08J5/18 , C08J2345/00 , C08J2365/00 , H01G4/18 , H01G4/206 , Y10T428/25 , Y10T428/252 , Y10T428/258 , Y10T428/26 , Y10T428/31 , Y10T428/31678 , Y10T428/31692 , Y10T428/31696 , Y10T428/31855 , Y10T428/31931
摘要： By using a polymeric film having a dielectric loss tangent of 0.002 or less measured at a frequency in the range of 1 kHz to 1 GHz at a temperature of 25 ° C., heat generation of dielectric loss of capacitors can be reduced and rising of temperature can be inhibited, and, can highly stand the rise of temperature, whereby further miniaturization and increase in capacity of capacitors become possible. Furthermore, the problems in handling that the films are apt to cut or become entangled at the rewinding step can be greatly improved by using polymeric films which are 1 or less in friction coefficient between the films of the same material. Accordingly, the polymeric films are excellent in performance of insulator film, namely, small in dielectric loss tangent, and, moreover, are free from the problems in handling that the films are apt to cut or become entangled at the rewinding step. Furthermore, the polymeric films are suitable for film capacitors.
摘要翻译：通过使用在25℃的温度下以1kHz〜1GHz的频率测定的介电损耗角正切为0.002以下的聚合物膜，可以降低电容器的介电损耗的发热和温度的升高可以被抑制，并且可以高度地承受温度的上升，从而可以进一步小型化和增加电容器的容量。此外，通过使用相同材料的膜之间的摩擦系数为1以下的聚合物膜，可以大大提高处理在回绕步骤中易于切割或变得缠结的问题。因此，聚合物膜的绝缘膜的性能优异，即介电损耗角正切较小，而且在回卷工序中，薄膜易于切割或缠绕的问题也不存在。此外，聚合物膜适用于薄膜电容器。

29. 发明授权

US06633722B1 Light guide plate with alicyclic resin 有权
标题翻译：带脂环树脂的导光板
公开(公告)号：US06633722B1
公开(公告)日：2003-10-14
申请号：US09674156
申请日：2000-10-27
申请人： Teiji Kohara , Yuichiro Konishi , Junko Maruyama , Koji Minami , Issei Ishimaru
发明人： Teiji Kohara , Yuichiro Konishi , Junko Maruyama , Koji Minami , Issei Ishimaru
IPC分类号： G02B610
CPC分类号： G02B6/0061 , G02B6/0001 , G02B6/0038 , G02B6/0046 , G02F1/133615
摘要： A light guide plate which is made of a polymeric resin having an alicyclic structure and has recesses for reflection formed on a light reflecting surface, the recesses being so arranged that the density of the recesses increases with the distance from a light source. Each recess is preferably a V-shaped groove each having an angle of 70° to 150° and a depth of 1 &mgr;m to 1000 &mgr;m or a groove which is long and approximately perpendicular to the direction in which light is incident at any position on the light reflection surface.
摘要翻译：一种导光板，其由具有脂环结构的聚合物树脂制成并具有形成在光反射表面上的反射凹槽，所述凹部被布置成使得凹部的密度随着距离光源的距离而增加。每个凹部优选为V形槽，每个凹槽各自具有70°至150°的角度和1μm至1000μm的深度，或者凹槽，其长度大致垂直于光入射到该位置上的任何位置的方向光反射面。

30. 发明授权

US6066380A Disc medium substrate and disc device 有权
标题翻译：盘式介质基板和光盘装置
公开(公告)号：US6066380A
公开(公告)日：2000-05-23
申请号：US51938
申请日：1998-10-13
申请人： Eiki Oyanagi , Takeshi Sasa , Yasuyuki Imai , Hiroshi Takino , Teiji Kohara , Masayoshi Oshima
发明人： Eiki Oyanagi , Takeshi Sasa , Yasuyuki Imai , Hiroshi Takino , Teiji Kohara , Masayoshi Oshima
IPC分类号： B29C70/64 , C08F32/04 , G11B5/596 , G11B5/60 , G11B5/73 , G11B5/82 , G11B5/84 , G11B21/21 , G11B23/00 , B32B3/00
CPC分类号： G11B23/0021 , B29C70/64 , C08F32/04 , G11B5/7315 , G11B5/82 , G11B5/8404 , G11B21/21 , G11B5/59633 , G11B5/6011 , Y10S428/913 , Y10T428/21
摘要： A molded thermoplastic resin disc substrate specially adapted for use with floating head type recording/reproduction apparatus is provided. The molded disc substrate has surface smoothness characteristics which are the same or better than are provided with mirror polished aluminum discs. The molded disc substrates include a floating head scanning surface wherein the maximum projection height or maximum surface irregularity is less than about 50 nm to reduce or eliminate damage to either the disc or floating head caused by unwanted collisions between them. In a preferred embodiment, the molded disc substrates are molded from a thermoplastic resin composition containing 10000 particles/gram or less of particles having a particle diameter of 0.5 .mu.m or more. In a preferred embodiment, control of particle size and content is achieved by subjecting the resin molding composition to a sequence of filtering steps using filters of decreasing mesh size.
摘要翻译： PCT No.PCT / JP97 / 02927 Sec。 371日期：1998年10月13日 102（e）日期1998年10月13日PCT 1997年8月22日PCT公布。第WO98 / 08217号公报日期1998年2月26日提供特别适用于浮头型记录/再现装置的模制热塑性树脂盘基片。模制的盘基片具有与设置有镜面抛光的铝盘相同或更好的表面平滑度特性。模制的盘基底包括浮动头扫描表面，其中最大突出高度或最大表面不规则小于约50nm，以减少或消除由它们之间的不必要的碰撞引起的盘或浮动头的损坏。在优选的实施方式中，由含有10000粒子/克以上的粒径为0.5μm以上的粒子的热塑性树脂组合物成型成型的盘基片。在优选的实施方案中，通过使用减小网眼尺寸的滤膜对树脂模塑组合物进行一系列过滤步骤来实现颗粒尺寸和含量的控制。

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